Phosphate sulfate

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The phosphate sulfates are mixed anion compounds containing both phosphate and sulfate ions. Related compounds include the arsenate sulfates, phosphate selenates, and arsenate selenates.

Contents

Some hydrogen phosphate sulfates are superprotonic conductors.

List

chemmwcrystal systemspace groupunit cellvolumedensitycommentreferences
Sanjuanite Al2(PO4)(SO4)(OH)·9H2O [1]
Hotsonite Al11(SO4)3(PO4)2(OH)21 · 16H2Otriclinica=11.23, b=11.66 c=10.55 α=112° 32′, β=107° 32′ γ=64° 27′refract: α = 1.519 γ = 1.521 [2]
Arangasite Al2F(PO4)(SO4)·9H2OmonoclinicP2/aa = 7.073, b = 9.634, c = 10.827, β = 100.40°, Z = 2725.7 [3]
peisleyiteNa3Al16(SO4)2(PO4)10(OH)17 · 20H2Omonoclinica 13.31, b 12.62, c 23.15, β 110.0°, Z = 2discredited [4]
peisleyiteNa2Al9[(P,S)O4]8(OH)6·28H2OtriclinicP1a = 9.28, b = 11.98, c = 13.25, α = 91.3, β = 75.6, γ = 67.67°, Z = 41308 [5]
Woodhouseite CaAl3(PO4)(SO4)(OH)6trigonalR3ma = 6.993, c = 16.386693.953.0Uniaxial (+) nω = 1.636 nε = 1.647 Birefringence: δ = 0.011 [6]
Ardéalite Ca2H(PO4)(SO4)•4H2Omonoclinica = 5.721, b = 30.95, c = 6.265, β= 117.26° Z = 4986.112.32 [7]
Destinezite Diadochite Fe2(PO4)(SO4)(OH)•6H2OtriclinicP1a = 9.570, b = 9.716, c = 7.313, α = 98.74°, β = 107.90°, γ = 63.86° Z = 2 [8]
bohuslaviteFeIII4(PO4)3(SO4)(OH)(H2O)10·nH2O (5 ≤ n ≤ 14)triclinicP1a = 13.376 b = 13.338 c = 10.863 α = 92.80, β = 91.03, γ = 119.92°, Z = 21675.7pink [9]
Borickyite (Ca,Mg)(Fe3+,Al)4(PO4,SO4,CO3)(OH)8·3–7.5H2O [10]
Camaronesite[Fe3+(H2O)2(PO3OH)]2(SO4)·1–2H2OtrigonalR32a = 9.0833, c = 42.944, Z = 93068.5 [11]
Fe3+4(PO4)3(SO4)(OH)·18H2OtriclinicP1a=13.376, b 13.338, c 10.863, α 92.80, β 91.03, γ 119.92°1675.7 [12]
vanderheydenite Zn6(PO4)2(SO4)(OH)4·7H2OmonoclinicP21/na = 6.204 b = 19.619, c = 7.782, β = 90.67°947.1biaxial (–) α = 1.565, β = 1.580 γ = 1.582. 2V = 39.8° [13]
Svanbergite SrAl3(PO4)(SO4)(OH)6trigonalR3ma = 6.97, c = 16.59 Z=3697.983.2Uniaxial (+) nω = 1.631 - 1.635 nε = 1.646 - 1.649 Birefringence: δ = 0.015 [14]
BirchiteCd2Cu2(PO4)2(SO4) ·5H2Oa = 10.489 b = 20.901 c = 6.155 Z=41349.63.647biaxial positive,

nα = 1.624, nβ = 1.636, nγ = 1.669, 2Vcalc = +63°.

