Sulfate fluoride

Last updated

The sulfate fluorides are double salts that contain both sulfate and fluoride anions. They are in the class of mixed anion compounds. Some of these minerals are deposited in fumaroles.

Contents

Fluoride sulfates were first discovered by Jean Charles de Marignac in 1859. [1] [2]

Some elements such as cobalt or uranium can form complexes that contain fluoride and sulfate groups, and would be referred to as fluoro and sulfato metallates.

List

Minerals

nameformularatiosystemspace groupunit cell Åvolumedensityopticalreferences
Chukhrovite-(Ca) Ca4.5Al2(SO4)F13·12H2O1:13 Isometric Fd3a = 16.749 Z=84698.62.23isotropic n = 1.432 [3]
Chukhrovite-(Ce) Ca3(Y,Ce)(AlF6)2(SO4)F · 10H2O1:13IsometricFd3 [4]
Chukhrovite-(Y) Ca3(Ce,Y)(AlF6)2(SO4)F · 10H2O1:13IsometricFd3 [5]
Chukhrovite-(Nd) Ca3(Nd,Y)Al2(SO4)F13·12H2O1:13IsometricFd3a = 16.759 Z=84,707.02.42isotropic nα = 1.443 [6]
Meniaylovite Ca4[(SO4)(SiF6)(AlF6)]F · 12H2O1:13IsometricFd3a = 16.722 Z=84,675.89Isotropic n = 1.43
Pseudograndreefite Pb6(SO4)F101:10 Orthorhombic F2 2 2a = 8.51 b = 19.57 c = 8.49 Z=41,413.93Biaxial (+) nα = 1.864 nβ = 1.865 nγ = 1.873

2V: measured: 30° , calculated: 40°

Max birefringence: δ = 0.009

 [7]
Creedite Ca3SO4Al2F8(OH)2 · 2H2O1:8 Monoclinic B2/ba = 13.936, b = 8.606, c = 9.985 β = 94.39° Z=41,194.022.713Biaxial (-) nα = 1.461 nβ = 1.478 nγ = 1.485

Max birefringence: δ = 0.024

 [8]
Thermessaite K2AlF3(SO4)1:3OrthorhombicPbcna = 10.81 b = 8.336 c = 6.822614.752.77
Grandreefite Pb2(SO4)F21:2monoclinicA2/aa = 8.667 b = 4.4419 c = 14.242 β = 107.418 Z=4523.157.15Biaxial (+) nα = 1.872 nβ = 1.873 nγ = 1.897

2V: Measured: 23°

Max Birefringence: δ = 0.025

 [9]
Arangasite Al2F(PO4)(SO4) · 9H2O1:1monoclinicP2/aa = 7.073 b = 9.634 c = 10.827 β = 100.40 Z = 2725.72.01Biaxial (+) ?nα = 1.493(5) nγ = 1.485(5)

Max birefringence: δ = 0.008

 [10] [11]
Khademite Al(SO4)F · 5H2O1:1orthorhombica = 11.17 b = 13.05 c = 10.881,585.961.925Biaxial (-) nα = 1.440 nβ = 1.460 nγ = 1.487

2V: measured: 68° calculated: 84°

Max birefringence δ = 0.047

colourless

 [12]
Kogarkoite Na3(SO4)F1:1Monoclinic?P21a = 18.07 b = 6.94 c = 11.44 β = 107.72° Z=121,366.582.676Biaxial (+) nα = 1.439 nβ = 1.439 nγ = 1.442

Max Birefringence: δ = 0.003

 [13]
kononovite NaMg(SO4)F1:1monoclinicC2/ca = 6.662 b = 8.584 c = 7.035 β = 114.06 Z=4367.42.91biaxial (+), nα = 1.488 nβ = 1.491 nγ = 1.496 2Vmeas = 75°

Max birefringence: δ = 0.008

 [14]
Lannonite Mg2Ca4Al4(SO4)8F8 · 24H2O8:8 Tetragonal I4/ma = 6.860 c = 28.0531,320.162.22Uniaxial (+) nω = 1.460 nε = 1.478

Max Birefringence:δ = 0.018

 [15]
Sulphohalite Na6(SO4)2FCl2:1IsometricFm3mIsotropic [16]
Uklonskovite NaMgSO4F•2H2O1:1monoclinica = 7.2 Å, b = 7.21 Å, c = 5.73 β = 113.23°273.34Biaxial (+) nα = 1.476 nγ = 1.500

