Identifiers | |
---|---|
3D model (JSmol) | |
ChemSpider | |
ECHA InfoCard | 100.011.284 |
EC Number |
|
PubChem CID | |
UNII | |
UN number | 2291 |
CompTox Dashboard (EPA) | |
| |
| |
Properties | |
PbC2O4 | |
Molar mass | 295.219 |
Appearance | White Powder |
Density | 5.28 g/cm3 |
Melting point | 327.4 °C (621.3 °F; 600.5 K) |
Boiling point | 1,740 °C (3,160 °F; 2,010 K) |
0.0091 g/100 ml (25 °C) | |
Thermochemistry | |
Std molar entropy (S⦵298) | 146.0216 J [1] |
Std enthalpy of formation (ΔfH⦵298) | -851.444 kJ/mol |
Hazards | |
Occupational safety and health (OHS/OSH): | |
Main hazards | Nephrotoxin, Reproductive Toxin, Neurotoxin, IARC Carcinogen, Birth Defects, Highly Toxic |
GHS labelling: | |
Danger | |
H302, H332, H360, H373, H410 | |
P201, P202, P260, P261, P264, P270, P271, P273, P281, P301+P312, P304+P312, P304+P340, P308+P313, P312, P314, P330, P391, P405, P501 | |
NIOSH (US health exposure limits): | |
PEL (Permissible) | 0.05 mg/m3, as Pb |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Lead(II) oxalate is an organic compound with the formula PbC2O4. It is naturally found as a heavy white solid. [2]
This compound is commercially available. It may be prepared by the metathesis reaction between lead(II) nitrate and sodium oxalate: [3]
A dihydrate may be formed with water solutions. But the dihydrate dehydrates in air: [4]
The trihydrate (PbC2O4•3H2O) can be made by reacting a solution of lead(II) carbonate in perchloric acid with oxalylhydroxamic acid. [5]
As well as an anhydrous form, a monohydrate (PbC2O4•H2O), [5] a dihydrate (PbC2O4•2H2O) and a trihydrate (PbC2O4•3H2O) are known. The dihydrate is from the orthorhombic crystal system, with space group Pnam (number 62), with unit cell dimensions: a = 9.053 Å b = 8.036 Å and c = 7.834 Å. The unit cell volume is 569.8 Å3 with four formula per cell, giving a density of 3.860 g/cm3 [4]
The trihydrate has triclinic crystals with space group P1 and unit cell dimensions and angles: a = 6.008 Å, b=6.671 Å, c=8.493 Å, α=74.70°, β=74.33°, and γ=80.98°. The unit cell volume is 314.41 Å3 with two formula per unit cell. Density is 3.69 g/cm3. [5]
Lead(II) oxalate is insoluble in water. Its solubility is increased in presence of excess oxalate anions, due to the formation of the Pb(C2O4)22− complex ion. [6]
Calcium oxalate (in archaic terminology, oxalate of lime) is a calcium salt of oxalic acid with the chemical formula CaC2O4 or Ca(COO)2. It forms hydrates CaC2O4·nH2O, where n varies from 1 to 3. Anhydrous and all hydrated forms are colorless or white. The monohydrate CaC2O4·H2O occurs naturally as the mineral whewellite, forming envelope-shaped crystals, known in plants as raphides. The two rarer hydrates are dihydrate CaC2O4·2H2O, which occurs naturally as the mineral weddellite, and trihydrate CaC2O4·3H2O, which occurs naturally as the mineral caoxite, are also recognized. Some foods have high quantities of calcium oxalates and can produce sores and numbing on ingestion and may even be fatal. Cultural groups with diets that depend highly on fruits and vegetables high in calcium oxalate, such as those in Micronesia, reduce the level of it by boiling and cooking them. They are a constituent in 76% of human kidney stones. Calcium oxalate is also found in beerstone, a scale that forms on containers used in breweries.
Barium chloride is an inorganic compound with the formula BaCl2. It is one of the most common water-soluble salts of barium. Like most other water-soluble barium salts, it is a white powder, highly toxic, and imparts a yellow-green coloration to a flame. It is also hygroscopic, converting to the dihydrate BaCl2·2H2O, which are colourless crystals with a bitter salty taste. It has limited use in the laboratory and industry.
Uranyl peroxide or uranium peroxide hydrate (UO4·nH2O) is a pale-yellow, soluble peroxide of uranium. It is found to be present at one stage of the enriched uranium fuel cycle and in yellowcake prepared via the in situ leaching and resin ion exchange system. This compound, also expressed as UO3·(H2O2)·(H2O), is very similar to uranium trioxide hydrate UO3·nH2O. The dissolution behaviour of both compounds are very sensitive to the hydration state (n can vary between 0 and 4). One main characteristic of uranium peroxide is that it consists of small needles with an average AMAD of about 1.1 μm.
