Ammonium sulfite

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Ammonium sulfite
Ammonium sulfite.svg
Ammonium-sulfite-3D-balls.png
Names
IUPAC name
Ammonium sulfite
Other names
Ammonium sulphite, Diammonium sulfite, Diammonium sulfonate, Sulfurous acid, Diammonium salt, Sulfurous acid, ammonium salt(1:2)
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.428 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 233-484-9
PubChem CID
UNII
UN number 3077
  • InChI=1S/2H3N.H2O3S/c;;1-4(2)3/h2*1H3;(H2,1,2,3) Yes check.svgY
    Key: PQUCIEFHOVEZAU-UHFFFAOYSA-N Yes check.svgY
  • [H][N+]([H])([H])[H].[H][N+]([H])([H])[H].O=S([O-])[O-]
  • [O-]S([O-])=O.[NH4+].[NH4+]
Properties
(NH4)2SO3
Molar mass 116.14 g/mol
Appearancecolourless [1] hygroscopic crystals [2]
Melting point 65 °C (149 °F; 338 K) decomposes [1]
35 g/100 mL [1]

32.4g/100mL at 0 degrees Celsius [3]

60.4g/100mL at 100 degrees Celsius [3]

Solubility Insoluble in acetone and alcohol [2]
1.515. [3]
Hazards
GHS labelling:
GHS-pictogram-acid.svg GHS-pictogram-exclam.svg
Danger
H314
P260, P264, P280, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P332+P313, P337+P313, P362, P363, P405, P501
NFPA 704 (fire diamond)
NFPA 704.svgHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2
0
0
Flash point Not Flammable [2]
Related compounds
Other anions
Ammonium hydroxide Ammonium thiosulfate Ammonium sulfate Ammonium bisulfate Ammonium persulfate
Other cations
Sodium sulfite
Potassium sulfite
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Yes check.svgY  verify  (what is  Yes check.svgYX mark.svgN ?)

Ammonium sulfite is the ammonium salt of sulfurous acid with the chemical formula (NH4)2SO3.

Contents

Preparation

Ammonium sulfite can be prepared by the reaction of ammonia with sulfur dioxide in aqueous solution:

2 NH3 + SO2 + H2O → (NH4)2SO3

Ammonium sulfite is produced in gas scrubbers, now obsolete, consisting of ammonium hydroxide to remove sulfur dioxide from emissions from power plants. The conversion is the basis of the Walther Process. The resulting ammonium sulfite can be air oxidized to give ammonium sulfate. [4]

Uses

Ammonium sulfite is the precursor to ammonium thiosulfate, by reaction with elemental sulfur.

Niche

For cosmetics, ammonium sulfite is used as a hair straightening agent and a hair waving agent. [5] Ammonium based hair products have been made to replace sodium hydroxide-based products due to the destructive nature of sodium hydroxide on hair.

The most common food product with ammonium sulfite is caramel coloring E150d. According to the FDA, caramel coloring contains ammonium, potassium, or sodium sulfite. [6]

Ammonium sulfite is used as a preservative for fixers in photography. When film photographs are being developed ammonium sulfite can be one of the reducing agents used to preserve the hypo (sodium thiosulfate or ammonium thiosulfate). [7]

Ammonium sulfite can also be used in the making of bricks. The bricks made using ammonium sulfite are mainly used for blast furnace linings. [8]

Ammonium sulfite can be included in lubricants for cold metal working. The lubricants are intended to reduce friction to keep heat production down and keep impurities out of the metals. [8]

Chemical properties

Ammonium sulfite is a reducing agent. [9] It emits sulfur dioxide and oxides of nitrogen upon heating to decomposition.

The specific gravity of ammonium sulfite is 1.41. [2] The refractive index of ammonium sulfite is 1.515. [3]

Related Research Articles

<span class="mw-page-title-main">Sodium carbonate</span> Chemical compound

Sodium carbonate is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield alkaline solutions in water. Historically, it was extracted from the ashes of plants grown in sodium-rich soils, and because the ashes of these sodium-rich plants were noticeably different from ashes of wood, sodium carbonate became known as "soda ash". It is produced in large quantities from sodium chloride and limestone by the Solvay process, as well as by carbonating sodium hydroxide which is made using the Chlor-alkali process.