 [15]
Corkite PbFe3(OH)6SO4PO4trigonalR3ma = 7.32, c = 17.02 Z=3781.24.295Uniaxial (-) nω = 1.930 nε = 1.930 n = 1.93 - 1.96 Birefringence 0.03 [16]
BaAl3(PO4)(SO4)(OH)6trigonalR3ma = , c = Z=3 [17]
hinsdalite (Pb,Sr)Al3(PO4)(SO4)(OH)6 [18]
Tsumebite Pb2Cu(PO4,SO4)(OH) [19]
Delvauxite CaFe43+(PO4,SO4)2(OH)8·4–6H2O [20]
Rossiantonite Al3(PO4)(SO4)2(OH)2(H2O)10·4H2OtriclinicP1a = 10.3410, b = 10.9600, c = 11.1446, α = 86.985, β = 65.727, γ = 75.064°, Z = 21110.5 [21]
Schlossmacherite (H3O,Ca)Al3(AsO4,PO4,SO4)2(OH)6 [22]
Arthurite Cu(Fe3+)2(AsO4,PO4,SO4)2(O,OH)2·4(H2O) [23]
cobaltarthurite [23]
Phosphoinnelite Ba4Na3Ti3Si4O14(PO4,SO4)2(O,F)3triclinicP1?a = 5.38, b = 7.10, c = 14.76; α = 99.00°, β = 94.94°, γ = 90.14° Z = 15553.82biaxial (+), α = 1.730, β = 1.745, and γ = 1.764, 2V 90° [24]
Francolite (Ca, Mg, Sr, Na)10(PO4, SO4, CO3)6F2–3 [25]
Al4(UO2)2(PO4)4(SO4)(OH)2 · 18H2O [26]
Al4(UO2)2(PO4)4(SO4)(OH)2 · 20H2O [26]
CoconinoiteFe2Al2(UO2)2(PO4)4(SO4)(OH)2 · 20H2OmonoclinicC2/ca =12.45, b = 12.96, c = 17.22, β = 105.7° [26]
xiangjiangite Fe2Al2(UO2)2(PO4)4(SO4)(OH)2 · 22H2Otetragonala = 7.17 Å, b = 7.17 Å, c = 22.22 Å Z=11,142Biaxial (-) nα = 1.558 nβ = 1.576 nγ = 1.593 2V: 87° [27]

