Oxalate phosphate

Last updated
Na2Fe(C2O4)(HPO4) crystal structure Na2Fe(C2O4)(HPO4)-jpmaterabe5f9f1 hr.jpg
Na2Fe(C2O4)(HPO4) crystal structure

The oxalate phosphates are chemical compounds containing oxalate and phosphate anions. They are also called oxalatophosphates or phosphate oxalates. Some oxalate-phosphate minerals found in bat guano deposits are known. [1] Oxalate phosphates can form metal organic framework compounds.

Related compounds include the arsenate oxalates, [2] [3] and phosphite oxalates, [4] oxalatomethylphosphonate, [5] and potentially other oxalate phosphonates.

List

namechemmwcrystal systemspace groupunit cell Åvolumedensitycommentreferences
Phoxite(NH4)2Mg2(C2O4)(PO3OH)2(H2O)4monoclinicP21/ca=7.2962 b=13.5993 c=7.8334 β=108.271° Z=2738.071.98mineral biaxial(-) α = 1.499, β = 1.541 γ = 1.542; 2V = 16 [6]
Thebaite-(NH4)(NH4,K)3Al(C2O4)(PO3OH)2(H2O)monoclinicP21/ca = 11.156, b = 6.234, c = 18.65, β = 102.93°, Z=412642.093biaxial (–) α = 1.490, β = 1.534, γ = 1.570; 2V = 82.7° [7]
bis(N-methylpiperazinedi-ium) bis(bis(μ-dihydrogen phosphato)-(oxalato)-scandium) oxalate trihydrateH2mpip⋅Sc(H2PO4)2(C2O4)·0.5C2O4·1.5H2OC2a=17.1307 b=6.6277 c=16.3543 β=103.336° [8]
Davidbrownite-(NH4)(NH4), (NH4,K)5(V4+O)2(C2O4)[PO4H]3·[PO4H2]·3H2OmonoclinicP21/ca = 10.356, b = 8.923, c = 13.486, β = 92.618°, Z = 21244.92.12green–blue mineral biaxial (+) α = 1.540, β = 1.550 γ = 1.582; 2V = 58.5 [1]
(NH4)2[(VO)2(HPO4)2C2O4]·5H2O [9]
Li2(VO)2(HPO4)2(C2O4) [10]
Li2(VO)2(HPO4)2(C2O4)·6H2O535.84triclinica = 6.4133 b = 9.2173, c = 14.6206 α = 95.016°, β = 91.797°, γ = 107.7622°, and Z = 2818.382.1743 [10]
Na2[(VO)2(HPO4)2C2O4].2H2OmonoclinicP21a = 6.3534, b = 17.1614, c = 6.5632, β = 106.59sheet morphology [9] [11]
K2[(VO)2(HPO4)2(C2O4)]492.05triclinica=6.316 b=7.489 c=10.861 α=56.8° β=57.99° γ=54.20° [12]
K2[(VO)2(HPO4)2(C2O4)]·4.5H2OtriclinicP1a = 6.3953, b = 9.1451, c = 14.6208, α = 97.269°, β = 91.351° γ = 106.500° Z=2 [12]
K2.5[(VO)2(HPO4)1.5(PO4)0.5(C2O4)]MOF [13]
LiK[(VO)2(HPO4)2(C2O4)]·4.5H2O [13]
(C2H10N2)[VO(HPO4)]2(C2O4)473.96triclinicP1a = 6.3595, b = 6.6236, c = 9.224, α = 98.216o, β = 108.128o, γ = 100.672o, Z = 1354.422.225 [14]
