Radium iodate

Last updated
Radium iodate
Radium iodate.svg
Names
Preferred IUPAC name
Radium iodate
Identifiers
3D model (JSmol)
  • InChI=1S/Ra.2HIO3/c;2*2-1(3)4/h;2*(H,2,3,4)/q+2;;/p-2
    Key: VAIVKVGPUBOYAD-UHFFFAOYSA-L
  • [Ra+2].[O-]I(=O)=O.[O-]I(=O)=O
Properties
I2O6Ra
Molar mass 576 g·mol−1
Appearancecolorless solid
poorly soluble
Related compounds
Related compounds
Barium iodate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Radium iodate is an inorganic compound, a salt of radium and iodic acid with the chemical formula Ra(IO3)2. [1] [2] [3]

Contents

Synthesis

Radium iodate is obtained by the reaction of a soluble radium salt and iodic acid:[ citation needed ]

RaCl2 + 2HIO3 → Ra(IO3)2 + 2HCl

Physical properties

Radium iodate forms colorless crystals. It is poorly soluble in water. [4]

Related Research Articles

<span class="mw-page-title-main">Iodine</span> Chemical element, symbol I and atomic number 53

Iodine is a chemical element; it has symbol I and atomic number 53. The heaviest of the stable halogens, it exists at standard conditions as a semi-lustrous, non-metallic solid that melts to form a deep violet liquid at 114 °C (237 °F), and boils to a violet gas at 184 °C (363 °F). The element was discovered by the French chemist Bernard Courtois in 1811 and was named two years later by Joseph Louis Gay-Lussac, after the Ancient Greek Ιώδης 'violet-coloured'.

<span class="mw-page-title-main">Radium</span> Chemical element, symbol Ra and atomic number 88

Radium is a chemical element; it has symbol Ra and atomic number 88. It is the sixth element in group 2 of the periodic table, also known as the alkaline earth metals. Pure radium is silvery-white, but it readily reacts with nitrogen (rather than oxygen) upon exposure to air, forming a black surface layer of radium nitride (Ra3N2). All isotopes of radium are radioactive, the most stable isotope being radium-226 with a half-life of 1,600 years. When radium decays, it emits ionizing radiation as a by-product, which can excite fluorescent chemicals and cause radioluminescence.

In chemistry, the common-ion effect refers to the decrease in solubility of an ionic precipitate by the addition to the solution of a soluble compound with an ion in common with the precipitate. This behaviour is a consequence of Le Chatelier's principle for the equilibrium reaction of the ionic association/dissociation. The effect is commonly seen as an effect on the solubility of salts and other weak electrolytes. Adding an additional amount of one of the ions of the salt generally leads to increased precipitation of the salt, which reduces the concentration of both ions of the salt until the solubility equilibrium is reached. The effect is based on the fact that both the original salt and the other added chemical have one ion in common with each other.

<span class="mw-page-title-main">Caesium fluoride</span> Chemical compound

Caesium fluoride or cesium fluoride is an inorganic compound with the formula CsF and it is a hygroscopic white salt. Caesium fluoride can be used in organic synthesis as a source of the fluoride anion. Caesium also has the highest electropositivity of all known elements and fluorine has the highest electronegativity of all known elements.

<span class="mw-page-title-main">Iodate</span> Polyatomic anion (IO3) with charge -1

An iodate is the polyatomic anion with the formula IO−3. It is the most common form of iodine in nature, as it comprises the major iodine-containing ores. Iodate salts are often colorless. They are the salts of iodic acid.

<span class="mw-page-title-main">Periodate</span> Negatively-charged molecule made of oxygen and iodine

Periodate is an anion composed of iodine and oxygen. It is one of a number of oxyanions of iodine and is the highest in the series, with iodine existing in oxidation state +7. Unlike other perhalogenates, such as perchlorate, it can exist in two forms: metaperiodateIO
4
and orthoperiodateIO5−
6
. In this regard it is comparable to the tellurate ion from the adjacent group. It can combine with a number of counter ions to form periodates, which may also be regarded as the salts of periodic acid.

<span class="mw-page-title-main">Iodic acid</span> Chemical compound (HIO3)

Iodic acid is a white water-soluble solid with the chemical formula HIO3. Its robustness contrasts with the instability of chloric acid and bromic acid. Iodic acid features iodine in the oxidation state +5 and is one of the most stable oxo-acids of the halogens. When heated, samples dehydrate to give iodine pentoxide. On further heating, the iodine pentoxide further decomposes, giving a mix of iodine, oxygen and lower oxides of iodine.

<span class="mw-page-title-main">Potassium iodate</span> Chemical compound

Potassium iodate (KIO3) is an ionic chemical compound consisting of K+ ions and IO3 ions in a 1:1 ratio.

