Americium(III) fluoride

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Americium(III) fluoride
Kristallstruktur Lanthanfluorid.png
Crystal structure
Names
IUPAC name
Americium(III) fluoride
Other names
Americium trifluoride
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
  • InChI=1S/Am.3FH/h;3*1H/q+3;;;/p-3 Yes check.svgY
  • F[Am](F)F
Properties
AmF3
Molar mass 300 g/mol [1]
Appearancepink, crystalline solid
Density 9.53 g/cm3 [1]
Melting point 1,393 °C (2,539 °F; 1,666 K) [1]
Structure
Rhombohedral, hR24
P3c1, No. 165 [2]
a = 0.7068 nm, c = 0.7246 nm
0.31349
6
Related compounds
Other anions
Americium(III) chloride
Americium(III) bromide
Americium(III) iodide
Other cations
Plutonium(III) fluoride
Curium(III) fluoride
Europium(III) fluoride
Americium(IV) fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Americium(III) fluoride or americium trifluoride is the chemical compound composed of americium and fluorine with the formula AmF3. It is a water soluble, pink salt.

Related Research Articles

<span class="mw-page-title-main">Americium</span> Chemical element, symbol Am and atomic number 95

Americium is a synthetic chemical element; it has symbol Am and atomic number 95. It is radioactive and a transuranic member of the actinide series in the periodic table, located under the lanthanide element europium and was thus named after the Americas by analogy.

The actinide or actinoid series encompasses at least the 14 metallic chemical elements in the 5f series, with atomic numbers from 89 to 102, actinium through nobelium. The actinide series derives its name from the first element in the series, actinium. The informal chemical symbol An is used in general discussions of actinide chemistry to refer to any actinide.

<span class="mw-page-title-main">Curium</span> Chemical element, symbol Cm and atomic number 96

Curium is a synthetic chemical element; it has symbol Cm and atomic number 96. This transuranic actinide element was named after eminent scientists Marie and Pierre Curie, both known for their research on radioactivity. Curium was first intentionally made by the team of Glenn T. Seaborg, Ralph A. James, and Albert Ghiorso in 1944, using the cyclotron at Berkeley. They bombarded the newly discovered element plutonium with alpha particles. This was then sent to the Metallurgical Laboratory at University of Chicago where a tiny sample of curium was eventually separated and identified. The discovery was kept secret until after the end of World War II. The news was released to the public in November 1947. Most curium is produced by bombarding uranium or plutonium with neutrons in nuclear reactors – one tonne of spent nuclear fuel contains ~20 grams of curium.

<span class="mw-page-title-main">Californium</span> Chemical element, symbol Cf and atomic number 98

Californium is a synthetic chemical element; it has symbol Cf and atomic number 98. The element was first synthesized in 1950 at Lawrence Berkeley National Laboratory, by bombarding curium with alpha particles. It is an actinide element, the sixth transuranium element to be synthesized, and has the second-highest atomic mass of all elements that have been produced in amounts large enough to see with the naked eye. The element was named after the university and the U.S. state of California.

Americium (95Am) is an artificial element, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no known stable isotopes. The first isotope to be synthesized was 241Am in 1944. The artificial element decays by ejecting alpha particles. Americium has an atomic number of 95. Despite 243
Am
being an order of magnitude longer lived than 241
Am
, the former is harder to obtain than the latter as more of it is present in spent nuclear fuel.

<span class="mw-page-title-main">Minor actinide</span> Category of elements in spent nuclear fuel

A minor actinide is an actinide, other than uranium or plutonium, found in spent nuclear fuel. The minor actinides include neptunium, americium, curium, berkelium, californium, einsteinium, and fermium. The most important isotopes of these elements in spent nuclear fuel are neptunium-237, americium-241, americium-243, curium-242 through -248, and californium-249 through -252.

<span class="mw-page-title-main">Americium dioxide</span> Chemical compound

Americium dioxide (AmO2) is a black compound of americium. In the solid state AmO2 adopts the fluorite, CaF2 structure. It is used as a source of alpha particles.