guanidine vanadyl hydrogenphosphate oxalate(CH6N3)2[VO(HPO4)]2(C2O4)532.02triclinicP1a = 6.3825, b = 7.8877, c = 9.202, α = 66.602o, β = 71.757o, γ = 79.821o, Z = 1403.072.192 [14]
catena-(4,4'-Bipyridinium bis(μ3-hydrogen phosphato)-(μ2-oxalato)-dioxo-di-vanadium)(C10H10N2)[(VO)(HPO4)]2(C2O4)monoclinicP21/ca=9.250 b=6.338 c=16.111, β=98.08° [15]
K2MnII2(H2O)2C2O4(HPO3)2oxalophosphite [16]
TREN = tris(2-aminoethyl)amine)(H3TREN)[Mn2(HPO4)(C2O4)2.5]·3H2OtriclinicP1a = 8.8385, b = 9.0586, c = 16.020, α = 77.616°, β = 83.359°, γ = 68.251°, and Z = 2. [17]
mpip1-methylpiperazine(H2mpip)1.5•Mn3(HPO4)(H2PO4)(C2O4)2 [18]
dap=1,2-diaminopropane(H2dap)•Mn3(HPO4)(H2PO4)(C2O4)2 [18]
pa=propylamine(Hpa)•Mn3(HPO4)(H2PO4)(C2O4)2 [18]
dmp = 1,4-dimethylpiperazine(H2dmp)0.5·Mn(H2PO4)(C2O4)triclinicP1a =5.8528 b =8.1833 c =11.1334, α =103.958° β =93.550° γ =90.572° [19]
TREN = tris(2-aminoethyl)amine)(H3TREN)[Fe2(HPO4)(C2O4)2.5]·3H2OtriclinicP1a = 8.7776, b = 8.9257, c = 15.884, α = 78.630°, β = 84.018°, and γ = 67.372° Z=2 [17]
1,3-diaminopropane[C3H12N2]2[Fe5(C2O4)2(HxPO4)8]1367.31triclinicP1a=9.7851 b=9.8986 c=10.7420 α =73.790 β = 71.684 γ = 79.300 Z=1942.992.408 [20]
Na2Fe(C2O4)(HPO4)monoclinicP21/ca=6.4728, b=20.210, c=10.4712 β=90.7451369.7orange [21]
K2Fe(C2O4)(HPO4)(OH2) · H2O354.08orthorhombicPbcaa=11.880 b=10.384 c=15.337 Z=81891.92.486yellow [22]
[NH3(CH2)3NH3][Zn6(PO4)4(C2O4)]456.12triclinicP1a =5.0030 b=8.5434 c=12.4336 α=92.99 β=97.138 γ = 91.465 Z=2526.332.878 [23]
MIL-90 pentagallium sesquitrimethylenediamine difluoride dihydroxy oxalate tetraphosphateGa5(PO4)4(C2O4)F2(OH)2·1.5N2C3H12triclinicP1a = 8.1217, b = 8.9601, c = 10.4611, α = 111.930°, β = 103.655°, γ = 101.903°648.59 [24]
NTHU-62(C13H16N2) Ga10 8(PO4)(HPO4)4(OH)2(C2O4).3(H2O)2251.61monoclinicC2/ma=23.048 b=24.649 c=17.081 β = 132.192 Z=47189.82.080yellow [25]
1,3-diaminopropane[Ga2(PO4)2(H2O)(C2O4)0.5](C3N2H12)0.5(H2O) [26]
ethylene diamine[Ga2(PO4)2(C2O4)0.5](C2N2H10)0.5(H2O) [26]
1,3-diaminopropane[Ga2(PO4)2(C2O4)0.5](C3N2H12)0.5 [26]
diethylene triamine[Ga2(PO4)2(H2PO4)0.5(C2O4)0.5](C4N3H16)0.5 (H2O)1.5 [26]
diethylene triamine[Ga2.5(PO4)2.5(H2O)1.5(C2O4)0.5](C4N3H15)0.5 [26]
dmpip = 2,6-dimethyl-piperazine