<span class="mw-page-title-main">Sodium sulfite</span> Chemical compound

Sodium sulfite (sodium sulphite) is the inorganic compound with the chemical formula Na2SO3. A white, water-soluble solid, it is used commercially as an antioxidant and preservative. It is also suitable for the softening of lignin in the pulping and refining processes of wood and lignocellulosic materials. A heptahydrate is also known but it is less useful because of its greater susceptibility toward oxidation by air.

<span class="mw-page-title-main">Sodium thiosulfate</span> Chemical compound

Sodium thiosulfate is an inorganic compound with the formula Na2S2O3·(H2O)x. Typically it is available as the white or colorless pentahydrate, which is a white solid that dissolves well in water. The compound is a reducing agent and a ligand, and these properties underpin its applications.

In chemistry, disproportionation, sometimes called dismutation, is a redox reaction in which one compound of intermediate oxidation state converts to two compounds, one of higher and one of lower oxidation states. The reverse of disproportionation, such as when a compound in an intermediate oxidation state is formed from precursors of lower and higher oxidation states, is called comproportionation, also known as symproportionation.

<span class="mw-page-title-main">Sodium chlorite</span> Chemical compound

Sodium chlorite (NaClO2) is a chemical compound used in the manufacturing of paper and as a disinfectant.

A relaxer is a type of lotion or cream generally used by people with tight curls or very curly hair which makes hair easier to straighten by chemically "relaxing" the natural curls. The active agent is usually a strong alkali, although some formulations are based on ammonium thioglycolate or formaldehyde.

In horticulture, lime sulfur (lime sulphur in British English, see American and British English spelling differences) is mainly a mixture of calcium polysulfides and thiosulfate (plus other reaction by-products as sulfite and sulfate) formed by reacting calcium hydroxide with elemental sulfur, used in pest control. It can be prepared by boiling in water a suspension of poorly soluble calcium hydroxide (lime) and solid sulfur together with a small amount of surfactant to facilitate the dispersion of these solids in water. After elimination of residual solids (flocculation, decantation, and filtration), it is normally used as an aqueous solution, which is reddish-yellow in colour and has a distinctive offensive odor of hydrogen sulfide (H2S, rotten eggs).

<span class="mw-page-title-main">Sodium dithionite</span> Chemical compound

Sodium dithionite is a white crystalline powder with a sulfurous odor. Although it is stable in dry air, it decomposes in hot water and in acid solutions.

<span class="mw-page-title-main">Potassium metabisulfite</span> Chemical compound

Potassium metabisulfite, K2S2O5, also known as potassium pyrosulfite, is a white crystalline powder with a pungent odour. It is mainly used as an antioxidant or chemical sterilant. As a disulfite, it is chemically very similar to sodium metabisulfite, with which it is sometimes used interchangeably. Potassium metabisulfite has a monoclinic crystal structure.

<span class="mw-page-title-main">Dithionite</span> Anion

The dithionite is the oxyanion with the formula [S2O4]2−. It is commonly encountered as the salt sodium dithionite. For historical reasons, it is sometimes called hydrosulfite, but it contains no hydrogen and is not a sulfite. The dianion has a steric number of 4 and trigonal pyramidal geometry.

<span class="mw-page-title-main">Thiosulfate</span> Polyatomic ion (S2O3, charge –2)

Thiosulfate is an oxyanion of sulfur with the chemical formula S2O2−3. Thiosulfate also refers to the compounds containing this anion, which are the salts of thiosulfuric acid, such as sodium thiosulfate Na2S2O3 and ammonium thiosulfate (NH4)2S2O3. Thiosulfate salts occur naturally. It rapidly dechlorinates water and is notable for its use to halt bleaching in the paper-making industry. Thiosulfate salts are mainly used in dying in textiles and the bleaching of natural substances.