Artificial

chemmwcrystal systemspace groupunit cell Åvolumedensitycommentreferences
[H4N+]2·HSO4−·H2PO4− [28] [29]
NH4(HSO4)0.45(H2PO4)0.55orthorhombic [30]
18-crown[6]·[NH4][H2PO4]0.5[HSO4]0.5·H2OorthrhombicF2dda=8.710 b= 28.868 c=31.206 Z=1678461.346dehydrate at 70° [31]
[(C2H5)4N+]2·HSO4−·H2PO4−MonoclinicC2/ca = 28.0787 b = 11.8671 c = 14.1533 β = 100.739° Z=84633.461.303colourless; decompose at 353K [32]
(NH2CH2COOH)3(H2SO4)0.7(H3PO4)0.3monocliniccalled TGSP; colourless; ferroelectric, curie point 51 °C; pyroelectric
Na(HSO4)(H3PO4)monoclinicP 21a = 5.449, b = 6.832, c = 8.718, β = 95.88°, Z = 2 322.8 [33]
K2(HSO4)(H2PO4)monoclinicP 21/ca = 11.150, b = 7.371, c = 9.436, β = 92.29°, Z = 4 774.9 [33]
K4(HSO4)3(H2PO4)triclinicP 1a = 7.217, b = 7.521, c = 7.574, α = 71.52°, β = 88.28°, γ = 86.20°, Z = 1 389.1 [33]
K4(PO2F2)2(S2O7)534.46monoclinicC2/ca = 13.00, b = 7.543, c = 19.01, β = 130.07°, Z = 41426.52.489colourless; pyrosulfate + difluorophosphate [34]
K3[O3SOPO2OSO3] [35]
H1−xTi2(PO4)3−x(SO4)x (x=0.5–1) [36]
Na2MgTi(SO4)(PO4)2trigonalR3ca=8.4796 c=21.8091 Z=61358.12.818 [37]
K2MgTi(SO4)(PO4)2cubicP213a=9.8743 Z=4962.842.872 [37]
Ca10-xNax(PO4)6-x(SO4)xF2monoclinic [38]
NaFe2(PO4)(SO4)2hexagonalR3ca=8.4243 c=21.973 [39]
NaFe1.4V0.6(PO4)(SO4)2 [40]
[Ni(C14H10N4)3]4(PO4)2(SO4) (C14H10N4=2,2'-bi-1H-benzimidazole)3331.96cubicI43da = 24.964 Z=4155581.423green [41]
Rb2(HSO4)(H2PO4)monoclinicP21/na=7.448, b=7.552, c=7.632, β=100.47°, Z=2422.1 [42] [43]
Rb2(HSO4)(H2PO4)monoclinicP21/ca=11.555, b=7.536, c=9.593, β=91.56, Z=4853.0at 160K [43]
Rb4(HSO4)3(H2PO4)orthorhombicP21212a=7.612, b=14.795, c=7.446, Z=2838.6 [42] [43]
18-crown[6]·Rb[H2PO4]0.5[HSO4]0.5·3H2OmonoclinicC2/ca=19.802 b=8.447 c=25.777 β=101.00° Z=842321.572dehydrate at 70° [31]
Rb2MgTi(SO4)(PO4)2 [37]
Sr4(PO4)2SO4 [44]
NaZrMg(PO4)(SO4)2hexagonalR3c [45]
NaZrCo(PO4)(SO4)2hexagonalR3c [45]
NaZrNi(PO4)(SO4)2hexagonalR3c [45]
NaZrCu(PO4)(SO4)2hexagonalR3c [45]
NaZrZn(PO4)(SO4)2hexagonalR3c [45]
NaZrAl(PO4)2(SO4)hexagonalR3c [45]
NaZrFe(PO4)2(SO4)hexagonalR3c [45]
H3OSb2(SO4)2(PO4)triclinicP1a=5.134 b=7.908 c=12.855, α=81.401° β=87.253° γ=86.49° [46]