Max Birefringence δ = 0.024

 [17]
Vlodavetsite AlCa2(SO4)2F2Cl · 4H2O2:2TetragonalI4/ma = 6.870, c = 13.342 Z=2629.70Uniaxial (+) nω = 1.509 nε = 1.526

Max birefringence: δ = 0.017

 [18]
Schairerite Na21(SO4)7ClF67:6 trigonal 3_2/ma = 12.17 c = 19.292,474.252.67Uniaxial (+) nω = 1.440 nε = 1.445

Max birefringence: δ = 0.005

 [19]
Galeite Na15(SO4)5F4Cl5:4Trigonala = 12.17 c = 13.941,788.03Uniaxial (+) nω = 1.447 nε = 1.449

Max Birefringence: δ = 0.002

 [20]
Fluorellestadite Ca10(SiO4)3(SO4)3F23:2hexagonala = 9.53 c = 6.91543.493.03Uniaxial (-) nω = 1.655 nε = 1.650

Max birefringence:δ = 0.005

 [21]
Straßmannite Al(UO2)(SO4)2F·16H2O2:1monoclinicC2/ca = 11.0187 b = 8.3284 c = 26.673 β = 97.426°2427.22.20pale yellowish green

Biaxial (-) nα = 1.477(2) nβ = 1.485(2) nγ = 1.489(2)

2V: measured: 70° calculated: 70.2°

Max birefringence: δ = 0.012

 [22]
Svyazhinite (Mg,Mn2+,Ca)(Al,Fe3+)(SO4)2F · 14H2O2:1 triclinic a = 6.21 b = 13.3 c = 6.25 α = 90.15°, β = 93.56°, γ = 82.08°510.29Biaxial (-) nα = 1.423 nβ = 1.439 nγ = 1.444

2V: calculated: 56°

Max birefringence: δ = 0.021

 [23]
Wilcoxite MgAl(SO4)2F · 17H2O2:1triclinicP1a = 6.644, b = 6.749, c = 14.892 α = 79.664°, β = 80.113°, γ = 62.487579.61.58Biaxial (-) nα = 1.424 nβ = 1.436 nγ = 1.438

2V: measured: 48° , calculated: 44°

Max birefringence: δ = 0.014

 [24]
Krasheninnikovite KNa2CaMg(SO4)3F3:1hexagonalP63/mcma = 16.6682 c = 6.9007 Z = 61660.362.68Uniaxial (-) nω = 1.500 nε = 1.492

Max birefringence: δ = 0.008

 [25]
Shuvalovite K2(Ca2Na)(SO4)3F3:1orthorhombicPnmaa = 13.2383 b = 10.3023 c = 8.9909 Z = 41226.222.64biaxial (−), nα = 1.493 nβ = 1.498 nγ = 1.498 2Vmeasured ≤ 20 [26]
Thermessaite-(NH4)(NH4)2AlSO4F31:3orthorhombicPbcna = 11.3005 b = 8.6125 c = 6.8501 Z = 4666.69 [27]