<span class="mw-page-title-main">Americium(III) chloride</span> Chemical compound

Americium(III) chloride or americium trichloride is the chemical compound composed of americium and chlorine with the formula AmCl3. This salt forms pink hexagonal crystals. In the solid state each americium atom has nine chlorine atoms as near neighbours, at approximately the same distance, in a tricapped trigonal prismatic configuration.

A hexafluoride is a chemical compound with the general formula QXnF6, QXnF6m−, or QXnF6m+. Many molecules fit this formula. An important hexafluoride is hexafluorosilicic acid (H2SiF6), which is a byproduct of the mining of phosphate rock. In the nuclear industry, uranium hexafluoride (UF6) is an important intermediate in the purification of this element.

Americium(III) bromide or americium tribromide is the chemical compound composed of americium and bromine with the formula AmBr3, with americium in a +3 oxidation state. The compound is a crystalline solid.

Americium(III) iodide or americium triiodide is the chemical compound, a salt composed of americium and iodine with the formula AmI3.

Americium(II) bromide or americium dibromide is the chemical compound composed of an americium cation in the +2 oxidation state and 2 bromide ions in each formula unit, with the formula AmBr2.

<span class="mw-page-title-main">Americium(III) oxide</span> Chemical compound

Americium(III) oxide or americium sesquioxide is an oxide of the element americium. It has the empirical formula Am2O3. Since all isotopes of americium are only artificially produced, americium (III) oxide has no natural occurrence. The colour depends on the crystal structure, of which there are more than one. It is soluble in acids.

<span class="mw-page-title-main">Americium(III) hydroxide</span> Chemical compound

Americium(III) hydroxide is a radioactive inorganic compound with the chemical formula Am(OH)3. It consists of one americium atom and three hydroxy groups. It was first discovered in 1944, closely related to the Manhattan Project. However, these results were confidential and were only released to the public in 1945. It was the first isolated sample of an americium compound, and the first americium compound discovered.

Americium(II) chloride, also known as dichloroamericium, is the chemical compound composed of americium and chloride with the formula AmCl2.

<span class="mw-page-title-main">Americium(III) nitrate</span> Chemical compound

Americium(III) nitrate is an inorganic compound, a salt of americium and nitric acid with the chemical formula Am(NO3)3. The compound is soluble in water and radioactive.

<span class="mw-page-title-main">Thulium(III) nitrate</span> Chemical compound

Thulium(III) nitrate is an inorganic compound, a salt of thulium and nitric acid with the chemical formula Tm(NO3)3. The compound forms dark-green crystals, readily soluble in water, also forms crystalline hydrates.

<span class="mw-page-title-main">Berkelium(III) chloride</span> Chemical compound

Berkelium(III) chloride also known as berkelium trichloride, is a chemical compound with the formula BkCl3. It is a water-soluble green salt with a melting point of 603 °C. This compound forms the hexahydrate, BkCl3·6H2O.

<span class="mw-page-title-main">Plutonium compounds</span> Chemical compounds containing the element plutonium

Plutonium compounds are compounds containing the element plutonium (Pu). At room temperature, pure plutonium is silvery in color but gains a tarnish when oxidized. The element displays four common ionic oxidation states in aqueous solution and one rare one:

Americium compounds are compounds containing the element americium (Am). These compounds can form in the +2, +3, and +4, although the +3 oxidation state is the most common. The +5, +6 and +7 oxidation states have also been reported.

References

  1. 1 2 3 Haynes, William M., ed. (2011). CRC Handbook of Chemistry and Physics (92nd ed.). Boca Raton, FL: CRC Press. p. 4.46. ISBN   1-4398-5511-0.
  2. Zachariasen, W. H. (1949). "Crystal chemical studies of the 5f-series of elements. XII. New compounds representing known structure types". Acta Crystallographica. 2 (6): 388–390. Bibcode:1949AcCry...2..388Z. doi: 10.1107/S0365110X49001016 .