Disulfur difluoride

Last updated
Disulfur difluoride
Disulfur-difluoride-2D-dimensions.png
Disulfur-difluoride-3D-balls.png
Disulfur-difluoride-3D-vdW.png
  Sulfur, S
  Fluorine, F
Names
IUPAC name
fluorosulfanyl thiohypofluorite
Other names
Difluorodisulfane [1]
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
  • InChI=1S/F2S2/c1-3-4-2
  • FSSF
Properties
S2F2
Molar mass 102.127 g/mol
Melting point −133 °C (−207 °F; 140 K)
Boiling point 15 °C (59 °F; 288 K)
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Disulfur difluoride is an inorganic compound with the chemical formula S 2 F 2. It is a halide of sulfur.

Contents

Structure

Disulfur difluoride has a chain structure F−S−S−F. The angle between the Fa−S−S and S−S−Fb planes is 87.9°, while the angles of Fa−S−S and S−S−Fb are equivalent, and are equal to 108.3°. Both S−F bonds are equivalent and their length is 163.5 pm, while the length of the S−S bond is 189 pm. This structure is referred to as gauche, and is similar to H2O2.

There is a branched isomer of disulfur difluoride, thiothionyl fluoride, with the structure S=SF2.

Synthesis

Silver(II) fluoride can fluorinate sulfur in a strictly dry container at 125 °C (257 °F; 398 K), and the reaction produces FS−SF: [2]

S8 + 8 AgF2 → 4 S2F2 + 8 AgF

Reactions

Disulfur difluoride undergoes intramolecular rearrangement in the presence of fluorides of alkali metals, yielding the isomer S=SF2: [3]

FS−SF → S=SF2
2 S2F2SF4 + 3 S
2 S2F2 + 2 H2O → SO2 + 3 S + 4 HF
S2F2 + 3 H2SO4 → 5 SO2 + 2 HF + 2 H2O
2 S2F2 + 6 NaOH → Na2SO3 + 3 S + 4 NaF + 3 H2O
2 S2F2 + 5 O2SOF4 + 3 SO3 [4] [5] [6]

Related Research Articles

<span class="mw-page-title-main">Oxygen difluoride</span> Chemical compound

Oxygen difluoride is a chemical compound with the formula OF2. As predicted by VSEPR theory, the molecule adopts a bent molecular geometry. It is a strong oxidizer and has attracted attention in rocketry for this reason. With a boiling point of −144.75 °C, OF2 is the most volatile (isolable) triatomic compound. The compound is one of many known oxygen fluorides.

<span class="mw-page-title-main">Sulfur tetrafluoride</span> Chemical compound

Sulfur tetrafluoride is the chemical compound with the formula SF4. It is a colorless corrosive gas that releases dangerous HF upon exposure to water or moisture. Despite these unwelcome characteristics, this compound is a useful reagent for the preparation of organofluorine compounds, some of which are important in the pharmaceutical and specialty chemical industries.

<span class="mw-page-title-main">Disulfur dichloride</span> Chemical compound

Disulfur dichloride is the inorganic compound of sulfur and chlorine with the formula S2Cl2. It is an amber oily liquid.

Oleg Nikolayevich Trubachyov was a Soviet and Russian linguist. A researcher of the etymology of Slavic languages and Slavic onomastics, specialist in historical linguistics and lexicographer. He was a Doctor of Sciences in Philological Sciences, an academician of the Russian Academy of Sciences and served as the editor-in-chief of the Etimologiya yearbook. His works are on the etymology of Slavic languages and on East Slavic onomastics.

<span class="mw-page-title-main">Thiazyl fluoride</span> Chemical compound

Thiazyl fluoride, NSF, is a colourless, pungent gas at room temperature and condenses to a pale yellow liquid at 0.4 °C. Along with thiazyl trifluoride, NSF3, it is an important precursor to sulfur-nitrogen-fluorine compounds. It is notable for its extreme hygroscopicity.

<span class="mw-page-title-main">Yttrium(III) phosphate</span> Chemical compound

Yttrium phosphate, YPO4, is the phosphate salt of yttrium. It occurs in nature as minerals xenotime and weinschenkite.

<span class="mw-page-title-main">Sulfur difluoride</span> Chemical compound

Sulfur difluoride is an inorganic compound with the chemical formula SF2. It can be generated by the reaction of sulfur dichloride and potassium fluoride or mercury(II) fluoride at low pressures:

<span class="mw-page-title-main">Thiophosphoryl fluoride</span> Chemical compound

Thiophosphoryl fluoride is an inorganic molecular gas with formula PSF3 containing phosphorus, sulfur and fluorine. It spontaneously ignites in air and burns with a cool flame. The discoverers were able to have flames around their hands without discomfort, and called it "probably one of the coldest flames known". The gas was discovered in 1888.

