Lanthanum trifluoride

Last updated
Lanthanum trifluoride
Kristallstruktur Lanthanfluorid.png
Crystal structure
Names
Other names
Lanthanum(III) fluoride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.851 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 237-252-8
PubChem CID
  • InChI=1S/La.3FH/h;3*1H/q+3;;;/p-3 Yes check.svgY
    Key: BYMUNNMMXKDFEZ-UHFFFAOYSA-K Yes check.svgY
  • InChI=1/La.3FH/h;3*1H/q+3;;;/p-3
  • F[La](F)F
Properties
LaF3
Molar mass 195.900 g/mol [1]
Appearancewhite, crystalline solid
Density 5.9 g/cm3 [1]
Melting point 1,493 °C (2,719 °F; 1,766 K) [1]
1.606
Structure
Rhombohedral, hR24
P3c1, No. 165 [2]
a = 0.7185 nm, c = 0.7351 nm
0.32865
6
Hazards
NFPA 704 (fire diamond)
[3] pg 3
NFPA 704.svgHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2
0
0
Safety data sheet (SDS) [3]
Related compounds
Other anions
Lanthanum(III) chloride
Lanthanum(III) bromide
Lanthanum(III) iodide
Other cations
Actinium(III) fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Yes check.svgY  verify  (what is  Yes check.svgYX mark.svgN ?)

Lanthanum trifluoride is a refractory ionic compound of lanthanum and fluorine. [4] The chemical formula is LaF
3
.

Contents

The LaF3 structure

Lanthanum coordination LaF3 structure.svg
Lanthanum coordination

Bonding is ionic with lanthanum highly coordinated. The cation sits at the center of a trigonal prism. Nine fluorine atoms are close: three at the bottom corners of the trigonal prism, three in the faces of the trigonal prism, and three at top corners of the trigonal prism. There are also two fluorides a little further away above and below the prism. The cation can be considered 9-coordinate or 11-coordinate. [4] At 300 K, the structure allows the formation of Schottky defects with an activation energy of 0.07 eV, and free flow of fluoride ions with an activation energy of 0.45 eV, making the crystal unusually electrically conductive. [5] [6]

The larger sized rare earth elements (lanthanides), which are those with smaller atomic number, also form trifluorides with the LaF3 structure. [4] Some actinides do as well.

Applications

This white salt is sometimes used as the "high-index" component in multilayer optical elements such as ultraviolet dichroic and narrowband mirrors. Fluorides are among the most commonly used compounds for UV optical coatings due to their relative inertness and transparency in the far ultraviolet (FUV) (100 nm < λ < 200 nm). Multilayer reflectors and antireflection coatings are typically composed of pairs of transparent materials, one with a low index of refraction, the other with a high index. LaF3 is one of very few high-index materials in the far UV. [7] The material is also a component of multimetal fluoride glasses such as ZBLAN. [8] It is also doped with europium(II) fluoride in fluoride selective electrodes. [9]

Natural occurrence

LaF3 occurs in the nature as the extremely rare mineral fluocerite-(La). [10] [11] The suffix in the name is known as the Levinson modifier and, by showing the dominant element at a particular site in the structure, is used to differentiate from similar minerals (here: fluocerite-(Ce)). [12]

Related Research Articles

<span class="mw-page-title-main">Lanthanum</span> Chemical element, symbol La and atomic number 57

Lanthanum is a chemical element; it has symbol La and atomic number 57. It is a soft, ductile, silvery-white metal that tarnishes slowly when exposed to air. It is the eponym of the lanthanide series, a group of 15 similar elements between lanthanum and lutetium in the periodic table, of which lanthanum is the first and the prototype. Lanthanum is traditionally counted among the rare earth elements. Like most other rare earth elements, the usual oxidation state is +3, although some compounds are known with oxidation state +2. Lanthanum has no biological role in humans but is essential to some bacteria. It is not particularly toxic to humans but does show some antimicrobial activity.

<span class="mw-page-title-main">Fluorite</span> Mineral form of calcium fluoride

Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon.

