Barium sulfite

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Barium sulfite
Barium sulfite.svg
Names
IUPAC name
Barium sulfite
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.193 OOjs UI icon edit-ltr-progressive.svg
PubChem CID
UNII
  • InChI=1S/Ba.H2O3S/c;1-4(2)3/h;(H2,1,2,3)/q+2;/p-2 Yes check.svgY
    Key: ARSLNKYOPNUFFY-UHFFFAOYSA-L Yes check.svgY
  • InChI=1/Ba.H2O3S/c;1-4(2)3/h;(H2,1,2,3)/q+2;/p-2
    Key: ARSLNKYOPNUFFY-NUQVWONBAA
  • [Ba+2].[O-]S([O-])=O
Properties
BaSO3
Molar mass 217.391 g/mol
Appearancewhite monoclinic crystals
Density 4.44 g/cm3
Melting point decomposes
0.0011 g/100 mL
Solubility insoluble in ethanol [1]
Related compounds
Other anions
Barium sulfate
Barium fluoride
Barium chloride
Barium bromide
Barium iodide
Other cations
Calcium sulfite
Magnesium sulfite
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Barium sulfite is the inorganic compound with the chemical formula BaSO3. It is a white powder that finds few applications. It is an intermediate in the carbothermal reduction of barium sulfate to barium sulfide: [2]

BaSO4 + CO → BaSO3 + CO2

Related Research Articles

<span class="mw-page-title-main">Barium</span> Chemical element, symbol Ba and atomic number 56

Barium is a chemical element; it has symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element.

<span class="mw-page-title-main">Lead(II) sulfate</span> Chemical compound

Lead(II) sulfate (PbSO4) is a white solid, which appears white in microcrystalline form. It is also known as fast white, milk white, sulfuric acid lead salt or anglesite.

<span class="mw-page-title-main">Barium hydroxide</span> Chemical compound

Barium hydroxide is a chemical compound with the chemical formula Ba(OH)2. The monohydrate (x = 1), known as baryta or baryta-water, is one of the principal compounds of barium. This white granular monohydrate is the usual commercial form.

<span class="mw-page-title-main">Barium sulfate</span> Inorganic chemical compound

Barium sulfate (or sulphate) is the inorganic compound with the chemical formula BaSO4. It is a white crystalline solid that is odorless and insoluble in water. It occurs in nature as the mineral barite, which is the main commercial source of barium and materials prepared from it. Its opaque white appearance and its high density are exploited in its main applications.

<span class="mw-page-title-main">Barium carbonate</span> Chemical compound

Barium carbonate is the inorganic compound with the formula BaCO3. Like most alkaline earth metal carbonates, it is a white salt that is poorly soluble in water. It occurs as the mineral known as witherite. In a commercial sense, it is one of the most important barium compounds.

<span class="mw-page-title-main">Barium chloride</span> Chemical compound

Barium chloride is an inorganic compound with the formula BaCl2. It is one of the most common water-soluble salts of barium. Like most other water-soluble barium salts, it is a white powder, highly toxic, and imparts a yellow-green coloration to a flame. It is also hygroscopic, converting to the dihydrate BaCl2·2H2O, which are colourless crystals with a bitter salty taste. It has limited use in the laboratory and industry.

<span class="mw-page-title-main">Barium nitrate</span> Chemical compound

Barium nitrate is the inorganic compound with the chemical formula Ba(NO3)2. It, like most barium salts, is colorless, toxic, and water-soluble. It burns with a green flame and is an oxidizer; the compound is commonly used in pyrotechnics.

<span class="mw-page-title-main">Barium iodide</span> Chemical compound

Barium iodide is an inorganic compound with the formula BaI2. The compound exists as an anhydrous and a hydrate (BaI2(H2O)2), both of which are white solids. When heated, hydrated barium iodide converts to the anhydrous salt. The hydrated form is freely soluble in water, ethanol, and acetone.

