Names | |
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IUPAC name Ammonium 2,4,6-trinitrophenolate | |
Other names Ammonium picrate; Picratol; 2,4,6-Trinitrophenol ammonium salt; Ammonium picronitrate; Explosive D | |
Identifiers | |
3D model (JSmol) | |
ChemSpider | |
ECHA InfoCard | 100.004.582 |
EC Number |
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PubChem CID | |
UNII | |
CompTox Dashboard (EPA) | |
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Properties | |
C6H6N4O7 | |
Molar mass | 246.135 g·mol−1 |
Density | 1.719 g/cm3 [1] |
Melting point | 265 °C (509 °F; 538 K) [1] |
10 g/L (20 °C) | |
Hazards | |
GHS labelling: | |
Danger | |
H201, H315, H317, H319 | |
P210, P230, P240, P250, P261, P264, P272, P280, P302+P352, P305+P351+P338, P321, P332+P313, P333+P313, P337+P313, P362, P363, P370+P380, P372, P373, P401, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Dunnite, also known as Explosive D or systematically as ammonium picrate, is an explosive developed in 1906 by US Army Major Beverly W. Dunn, who later served as chief inspector of the Bureau of Transportation Explosives. [2] [3] Ammonium picrate is a salt formed by reacting picric acid and ammonia. It is chemically related to the more stable explosive trinitrotoluene (TNT).
Ammonium picrate was proposed for use as a component in gunpowder by Brugère and Abel as early as 1869: the former proposed to mix 54% of it with 46% of saltpetre while the latter, 60% with 40%. [4] Their compositions gave less smoke and were more energetic than black powder but neither was adopted by any military, even though in the 1890s "semi-smokeless" powder compositions featuring ammonium picrates were sold commercially in the US. [5] It also was a minor component of the Peyton powder made by the California Powder Works which was procured by the US military in the same period. [5]
It was the first explosive used in an aerial bombing operation in military history, performed by Italian pilots in Libya in 1911. [6] It was used extensively by the United States Navy during World War I. [7]
Though Dunnite was generally considered an insensitive substance, by 1911 the United States Army had abandoned its use in favor of other alternatives. [8] The Navy, however, used it in armor-piercing artillery shells and projectiles, and in coastal defense.
By the end of WWI a pound of ammonium picrate cost US government 64 cents, while TNT cost 26.5 c/lb, ammonium nitrate used in amatol only 17.5 c/'b and black powder about 25 c/lb. [9]
Dunnite typically did not detonate on striking heavy armor. Rather, the encasing shell would penetrate the armor, after which the charge would be triggered by a base fuze.
During WWII, it was gradually replaced by RDX-based Composition A-3. [10]
In 2008 caches of discarded Dunnite in remote locations were mistaken for rusty rocks at Cape Porcupine, Newfoundland and Labrador, Canada. [11] [12]
Dunnite can be used as a precursor to the highly stable explosive TATB (1,3,5-triamino-2,4,6-trinitrobenzene), by first dehydrating it to form picramide (attaching the ammonia as an amine group instead of an ion) and then further aminating it, using 1,1,1-trimethylhydrazinium iodide (TMHI) made from unsymmetrical dimethylhydrazine rocket fuel and methyl iodide. Thus, surplus materials that would have to be destroyed when no longer needed are converted into a high value explosive. [13] [14]
RDX (abbreviation of "Research Department eXplosive" or Royal Demolition eXplosive) or hexogen, among other names, is an organic compound with the formula (CH2N2O2)3. It is white, odorless, and tasteless, widely used as an explosive. Chemically, it is classified as a nitroamine alongside HMX, which is a more energetic explosive than TNT. It was used widely in World War II and remains common in military applications.
Dynamite is an explosive made of nitroglycerin, sorbents, and stabilizers. It was invented by the Swedish chemist and engineer Alfred Nobel in Geesthacht, Northern Germany, and was patented in 1867. It rapidly gained wide-scale use as a more robust alternative to the traditional black powder explosives. It allows the use of nitroglycerine's favorable explosive properties while greatly reducing its risk of accidental detonation.
An explosive is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances.
Trinitrotoluene, more commonly known as TNT (and more specifically 2,4,6-trinitrotoluene, and by its preferred IUPAC name 2-methyl-1,3,5-trinitrobenzene), is a chemical compound with the formula C6H2(NO2)3CH3. TNT is occasionally used as a reagent in chemical synthesis, but it is best known as an explosive material with convenient handling properties. The explosive yield of TNT is considered to be the standard comparative convention of bombs and asteroid impacts. In chemistry, TNT is used to generate charge transfer salts.
2,4,6-Trinitrophenylmethylnitramine or tetryl (C7H5N5O8) is an explosive compound used to make detonators and explosive booster charges.