<span class="mw-page-title-main">Praseodymium</span> Chemical element, symbol Pr and atomic number 59

Praseodymium is a chemical element; it has symbol Pr and the atomic number 59. It is the third member of the lanthanide series and is considered one of the rare-earth metals. It is a soft, silvery, malleable and ductile metal, valued for its magnetic, electrical, chemical, and optical properties. It is too reactive to be found in native form, and pure praseodymium metal slowly develops a green oxide coating when exposed to air.

Neodymium(III) chloride or neodymium trichloride is a chemical compound of neodymium and chlorine with the formula NdCl3. This anhydrous compound is a mauve-colored solid that rapidly absorbs water on exposure to air to form a purple-colored hexahydrate, NdCl3·6H2O. Neodymium(III) chloride is produced from minerals monazite and bastnäsite using a complex multistage extraction process. The chloride has several important applications as an intermediate chemical for production of neodymium metal and neodymium-based lasers and optical fibers. Other applications include a catalyst in organic synthesis and in decomposition of waste water contamination, corrosion protection of aluminium and its alloys, and fluorescent labeling of organic molecules (DNA).

Fluocerite, also known as tysonite, is a mineral consisting of cerium and lanthanum fluorides, with the chemical formula (Ce,La)F3. The end members are classified as two different mineral types depending on the cation, fluocerite-(Ce) and fluocerite-(La), corresponding respectively to lanthanum trifluoride and cerium trifluoride. Both crystallize in the trigonal system.

<span class="mw-page-title-main">Scandium fluoride</span> Chemical compound

Scandium(III) fluoride, ScF3, is an ionic compound. This salt is slightly soluble in water but dissolves in the presence of excess fluoride to form the ScF63− anion.

<span class="mw-page-title-main">Selenium tetrafluoride</span> Chemical compound

Selenium tetrafluoride (SeF4) is an inorganic compound. It is a colourless liquid that reacts readily with water. It can be used as a fluorinating reagent in organic syntheses (fluorination of alcohols, carboxylic acids or carbonyl compounds) and has advantages over sulfur tetrafluoride in that milder conditions can be employed and it is a liquid rather than a gas.

<span class="mw-page-title-main">Phosphorus pentafluoride</span> Chemical compound

Phosphorus pentafluoride, PF5, is a phosphorus halide. It is a colourless, toxic gas that fumes in air.

A fluoride selective electrode is a type of ion selective electrode sensitive to the concentration of the fluoride ion. A common example is the lanthanum fluoride electrode.

<span class="mw-page-title-main">Bismuth trifluoride</span> Chemical compound

Bismuth(III) fluoride or bismuth trifluoride is a chemical compound of bismuth and fluorine. The chemical formula is BiF3. It is a grey-white powder melting at 649 °C.

Trifluorides are compounds in which one atom or ion has three fluorine atoms or ions associated. Many metals form trifluorides, such as iron, the rare-earth elements, and the metals in the aluminium and scandium columns of the periodic table. Most metal trifluorides are poorly soluble in water except Ferric fluoride and Indium(III) fluoride, but several are soluble in other solvents.

<span class="mw-page-title-main">Cerium(III) fluoride</span> Chemical compound

Cerium(III) fluoride (or cerium trifluoride), CeF3, is an ionic compound of the rare earth metal cerium and fluorine.

<span class="mw-page-title-main">Actinium(III) fluoride</span> Chemical compound

Actinium(III) fluoride (AcF3) is an inorganic compound, a salt of actinium and fluorine.

<span class="mw-page-title-main">Curium(III) fluoride</span> Chemical compound

Curium(III) fluoride or curium trifluoride is the chemical compound composed of curium and fluorine with the formula CmF3. It is a white, nearly insoluble salt that has the same crystal structure as LaF3. It precipitates as a hydrate when fluoride ions are added to a weakly acidic Cm(III) solution; alternatively it can be synthesized by reacting hydrofluoric acid with Cm(OH)3. The anhydrous form is then obtained by desiccation or by treatment with hydrogen fluoride gas.