catena-(bis(2,6-dimethylpiperazine-1,4-di-ium) bis(μ-hydrogen phosphato)-bis(μ-phosphato)-(μ-oxalato)-bis(hydrogen phosphato)-tetra-gallium dihydrate

[H2dmpip][Ga2(HPO4)2(PO4)(C2O4)0.5]·H2OmonoclinicP21/ca 8.904 b 28.036 c 8.173, β =100.74° [27]
catena-(2-(3-ammoniopropyl)propane-1,3-diammonium bis(μ4-phosphato)-bis(μ3-phosphato)-(μ2-oxalato)-(μ2-monohydrogen phosphato)-tetra-gallium dihydrate)[C6N3H19][Ga4(C2O4)(PO4)4(H2PO4)]·2H2OmonoclinicC2/ca =20.355 b =15.649 c =9.0517 β =105.781° [28]
Piperazinediium bis(μ2-oxalato-O,O',O'',O''')-bis(μ2-hydrogen phosphato-O,O')-diaqua-di-indium dihydrate[C4N2H12]0.5In(HPO4)(C2O4).H2OmonoclinicP21/ca =6.4726 b =11.080 c =14.311, β =100.316° [29]
Piperazinium bis(μ3-monhydrogenphosphato)-(μ2-monohydrogenphosphato)-(μ2-oxalato)-di-indium monohydrate[C4H12N2][In2(C2O4)(HPO4)3]·H2OmonoclinicP21a =6.5052 b =17.5005 c =8.1811 β =107.656 [30]
dmp = 1,4-dimethylpiperazine

bis(1,4-dimethylpiperazine-1,4-diium) bis(μ-oxalato)-tetrakis(μ-dihydrogen phosphato)-tetrakis(μ-hydrogen phosphato)-tetra-indium(iii) dihydrate

H2dmp·In2(HPO4)2(H2PO4)2(C2O4)·H2Oa 7.9684 b 11.9582 c 12.5204, α 89.946° β 84.035° γ 87.287° [19]
dmapa = 3-(dimethylamino)-1-propylamineH2dmapa·In2(HPO4)2(H2PO4)2(C2O4)·H2Oa 7.8398 b 12.0428 c 12.4877, α 90.013° β 96.335° γ 92.640° [19]
Cs2Fe(C2O4)0.5(HPO4)2 [31]
CsFe(C2O4)0.5(H2PO4)(HPO4) [31]
APPIP = 1,4-bis(3-aminopropyl)piperazine(H4APPIP)[Er3(C2O4)5.5(H2PO4)2]·5H2O [32]
APPIP = 1,4-bis(3-aminopropyl)piperazine(H4APPIP)[Tm3(C2O4)5.5(H2PO4)2]·5H2O [32]
APPIP = 1,4-bis(3-aminopropyl)piperazine(H4APPIP)[Yb3(C2O4)5.5(H2PO4)2]·5H2O [32]
APPIP = 1,4-bis(3-aminopropyl)piperazine(H4APPIP)[Lu3(C2O4)5.5(H2PO4)2]·5H2O [32]
K4[Th(HPO4)2(C2O4)2(H2O)2]•4Н2O [33]
Plutonium(IV) oxalatophosphate? [34]

Related Research Articles

<span class="mw-page-title-main">Polyoxometalate</span> Polyatomic ion made of ≥3 transition metal oxyanions bound by oxygen in a 3D structure

In chemistry, a polyoxometalate is a polyatomic ion, usually an anion, that consists of three or more transition metal oxyanions linked together by shared oxygen atoms to form closed 3-dimensional frameworks. The metal atoms are usually group 6 or less commonly group 5 transition metals and Tc in their high oxidation states. Polyoxometalates are often colorless, orange or red diamagnetic anions. Two broad families are recognized, isopolymetalates, composed of only one kind of metal and oxide, and heteropolymetalates, composed of one metal, oxide, and a main group oxyanion. Many exceptions to these general statements exist.

Aluminium phosphate is a chemical compound. In nature it occurs as the mineral berlinite. Many synthetic forms of aluminium phosphate are known. They have framework structures similar to zeolites and some are used as catalysts, ion-exchangers or molecular sieves. Commercial aluminium phosphate gel is available.

<span class="mw-page-title-main">Monofluorophosphate</span> Chemical compound

Monofluorophosphate is an anion with the formula PO3F2−, which is a phosphate group with one oxygen atom substituted with a fluoride atom. The charge of the ion is −2. The ion resembles sulfate in size, shape and charge, and can thus form compounds with the same structure as sulfates. These include Tutton's salts and langbeinites. The most well-known compound of monofluorophosphate is sodium monofluorophosphate, commonly used in toothpaste.

Vanadium phosphates are inorganic compounds with the formula VOxPO4 as well related hydrates with the formula VOxPO4(H2O)n. Some of these compounds are used commercially as catalysts for oxidation reactions.

<span class="mw-page-title-main">Caesium oxalate</span> Chemical compound

Caesium oxalate (standard IUPAC spelling) dicesium oxalate, or cesium oxalate (American spelling) is the oxalate of caesium. Caesium oxalate has the chemical formula of Cs2C2O4.

