Borate phosphate

Last updated
Borate phosphate
Identifiers
3D model (JSmol)
ChemSpider
  • 1:1:InChI=1S/BO3.H3O4P/c2-1(3)4;1-5(2,3)4/h;(H3,1,2,3,4)/q-3;/p-3
    Key: IVHMVLWSSMPWPQ-UHFFFAOYSA-K
  • 1:1:B([O-])([O-])[O-].[O-]P(=O)([O-])[O-]
Properties
BO7P−6
Molar mass 153.78 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Borate phosphates are mixed anion compounds containing separate borate and phosphate anions. They are distinct from the borophosphates where the borate is linked to a phosphate via a common oxygen atom. The borate phosphates have a higher ratio of cations to number of borates and phosphates, as compared to the borophosphates. [1]

Contents

There are also organic esters of both borate and phosphate, e.g. NADH-borate. [2]

Production

In the high temperature method, ingredients are heated together at atmospheric pressure. Products are anhydrous, and production or borophosphates is likely. [3]

The boron flux method involves dissolving ingredients such as an ammonium phosphate and metal carbonate in an excess of molten boric acid. [3]

Use

Borate phosphates are of research interest for their optical, electrooptical or magnetic properties. [3]

List

chemmwcrystal systemspace groupunit cell Åvolumedensitycommentreferences
Be3(BO3)(PO4)hexagonalSHG [1] [4]
α-Mg3[BPO7]orthorhombicImmma=8·495, b=4·886, c=12·565 Z=4 [5]
Mg3[BPO7]monoclinicCm [3]
Mg3[BPO7]hexagonalP6_2m [3]
Lüneburgite Mg3[B2(OH)6](PO4)2 · 6H2Otriclinic2.05Biaxial (-) nα = 1.520 – 1.522 nβ = 1.540 – 1.541 nγ = 1.545 – 1.548

2V 52° to 60°

Max birefringence δ = 0.025 – 0.026

 [6] [7]
Ca3[BPO7]monoclinica=8.602 b=4.891 c=12.806 β=102.30 [5]
Seamanite Mn2+3[B(OH)4](PO4)(OH)2orthorhombicPbnma = 7.81 Å, b = 15.11 Å, c = 6.69 Å Z=4789.483.08Biaxial (+) nα = 1.640 nβ = 1.663 nγ = 1.665

2V 40°

Max birefringence δ = 0.025

 [8] [9]
Laptevite-(Ce) Ca6(Fe2+,Mn2+)Y3REE7(SiO4)3(PO4)(B3Si3O18)(BO3)F11trigonalR3ma = 10.804, c = 27.726 Z=32802.64.61Uniaxial (-) nω = 1.741 nε = 1.720

Max birefringence δ = 0.021

 [10]
(CoPO4)4, B5O6(OH)4N(CH3)4(CH3NH3)1036.10orthorhombicI222a=6.7601 b=7.5422 c=34.822 Z=21775.41.938red [11]
Co3[BPO7]monoclinicCma=9.774, b=12.688, c=4.9057, β=119.749°; Z=4528.2purple [3]
α-Zn3[BPO7]349.89orthorhombica=8.438 b=4.884 c=12.558 [5]
α-Zn3[BPO7]349.89monoclinicCma=9.725 b=12.720 c=4.874 β=119.80 Z=4 [3] [12]
β-Zn3[BPO7]349.89hexagonalP-6a=8.4624 c=13.0690 Z=6810.514.301colourless [3] [13]
α-Sr3[BPO7]orthorhombica=9.0561, b=9.7984, c=13.9531 [14]
Sr10[(PO4)5.5(BO4)0.5](BO2)P3_a=9.7973, c=7.3056, Z=1607.29 [15]
SrCo2(BO3)(PO4)359.26monoclinicP21/ca=6.485 b=9.270 c=10.066 β=111.14 Z=4548.74.349red [1] [16]
Byzantievite Ba5(Ca,REE,Y)22(Ti,Nb)18(SiO4)4[(PO4, SiO4)]4(BO3)9O22[(OH),F]43(H2O)1.5trigonalR3a = 9.1202, c = 102.1457,357.94.10Uniaxial (-) nω = 1.940 nε = 1.860