KSb2(SO4)2(PO4)triclinicP1a=5.1453 =7.9149 c=12.6146, α=82.054° β=87.715° γ=86.655° [46]
RbSb2(SO4)2(PO4)triclinicP1a=5.1531 b=7.957 c=12.845, α=81.801° β=87.676° γ=86.703° [46]
Cs2(HSO4)(H2PO4)cubicao=4.926>105 °C but can be supercooled [47]
Cs2(HSO4)(H2PO4)monoclinicP21/na = 7.856 b = 7.732 c = 7.827, β= 99.92° Z=2468.33.261can substitute 2.3% ammonium; proton conductivity at 110 °C is 3×10−3 Ω−1cm−1 [48] [49]
Cs3(HSO4)2(H2PO4)monoclinicC2/ca=19.824 b=7.859 c=19.047 β=100.20° Z=41387.23.302stable against water solution 298-313K; phase transition at 411K [50]
Cs4(HSO4)3(H2PO4)monoclinicC2/ca=19.945 b=7.8565 c=8.9949 β=100.119° Z=31387.53.301colourless [51] [52]
Cs5(HSO4)2(H2PO4)3cubicI43da=14.5668over 381K goes to tetragonal a=4.965 c=5.016 [53]
Cs6H(HSO4)3(H2PO4)4cubicI43da=14.47583033.383.236colourless [54]
Cs5(HSO4)3(H2PO4)2monoclinicC2/ca=34.07 Å,b=7.661,c=9.158,β=90.44°23903.198 [55]
18-crown[6]·Cs[H2PO4]0.5[HSO4]0.5·3H2OmonoclinicC2/ca=19.840 b=8.460 c=26.19 β=101.14 Z=843131.689dehydrate at 70° [31]
CsNH4(HSO4)(H2PO4) [56]
Cs3NH4(HSO4)3(H2PO4) [56]
Cs2MgTi(SO4)(PO4)2 [37]
Ba4(PO4)2SO4 [44]
NaBa6Zr(PO4)5SO4cubicI43da = 10.5449 Z=41172.54 eulytite mineral structure [44]
Ba2Sr2(PO4)2SO4 [44]
Ba3Sr(PO4)2SO4 [44]
Ce2O(HPO4)2(SO4). 4H2OCeIV [57]
Ce2O(HPO4)2.4(SO4)0.6. 2H2OCeIII [58]
[enH2]0.5[CeIII(PO4)(HSO4)(OH2)]monoclinicP21/aa=12.999 b=7.150 c=9.212 β=95.33cream colour [59]
KSr2Eu(PO4)2SO4 [44]
RbSr2Eu(PO4)2SO4 [44]
CsSr2Eu(PO4)2SO4 [44]
[enH2]0.5[Ho(HPO4)(SO4)(H2O)]monoclinicP21/aa = 12.938 b = 6.834 c = 9.100 β = 88.12° [60]
Pb2Mg2(PO4)2SO4 [44]
MgPb3(PO4)2(SO4)cubicI43da = 10.299 Z=41092.45.67 [61]
CaPb3(PO4)2(SO4)cubicI43da = 10.296 Z=41091.55.77 [61]
MnPb3(PO4)2(SO4)cubicI43da = 10.258 Z=41079.45.92 [61]
CoPb3(PO4)2(SO4)cubicI43da = 10.356 Z=41110.65.78 [61]
NiPb3(PO4)2(SO4)cubicI43da = 10.434 Z=41135.95.65 [61]
CuPb3(PO4)2(SO4)cubicI43da = 10.422 Z=41132.05.70 [61]
ZnPb3(PO4)2(SO4)cubicI43da = 10.449 Z=41140.85.67 [61]
CdPb3(PO4)2(SO4)cubicI43da = 10.315 Z=41097.56.17 [61]
SrPb3(PO4)2(SO4)cubicI43da = 10.369 Z=41114.85.93 [61]
Th2(PO4)2SO4·2 H2Odecompose 450 °C [62]