The borate carbonates are mixed anion compounds containing both borate and carbonate ions. Compared to mixed anion compounds containing halides, these are quite rare. They are hard to make, requiring higher temperatures, which are likely to decompose carbonate to carbon dioxide. The reason for the difficulty of formation is that when entering a crystal lattice, the anions have to be correctly located, and correctly oriented. They are also known as borocarbonates. Although these compounds have been termed carboborate, that word also refers to the C=B=C5− anion, or CB11H12− anion. This last anion should be called 1-carba-closo-dodecaborate or monocarba-closo-dodecaborate.

The oxynitrides are a group of inorganic compounds containing oxygen and nitrogen not bound to each other, instead combined with other non-metallic or metallic elements. Some of these are oxosalts with oxygen replaced by nitrogen. Some of these compounds do not have a fixed oxygen to nitrogen ratio, but instead form ceramics with a range of compositions. They are in the class of mixed anion compounds.

<span class="mw-page-title-main">MIL-53</span> Chemical compound

MIL-53 belongs to the class of metal-organic framework (MOF) materials. The first synthesis and the name was established by the group of Gérard Férey in 2002. The MIL-53 structure consists of inorganic [M-OH] chains, which are connected to four neighboring inorganic chains by therephthalate-based linker molecules. Each metal center is octahedrally coordinated by six oxygen atoms. Four of these oxygen atoms originate from four different carboxylate groups and the remaining two oxygen atoms belong to two different μ-OH moieties, which bridge neighboring metal centers. The resulting framework structure contains one-dimensional diamond-shaped pores. Many research group have investigated the flexibility of the MIL-53 structure. This flexible behavior, during which the pore cross-section changes reversibly, was termed 'breathing.effect' and describes the ability of the MIL-53 framework to respond to external stimuli.

<span class="mw-page-title-main">HKUST-1</span>

HKUST-1, which is also called MOF-199, is a material in the class of metal-organic frameworks (MOFs). Metal-organic frameworks are crystalline materials, in which metals are linked by ligands to form repeating coordination motives extending in three dimensions. The HKUST-1 framework is built up of dimeric metal units, which are connected by benzene-1,3,5-tricarboxylate linker molecules. The paddlewheel unit is the commonly used structural motif to describe the coordination environment of the metal centers and also called secondary building unit (SBU) of the HKUST-1 structure. The paddlewheel is built up of four benzene-1,3,5-tricarboxylate linkers molecules, which bridge two metal centers. One water molecules is coordinated to each of the two metal centers at the axial position of the paddlewheel unit in the hydrated state, which is usually found if the material is handled in air. After an activation process, these water molecules can be removed and the coordination site at the metal atoms is left unoccupied. This unoccupied coordination site is called coordinatively unsaturated site (CUS) and can be accessed by other molecules.

A selenite fluoride is a chemical compound or salt that contains fluoride and selenite anions. These are mixed anion compounds. Some have third anions, including nitrate, molybdate, oxalate, selenate, silicate and tellurate.

The borophosphates are mixed anion compounds containing borate and phosphate anions, which may be joined together by a common oxygen atom. Compounds that contain water or hydroxy groups can also be included in the class of compounds.

The borate bromides are mixed anion compounds that contain borate and bromide anions. They are in the borate halide family of compounds which also includes borate fluorides, borate chlorides, and borate iodides.

Selenogallates are chemical compounds which contain anionic units of selenium connected to gallium. They can be considered as gallates where selenium substitutes for oxygen. Similar compounds include the thiogallates and selenostannates. They are in the category of chalcogenotrielates or more broadly chalcogenometallates.

Sulfidostannates, or thiostannates are chemical compounds containing anions composed of tin linked with sulfur. They can be considered as stannates with sulfur substituting for oxygen. Related compounds include the thiosilicates, and thiogermannates, and by varying the chalcogen: selenostannates, and tellurostannates. Oxothiostannates have oxygen in addition to sulfur. Thiostannates can be classed as chalcogenidometalates, thiometallates, chalcogenidotetrelates, thiotetrelates, and chalcogenidostannates. Tin is almost always in the +4 oxidation state in thiostannates, although a couple of mixed sulfides in the +2 state are known,

A selenate selenite is a chemical compound or salt that contains selenite and selenate anions (SeO32- and SeO42-). These are mixed anion compounds. Some have third anions.