Max birefringence δ = 0.080

16 different layers in structure

 [17] [18]
Rhabdoborite Mg12(V5+,Mo6+,W6+)1 · 5O6{[BO3]6-x[(P,As)O4]xF2-x} (x < 1)hexagonalP63a = 10.6314, c = 4.5661446.95 [19]
CsNa2Y2(BO3)(PO4)2605.46orthorhombicCmcma=6.9491 b=14.907 c=10.6201 Z=41100.23.655colourless [20]
CsZn4(BO3)(PO4)2679.30orthorhombicPbcaa=14.49 b=10.02 c=16.45 Z=823883.779colourless [21]
Ba3(BO3)(PO4)hexagonalP63mca=5.4898, c=14.7551, Z=2 [1] [22]
Ba3(BO3)(PO4)monoclinicP2/ma = 11.7947, b = 9.6135, c = 12.9548, β= 111.25°1369.08 [23]
Ba11B26O44(PO4)2(OH)6monoclinicP21/ca=6.891, b=13.629, c=25.851, β=90.04° [24]
Ba3(ZnB5O10)PO4786.41orthorhombicPnm21a = 10.399 b = 7.064 c = 8.204 Z=2602.64.334 [25]
La7O6(BO3)(PO4)2monoclinica=7.019 b=17.915 c=12.653 β=97.521577.27 [1] [26]
Pr7O6(BO3)(PO4)2monoclinicP121/n1a=6.8939 b=17.662 c=12.442 β=97.24 Z=41502.9green [1] [27]
Nd7O6(BO3)(PO4)2monoclinica=6.862 b=17.591 c=12.375 β=97.181482.12 [1] [26]
Sm7O6(BO3)(PO4)2monoclinicP121/n1a=6.778 b=17.396 c=12.218 β=96.96 Z=41430.0yellow [1] [27]
CsNa2Sm2(BO3)(PO4)2728.34orthorhombicCmcma=7.0631 b=15.288 c=10.725 Z=41158.14.177colourless [28]
CsNa2Ho2(BO3)(PO4)2 [29]
CsNa2Er2(BO3)(PO4)2 [29]
CsNa2Tm2(BO3)(PO4)2 [29]
Gd7O6(BO3)(PO4)2monoclinica=6.704 b=17.299 c=12.100 β=96.941393.11 [1] [26]
Dy7O6(BO3)(PO4)2monoclinica=6.623 b=17.172 c=11.960 β=96.761350.84 [1] [26]
K3Yb[OB(OH)2]2[HOPO3]2R3_a=5.6809, c=36.594 Z=31022.8 [1] [30]
CsNa2Yb2(BO3)(PO4)2 [29]
K3Lu[OB(OH)2]2[HOPO3]2R3_a=5.6668, c=36.692 Z=31020.4 [1] [30]
CsNa2Lu2(BO3)(PO4)2777.58orthorhombicCmcma = 6.8750 b = 14.6919 c = 10.55811066.444.843
Pb4O(BO3)(PO4)998.54monoclinicP21/ca=10.202 b=7.005 c=12.92 β=113.057 Z=4849.67.807colourless [31]
LiPb4(BO3)(PO4)21084.85orthorhombicPbcaa=12.613 b=6.551 c=25.63 Z=820956.875colourless [1]
Bi4O3(BO3)(PO4)1037.70orthorhombicPbcaa=5.536 b=14.10 c=22.62 Z=817667.807colourless [31]
Th2[BO4][PO4]monoclinicP21/ca=8.4665, b=7.9552, c=8.2297, β= 103.746° Z = 4 [32]
Ba5[(UO2)(PO4)3(B5O9)]·nH2Ointerlocking nanotubes; absorbs water from air [33]
U2[BO4][PO4]645.84monoclinicP21/ca = 8.546, b = 7.753, c = 8.163 β = 102.52° Z=4528.08.12generated at 12.5 GPa + 1000 °C; emerald green [34]
[Sr8(PO4)2][(UO2)(PO4)2(B5O9)2]1746.97monoclinicP21/na = 6.5014, b =22.4302, c =9.7964 β = 90.241° Z=21428.574.061orange [35]

Related Research Articles

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<span class="mw-page-title-main">Terbium compounds</span> Chemical compounds with at least one terbium atom

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References

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  32. ↑ Lipp, C.; Burns, P. C. (2011-10-01). "Th2[BO4][PO4]: A RARE EXAMPLE OF AN ACTINIDE BORATE-PHOSPHATE". The Canadian Mineralogist. 49 (5): 1211–1220. Bibcode:2011CaMin..49.1211L. doi:10.3749/canmin.49.5.1211. ISSN   0008-4476.
  33. ↑ Wu, Shijun; Wang, Shuao; Diwu, Juan; Depmeier, Wulf; Malcherek, Thomas; Alekseev, Evgeny V.; Albrecht-Schmitt, Thomas E. (2012). "Complex clover cross-sectioned nanotubules exist in the structure of the first uranium borate phosphate". Chemical Communications. 48 (29): 3479–81. doi:10.1039/c2cc17517g. ISSN   1359-7345. PMID   22267020.
  34. ↑ Hinteregger, Ernst; Wurst, Klaus; Perfler, Lukas; Kraus, Florian; Huppertz, Hubert (2013-10-14). "High-Pressure Synthesis and Characterization of the Actinide Borate Phosphate U 2 [BO 4 ][PO 4 ]: High-Pressure Synthesis and Characterization of U 2 [BO 4 ][PO 4 ]". European Journal of Inorganic Chemistry. 2013 (30): 5247–5252. doi:10.1002/ejic.201300662. PMC   3939824 . PMID   24611029.
  35. ↑ Hao, Yucheng (2017). "New Insight into the Crystal Chemistry of Uranium and Thorium Borates, Borophosphates and Borate-phosphates". p. 109.
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