Lanthanum(III) iodate

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Lanthanum(III) iodate
3.svg Iodat-Ion.svg La3+.svg
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.187 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 237-621-3
PubChem CID
  • InChI=1S/3HIO3.La/c3*2-1(3)4;/h3*(H,2,3,4);/q;;;+3/p-3
    Key: BULVJAIIOVREOT-UHFFFAOYSA-K
  • [O-]I(=O)=O.[O-]I(=O)=O.[O-]I(=O)=O.[La+3]
Properties
La(IO3)3
Molar mass 663.617
Appearancecolourless crystals
1.07×10-3mol·L-1 [1]
Related compounds
Other anions
lanthanum(III) nitrate
lanthanum(III) oxide
Other cations
cerium(III) iodate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Lanthanum(III) iodate is an inorganic compound with the chemical formula La(IO3)3.

Contents

Preparation

Lanthanum(III) iodate can be obtained by reacting a La3+ salt with potassium iodate or ammonium iodate and precipitating it: [1]

La3+ + 3 IO3 → La(IO3)3

Properties

Lanthanum(III) iodate can disproportionate and decompose to a periodate when heated: [2]

10 La(IO3)3 → 2 La5(IO6)3 + 12 I2↑ + 27 O2

Related Research Articles

<span class="mw-page-title-main">Lanthanum</span> Chemical element, symbol La and atomic number 57

Lanthanum is a chemical element; it has symbol La and atomic number 57. It is a soft, ductile, silvery-white metal that tarnishes slowly when exposed to air. It is the eponym of the lanthanide series, a group of 15 similar elements between lanthanum and lutetium in the periodic table, of which lanthanum is the first and the prototype. Lanthanum is traditionally counted among the rare earth elements. Like most other rare earth elements, the usual oxidation state is +3, although some compounds are known with oxidation state +2. Lanthanum has no biological role in humans but is essential to some bacteria. It is not particularly toxic to humans but does show some antimicrobial activity.

<span class="mw-page-title-main">Iodate</span> Polyatomic anion (IO3) with charge -1

An iodate is the polyatomic anion with the formula IO−3. It is the most common form of iodine in nature, as it comprises the major iodine-containing ores. Iodate salts are often colorless. They are the salts of iodic acid.

<span class="mw-page-title-main">Periodate</span> Negatively-charged molecule made of oxygen and iodine

Periodate is an anion composed of iodine and oxygen. It is one of a number of oxyanions of iodine and is the highest in the series, with iodine existing in oxidation state +7. Unlike other perhalogenates, such as perchlorate, it can exist in two forms: metaperiodateIO
4
and orthoperiodateIO5−
6
. In this regard it is comparable to the tellurate ion from the adjacent group. It can combine with a number of counter ions to form periodates, which may also be regarded as the salts of periodic acid.

<span class="mw-page-title-main">Sodium periodate</span> Chemical compound

Sodium periodate is an inorganic salt, composed of a sodium cation and the periodate anion. It may also be regarded as the sodium salt of periodic acid. Like many periodates, it can exist in two different forms: sodium metaperiodate (formula‍ NaIO4) and sodium orthoperiodate (normally Na2H3IO6, but sometimes the fully reacted salt Na5IO6). Both salts are useful oxidising agents.

<span class="mw-page-title-main">Lanthanum oxide</span> Chemical compound

Lanthanum(III) oxide, also known as lanthana, chemical formula La2O3, is an inorganic compound containing the rare earth element lanthanum and oxygen. It is used in some ferroelectric materials, as a component of optical materials, and is a feedstock for certain catalysts, among other uses.

The Old Nassau reaction or Halloween reaction is a chemical clock reaction in which a clear solution turns orange and then black. This reaction was discovered by two undergraduate students at Princeton University researching the inhibition of the iodine clock reaction (or Landolt reaction) by Hg2+, resulting in the formation of orange HgI2. Orange and black are the school colors of Princeton University, and "Old Nassau" is a nickname for Princeton, named for its historic administration building, Nassau Hall.