A phosphate phosphite is a chemical compound or salt that contains phosphate and phosphite anions (PO33- and PO43-). These are mixed anion compounds or mixed valence compounds. Some have third anions.

The oxalate phosphites are chemical compounds containing oxalate and phosphite anions. They are also called oxalatophosphites or phosphite oxalates. Oxalate phosphates can form metal organic framework compounds.

Sulfidogermanates or thiogermanates are chemical compounds containing anions with sulfur atoms bound to germanium. They are in the class of chalcogenidotetrelates. Related compounds include thiosilicates, thiostannates, selenidogermanates, telluridogermanates and selenidostannates.

Oxalate sulfates are mixed anion compounds containing oxalate and sulfate. They are mostly transparent, and any colour comes from the cations.

<span class="mw-page-title-main">Europium compounds</span> Chemical compounds with at least one europium atom

Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.

References

  1. 1 2 Kampf, Anthony R.; Cooper, Mark A.; Rossman, George R.; Nash, Barbara P.; Hawthorne, Frank. C.; Marty, Joe (December 2019). "Davidbrownite-(NH 4 ), (NH 4 ,K) 5 (V 4+ O) 2 (C 2 O 4 )[PO 2.75 (OH) 1.25 ] 4 ·3H 2 O, a new phosphate–oxalate mineral from the Rowley mine, Arizona, USA". Mineralogical Magazine. 83 (6): 869–877. Bibcode:2019MinM...83..869K. doi:10.1180/mgm.2019.56. ISSN   0026-461X. S2CID   202917386.
  2. ↑ "Crystal Structure of Novel Layered Iron Arsenate-Oxalate (NH4)3K3[Fe2(HAsO4)2(C2O4)4]x2H2O" (PDF). Журнал структурной химии (4). 2016. doi:10.15372/JSC20160428.
  3. ↑ Chakrabarti, Sandip; Green, Mark A.; Natarajan, Srinivasan (March 2002). "Hydrothermal synthesis of the first iron arsenate-oxalate [C4N2H12]2[Fe4(HAsO4)6( C2O4)2], possessing open architecture". Solid State Sciences. 4 (3): 405–412. Bibcode:2002SSSci...4..405C. doi:10.1016/S1293-2558(02)01268-2.
  4. ↑ Ramaswamy, Padmini; Hegde, Nayana N.; Prabhu, Ramanath; Vidya, V. M.; Datta, Ayan; Natarajan, Srinivasan (2009-12-21). "Synthesis, Structure, and Transformation Studies in a Family of Inorganic−Organic Hybrid Framework Structures Based on Indium". Inorganic Chemistry. 48 (24): 11697–11711. doi:10.1021/ic901744m. ISSN   0020-1669. PMID   19911816.
  5. ↑ Huang, Ya-Ling; Huang, Meow-Yu; Chan, Tsung-Han; Chang, Bor-Chen; Lii, Kwang-Hwa (June 2007). "Synthesis, Structural Characterization, and Luminescence Properties of Lanthanide Oxalatophosphonates: Na[M 3 (H 2 O) 4 (C 2 O 4 ) 4 (CH 3 PO 3 )]·2H 2 O (M = Nd and Pr)". Chemistry of Materials. 19 (13): 3232–3237. doi:10.1021/cm070602i.
  6. ↑ Kampf, Anthony R.; Celestian, Aaron J.; Nash, Barbara P.; Marty, Joe (2019-07-01). "Phoxite, (NH4)2Mg2(C2O4)(PO3OH)2(H2O)4, the first phosphate-oxalate mineral". American Mineralogist. 104 (7): 973–979. Bibcode:2019AmMin.104..973K. doi:10.2138/am-2019-6991. ISSN   0003-004X. S2CID   195790216.
