Ammonium iodate

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Ammonium iodate
Ammonium cation Ammonium.svg
Ammonium cation
Iodate anion.svg
Names
IUPAC name
Ammonium iodate
Other names
Iodic acid, ammonium salt
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.252 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 236-592-4
PubChem CID
  • InChI=1S/HIO3.H3N/c2-1(3)4;/h(H,2,3,4);1H3
    Key: ZRDJERPXCFOFCP-UHFFFAOYSA-N
  • [NH4+].[O-]I(=O)=O
Properties
NH4IO3
Molar mass 192.94 g/mol
Appearancewhite crystalline powder
Density 3.309 g/cm3
Melting point decomposes at 150 °C
29.883 g/L (25 °C) [1]
-62.3·10−6 cm3/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Ammonium iodate is an inorganic salt which is sparingly soluble in cold, and moderately soluble in hot water, like all iodate salts, it is a strong oxidizer.

Contents

Ammonium Iodate Ammonium Iodate.jpg
Ammonium Iodate

Preparation

Ammonium iodate can be obtained by neutralising a solution of iodic acid with ammonia. [2]

HIO3 + NH3 → NH4IO3

Using its low solubility in water, it can also be precipitated from an iodate solution with an ammonium salt.

2 KIO3 + (NH4)2SO4 → 2 NH4IO3 + K2SO4

Unlike other iodates, ammonium iodate can't be prepared by dissolving iodine in an ammonium hydroxide solution, instead the highly explosive nitrogen triiodide is formed.

3 I2 + 5 NH3 → 3 NH4I + NH3·NI3

Chemical properties

Because ammonium iodate consists of the reducing ammonium ion and the oxidizing iodate ion, it already starts to decompose at 150 °C into nitrogen, oxygen, iodine and water.

NH4IO31/2 N2 + 1/2 O2 + 1/2I2 + 2H2O

Below 60 °C this reaction cannot sustain itself, but with catalysts like potassium dichromate or copper(II) chloride it can also combust at room temperature. [2]

Safety

Like all iodates, ammonium iodate is a strong oxidizer and should therefore be kept away from flammable materials like sulfur, phosphorus and metals powders [3]

Related Research Articles

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<span class="mw-page-title-main">Ammonium perchlorate</span> Chemical compound

Ammonium perchlorate ("AP") is an inorganic compound with the formula NH4ClO4. It is a colorless or white solid that is soluble in water. It is a powerful oxidizer. Combined with a fuel, it can be used as a rocket propellant called ammonium perchlorate composite propellant. Its instability has involved it in a number of accidents, such as the PEPCON disaster.

<span class="mw-page-title-main">Ammonium</span> Chemical compound

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<span class="mw-page-title-main">Ammonium nitrate</span> Chemical compound with formula NH4NO3

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<span class="mw-page-title-main">Sodium thiosulfate</span> Chemical compound

Sodium thiosulfate is an inorganic compound with the formula Na2S2O3·(H2O)(x) .Typically it is available as the white or colorless pentahydrate, It is a white solid that dissolves well in water. The compound is a reducing agent and a ligand, and these properties underpin its applications.

<span class="mw-page-title-main">Ammonium sulfate</span> Chemical compound

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Hydrogen iodide (HI) is a diatomic molecule and hydrogen halide. Aqueous solutions of HI are known as hydroiodic acid or hydriodic acid, a strong acid. Hydrogen iodide and hydroiodic acid are, however, different in that the former is a gas under standard conditions, whereas the other is an aqueous solution of the gas. They are interconvertible. HI is used in organic and inorganic synthesis as one of the primary sources of iodine and as a reducing agent.

<span class="mw-page-title-main">Iodic acid</span> Chemical compound (HIO3)

Iodic acid is a white water-soluble solid with the chemical formula HIO3. Its robustness contrasts with the instability of chloric acid and bromic acid. Iodic acid features iodine in the oxidation state +5 and is one of the most stable oxo-acids of the halogens. When heated, samples dehydrate to give iodine pentoxide. On further heating, the iodine pentoxide further decomposes, giving a mix of iodine, oxygen and lower oxides of iodine.

<span class="mw-page-title-main">Iodine clock reaction</span> Experiment to show chemical kinetics in action

The iodine clock reaction is a classical chemical clock demonstration experiment to display chemical kinetics in action; it was discovered by Hans Heinrich Landolt in 1886. The iodine clock reaction exists in several variations, which each involve iodine species and redox reagents in the presence of starch. Two colourless solutions are mixed and at first there is no visible reaction. After a short time delay, the liquid suddenly turns to a shade of dark blue due to the formation of a triiodide–starch complex. In some variations, the solution will repeatedly cycle from colorless to blue and back to colorless, until the reagents are depleted.

<span class="mw-page-title-main">Ammonium perrhenate</span> Chemical compound

Ammonium perrhenate (APR) is the ammonium salt of perrhenic acid, NH4ReO4. It is the most common form in which rhenium is traded. It is a white salt; soluble in ethanol and water, and mildly soluble in NH4Cl. It was first described soon after the discovery of rhenium.

<span class="mw-page-title-main">Potassium iodate</span> Chemical compound

Potassium iodate (KIO3) is an ionic inorganic compound with the formula KIO3. It is a white salt that is soluble in water.

<span class="mw-page-title-main">Sodium iodate</span> Chemical compound

Sodium iodate (NaIO3) is the sodium salt of iodic acid. Sodium iodate is an oxidizing agent. It has several uses.

Iodine compounds are compounds containing the element iodine. Iodine can form compounds using multiple oxidation states. Iodine is quite reactive, but it is much less reactive than the other halogens. For example, while chlorine gas will halogenate carbon monoxide, nitric oxide, and sulfur dioxide, iodine will not do so. Furthermore, iodination of metals tends to result in lower oxidation states than chlorination or bromination; for example, rhenium metal reacts with chlorine to form rhenium hexachloride, but with bromine it forms only rhenium pentabromide and iodine can achieve only rhenium tetraiodide. By the same token, however, since iodine has the lowest ionisation energy among the halogens and is the most easily oxidised of them, it has a more significant cationic chemistry and its higher oxidation states are rather more stable than those of bromine and chlorine, for example in iodine heptafluoride.

<span class="mw-page-title-main">Potassium thiosulfate</span> Chemical compound

Potassium thiosulfate, commonly abbreviated KTS, is an inorganic compound with the formula K2S2O3. This salt can form multiple hydrates, such as the monohydrate, dihydrate, and the pentahydrate, all of which are white or colorless solids. It is used as a fertilizer.

<span class="mw-page-title-main">Astatine compounds</span>

Astatine compounds are compounds that contain the element astatine (At). As this element is very radioactive, few compounds have been studied. Less reactive than iodine, astatine is the least reactive of the halogens. Its compounds have been synthesized in nano-scale amounts and studied as intensively as possible before their radioactive disintegration. The reactions involved have been typically tested with dilute solutions of astatine mixed with larger amounts of iodine. Acting as a carrier, the iodine ensures there is sufficient material for laboratory techniques to work. Like iodine, astatine has been shown to adopt odd-numbered oxidation states ranging from −1 to +7.

References

  1. "Eigenschaften von Ammoniumiodat - Das Periodensystem online".
  2. 1 2 "Combustion of the Inorganic Salts Ammonium Iodate And Hydroxylamine Sulfate" (PDF). Archived from the original (PDF) on 2016-10-28. Retrieved 2016-10-28.
  3. "Safety Data Sheet Ammonium iodate" (PDF). Alpha Aesar. 1 June 2012. Archived from the original (PDF) on 2016-10-29. Retrieved 2016-10-28.