Ammonium hexachloropalladate

Last updated
Ammonium hexachloropalladate
Names
IUPAC name
diazanium; hexach loropalladium(2-)
Other names
Ammonium hexachloropalladate(IV)
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.038.943 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 242-854-9
PubChem CID
  • InChI=1S/6ClH.2H3N.Pd/h6*1H;2*1H3;/q;;;;;;;;+4/p-4
    Key: LOLIPEAFAJNGJM-UHFFFAOYSA-J
  • [NH4+].[NH4+].Cl[Pd-2](Cl)(Cl)(Cl)(Cl)Cl
Properties
Cl6H8N2Pb
Molar mass 456.0 g·mol−1
Appearancered-brown crystals
Density 2.148 g/cm3
slightly soluble
Hazards
GHS labelling:
GHS-pictogram-exclam.svg
Warning
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Ammonium hexachloropalladate is an inorganic chemical compound with the chemical formula (NH4)2PdCl6. [1] [2]

Contents

Synthesis

Ammonium hexachloropalladate can be made by passing chlorine through a suspension of ammonium tetrachloropalladate(II) in ammonium chloride solution:

(NH4)2[PdCl4] + Cl2 → (NH4)2[PdCl6]

The compound is precipitated from the palladium(IV) chloride solution with adding ammonium chloride: [3]

PdCl6 + 2NH4Cl → (NH4)2[PdCl6] + 2HCl

Physical properties

Ammonium hexachloropalladate forms red-brown crystals [4] of cubic system, space group Fm3m, cell parameters a = 0.983 nm, Z = 4. [5]

It is slightly soluble in water.

Chemical properties

The compound decomposes upon heating to form ammonium tetrachloropalladate(II):

(NH4)2[PdCl6] → (NH4)2[PdCl4] + Cl2

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<span class="mw-page-title-main">Chloroplatinic acid</span> Chemical compound

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6
). Hexachloroplatinic acid is highly hygroscopic.

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Sodium tetrachloropalladate is an inorganic compound with the chemical formula Na2PdCl4. This salt, and the analogous alkali metal salts of the form M2PdCl4, may be prepared simply by reacting palladium(II) chloride with the appropriate alkali metal chloride in aqueous solution. Palladium(II) chloride is insoluble in water, whereas the product dissolves:

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<span class="mw-page-title-main">Transition metal chloride complex</span> Coordination complex

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Ammonium hexachlorostannate is an inorganic chemical compound with the chemical formula (NH4)2SnCl6.

Ammonium hexachloroplumbate is an inorganic chemical compound with the chemical formula (NH4)2PbCl6.

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References

  1. "Ammonium hexachloropalladate(IV)". Sigma Aldrich . Retrieved 7 October 2024.
  2. "Ammonium Hexachloropalladate(IV)". American Elements . Retrieved 7 October 2024.
  3. Guindy, M. I. El (22 October 2013). Precious Metals 1982: Proceedings of the Sixth International Precious Metals Institute Conference, Held in Newport Beach, California, June 7 - 11, 1982. Elsevier. p. 466. ISBN   978-1-4831-8948-2 . Retrieved 7 October 2024.
  4. Lide, David R. (9 March 1995). CRC Handbook of Chemistry and Physics: A Ready-reference Book of Chemical and Physical Data. CRC Press. p. 4-41. ISBN   978-0-8493-0595-5 . Retrieved 7 October 2024.
  5. Donnay, Joseph Désiré Hubert (1973). Crystal Data: Inorganic compounds. National Bureau of Standards. p. 254. Retrieved 7 October 2024.