  7. ↑ Kampf, Anthony R.; Cooper, Mark A.; Celestian, Aaron J.; Nash, Barbara P.; Marty, Joe (2021-03-16). "Thebaite-(NH 4 ), (NH 4 ,K) 3 Al(C 2 O 4 )(PO 3 OH) 2 (H 2 O), a new phosphate–oxalate mineral from the Rowley mine, Arizona, USA". Mineralogical Magazine. 85 (3): 379–386. Bibcode:2021MinM...85..379K. doi:10.1180/mgm.2021.26. ISSN   0026-461X. S2CID   233712768.
  8. ↑ Cao, Yue; Zhou, Xiaoying; Luan, Lindong; Zeng, Hongmei; Zou, Guohong; Lin, Zhien (February 2021). "Organically templated metal phosphate-oxalates: Solvent-free synthesis, crystal structure, and proton conduction". Inorganic Chemistry Communications. 124: 108403. doi:10.1016/j.inoche.2020.108403. ISSN   1387-7003. S2CID   234052257.
  9. 1 2 Colin, J. F.; Bataille, T.; Ashbrook, S. E.; Audebrand, N.; Le Pollès, L.; Pivan, J. Y.; Le Fur, E. (July 2006). "Na 2 [(VO) 2 (HPO 4 ) 2 C 2 O 4 ]·2H 2 O: Crystal Structure Determination from Combined Powder Diffraction and Solid-State NMR". Inorganic Chemistry. 45 (15): 6034–6040. doi:10.1021/ic060483t. ISSN   0020-1669. PMID   16842011.
  10. 1 2 Shahul Hameed, A.; Nagarathinam, Mangayarkarasi; Schreyer, Martin; Reddy, M. V.; Chowdari, B. V. R.; Vittal, Jagadese J. (2013). "A layered oxalatophosphate framework as a cathode material for Li-ion batteries". Journal of Materials Chemistry A. 1 (18): 5721. doi:10.1039/c3ta10464h. ISSN   2050-7488.
  11. ↑ Zhao, Qian; Zhu, Yaru; Xiao, Bo; Liu, Shanshan; He, Tao; Yang, Xin; Feng, Kai (2022-12-04). "Na 2 [(VO) 2 (HPO 4 ) 2 (C 2 O 4 )]·2H 2 O: A Promising Mixed Polyanionic Cathode Material for Aqueous Zn-Ion Batteries". Inorganic Chemistry. 61 (50): 20211–20215. doi:10.1021/acs.inorgchem.2c03308. ISSN   0020-1669. PMID   36463495. S2CID   254220629.
  12. 1 2 Hameed, A. Shahul; Reddy, M. V.; Nagarathinam, M.; Runčevski, Tomče; Dinnebier, Robert E; Adams, Stefan; Chowdari, B. V. R.; Vittal, Jagadese J. (December 2015). "Room temperature large-scale synthesis of layered frameworks as low-cost 4 V cathode materials for lithium ion batteries". Scientific Reports. 5 (1): 16270. Bibcode:2015NatSR...516270H. doi:10.1038/srep16270. ISSN   2045-2322. PMC   4655412 . PMID   26593096.
  13. 1 2 Nagarathinam, Mangayarkarasi; Saravanan, Kuppan; Phua, Eunice Jia Han; Reddy, M. V.; Chowdari, B. V. R.; Vittal, Jagadese J. (2012-06-11). "Redox-Active Metal-Centered Oxalato Phosphate Open Framework Cathode Materials for Lithium Ion Batteries". Angewandte Chemie International Edition. 51 (24): 5866–5870. doi:10.1002/anie.201200210. PMID   22539247.
  14. 1 2 Do, Junghwan; Bontchev, Ranko P.; Jacobson, Allan J. (2001-08-01). "Vanadyl Oxalatophosphate Compounds (C 2 H 10 N 2 )[VO(HPO 4 )] 2 (C 2 O 4 ) and (CH 6 N 3 ) 2 [[VO(HPO 4 )] 2 (C 2 O 4 ) and Their Thermal Transformation to (VO) 2 P 2 O 7 via VOHPO 4". Chemistry of Materials. 13 (8): 2601–2607. doi:10.1021/cm010043u. ISSN   0897-4756.
  15. ↑ Shi, Fa-Nian; Almeida Paz, Filipe A.; Rocha, João; Klinowski, Jacek; Trindade, Tito (March 2005). "Synthesis and characterisation of a new vanadyl oxalatophosphate compound: (C10H10N2)[(VO)(HPO4)]2(C2O4)". Inorganica Chimica Acta. 358 (4): 927–932. doi:10.1016/j.ica.2004.10.017.
