Barium selenate

Last updated
Barium selenate
Ba2+.svg Selenate.png
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.194 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 232-113-8
PubChem CID
UNII
UN number 2630
  • InChI=1S/Ba.H2O4Se/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+2;/p-2
    Key: ZIGAPMSTBOKWRT-UHFFFAOYSA-L
  • [O-][Se](=O)(=O)[O-].[Ba+2]
Properties
BaSeO4
Molar mass 280.29
Appearancecolourless crystals [1]
0.0118 g (20 °C)
0.0138 g (100 °C)
Hazards
GHS labelling: [2]
GHS-pictogram-skull.svg GHS-pictogram-silhouette.svg GHS-pictogram-pollu.svg
Danger
H301, H331, H373, H410
P260, P261, P264, P270, P271, P273, P301+P316, P304+P340, P316, P319, P321, P330, P391, P403+P233, P405, P501
Related compounds
Other anions
barium sulfate
Other cations
magnesium selenate
calcium selenate
strontium selenate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Barium selenate is an inorganic compound with the chemical formula BaSeO4. It is isomorphous with barium sulfate, but its solubility is 18 times that of barium sulfate, and its thermal stability is worse than that of barium sulfate. [3]

Contents

Preparation

Barium selenate can be obtained from the reaction of any soluble barium salt and sodium selenate: [1]

BaCl2 + Na2SeO4 → BaSeO4↓ + 2 NaCl

Properties

Barium selenate is a white solid that is slightly soluble in water. [4] When heated above 425 °C, the compound decomposes. Another barium selenate, barium diselenate, BaSe2O7, is also known. It has an orthorhombic baryte-type crystal structure with the space group Pnma (space group no. 62) (a = 8.993 Å, b = 5.675 Å, c = 7.349 Å). [5]

Uses

Barium selenate has been used as a "slow release" source of selenium for grazing animal feed crops and was intended to ensure selenium supply to grazing animals. In Switzerland and the EU, direct use as a feed additive is prohibited. [6] [7] Barium selenide can be obtained by reducing barium selenate in a hydrogen stream: [8]

BaSeO4 + 4 H2 → BaSe + 4 H2O

Related Research Articles

<span class="mw-page-title-main">Barium hydroxide</span> Chemical compound

Barium hydroxide is a chemical compound with the chemical formula Ba(OH)2. The monohydrate (x = 1), known as baryta or baryta-water, is one of the principal compounds of barium. This white granular monohydrate is the usual commercial form.

Selenic acid is the inorganic compound with the formula H2SeO4. It is an oxoacid of selenium, and its structure is more accurately described as O2Se(OH)2. It is a colorless compound. Although it has few uses, one of its salts, sodium selenate is used in the production of glass and animal feeds.

<span class="mw-page-title-main">Tellurate</span> Compound containing an oxyanion of tellurium

In chemistry tellurate is a compound containing an oxyanion of tellurium where tellurium has an oxidation number of +6. In the naming of inorganic compounds it is a suffix that indicates a polyatomic anion with a central tellurium atom.

Selenium trioxide is the inorganic compound with the formula SeO3. It is white, hygroscopic solid. It is also an oxidizing agent and a Lewis acid. It is of academic interest as a precursor to Se(VI) compounds.

<span class="mw-page-title-main">Sodium selenate</span> Chemical compound

Sodium selenate is the inorganic compound with the formula Na
2
SeO
4
, not to be confused with sodium selenite. It exists as the anhydrous salt, the heptahydrate, and the decahydrate. These are white, water-soluble solids. The decahydrate is a common ingredient in multivitamins and livestock feed as a source of selenium. The anhydrous salt is used in the production of some glass. Although the selenates are much more toxic, many physical properties of sodium selenate and sodium sulfate are similar.

<span class="mw-page-title-main">Praseodymium(III) sulfate</span> Chemical compound

Praseodymium(III) sulfate is a praseodymium compound with formula Pr2(SO4)3. It is an odourless whitish-green crystalline compound. The anhydrous substance readily absorbs water forming pentahydrate and octahydrate.

Barium permanganate is a chemical compound, with the formula Ba(MnO4)2. It forms violet to brown crystals that are sparingly soluble in water.

<i>Zeitschrift für Kristallographie – New Crystal Structures</i> Academic journal

Zeitschrift für Kristallographie – New Crystal Structures is a bimonthly peer-reviewed scientific journal published in English. Its first issue was published in December 1997 and bore the subtitle "International journal for structural, physical, and chemical aspects of crystalline materials." Created as a spin-off of Zeitschrift für Kristallographie for reporting novel and refined crystal structures, it began at volume 212 in order to remain aligned with the numbering of the parent journal. Paul von Groth, Professor of Mineralogy at the University of Strasbourg, established Zeitschrift für Krystallographie und Mineralogie in 1877; after several name changes, the journal adopted its present name, Zeitschrift für Kristallographie – Crystalline Materials, in 2010.