Organic derivatives

A catenated sulfophosphate has the sulfur and phosphorus joined by an oxygen atom. In biochemistry, metabolism of sulfate may use such a group, for example with adenosine-5'-phosphosulfate. [63]

References

  1. ↑ Frost, Ray L.; Palmer, Sara J. (September 2011). "A vibrational spectroscopic study of the mixed anion mineral sanjuanite Al2(PO4)(SO4)(OH)·9H2O" (PDF). Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 79 (5): 1210–1214. Bibcode:2011AcSpA..79.1210F. doi:10.1016/j.saa.2011.04.044. PMID   21646042.
  2. ↑ Beukes, Gerhard J.; Schoch, Aylva E.; Van der Westhuizen, Willem A.; Bok, Louis D. C.; Bruiyn, Hendrik (1984-10-01). "Hotsonite, a new hydrated aluminum-phosphate-sulphate from Pofadder, South Africa". American Mineralogist. 69 (9–10): 979–983. ISSN   0003-004X.
  3. ↑ Yakubovich, O. V.; Steele, I. M.; Chernyshev, V. V.; Zayakina, N. V.; Gamyanin, G. N.; Karimova, O. V. (August 2014). "The crystal structure of arangasite, Al 2 F(PO 4 )(SO 4 )·9H 2 O determined using low-temperature synchrotron data" . Mineralogical Magazine. 78 (4): 889–903. Bibcode:2014MinM...78..889Y. doi:10.1180/minmag.2014.078.4.09. ISSN   0026-461X. S2CID   94078023.
  4. ↑ Pilkington, E. S.; Segnit, E. R.; Watts, J. A. (December 1982). "Peisleyite, a new sodium aluminium sulphate phosphate" . Mineralogical Magazine. 46 (341): 449–452. Bibcode:1982MinM...46..449P. doi:10.1180/minmag.1982.046.341.07. ISSN   0026-461X. S2CID   129726668.
  5. ↑ Mills, S. J.; Ma, C.; Birch, W. D. (December 2011). "A contribution to understanding the complex nature of peisleyite". Mineralogical Magazine. 75 (6): 2733–2737. Bibcode:2011MinM...75.2733M. doi:10.1180/minmag.2011.075.6.2733. ISSN   0026-461X. S2CID   18661193.
  6. ↑ "Woodhouseite". www.mindat.org. Retrieved 2022-05-25.
  7. ↑ BALENZANO, F; DELL'ANNA, L.; DI PIERRO, M.; FIORE, S. (1982). "Ardealite, Ca2H(PO4) (SO4).4H2O, un rarissimo fosfato-solfato idrato di calcio: risultati mineralogici preliminari". Ardealite, Ca2H(PO4) (SO4).4H2O, Un Rarissimo Fosfato-solfato Idrato di Calcio: Risultati Mineralogici Preliminari. 38 (2): 899–900. ISSN   0037-8828.
  8. ↑ Peacor, Donald R. (1999). "Destinezite ("Diadochite"), Fe2(PO4)(SO4)(OH)·6H2O: Its Crystal Structure and Role as a Soil Mineral at Alum Cave Bluff, Tennessee†". Clays and Clay Minerals. 47 (1): 1–11. Bibcode:1999CCM....47....1P. doi: 10.1346/CCMN.1999.0470101 . ISSN   0009-8604. S2CID   98406559.
  9. ↑ Mauro, Daniela; Biagioni, Cristian; Bonaccorsi, Elena; Hålenius, Ulf; Pasero, Marco; Skogby, Henrik; Zaccarini, Federica; Sejkora, Jiří; Plášil, Jakub; Kampf, Anthony R.; Filip, Jan (2019-12-20). "Bohuslavite, Fe 4 3 + (PO4)3(SO4)(OH)(H2O)10·nH2O, a new hydrated iron phosphate-sulfate" . European Journal of Mineralogy. 31 (5–6): 1033–1046. Bibcode:2019EJMin..31.1033M. doi:10.1127/ejm/2019/0031-2892. ISSN   0935-1221. S2CID   213555293.
  10. ↑ Frost, Ray L.; Palmer, Sara J.; Xi, Yunfei (June 2012). "Is the mineral borickyite (Ca,Mg)(Fe3+,Al)4(PO4,SO4,CO3)(OH)8·3–7.5H2O the same as delvauxite CaFe43+(PO4,SO4)2(OH)8·4–6H2O?". Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 92: 377–381. Bibcode:2012AcSpA..92..377F. doi:10.1016/j.saa.2012.02.102. PMID   22446787.
  11. ↑ Kampf, A. R.; Mills, S. J.; Nash, B. P.; Housley, R. M.; Rossman, G. R.; Dini, M. (June 2013). "Camaronesite, [Fe 3+ (H 2 O) 2 (PO 3 OH)] 2 (SO 4 )·1–2H 2 O, a new phosphate-sulfate from the Camarones Valley, Chile, structurally related to taranakite". Mineralogical Magazine. 77 (4): 453–465. Bibcode:2013MinM...77..453K. doi:10.1180/minmag.2013.077.4.05. ISSN   0026-461X. S2CID   129777006.
  12. ↑ Mauro, D.; Biagioni, C.; Bonaccorsi, E.; Pasero, M.; Skogby, H.; Zaccarini, F. (2018). "A new iron (III) phosphate-sulfate from Apuan Alps (Tuscany, Italy): a difficult puzzle solved through a multi-technique approach". Congresso Sgi-Simp 2018: 521.
  13. ↑ Elliott, Peter; Kolitsch, Uwe (2018-10-31). "Description and crystal structure of vanderheydenite, Zn6(PO4)2(SO4)(OH)4·7H2O, a new mineral from Broken Hill, New South Wales, Australia" . European Journal of Mineralogy. 30 (4): 835–840. Bibcode:2018EJMin..30..835E. doi:10.1127/ejm/2018/0030-2750. ISSN   0935-1221. S2CID   134655965.
  14. ↑ "Svanbergite". www.mindat.org. Retrieved 2022-05-25.