Artificial

nameformulaMWratiosystemspace groupunit cellvolumedensityopticalCASreferences
LiMgFSO41:1triclinicP1a = 5.1623 b = 5.388 c = 7.073 α = 106.68 β=107.40 and γ=97.50° Z=2 [28]
NaMgSO4F1:1monoclinicC2/cZ=4109.8022.84 [29]
Na2AlSO4F31:1monoclinicP2/ca=6.3562 b=6.2899 c=7.1146 β=115.687° Z=2256.332.928 [30]
Li4NH4Al(SO4)2F42:4monoclinicC2/ca=13.6561 b=4.9761 c=13.9919 β=92.135° Z=4950.22.383 [30]
Na4TiF4(SO4)22:4 [31]
β-K3[SO4]F1:1tetragonalI4/mcma= 7.2961 c= 10.854 [32]
α-K3[SO4]F1:1cubicPm3ma≈5.43 ≥585 °C [32]
KMgSO4F178.471:1orthorhombicPna21a=12.973 b=6.4585 c=10.635 Z=8891.12.661colourless [33] [34]
Li6K3Al(SO4)4F44:4triclinicP1a=5.0304 b=9.5690 c=9.7078 α=70.968° β=75.531° γ=75.183° Z=1420.082.554 [30]
sodium calcium sulfapatiteNa6Ca4(SO4)6F26:2
K3Ca2(SO4)3F3:1orthorhombicPn21aa=13.467 b=10.521 c=9.167 Z=41299.9 [35]
[N2C10H12] TiF4SO4378.16?1:4triclinicP1a=8.691 b=9.208 c=9.288 α=68.56 β=84.30 γ=81.59 Z=2              683.61.837colourless [31]
[N2C10H12]TiF2(SO4)2436.22?2:2triclinicP1a=4.5768 b=8.9162 c=10.1236 α=112.888 β=95.196 γ=98.706 Z=1              371.111.952colourless [31]
Rb2TiF2(SO4)2 · 2H2O1:1 [36]
Cs2TiF2(SO4)2 · 3H2O1:1 [36]
[N2C6H16]V(SO4)2F378.272:1monoclinicP21/ca=10.262 b =17.761 c=7.0518 β=93.93 Z=4                 1282.31.959green [31]
Na2VF3SO41:3 [31]
Na3CrF2(SO4)22:2 [31]
LiMnSO4F1:1monoclinica=13.2406 b=6.4082 c=10.0229 β=120.499732.76 [37]
[N2C6H16]2+Mn2F2(SO4)22:2 [31]
Li2MnF3(SO4)1:3pink-brown [38]
(NH4)2MnF3(SO4)1:3pink-brown [38]
Na2MnF3(SO4)1:3pink-brown [38]
Dipotassium trifluorosulfato manganate(III)K2MnF3(SO4)1:3pink-brown [38]
FeFSO4170.911:1monoclinicC2/ca = 7.3037 b = 7.0753 c = 7.3117 β = 119.758°328.0173.461 [39]
K2FeF3SO41:3 [31]
Li3FeF2(SO4)2·H2O2:2 [31]
[N2C6H16]Fe(SO4)2F383.182:1monoclinicP21/ca=10.2220 b=17.6599 c=7.0437 β=93.894 Z=41268.592.006brown [31]
LiFeFSO4177.851:1triclinicP1a = 5.1751 b = 5.4915 c = 7.2211 α = 106.506° β = 107.178° γ=97.865°182.443.237grass green [39]
sodium ferrous sulfate fluorideNaFeFSO4193.911:1monoclinicP21/ca = 6.6739 b = 8.6989 c = 7.1869 β = 113.525°382.5673.366 [39]
sodium ferrous sulfate fluoride dihydrateNaFeFSO4·2H2O1:1monoclinicP21/ma=5.75959 b=7.38273 c=7.25047 β=113.3225283.109white [40]
trisodium ferric disulfate difluorideNa3Fe(SO4)2F22:2orthorhombicPncaa = 6.6419 b = 8.8115 c = 14.0023 [41]
NaCoFSO41:1monoclinicC2/ca=6.6687 b=8.6251 c=7.1444 β=114.323374.46 [42]
NaCoFSO4·2H2O1:1monoclinicP21/ma=5.73364 b=7.31498 c=7.18640 β=113.5028276.40pink [40]
NH4CoFSO4·2H2O1:1 [43]
KCoFSO4·2H2O1:1 [43]
NaNiFSO4·2H2O1:1monoclinicP21/ma=5.70118 b=7.27603 c=7.15634 β=113.8883271.429green [40]
LiZnSO4F1:1orthorhombicPnma7.40357 b=6.32995 c=7.42016347.740 [44]
KZnSO4F219.531:1orthorhombicPna21a=13.0602 b=6.4913 c=10.7106 Z=8908.023.212transparent <190 nm [34]
K2Zn3(SO4)(HSO4)2F41:4orthorhombicCmc21a=17.725 b=7.6650 c=9.7505 Z=41324.73.212colourless [45]