<span class="mw-page-title-main">Silver iodate</span> Chemical compound

Silver iodate (AgIO3) is a light-sensitive, white crystal composed of silver, iodine and oxygen. Unlike most metal iodates, it is practically insoluble in water.

<span class="mw-page-title-main">Potassium iodate</span> Chemical compound

Potassium iodate (KIO3) is an ionic chemical compound consisting of K+ ions and IO3 ions in a 1:1 ratio.

<span class="mw-page-title-main">Sodium iodate</span> Chemical compound

Sodium iodate (NaIO3) is the sodium salt of iodic acid. Sodium iodate is an oxidizing agent. It has several uses.

<span class="mw-page-title-main">Lanthanum carbide</span> Chemical compound

Lanthanum carbide (LaC2) is a chemical compound. It is being studied in relation to the manufacture of certain types of superconductors and nanotubes.

Calcium iodate is any of two inorganic compounds with the formula Ca(IO3)2(H2O)x, where x = 0 or 1. Both are colourless salts that occur as the minerals lautarite and bruggenite, respectively. A third mineral form of calcium iodate is dietzeite, a salt containing chromate with the formula Ca2(IO3)2CrO4. These minerals are the most common compounds containing iodate.

Lead(II) iodate is an inorganic compound with the molecular formula Pb(IO3)2. It is naturally found as heavy white powder.

<span class="mw-page-title-main">Lithium iodate</span> Chemical compound

Lithium iodate (LiIO3) is a negative uniaxial crystal for nonlinear, acousto-optical and piezoelectric applications. It has been utilized for 347 nm ruby lasers.

<span class="mw-page-title-main">Barium iodate</span> Chemical compound

Barium iodate is an inorganic chemical compound with the chemical formula Ba(IO3)2. It is a white, granular substance.

Lanthanum ytterbium oxide is a solid inorganic compound of lanthanum, ytterbium and oxygen with the chemical formula of LaYbO3. This compound adopts the Perovskite structure.

The iodate fluorides are chemical compounds which contain both iodate and fluoride anions (IO3 and F). In these compounds fluorine is not bound to iodine as it is in fluoroiodates.

<span class="mw-page-title-main">Neodymium compounds</span> Chemical compounds with at least one neodymium atom

Neodymium compounds are compounds formed by the lanthanide metal neodymium (Nd). In these compounds, neodymium generally exhibits the +3 oxidation state, such as NdCl3, Nd2(SO4)3 and Nd(CH3COO)3. Compounds with neodymium in the +2 oxidation state are also known, such as NdCl2 and NdI2. Some neodymium compounds have colors that vary based upon the type of lighting.

Praseodymium compounds are compounds formed by the lanthanide metal praseodymium (Pr). In these compounds, praseodymium generally exhibits the +3 oxidation state, such as PrCl3, Pr(NO3)3 and Pr(CH3COO)3. However, compounds with praseodymium in the +2 and +4 oxidation states, and unlike other lanthanides, the +5 oxidation state, are also known.

<span class="mw-page-title-main">Lanthanum diiodide</span> Chemical compound

Lanthanum diiodide is an iodide of lanthanum, with the chemical formula of LaI2. It is an electride, actually having a chemical formula of La3+[(I)2e].

Iodate sulfates are mixed anion compounds that contain both iodate and sulfate anions. Iodate sulfates have been investigated as optical second harmonic generators, and for separation of rare earth elements. Related compounds include the iodate selenates and chromate iodates.

References

  1. 1 2 《无机化学丛书》. 第七卷 钪 稀土元素. 易宪武 等主编. 科学出版社. P184~185. 13. 卤素含氧酸盐
  2. K. Nassau, J.W. Shiever, B.E. Prescott (Jun 1975). "Transition metal iodates. VI. Preparation and characterization of the larger lanthanide iodates". Journal of Solid State Chemistry. 14 (2): 122–132. doi:10.1016/0022-4596(75)90002-X. Archived from the original on 2018-07-01. Retrieved 2020-05-29.{{cite journal}}: CS1 maint: multiple names: authors list (link)