Nickel is one of the metals that can form Tutton's salts. The singly charged ion can be any of the full range of potassium, rubidium, cesium, ammonium (), or thallium. As a mineral the ammonium nickel salt, (NH4)2Ni(SO4)2 · 6 H2O, can be called nickelboussingaultite. With sodium, the double sulfate is nickelblödite Na2Ni(SO4)2 · 4 H2O from the blödite family. Nickel can be substituted by other divalent metals of similar sized to make mixtures that crystallise in the same form.

A chloride nitride is a mixed anion compound containing both chloride (Cl) and nitride ions (N3−). Another name is metallochloronitrides. They are a subclass of halide nitrides or pnictide halides.

A selenate selenite is a chemical compound or salt that contains selenite and selenate anions (SeO32- and SeO42-). These are mixed anion compounds. Some have third anions.

A tellurite tellurate is chemical compound or salt that contains tellurite and tellurate anions [TeO3]2- [TeO4 ]2-. These are mixed anion compounds, meaning the compounds are cations that contain one or more anions. Some have third anions. Environmentally, tellurite [TeO3]2- is the more abundant anion due to tellurate's [TeO4 ]2- low solubility limiting its concentration in biospheric waters. Another way to refer to the anions is tellurium's oxyanions, which happen to be relatively stable.

<span class="mw-page-title-main">Germanium tetrabromide</span> Chemical compound

Germanium tetrabromide is the inorganic compound with the formula GeBr4. It is a colorless solid that melts near room temperature. It can be formed by treating solid germanium with bromine, or by treating a germanium-copper mixture with bromine:

<span class="mw-page-title-main">Praseodymium orthoscandate</span> Chemical compound

Praseodymium orthoscandate is a chemical compound, a rare-earth oxide with a perovskite structure. It has the chemical formula of PrScO3.

<span class="mw-page-title-main">Europium(III) arsenate</span> Chemical compound

Europium(III) arsenate is an arsenate salt of europium, with the chemical formula of EuAsO4. It has good thermal stability, with its pKsp,c of 22.53±0.03. It is a colorless crystal with a xenotime structure.

<span class="mw-page-title-main">Barium selenide</span> Chemical compound

Barium selenide is an inorganic compound, with the chemical formula of BaSe. It is a white solid although typically samples are colored owing to the effects of air oxidation.

<span class="mw-page-title-main">Strontium selenide</span> Chemical compound

Strontium selenide is an inorganic compound with the chemical formula SrSe.

Nickel(II) selenate is a selenate of nickel with the chemical formula NiSeO4.

Lead(II) selenate is a selenate of lead, with the chemical formula PbSeO4.

<span class="mw-page-title-main">Trimethylsulfoxonium</span> Chemical compound

Trimethylsulfoxonium (abbreviated TMSO) is a cation with a formula (CH3)3SO+ consisting of a sulfur atom attached to three methyl groups and one oxygen atom. It has a net charge of +1.

References

  1. 1 2 Andara, A.; Salvado, M. A.; Fernández-González, Á.; García-Granda, S.; Prieto, M. (Apr 2005). "Crystal structure of barium selenate, BaSeO4". Zeitschrift für Kristallographie - New Crystal Structures. 220 (1–4): 5–6. doi:10.1524/ncrs.2005.220.14.5. ISSN   2197-4578.
  2. "Barium selenate". pubchem.ncbi.nlm.nih.gov.
  3. 无机化学丛书 第五卷 氧 硫 硒分族. 3. Selenates和碲酸盐. pp 392
  4. "GESTIS-Stoffdatenbank". gestis.dguv.de. Retrieved 2024-01-25.
  5. Andara, A.; Salvado, M. A.; Fernández-González, Á; García-Granda, S.; Prieto, M. (2005-04-01). "Crystal structure of barium selenate, BaSeO4". Zeitschrift für Kristallographie - New Crystal Structures (in German). 220 (1–4): 5–6. doi:10.1524/ncrs.2005.220.14.5. ISSN   2197-4578.
  6. "Wirkstoff: Bariumselenat - Chemie". www.vetpharm.uzh.ch. Retrieved 2024-01-25.
  7. Durchführungsverordnung (EU) 2015/446 der Kommission vom 17. März 2015 zur Änderung der Verordnung (EU) Nr. 37/2010 hinsichtlich des Stoffs "Bariumselenat" Text von Bedeutung für den EWR (in German), 2015-03-17, retrieved 2024-01-25
  8. Handbuch der präparativen anorganischen Chemie. 2 (3., umgearb. Aufl ed.). Stuttgart: Enke. 1978. ISBN   978-3-432-87813-3.