  16. ↑ Orive, Joseba; Sivasamy, Ramesh; Fernández de Luis, Roberto; Mosquera, Edgar; Arriortua, María I. (2018). "K 2 MnII2(H 2 O) 2 C 2 O 4 (HPO 3 ) 2 : a new 2D manganese( ii ) oxalatophosphite with double-layered honeycomb sheets stabilized by potassium ions". CrystEngComm. 20 (3): 301–311. doi:10.1039/C7CE01637A. hdl: 10810/25291 . ISSN   1466-8033.
  17. 1 2 Jiang, Yau-Chen; Wang, Sue-Lein; Lee, Shang-Fan; Lii, Kwang-Hwa (October 2003). "Novel Transition Metal Oxalatophosphates with a Two-Dimensional Honeycomb Structure: (H 3 TREN)[M 2 (HPO 4 )(C 2 O 4 ) 2.5 ]·3H 2 O (M = Mn II and Fe II , TREN = Tris(2-aminoethyl)amine) †". Inorganic Chemistry. 42 (20): 6154–6156. doi:10.1021/ic030019d. ISSN   0020-1669. PMID   14514286.
  18. 1 2 3 Luan, Lindong; Li, Jing; Yin, Changzhen; Lin, Zhien; Huang, Hui (2015). "Solvent-free synthesis of new inorganic–organic hybrid solids with finely tuned manganese oxalate structures". Dalton Transactions. 44 (13): 5974–5977. doi:10.1039/C5DT00431D. ISSN   1477-9226. PMID   25742937.
  19. 1 2 3 Luan, Lindong; Zou, Guohong; Lin, Zhien; Cai, Huaqiang; Huang, Hui (October 2018). "Solvent-free synthesis of metal phosphate-oxalates with layered and zeolitic structures". Inorganic Chemistry Communications. 96: 65–68. doi:10.1016/j.inoche.2018.08.003. S2CID   105948051.
  20. ↑ Kizewski, Fiona R.; Boyle, Paul; Hesterberg, Dean; Martin, James D. (2010-02-24). "Mixed Anion (Phosphate/Oxalate) Bonding to Iron(III) Materials". Journal of the American Chemical Society. 132 (7): 2301–2308. doi:10.1021/ja908807b. ISSN   0002-7863. PMID   20121236.
  21. ↑ Pramanik, Atin; Bradford, Alasdair J; Lee, Stephen L; Lightfoot, Philip; Armstrong, A Robert (2021-04-01). "Na 2 Fe(C 2 O 4 )(HPO 4 ): a promising new oxalate-phosphate based mixed polyanionic cathode for Li/Na ion batteries". Journal of Physics: Materials. 4 (2): 024004. Bibcode:2021JPhM....4b4004P. doi:10.1088/2515-7639/abe5f9. hdl: 10023/21569 . ISSN   2515-7639. S2CID   233919183.
  22. ↑ Yang, Xin; Li, Jiang; Hou, Yawei; Shi, Shenyi; Shan, Yongkui (April 2008). "K2Fe(C2O4)(HPO4)(OH2)·H2O: A layered oxalatophosphate hybrid material". Inorganica Chimica Acta. 361 (5): 1510–1514. doi:10.1016/j.ica.2007.08.013.
  23. ↑ Neeraj, S.; Natarajan, Srinivasan; Rao, C. N. R. (2001). "A zinc phosphate oxalate with phosphate layers pillared by the oxalate units". Journal of the Chemical Society, Dalton Transactions (3): 289–291. doi:10.1039/b007980o.
  24. ↑ Loiseau, Thierry; Férey, Gérard; Haouas, Mohamed; Taulelle, Francis (2004-12-01). "Structural Analysis of F/OH Distribution in a Hybrid Open-Framework Fluorinated Gallium Oxalate−Phosphate Templated by 1,3-Diaminopropane (MIL-90)". Chemistry of Materials. 16 (25): 5318–5326. doi:10.1021/cm048820o. ISSN   0897-4756.