<span class="mw-page-title-main">Barium sulfide</span> Chemical compound

Barium sulfide is the inorganic compound with the formula BaS. BaS is the barium compound produced on the largest scale. It is an important precursor to other barium compounds including BaCO3 and the pigment lithopone, ZnS/BaSO4. Like other chalcogenides of the alkaline earth metals, BaS is a short wavelength emitter for electronic displays. It is colorless, although like many sulfides, it is commonly obtained in impure colored forms.

<span class="mw-page-title-main">Barium peroxide</span> Chemical compound

Barium peroxide is an inorganic compound with the formula BaO2. This white solid is one of the most common inorganic peroxides, and it was the first peroxide compound discovered. Being an oxidizer and giving a vivid green colour upon ignition, it finds some use in fireworks; historically, it was also used as a precursor for hydrogen peroxide.

<span class="mw-page-title-main">Tetrathionate</span>

The tetrathionate anion, S
4
O2−
6
, is a sulfur oxyanion derived from the compound tetrathionic acid, H2S4O6. Two of the sulfur atoms present in the ion are in oxidation state 0 and two are in oxidation state +5. Alternatively, the compound can be viewed as the adduct resulting from the binding of S2−
2
to SO3. Tetrathionate is one of the polythionates, a family of anions with the formula [Sn(SO3)2]2−. Its IUPAC name is 2-(dithioperoxy)disulfate, and the name of its corresponding acid is 2-(dithioperoxy)disulfuric acid. The Chemical Abstracts Service identifies tetrathionate by the CAS Number 15536-54-6.

<span class="mw-page-title-main">Potassium pyrosulfate</span> Chemical compound

Potassium pyrosulfate, or potassium disulfate, is an inorganic compound with the chemical formula K2S2O7.

<span class="mw-page-title-main">Barium bromide</span> Chemical compound

Barium bromide is the chemical compound with the formula BaBr2. It is ionic and hygroscopic in nature.

<span class="mw-page-title-main">Barium ferrate</span> Chemical compound

Barium ferrate is the chemical compound of formula BaFeO4. This is a rare compound containing iron in the +6 oxidation state. The ferrate(VI) ion has two unpaired electrons, making it paramagnetic. It is isostructural with BaSO4, and contains the tetrahedral [FeO4]2− anion.

<span class="mw-page-title-main">Dithionic acid</span> Chemical compound

Dithionic acid, H2S2O6, is a chemical compound known only in solution.

<span class="mw-page-title-main">Barium manganate</span> Chemical compound

Barium manganate is an inorganic compound with the formula BaMnO4. It is used as an oxidant in organic chemistry. It belongs to a class of compounds known as manganates in which the manganese resides in a +6 oxidation state. Manganate should not be confused with permanganate which contains manganese(VII). Barium manganate is a powerful oxidant, popular in organic synthesis and can be used in a wide variety of oxidation reactions.

<span class="mw-page-title-main">Barium cyanide</span> Chemical compound

Barium cyanide is a chemical compound with the formula Ba(CN)2. It is synthesized by the reaction of hydrogen cyanide and barium hydroxide in water or petroleum ether. It is a white crystalline salt.

Barium permanganate is a chemical compound, with the formula Ba(MnO4)2. It forms violet to brown crystals that are sparingly soluble in water.

Barium hydride is a chemical compound with the chemical formula BaH2.

Barium bromate is a chemical compound composed of the barium ion and the bromate ion, with the chemical formula of Ba(BrO3)2.

References

  1. Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, Florida: CRC Press, pp. 4–45, ISBN   0-8493-0594-2
  2. Kresse, Robert; Baudis, Ulrich; Jäger, Paul; Riechers, H. Hermann; Wagner, Heinz; Winkler, Jochen; Wolf, Hans Uwe (2007). "Barium and Barium Compounds". Ullmann's Encyclopedia of Industrial Chemistry . Weinheim: Wiley-VCH. doi:10.1002/14356007.a03_325.pub2. ISBN   978-3527306732.