<span class="mw-page-title-main">Fluorocarbonate</span> Class of chemical compounds

A carbonate fluoride, fluoride carbonate, fluorocarbonate or fluocarbonate is a double salt containing both carbonate and fluoride. The salts are usually insoluble in water, and can have more than one kind of metal cation to make more complex compounds. Rare-earth fluorocarbonates are particularly important as ore minerals for the light rare-earth elements lanthanum, cerium and neodymium. Bastnäsite is the most important source of these elements. Other artificial compounds are under investigation as non-linear optical materials and for transparency in the ultraviolet, with effects over a dozen times greater than Potassium dideuterium phosphate.

Europium(II) fluoride is an inorganic compound with a chemical formula EuF2. It was first synthesized in 1937.

Fluoride-ion batteries are rechargeable battery technology based on the shuttle of fluoride ions as ionic charge carriers.

Praseodymium compounds are compounds formed by the lanthanide metal praseodymium (Pr). In these compounds, praseodymium generally exhibits the +3 oxidation state, such as PrCl3, Pr(NO3)3 and Pr(CH3COO)3. However, compounds with praseodymium in the +2 and +4 oxidation states, and unlike other lanthanides, the +5 oxidation state, are also known.

Einsteinium compounds are compounds that contain the element einsteinium (Es). These compounds largely have einsteinium in the +3 oxidation state, or in some cases in the +2 and +4 oxidation states. Although einsteinium is relatively stable, with half-lives ranging from 20 days upwards, these compounds have not been studied in great detail.

Einsteinium fluoride is a binary inorganic chemical compound of einsteinium and fluorine with the chemical formula EsF3.

References

  1. 1 2 3 Haynes, William M., ed. (2011). CRC Handbook of Chemistry and Physics (92nd ed.). Boca Raton, FL: CRC Press. p. 4.69. ISBN   1-4398-5511-0.
  2. Zalkin, A.; Templeton, D. H. (1985). "Refinement of the trigonal crystal structure of lanthanum trifluoride with neutron diffraction data" (PDF). Acta Crystallographica Section B. 41 (2): 91. doi:10.1107/S0108768185001689.
  3. 1 2 "Safety Data Sheet: Lanthanum(III) fluoride". Thermo Fisher Scientific . 19 January 2018. Retrieved 17 August 2018.
  4. 1 2 3 Cotton, Simon (30 January 2007). Lanthanide and Actinide Chemistry. Wiley. pp. 25–27. ISBN   978-0-470-01007-5.
  5. Frant, Martin S.; Ross, James W. (23 December 1966). "Electrode for Sensing Fluoride Ion Activity in Solution" (PDF). Science. 154 (3756): 1553–1555. Bibcode:1966Sci...154.1553F. doi:10.1126/science.154.3756.1553. JSTOR   1720460. PMID   5924922. S2CID   11042445.
  6. Sher, A.; Solomon, R.; Lee, K.; Muller, M. W. (15 April 1966). "Transport Properties of La F 3". Physical Review. 144 (2): 593–604. Bibcode:1966PhRv..144..593S. doi:10.1103/PhysRev.144.593.
  7. Rodríguez-de Marcos, Luis (23 September 2015). Lequime, Michel; MacLeod, H. Angus; Ristau, Detlev (eds.). "Multilayers and optical constants of various fluorides in the far UV". Proceedings of SPIE: Advances in Optical Thin Films V. Optical Systems Design 2015: Advances in Optical Thin Films V. 9627 (B0): 96270B. Bibcode:2015SPIE.9627E..0BR. doi:10.1117/12.2191309. hdl: 10261/134764 . S2CID   138737136 . Retrieved 27 February 2019.
  8. Harrington, James A. "Infrared Fiber Optics" (PDF). Rutgers University. Archived from the original (PDF) on 9 May 2008.
  9. Light, Truman S.; Cappuccino, Carleton C. (April 1975). "Determination of fluoride in toothpaste using an ion-selective electrode". Journal of Chemical Education. 52 (4): 247–250. Bibcode:1975JChEd..52..247L. doi:10.1021/ed052p247. PMID   1133123.
  10. "Fluocerite-(La)".
  11. "List of Minerals". 21 March 2011.
  12. Burke, Ernst A.J. (2008). "Tidying up mineral names: an IMA-CNMNC scheme for suffixes, hyphens and diacrital marks". Mineralogical Record. 39 (2): 131–135. Retrieved 14 November 2020.