  15. ↑ Elliott, P.; Brugger, J.; Pring, A.; Cole, M. L.; Willis, A. C.; Kolitsch, U. (2008-05-01). "Birchite, a new mineral from Broken Hill, New South Wales, Australia: Description and structure refinement" . American Mineralogist. 93 (5–6): 910–917. Bibcode:2008AmMin..93..910E. doi:10.2138/am.2008.2732. ISSN   0003-004X. S2CID   95773593.
  16. ↑ "Corkite". www.mindat.org. Retrieved 2022-05-25.
  17. ↑ Izbrodin, Ivan A.; Ripp, German S.; Doroshkevich, Anna G. (January 2011). "Aluminium phosphate and phosphate-sulphate minerals in kyanite schists of the Ichetuyskoye area, West Transbaikalia, Russia: crystal chemistry and evolution" . Mineralogy and Petrology. 101 (1–2): 81–96. Bibcode:2011MinPe.101...81I. doi:10.1007/s00710-010-0135-5. ISSN   0930-0708. S2CID   129698260.
  18. ↑ Frost, Ray L.; Palmer, Sara J.; Xi, Yunfei (August 2011). "A vibrational spectroscopic study of the mineral hinsdalite (Pb,Sr)Al3(PO4)(SO4)(OH)6". Journal of Molecular Structure. 1001 (1–3): 43–48. Bibcode:2011JMoSt1001...43F. doi:10.1016/j.molstruc.2011.06.014.
  19. ↑ Frost, Ray L.; Palmer, Sara J. (September 2011). "Vibrational spectroscopic study of the mineral tsumebite Pb2Cu(PO4,SO4)(OH)". Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 79 (5): 1794–1797. Bibcode:2011AcSpA..79.1794F. doi:10.1016/j.saa.2011.05.058. PMID   21680232.
  20. ↑ Frost, Ray L.; Palmer, Sara J. (April 2011). "A Raman and infrared spectroscopic study of the mineral delvauxite CaFe43+(PO4,SO4)2(OH)8·4–6H2O—A 'colloidal' mineral". Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 78 (4): 1250–1254. Bibcode:2011AcSpA..78.1250F. doi:10.1016/j.saa.2010.12.039. PMID   21277823.
  21. ↑ Galli, E.; Brigatti, M. F.; Malferrari, D.; Sauro, F.; De Waele, J. (2013-10-01). "Rossiantonite, Al3(PO4)(SO4)2(OH)2(H2O)10{middle dot}4H2O, a new hydrated aluminum phosphate-sulfate mineral from Chimanta massif, Venezuela: Description and crystal structure" . American Mineralogist. 98 (10): 1906–1913. doi:10.2138/am.2013.4393. hdl:11585/185099. ISSN   0003-004X. S2CID   102265894.
  22. ↑ Frost, Ray L.; Palmer, Sara J.; Xi, Yunfei (February 2012). "Raman spectroscopy of the multi-anion mineral schlossmacherite (H3O,Ca)Al3(AsO4,PO4,SO4)2(OH)6". Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 87: 209–213. Bibcode:2012AcSpA..87..209F. doi:10.1016/j.saa.2011.11.040. PMID   22169025.
  23. 1 2 Palmer, Sara J.; Frost, Ray L. (May 2011). "The structure of the mineral arthurite (AsO4,PO4,SO4)2(O,OH)2·4H2O – A Raman spectroscopic study" . Journal of Molecular Structure. 994 (1–3): 283–288. doi:10.1016/j.molstruc.2011.03.034.
  24. ↑ Pekov, I. V.; Chukanov, N. V.; Kulikova, I. M.; Belakovsky, D. I. (December 2007). "Phosphoinnelite, Ba4Na3Ti3Si4O14(PO4,SO4)2(O,F)3, a new mineral species from peralkaline pegmatite of the Kovdor pluton, Kola Peninsula" . Geology of Ore Deposits. 49 (7): 530–536. Bibcode:2007GeoOD..49..530P. doi:10.1134/S1075701507070070. ISSN   1075-7015. S2CID   129616074.
  25. ↑ Benmore, Richard A.; Coleman, Max L.; McArthur, John M. (April 1983). "Origin of sedimentary francolite from its sulphur and carbon isotope composition" . Nature. 302 (5908): 516–518. Bibcode:1983Natur.302..516B. doi:10.1038/302516a0. ISSN   0028-0836. S2CID   4350036.
  26. 1 2 3 Frost, Ray L.; Palmer, Sara J; Čejka, Jiří (September 2011). "The Application of Raman Spectroscopy to the Study of the Uranyl Mineral Coconinoite Fe 2 Al 2 (UO 2 ) 2 (PO 4 ) 4 (SO 4 )(OH) 2 · 20H 2 O". Spectroscopy Letters. 44 (6): 381–387. Bibcode:2011SpecL..44..381F. doi:10.1080/00387010.2010.551445. ISSN   0038-7010. S2CID   96609983.
  27. ↑ "Xiangjiangite". www.mindat.org. Retrieved 2022-07-13.
  28. ↑ BEKTUROV, AB; NA, DZHUMAGULOVA; ZK, KAIPOVA; RS, ERZHANOVA; VI, LITVINENKO (1980). "RECHERCHES DANS LE DOMAINE DES SULFATOPHOSPHATES. 5. TRANSFORMATIONS THERMIQUES DES MELANGES DE PHOSPHATE ET DE SULFATE D'AMMONIUM MONOSUBSTITUES ET D'HYDROSULFATE-DIHYDRO-PHOSPHATE D'AMMONIUM (NH4)2(HSO4.H2PO4)". Recherches dans le Domaine des Sulfatophosphates. 5. Transformations Thermiques des Melanges de Phosphate et de Sulfate d'Ammonium Monosubstitues et d'Hydrosulfate-Dihydro-Phosphate d'Ammonium (Nh4)2(Hso4.H2Po4).
  29. ↑ PubChem. "Diammonium phosphate sulphate". pubchem.ncbi.nlm.nih.gov. Retrieved 2022-07-13.
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