<i>Bezbozhnik</i> (magazine) Soviet llustrated magazine (1925–1941)

Bezbozhnik was an illustrated magazine, an organ of the Centre Soviet and Moscow Oblast Soviet of the League of the Militant Godless.

Nikolai Vasilyevich Rumyantsev was a Soviet author of several polemics on the history of Christianity, translator. He was also a member of the Soviet circle "Atheist" and the League of Militant Atheists. In the 1920s Rumyantsev was one of the leading proponents of the so-called mythological school in the Soviet academia. He authored such publications, as "The Pre-Christian Christ", "The Pagan Christs – the Ancient Precursors of Christianity", "The Apocalypse – The Revelation of John" and "Orthodox Holidays, Their Origin and Class Essence" (1936). "The Apocalypse – The Revelation of John" was published under the influence of Abram Ranovich. In that publication Rumyantsev, while not explicitly retracting his earlier opinions, offered a study of early Christianity which stressed not its derivation from supposed ancient mythology, but its intrinsic relation to revolutionary, messianic elements in contemporary Judaism.

The Türkmenbaşy Gulf or Türkmenbaşy Aýlagy or Türkmenbaşy Bay is a bay of the Caspian Sea in the coast of Turkmenistan.

Atheistic Dictionary is a one-volume reference work devoted to various aspects of religion and atheism. It contains more than 2,500 terms.

<span class="mw-page-title-main">Difluorodisulfanedifluoride</span> Chemical compound

1,1,1,2-tetrafluorodisulfane, also known as 1,2-difluorodisulfane 1,1-difluoride or just difluorodisulfanedifluoride (FSSF3) is an unstable molecular compound of fluorine and sulfur. The molecule has a pair of sulfur atoms, with one fluorine atom on one sulfur, and three fluorine atoms on the other. It has the uncommon property that all the bond lengths are different. The bond strength is not correlated with bond length but is inversely correlated with the force constant (Badger's rule). The molecule can be considered as sulfur tetrafluoride in which a sulfur atom is inserted into a S-F bond.

<i>Derevenskiy Bezbozhnik</i> Soviet anti-religious magazine (1928–1932)

Derevenskiy Bezbozhnik was an illustrated magazine, an organ of the Centre Soviet and Moscow Oblast Soviet of the League of the Militant Godless.

Cobalt(II) hydride is an inorganic compound with a chemical formula CoH2. It has dark grey crystals. It oxidizes slowly in air and reacts with water.

Praseodymium(III) fluoride is an inorganic compound with the formula PrF3, being the most stable fluoride of praseodymium.

<span class="mw-page-title-main">Thiothionyl fluoride</span> Chemical compound

Thiothionyl fluoride is a chemical compound of fluorine and sulfur, with the chemical formula S=SF2. It is an isomer of disulfur difluoride (difluorodisulfane) F−S−S−F.

<span class="mw-page-title-main">Ytterbium(III) acetate</span> Chemical compound

Ytterbium(III) acetate is an inorganic salt of ytterbium and acetic acid, with a chemical formula of Yb(CH3COO)3. It has colorless crystals that are soluble in water and can form hydrates.

<span class="mw-page-title-main">Gadolinium acetate</span> Chemical compound

Gadolinium acetate is the acetate salt of the lanthanide element gadolinium, with the chemical formula Gd(CH3COO)3. It is a colorless crystal that is soluble in water and can form a hydrate. Its tetrahydrate has ground state ferromagnetism.

Praseodymium bromide is an inorganic compound with the chemical formula Pr(BrO3)3. It is soluble in water and can form the dihydrate, tetrahydrate and nonahydrate. The nonahydrate melts in its own crystal water at 56.5 °C and completely loses its crystal water at 130 °C. It can be produced by the reaction of barium bromate and praseodymium sulfate.

References

  1. "Difluorodisulfane".
  2. Davis, R.Wellington; Firth, Steven (1991). "The microwave spectrum of the chain isomer of disulfur difluoride: FS-SF". Journal of Molecular Spectroscopy. 145 (2): 225. doi:10.1016/0022-2852(91)90109-N.
  3. Davis, R.Wellington (1986). "The microwave spectrum of the pyramidal isomer of disulfur difluoride: S=SF2". Journal of Molecular Spectroscopy. 116 (2): 371–383. doi:10.1016/0022-2852(86)90134-7.
  4. Справочник химика / Редкол.: Никольский Б.П. и др.. — 3-е изд., испр. — Л.: Химия, 1971. — Т. 2. — 1168 с. (in Russian)
  5. Химическая энциклопедия / Редкол.: Кнунянц И.Л. и др.. — М.: Советская энциклопедия, 1995. — Т. 4. — 639 с. — ISBN   978-5-85270-092-6 (in Russian)
  6. Лидин Р.А. и др. Химические свойства неорганических веществ: Учеб. пособие для вузов. — 3-е изд., испр. — М.: Химия, 2000. — 480 с. — ISBN   978-5-7245-1163-6 (in Russian)