Names | |
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IUPAC name diazanium; hexach loropalladium(2-) | |
Other names Ammonium hexachloropalladate(IV) | |
Identifiers | |
3D model (JSmol) | |
ChemSpider | |
ECHA InfoCard | 100.038.943 |
EC Number |
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PubChem CID | |
CompTox Dashboard (EPA) | |
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Properties | |
Cl6H8N2Pb | |
Molar mass | 456.0 g·mol−1 |
Appearance | red-brown crystals |
Density | 2.148 g/cm3 |
slightly soluble | |
Hazards | |
GHS labelling: | |
Warning | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Ammonium hexachloropalladate is an inorganic chemical compound with the chemical formula (NH4)2PdCl6. [1] [2]
Ammonium hexachloropalladate can be made by passing chlorine through a suspension of ammonium tetrachloropalladate(II) in ammonium chloride solution:
The compound is precipitated from the palladium(IV) chloride solution with adding ammonium chloride: [3]
Ammonium hexachloropalladate forms red-brown crystals [4] of cubic system, space group Fm3m, cell parameters a = 0.983 nm, Z = 4. [5]
It is slightly soluble in water.
The compound decomposes upon heating to form ammonium tetrachloropalladate(II):
Aqua regia is a mixture of nitric acid and hydrochloric acid, optimally in a molar ratio of 1:3. Aqua regia is a fuming liquid. Freshly prepared aqua regia is colorless, but it turns yellow, orange or red within seconds from the formation of nitrosyl chloride and nitrogen dioxide. It was so named by alchemists because it can dissolve noble metals like gold and platinum, though not all metals.
Zinc chloride is an inorganic chemical compound with the formula ZnCl2·nH2O, with n ranging from 0 to 4.5, forming hydrates. Zinc chloride, anhydrous and its hydrates, are colorless or white crystalline solids, and are highly soluble in water. Five hydrates of zinc chloride are known, as well as four forms of anhydrous zinc chloride.
Lead(II) chloride (PbCl2) is an inorganic compound which is a white solid under ambient conditions. It is poorly soluble in water. Lead(II) chloride is one of the most important lead-based reagents. It also occurs naturally in the form of the mineral cotunnite.
Manganese(II) chloride is the dichloride salt of manganese, MnCl2. This inorganic chemical exists in the anhydrous form, as well as the dihydrate (MnCl2·2H2O) and tetrahydrate (MnCl2·4H2O), with the tetrahydrate being the most common form. Like many Mn(II) species, these salts are pink, with the paleness of the color being characteristic of transition metal complexes with high spin d5 configurations.
Chloroplatinic acid (also known as hexachloroplatinic acid) is an inorganic compound with the formula [H3O]2[PtCl6](H2O)x (0 ≤ x ≤ 6). A red solid, it is an important commercial source of platinum, usually as an aqueous solution. Although often written in shorthand as H2PtCl6, it is the hydronium (H3O+) salt of the hexachloroplatinate anion (PtCl2−
6). Hexachloroplatinic acid is highly hygroscopic.
Platinum(II) chloride is the chemical compound PtCl2. It is an important precursor used in the preparation of other platinum compounds. It exists in two crystalline forms, but the main properties are somewhat similar: dark brown, insoluble in water, diamagnetic, and odorless.
Platinum(IV) chloride is the inorganic compound of platinum and chlorine with the empirical formula PtCl4. This brown solid features platinum in the 4+ oxidation state.
Thorium(IV) chloride describes a family of inorganic compounds with the formula ThCl4(H2O)n. Both the anhydrous and tetrahydrate (n = 4) forms are known. They are hygroscopic, water-soluble white salts.
Ammonium hexachloroplatinate, also known as ammonium chloroplatinate, is the inorganic compound with the formula (NH4)2[PtCl6]. It is a rare example of a soluble platinum(IV) salt that is not hygroscopic. It forms intensely yellow solutions in water. In the presence of 1M NH4Cl, its solubility is only 0.0028 g/100 mL.
Osmium(IV) chloride or osmium tetrachloride is the inorganic compound composed of osmium and chlorine with the empirical formula OsCl4. It exists in two polymorphs (crystalline forms). The compound is used to prepare other osmium complexes.
Technetium(IV) chloride is the inorganic compound with the formula TcCl4. It was discovered in 1957 as the first binary halide of technetium. It is the highest oxidation binary chloride of technetium that has been isolated as a solid. It is volatile at elevated temperatures and its volatility has been used for separating technetium from other metal chlorides. Colloidal solutions of technetium(IV) chloride are oxidized to form Tc(VII) ions when exposed to gamma rays.
Sodium tetrachloropalladate is an inorganic compound with the chemical formula Na2PdCl4. This salt, and the analogous alkali metal salts of the form M2PdCl4, may be prepared simply by reacting palladium(II) chloride with the appropriate alkali metal chloride in aqueous solution. Palladium(II) chloride is insoluble in water, whereas the product dissolves:
Metal halides are compounds between metals and halogens. Some, such as sodium chloride are ionic, while others are covalently bonded. A few metal halides are discrete molecules, such as uranium hexafluoride, but most adopt polymeric structures, such as palladium chloride.
Lead tetrachloride, also known as lead(IV) chloride, has the molecular formula PbCl4. It is a yellow, oily liquid which is stable below 0 °C, and decomposes at 50 °C. It has a tetrahedral configuration, with lead as the central atom. The Pb–Cl covalent bonds have been measured to be 247 pm and the bond energy is 243 kJ⋅mol−1.
Ammonium hexachloroiridate(IV) is the inorganic compound with the formula (NH4)2[IrCl6]. This dark red solid is the ammonium salt of the iridium(IV) complex [IrCl6]2−. It is a commercially important iridium compound, one of the most common complexes of iridium(IV). A related but ill-defined compound is iridium tetrachloride, which has been used interchangeably.
In chemistry, a transition metal chloride complex is a coordination complex that consists of a transition metal coordinated to one or more chloride ligand. The class of complexes is extensive.
Ammonium hexachlorostannate is an inorganic chemical compound with the chemical formula (NH4)2SnCl6.
Ammonium hexachloroplumbate is an inorganic chemical compound with the chemical formula (NH4)2PbCl6.
Ammonium hexachloroselenate is an inorganic chemical compound with the chemical formula (NH4)2SeCl6.