Picric acid is an organic compound with the formula (O2N)3C6H2OH. Its IUPAC name is 2,4,6-trinitrophenol (TNP). The name "picric" comes from Greek: πικρός (pikros), meaning "bitter", due to its bitter taste. It is one of the most acidic phenols. Like other strongly nitrated organic compounds, picric acid is an explosive, which is its primary use. It has also been used as medicine (antiseptic, burn treatments) and as a dye.
Ammonium nitrate is a chemical compound with the formula NH4NO3. It is a white crystalline salt consisting of ions of ammonium and nitrate. It is highly soluble in water and hygroscopic as a solid, although it does not form hydrates. It is predominantly used in agriculture as a high-nitrogen fertilizer.
Amatol is a highly explosive material made from a mixture of TNT and ammonium nitrate. The British name originates from the words ammonium and toluene. Similar mixtures were known as Schneiderite in France. Amatol was used extensively during World War I and World War II, typically as an explosive in military weapons such as aircraft bombs, shells, depth charges, and naval mines. It was eventually replaced with alternative explosives such as Composition B, Torpex, and Tritonal.
A shell, in a military context, is a projectile whose payload contains an explosive, incendiary, or other chemical filling. Originally it was called a bombshell, but "shell" has come to be unambiguous in a military context. A shell can hold a tracer.
Tritonal is a mixture of 80% TNT and 20% aluminium powder, used in several types of ordnance such as air-dropped bombs. The aluminium increases the total heat output and hence impulse of the TNT – the length of time during which the blast wave is positive. Tritonal is approximately 18% more powerful than TNT alone.
Torpex is a secondary explosive, 50% more powerful than TNT by mass. Torpex comprises 42% RDX, 40% TNT and 18% powdered aluminium. It was used in the Second World War from late 1942, at which time some used the names Torpex and RDX interchangeably, much to the confusion of today's historical researchers. Torpex proved to be particularly useful in underwater munitions because the aluminium component had the effect of making the explosive pulse last longer, which increased the destructive power. Besides torpedoes, naval mines, and depth charges, Torpex was only used in the Upkeep, Tallboy and Grand Slam bombs as well as the drones employed in Operation Aphrodite. Torpex has long been superseded by H6 and Polymer-bonded explosive (PBX) compositions. It is therefore regarded as obsolete and Torpex is unlikely to be encountered except in old munitions or unexploded ordnance, although a notable exception to this is the Sting Ray lightweight torpedo, which as of October 2020 remains in service with the Royal Navy and several foreign militaries. The German equivalent of Torpex was Trialen.
Naval Surface Warfare Center, Indian Head Division is a United States Navy installation in Charles County, Maryland. Part of Naval Sea Systems Command (NAVSEA), it is one of ten divisions of the Naval Surface Warfare Center (WFC). Its mission is to research, develop, test, evaluate, and produce energetics.
TATB, triaminotrinitrobenzene or 2,4,6-triamino-1,3,5-trinitrobenzene is an aromatic explosive, based on the basic six-carbon benzene ring structure with three nitro functional groups (NO2) and three amine (NH2) groups attached, alternating around the ring.
A World War I explosive factory, which was to be later known as NEF Pembrey was built, by Nobel's Explosives, with British Government approval, near the village of Pembrey, Carmarthenshire, Wales. The factory was built on a site consisting of mainly sandhills and sand dunes to provide some protection against damage caused by an explosion. Its main product was TNT (Trinitrotoluene) used for shell filling. The same site was used in World War II to build another explosive factory ROF Pembrey, which also made TNT.
Minol is a military explosive developed by the Admiralty early in the Second World War to augment supplies of trinitrotoluene (TNT) and RDX, which were in short supply. The aluminium component in Minol significantly prolongs the explosive pulse, making it ideal for use in underwater naval weapons where munitions with a longer explosive pulse are more destructive than those with high brisance. Minol cannot be used in weapons fired from gun barrels because there is a risk of detonation when subjected to over 250 gs of acceleration. Initially, three Minol formulas were used. All percentages shown are by weight:
Oxygen balance is an expression that is used to indicate the degree to which an explosive can be oxidized, to determine if an explosive molecule contains enough oxygen to fully oxidize the other atoms in the explosive. For example, fully oxidized carbon forms carbon dioxide, hydrogen forms water, sulfur forms sulfur dioxide, and metals form metal oxides. A molecule is said to have a positive oxygen balance if it contains more oxygen than is needed and a negative oxygen balance if it contains less oxygen than is needed.
Explosive materials are produced in numerous physical forms for their use in mining, engineering, or military applications. The different physical forms and fabrication methods are grouped together in several use forms of explosives.
Potassium picrate, or potassium 2,4,6-trinitrophenolate, is an organic chemical, a picrate of potassium. It is a reddish yellow or green crystalline material. It is a primary explosive. Anhydrous potassium picrate forms orthorhombic crystals.
Bluebonnet Ordnance Plant was a munitions plant near McGregor, Texas, which manufactured TNT, bombs, ammonium nitrate and similar products for the American troops during World War II. BlueBonnet Ordnance Plant was one of four ordnance plants in the United States during World War II.