Indium(III) sulfate (In2(SO4)3) is a sulfate salt of the metal indium. It is a sesquisulfate, meaning that the sulfate group occurs 11/2 times as much as the metal. It may be formed by the reaction of indium, its oxide, or its carbonate with sulfuric acid. An excess of strong acid is required, otherwise insoluble basic salts are formed. As a solid indium sulfate can be anhydrous, or take the form of a pentahydrate with five water molecules or a nonahydrate with nine molecules of water. Indium sulfate is used in the production of indium or indium containing substances. Indium sulfate also can be found in basic salts, acidic salts or double salts including indium alum.
Potassium ferrioxalate, also called potassium trisoxalatoferrate or potassium tris(oxalato)ferrate(III) is a chemical compound with the formula K3[Fe(C2O4)3]. It often occurs as the trihydrate K3[Fe(C2O4)3]·3H2O. Both are crystalline compounds, lime green in colour.
A dicarbonate, also known as a pyrocarbonate, is a chemical containing the divalent −O−C(=O)−O−C(=O)−O− or −C2O5− functional group, which consists of two carbonate groups sharing an oxygen atom. These compounds can be viewed as derivatives of the hypothetical compound dicarbonic acid, HO−C(=O)−O−C(=O)−OH or H2C2O5. Two important organic compounds containing this group are dimethyl dicarbonate H3C−C2O5−CH3 and di-tert-butyl dicarbonate(H3C−)3C−C2O5−C(−CH3)3.
Ferrous oxalate (iron(II) oxalate) are inorganic compound with the formula FeC2O4(H2O)x where x is 0 or 2. These are orange compounds, poorly soluble in water.
Magnesium oxalate is an organic compound comprising a magnesium cation with a 2+ charge bonded to an oxalate anion. It has the chemical formula MgC2O4. Magnesium oxalate is a white solid that comes in two forms: an anhydrous form and a dihydrate form where two water molecules are complexed with the structure. Both forms are practically insoluble in water and are insoluble in organic solutions.
Chromium(II) oxalate is an inorganic compound with the chemical formula CrC2O4.
Cerium nitrate refers to a family of nitrates of cerium in the +3 or +4 oxidation state. Often these compounds contain water, hydroxide, or hydronium ions in addition to cerium and nitrate. Double nitrates of cerium also exist.
Zirconium nitrate is a volatile anhydrous transition metal nitrate salt of zirconium with formula Zr(NO3)4. It has alternate names of zirconium tetranitrate, or zirconium(IV) nitrate.
Thorium oxalate is the inorganic compound with the formula Th(C2O4)2(H2O)4. It is a white insoluble solid prepared by the reaction of thorium(IV) salts with an oxalic acid. The material is a coordination polymer. Each Th(IV) center is bound to 10 oxygen centers: eight provided by the bridging oxalates and two by a pair of aquo ligands. Two additional water of hydration are observed in the lattice.
Potassium ferrooxalate, also known as potassium bisoxalatoferrate(II), is a salt with the formula K2Fe(C2O4)2(H2O)x. The anion is a transition metal oxalate complex, consisting of an atom of iron in the +2 oxidation state bound to oxalate (C
2O2−
4) ligands and water.
Caesium oxalate, or dicesium oxalate, or cesium oxalate is a chemical compound with the chemical formula Cs2C2O4. It is a caesium salt of oxalic acid. It consists of caesium cations Cs+ and oxalate anions C2O2−4.
The nickel organic acid salts are organic acid salts of nickel. In many of these the ionised organic acid acts as a ligand.
Yttrium oxalate is an inorganic compound, a salt of yttrium and oxalic acid with the chemical formula Y2(C2O4)3. The compound does not dissolve in water and forms crystalline hydrates—colorless crystals.
Manganese oxalate is a chemical compound, a salt of manganese and oxalic acid with the chemical formula MnC
2O
4. The compound creates light pink crystals, does not dissolve in water, and forms crystalline hydrates. It occurs naturally as the mineral Lindbergite.
Niobium(V) oxalate is the hydrogen oxalate salt of niobium(V). The neutral salt has not been prepared.
Rubidium oxalate is a chemical compound with the chemical formula Rb2C2O4. It is a rubidium salt of oxalic acid. It consists of rubidium cations Rb+ and oxalate anions C2O2−4. Rubidium oxalate forms a monohydrate Rb2C2O4·H2O.
An oxalate chloride or oxalato chloride is a mixed anion compound contains both oxalate and chloride anions.