<span class="mw-page-title-main">Caramel color</span> Water soluble food coloring

Caramel color or caramel coloring is a water-soluble food coloring. It is made by heat treatment of carbohydrates (sugars), in general in the presence of acids, alkalis, or salts, in a process called caramelization. It is more fully oxidized than caramel candy, and has an odor of burnt sugar and a somewhat bitter taste. Its color ranges from pale yellow to amber to dark brown.

<span class="mw-page-title-main">Potassium bisulfite</span> Chemical compound

Potassium bisulfite (or potassium hydrogen sulfite) is a chemical mixture with the approximately correctly mentioned formula chemical formula KHSO3. Potassium bisulfite in fact is not a real compound, but a mixture of salts that dissolve in water to give solutions composed of potassium ions and bisulfite ions. It is a white solid with an odor of sulfur dioxide. Attempts to crystallize potassium bisulfite yield potassium metabisulfite, K2S2O5.

The sulfite process produces wood pulp that is almost pure cellulose fibers by treating wood chips with solutions of sulfite and bisulfite ions. These chemicals cleave the bonds between the cellulose and lignin components of the lignocellulose. A variety of sulfite/bisulfite salts are used, including sodium (Na+), calcium (Ca2+), potassium (K+), magnesium (Mg2+), and ammonium (NH4+). The lignin is converted to lignosulfonates, which are soluble and can be separated from the cellulose fibers. For the production of cellulose, the sulfite process competes with the Kraft process which produces stronger fibers and is less environmentally costly.

The Wellman–Lord process is a regenerable process to remove sulfur dioxide from flue gas without creating a throwaway sludge product.

<span class="mw-page-title-main">Sodium bisulfite</span> Chemical compound

Sodium bisulfite (or sodium bisulphite, sodium hydrogen sulfite) is a chemical mixture with the approximate chemical formula NaHSO3. Sodium bisulfite is not a real compound, but a mixture of salts that dissolve in water to give solutions composed of sodium and bisulfite ions. It appears in form of white or yellowish-white crystals with an odor of sulfur dioxide. Regardless of its ill-defined nature, sodium bisulfite is used in many different industries such as a food additive with E number E222 in the food industry, a reducing agent in the cosmetic industry, and a decomposer of residual hypochlorite used in the bleaching industry.

<span class="mw-page-title-main">Ammonium thiosulfate</span> Chemical compound

Ammonium thiosulfate is an inorganic compound with the formula [NH4]2S2O3. It is white crystalline solid with ammonia odor, readily soluble in water, slightly soluble in acetone and insoluble in ethanol and diethyl ether.

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<span class="mw-page-title-main">Potassium thiosulfate</span> Chemical compound

Potassium thiosulfate, commonly abbreviated KTS, is an inorganic compound with the formula K2S2O3. This salt can form multiple hydrates, such as the monohydrate, dihydrate, and the pentahydrate, all of which are white or colorless solids. It is used as a fertilizer.

References

  1. 1 2 3 "Chemical Entity Data Page".
  2. 1 2 3 4 "Material Safety Data Sheet: Ammonium sulfite MSDS. accessed Oct 19, 2011)". Archived from the original on October 3, 2018. Retrieved November 29, 2011.
  3. 1 2 3 4 Pubchem. "SID 167823 - PubChem".
  4. Karl-Heinz Zapp (2012). "Ammonium Compounds". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a02_243. ISBN   978-3527306732.
  5. Europe. European Commission. Health and Consumers. Cosmetics - CosIng [Cosmetics Directive (v.1)]. European Commission. Web. 26 Oct. 2011.
  6. United States. FDA. CFR - Code of Federal Regulations Title 21. Health and Human Services. 1 Apr. 2011. Web
  7. Haist, Grant Milford (1979). Modern photographic processing. New York: Wiley. ISBN   0-471-02228-4. OCLC   251467968.
  8. 1 2 O'Neil, Maryadele J. The Merck Index: an Encyclopedia of Chemicals, Drugs, and Biologicals. Whitehouse Station, NJ: Merck, 2001. 561. Print.
  9. "Ammoniumsulfit - 10196-04-0".