<span class="mw-page-title-main">Sodium iodate</span> Chemical compound

Sodium iodate (NaIO3) is the sodium salt of iodic acid. Sodium iodate is an oxidizing agent. It has several uses.

Iodine compounds are compounds containing the element iodine. Iodine can form compounds using multiple oxidation states. Iodine is quite reactive, but it is much less reactive than the other halogens. For example, while chlorine gas will halogenate carbon monoxide, nitric oxide, and sulfur dioxide, iodine will not do so. Furthermore, iodination of metals tends to result in lower oxidation states than chlorination or bromination; for example, rhenium metal reacts with chlorine to form rhenium hexachloride, but with bromine it forms only rhenium pentabromide and iodine can achieve only rhenium tetraiodide. By the same token, however, since iodine has the lowest ionisation energy among the halogens and is the most easily oxidised of them, it has a more significant cationic chemistry and its higher oxidation states are rather more stable than those of bromine and chlorine, for example in iodine heptafluoride.

Calcium iodate is any of two inorganic compounds with the formula Ca(IO3)2(H2O)x, where x = 0 or 1. Both are colourless salts that occur as the minerals lautarite and bruggenite, respectively. A third mineral form of calcium iodate is dietzeite, a salt containing chromate with the formula Ca2(IO3)2CrO4. These minerals are the most common compounds containing iodate.

Lead(II) iodate is an inorganic compound with the molecular formula Pb(IO3)2. It is naturally found as heavy white powder.

<span class="mw-page-title-main">Lithium iodate</span> Chemical compound

Lithium iodate (LiIO3) is a negative uniaxial crystal for nonlinear, acousto-optical and piezoelectric applications. It has been utilized for 347 nm ruby lasers.

<span class="mw-page-title-main">Barium iodate</span> Chemical compound

Barium iodate is an inorganic chemical compound with the chemical formula Ba(IO3)2. It is a white, granular substance.

<span class="mw-page-title-main">Radium sulfate</span> Chemical compound

Radium sulfate (or radium sulphate) is an inorganic compound with the formula RaSO4 and an average molecular mass of 322.088 g/mol. This white salt is the least soluble of all known sulfate salts. It was formerly used in radiotherapy and smoke detectors, but this has been phased out in favor of less hazardous alternatives.

Radium carbonate is a compound of radium, carbon, and oxygen. This salt is a highly radioactive, amorphous, white powder that has potential applications in medicine. It is notable for forming disordered crystals at room temperature and for being approximately 10 times more soluble than the corresponding barium carbonate - witherite. Radium carbonate is one of a few radium compounds which has significantly different properties from corresponding barium compounds. Moreover, radium is the only alkaline-earth metal which forms disordered crystals in its carbonate phase. Even though radium carbonate has very low solubility in water, it is soluble in dilute mineral acids and concentrated ammonium carbonate.

<span class="mw-page-title-main">Tetraiodine nonoxide</span> Chemical compound

Tetraiodine nonoxide is an iodine oxide with the chemical formula I4O9.

Radium compounds are compounds containing the element radium (Ra). Due to radium's radioactivity, not many compounds have been well characterized. Solid radium compounds are white as radium ions provide no specific coloring, but they gradually turn yellow and then dark over time due to self-radiolysis from radium's alpha decay. Insoluble radium compounds coprecipitate with all barium, most strontium, and most lead compounds.

<span class="mw-page-title-main">Iodine dioxide</span> Chemical compound

Iodine dioxide is a binary inorganic compound of iodine and oxygen with the chemical formula IO
2
. This compound is one of many iodine oxides.

Radium tungstate is an inorganic compound of radium, oxygen, and tungsten with the chemical formula RaWO4. This is a salt of wolframic acid and radium.

References

  1. Haynes, William M. (22 June 2012). CRC Handbook of Chemistry and Physics, 93rd Edition. CRC Press. p. 5-197. ISBN   978-1-4398-8049-4 . Retrieved 14 June 2023.
  2. MaHam, Aihui; Ham, Bryan M. (1 October 2015). Analytical Chemistry: A Chemist and Laboratory Technician's Toolkit. John Wiley & Sons. p. 166. ISBN   978-1-119-06969-0 . Retrieved 14 June 2023.
  3. Macintyre, Jane E. (5 December 1996). Dictionary of Inorganic Compounds, Supplement 4. CRC Press. p. 484. ISBN   978-0-412-75020-5 . Retrieved 14 June 2023.
  4. Brown, Paul L.; Matyskin, Artem V.; Ekberg, Christian (1 June 2022). "The aqueous chemistry of radium". Radiochimica Acta. 110 (6–9): 505–513. doi: 10.1515/ract-2021-1141 . ISSN   2193-3405. S2CID   248301187.