Barium metaphosphate

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Barium metaphosphate
Barium metaphosphate.svg
Names
IUPAC name
barium(2+); dioxido(oxo)phosphanium
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.951 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 237-362-6
PubChem CID
  • InChI=1S/Ba.2HO3P/c;2*1-4(2)3/h;2*(H,1,2,3)/q+2;;/p-2
    Key: XNJIKBGDNBEQME-UHFFFAOYSA-L
  • [O-][P+](=O)[O-].[O-][P+](=O)[O-].[Ba+2]
Properties
Ba(PO3)2
Molar mass 295.27 g/mol
AppearancePowder [1]
Density 3.63 g/cm3
Melting point 1,560 [2]  °C (2,840 °F; 1,830 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Barium metaphosphate is an inorganic substance with the molecular formula Ba(PO3)2. It is a colourless solid that is insoluble in water, though is soluble in acidic solutions through "slow dissolution". [3] X-ray crystallography shows that this material is composed of Ba2+ cations attached to a polyphosphate ((PO3)n) anion. [4] A number of hydrated forms are known which are actually cyclic metaphosphates, Ba2(P4O12)·3.5H2O, Ba3(P3O9)2·6H2O.[ citation needed ]

Contents

Structure of a subunit of linear polyphosphate anion. PolyphosphateChainP4.png
Structure of a subunit of linear polyphosphate anion.

Preparation

Barium metaphosphate can be prepared by the reaction of barium carbonate with metaphosphoric acid:[ citation needed ]

BaCO3 + 2HPO3 → Ba(PO3)2 +CO2 +H2O

or alternatively by the aqueous reaction of barium chloride and sodium metaphosphate:[ citation needed ] BaCl2(aq) + 2NaPO3(aq) → Ba(PO3)2 + 2NaCl

Applications

The combination of sodium and barium polyphosphate forms a low-melting glass with a high coefficient of thermal expansion. The melting point of the glass increases with barium content. This glass makes seals with low melting metals like aluminium (melting point 650 °C). Normal borosilicate glasses soften above the melting point of aluminium. This mixture is prepared by heating a mixture of diammonium phosphate, sodium carbonate, and barium carbonate. [5]

Related Research Articles

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<span class="mw-page-title-main">Alkaline earth metal</span> Group of chemical elements

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2x
Si
y
O
2y+x
or (Na
2
O)
x
·(SiO
2
)
y
, such as sodium metasilicate Na
2
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3
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Si
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Barium chloride is an inorganic compound with the formula BaCl2. It is one of the most common water-soluble salts of barium. Like most other water-soluble barium salts, it is a white powder, highly toxic, and imparts a yellow-green coloration to a flame. It is also hygroscopic, converting to the dihydrate BaCl2·2H2O, which are colourless crystals with a bitter salty taste. It has limited use in the laboratory and industry.

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SiF
6
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References

  1. Elements, American. "Barium Metaphosphate". American Elements. Retrieved 17 April 2018.
  2. "BARIUM METAPHOSPHATE - 13762-83-9". www.chemicalbook.com. Retrieved 17 April 2018.
  3. "Barium Metaphosphate". Chemical Book. 2017. Retrieved November 27, 2017.
  4. "Form of barium metaphosphate" Grenier, Jean C.; Martin, Claude M.; Durif, Andre; Tran Qui Duc; Guitel, J. C. Bulletin de la Société Francaise de Minéralogie et de Cristallographie (1967), vol. 90, 24-31.
  5. Wilder Jr., J.A. "Glasses and glass ceramics for sealing to aluminum alloys" Journal of Non-Crystalline Solids Volume 38-39, Issue PART 2, May 1980, Pages 879-884. Hart, Patricia E.; Mesko, Melissa G.; Shelby, James E. "Crystallization and phase equilibrium in the sodium barium metaphosphate system" Journal of Non-Crystalline Solids (2000), 263&264, 305-311. doi : 10.1016/S0022-3093(99)00642-0