Lead(II) selenate

Lead(II) selenate

Identifiers
CAS Number	7446-15-3  Y
3D model (JSmol)	Interactive image
ChemSpider	21172687
ECHA InfoCard	100.028.363
EC Number	231-199-4
PubChem CID	53471519
UNII	61521P1U0Z
CompTox Dashboard (EPA)	DTXSID10883503
InChI InChI=1S/H2O4Se.Pb/c1-5(2,3)4;/h(H2,1,2,3,4);/q;+2/p-2 Key: PKMXSWXQNCMWNG-UHFFFAOYSA-L
SMILES [Pb+2].[O-][Se](=O)(=O)[O-]
Properties
Chemical formula	PbSeO4
Molar mass	350.16
Appearance	transparent solid [1] [2]
Density	6.37 g·cm−3 [2]
Solubility in water	130 mg/l at 25 °C [3]
Solubility	Soluble in concentrated acids [2]
Hazards
GHS labelling: [4]
Pictograms
Signal word	Warning
Hazard statements	H301, H330, H331, H360, H373, H410
Precautionary statements	P203, P260, P261, P264, P270, P271, P273, P280, P284, P301+P316, P304+P340, P316, P318, P319, P320, P321, P330, P391, P403+P233, P405, P501
Related compounds
Other anions	lead(II) sulfate lead(II) tellurate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Lead(II) selenate is a selenate of lead, with the chemical formula PbSeO₄.

Preparation

Lead(II) selenate can be obtained by reacting a mixture of lead(II,IV) oxide and selenium dioxide with hydrogen peroxide. ^[5] Lead(II) selenate is poorly soluble in water and can also be obtained through precipitation: ^[6]

Pb²⁺
+ SeO²⁻
₄ → PbSeO
_⁴↓

References

1. Effenberger, H.; Pertlik, F. (Jan 1986). "Four monazite type structures: comparison of SrCrO 4 , SrSeO 4 , PbCrO 4 (crocoite), and PbSeO 4" . Zeitschrift für Kristallographie. 176 (1–2): 75–83. Bibcode:1986ZK....176...75E. doi:10.1524/zkri.1986.176.1-2.75. ISSN   0044-2968.
2. Lead(II) selenate, 99.9% at AlfaAesar, accessed on {{{Datum}}} (PDF) (JavaScript required).^{[ dead link ]}
3. William M. Haynes (2016), [ , p. 71, at Google Books CRC Handbook of Chemistry and Physics] (93 ed.), CRC Press, p. 71, ISBN   978-1-4398-8050-0 {{citation}}: Check |url= value (help)
4. "Lead selenate". pubchem.ncbi.nlm.nih.gov.
5. Effenberger, H.; Pertlik, F. (1986-10-01). "Four monazite type structures: comparison of SrCrO₄, SrSeO₄, PbCrO₄(crocoite), and PbSeO₄" . Zeitschrift für Kristallographie - Crystalline Materials. 176 (1–2): 75–84. doi:10.1524/zkri.1986.176.12.75. ISSN   2196-7105. S2CID   101572453.
6. Selivanova, N. M.; Kapustinskii, A. F.; Zubova, G. A. (Feb 1959). "Thermochemical properties of sparingly soluble selenates and entropy of aqueous selenate ion" . Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 8 (2): 174–180. doi:10.1007/bf00917358. ISSN   0568-5230.