  25. ↑ Yang, Ya-Ching; Wang, Sue-Lein (January 2008). "Intrinsic Yellow Light Phosphor: An Organic−Inorganic Hybrid Gallium Oxalatophosphate with Hexameric Octahedral Ga 6 (OH) 4 O 26 Cluster". Journal of the American Chemical Society. 130 (4): 1146–1147. doi:10.1021/ja7101423. ISSN   0002-7863. PMID   18181630.
  26. 1 2 3 4 5 Chen, Zhenxia; Tan, Songliang; Weng, Linhong; Zhou, Yaming; Gao, Xiang; Zhao, Dongyuan (July 2006). "New organically templated gallium oxalate-phosphate structures based on Ga4(PO4)4(C2O4) building unit". Journal of Solid State Chemistry. 179 (7): 1931–1937. Bibcode:2006JSSCh.179.1931C. doi:10.1016/j.jssc.2006.03.031.
  27. ↑ Xue, Zhen-Zhen; Pan, Jie; Li, Jin-Hua; Wang, Zong-Hua; Wang, Guo-Ming (June 2017). "Synthesis, structure and characterization of two new organic template-directed gallium phosphate/phosphite-oxalates". Journal of Molecular Structure. 1138: 1–5. Bibcode:2017JMoSt1138....1X. doi:10.1016/j.molstruc.2017.02.102.
  28. ↑ Ramaswamy, Padmini; Mandal, Sukhendu; Natarajan, Srinivasan (June 2011). "New open-framework phosphate and phosphite compounds of gallium". Inorganica Chimica Acta. 372 (1): 136–144. doi:10.1016/j.ica.2011.02.034.
  29. ↑ Ramaswamy, Padmini; Hegde, Nayana N.; Prabhu, Ramanath; Vidya, V. M.; Datta, Ayan; Natarajan, Srinivasan (2009-12-21). "Synthesis, Structure, and Transformation Studies in a Family of Inorganic−Organic Hybrid Framework Structures Based on Indium". Inorganic Chemistry. 48 (24): 11697–11711. doi:10.1021/ic901744m. ISSN   0020-1669. PMID   19911816.
  30. ↑ Huang, Yuh-Feng; Lii, Kwang-Hwa (1998). "Organically templated inorganic/organic hybrid materials: hydrothermal synthesis and structural characterization of [C4H12N2][In2(C2O4)(HPO4)3]·H2O". Journal of the Chemical Society, Dalton Transactions (24): 4085–4086. doi:10.1039/a807345g.
  31. 1 2 Lee, S. F.; Tsai, T. C.; Chang, G. S.; Sheu, C. Y.; Lii, K. H. (May 2007). "Magnetic properties of iron oxalatophosphates with layer and framework structures". Journal of Applied Physics. 101 (9): 09E107. Bibcode:2007JAP...101iE107L. doi:10.1063/1.2713207. ISSN   0021-8979.
  32. 1 2 3 4 Wang, Chih-Min; Wu, Yi-Ying; Hou, Chia-Hung; Chen, Chii-Chang; Lii, Kwang-Hwa (2009-02-16). "Synthesis, Characterization, and Properties of Organically Templated Lanthanide Oxalatophosphates with a Three-Dimensional Honeycomb Structure: (H4APPIP)[Ln3(C2O4)5.5(H2PO4)2]·5H2O (Ln = Er−Lu, APPIP = 1,4-Bis(3-aminopropyl)piperazine)". Inorganic Chemistry. 48 (4): 1519–1523. doi:10.1021/ic801817e. ISSN   0020-1669. PMID   19159316.
  33. ↑ Bagnall, Kenneth W. (2013-12-12). Th Thorium: Compounds with Carbon: Carbonates, Thiocyanates, Alkoxides, Carboxylates. Springer Science & Business Media. pp. 102–103. ISBN   978-3-662-06315-6.
  34. ↑ Bjorklund, Carl W. (December 1957). "The Preparation of PuP 2 O 7 and PuPO 4 1". Journal of the American Chemical Society. 79 (24): 6347–6350. doi:10.1021/ja01581a001. ISSN   0002-7863.
This page is based on this Wikipedia article
Text is available under the CC BY-SA 4.0 license; additional terms may apply.
Images, videos and audio are available under their respective licenses.