Radium hydroxide

Radium hydroxide

Identifiers
CAS Number	98966-86-0  Y
3D model (JSmol)	Interactive image
ChemSpider	66737595
InChI InChI=1S/2H2O.Ra/h2*1H2;/q;;+2/p-2 Key: ARVNHJBMBBFPCP-UHFFFAOYSA-L
SMILES [Ra+2].[O-H].[O-H]
Properties
Chemical formula	H2O2Ra
Molar mass	260 g·mol−1
Appearance	colorless crystals
Solubility in water	soluble
Related compounds
Related compounds	Barium hydroxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Radium hydroxide is an inorganic compound of radium, hydrogen, and oxygen with the chemical formula Ra(OH)₂. ^[1] Stability constant of aqueous RaOH⁺ ion pair at zero ionic strength is equal to 5. ^[2]

Synthesis

• A reaction of radium metal with water:^{[ citation needed ]}

Ra + 2H₂O → Ra(HO)₂ + H₂

• The reaction of radium oxide and water can also generate radium hydroxide, and the reaction releases a lot of heat:^{[ citation needed ]}

RaO + H₂O → Ra(HO)₂

• The compound can also be prepared by reacting radium nitrate with NaOH in solution.^{[ citation needed ]}

Physical properties

Radium hydroxide forms colorless crystals that dissolve in water better than does barium hydroxide, and has more basic properties.

The compound forms a hydrate of the composition Ra(OH)₂·8H₂O. ^[3]

Radium hydroxide is a caustic, toxic, and corrosive substance. It is significantly more toxic than barium hydroxide (Ba(OH)₂) and strontium hydroxide (Sr(OH)₂).

References

1. Brown, Paul L.; Matyskin, Artem V.; Ekberg, Christian (1 June 2022). "The aqueous chemistry of radium". Radiochimica Acta. 110 (6–9): 505–513. doi: 10.1515/ract-2021-1141 . ISSN   2193-3405. S2CID   248301187.
2. Matyskin, Artem V.; Brown, Paul L.; Ekberg, Christian (2019). "Weak barium and radium hydrolysis using an ion exchange method and its uncertainty assessment" . Journal of Chemical Thermodynamics. 128: 362–371. Bibcode:2019JChTh.128..362M. doi:10.1016/j.jct.2018.08.037. S2CID   105458974.
3. Schweitzer, George K.; Pesterfield, Lester L. (14 January 2010). The Aqueous Chemistry of the Elements. Oxford University Press. p. 448. ISBN   978-0-19-974219-6 . Retrieved 8 June 2023.