Li4RbAl(SO4)2F42:4monoclinicC2/ca=13.6503 b=4.984 c=14.0081 β=91.509° Z=4948.822.858 [46]
Y(SO4)F203.971:1orthorhombicPnmaa=8.3128, b=6.9255, c=6.3905 Z=4367.903.682 [47]
YSO4F·H2O1:1monoclinicP21/na=4.9707 b=7.306 c=11.493 β =96.95°birefringence 0.0357 at 546 nm [48]
Y2Cu(OH)3(SO4)2F·H2O521.522:1monoclinicP21/na=11.6889, b=6.8660, c=12.5280, β=97.092° Z=4997.83.472blue [47]
KYSO4F21:2monoclinicP21/ma=6.4402 b=5.7784 c=6.992 β=113.684° Z=2238.303.652band gap 7.79 eV; birefringence 0.015 @ 546.1 nm [49]
RbYSO4F21:2monoclinicP21/ma=6.5347 b=5.8212 c=7.1383 β=114.332° Z=2247.424.140band gap 7.82 eV; birefringence 0.02 @ 546.1 nm [49]
Zr2O2F2SO4 · 6H2O1:2 [50]
α-K3ZrF5SO4 · H2O1:5 [36]
K2ZrF4SO41:4 [36]
K2ZrF2(SO4)2 · 2.5H2O2:2 [36]
K3Zr2F9SO4 · 2H2O1:9 [36]
(NH4)3Zr2F9SO4 · 2H2O1:9 [36]
(NH4)2ZrF4SO41:4 [36]
(NH4)2ZrF2(SO4)2 · 2.5H2O2:2 [36]
Rb2ZrF4SO41:4 [36]
Rb2ZrF2(SO4)2 · 3H2O2:2 [36]
Rb3Zr2F9SO4 ·2H2O1:9 [36]
RbZr2O2F(SO4)2 · 5H2O2:1 [36]
Cs2ZrF4SO41:4 [36]
Cs2ZrF2(SO4)2 · 2H2O2:2 [36]
Cs8Zr4F2(SO4)11 · 16H2O11:2 [36]
CsZr2O2F(SO4)2 · 6H2O2:1 [36]
Zr2O2F2SO4 · 5H2O1:2 [36]
triindium trifluoride sulfate ditellurite hydrateIn3(SO4)(TeO3)2F3(H2O)866.741:3orthorhombicP212121a=8.3115 b=9.4341 c=14.80681161.04.959band gap 4.10 eV; white [51]
4,4'-bipyridine distannous difluoride disulfate(C10H10N2)0.5[SnF(SO4)]2:2triclinicP1a=4.726 b=7.935 c=11.203 α = 81.05° β = 87.59° γ=73.70° Z=2398.32.608colourless [52]
diantimony dipotassium hexafluoride sulfateK2SO4·(SbF3)2531.761:6monoclinicP21/ca=9.1962 b=5.6523 c=19.2354 β =103.209 Z=4973.403.629colourless [53]
diantimony dirubidium hexafluoride sulfateRb2SO4·(SbF3)2624.501:6monoclinicP21a=9.405 b=5.7210 c=9.879 β = 103.850 Z=2516.14.018colourless [53]
tetraantimony hexarubidium dodecafluoride trisulfateRb6Sb4F12(SO4)31515.9893:12trigonalP3a=16.9490 c=7.5405 Z=21875.944.026white53168-89-1 [54] [55]
hexaammonium dodecafluorotrisulfatotetraantimonate(III)[NH4]6Sb4F12(SO4)33:12trigonalP3a=17.07 c=7.515 Z=318962.92 [56]
hexarubidium dodecafluorotrisulfatotetraantimonate(III)Rb6Sb4F12(SO4)33:12 [56]
Li4CsAl(SO4)2F42:4monoclinicC2/ca=13.574 b=5.0427 c=14.258 β=91.961° Z=4975.73.103 [46]
tetraantimony hexacaesium dodecafluoride trisulfateCs6Sb4F12(SO4)31800.6013:12triclinicP1a=7.9044 b=10.5139 c=17.3534 al=90.350 β = 90.151 ga=104.797 Z=41394.34.289white53200-54-7 [54] [57]
antimony caesium difluoride sulfateCsSbF2SO4388.721:2orthorhombicPna21a=9.9759 b=11.6616 c=5.2968515.204.19clear, non-linear SH [58]
LiLa2F3(SO4)22:3monoclinicI2/aa = 8.283, b = 6.947, c = 14.209 β = 95.30° Z=4 [59]
CeF2(SO4)1:2orthorhombicPca21a=8.3668 b=6.3600 c=8.3862birefringence 0.361@ 546 nm; SHG 8×KDP [60]
NdFSO4·H2O277.321:1monoclinicP21/na = 4.9948 b = 7.3684 c = 11.6366 β = 96.672° Z=4425.374.330pink [61]
NaPr2F3(SO4)22:3monoclinicI2/aa = 8.223, b = 6.9212, c = 14.199, β = 95.88° Z=4light green [62]
LiEr2F3(SO4)22:3orthorhombicPbcna = 14.791, b = 6.336, c = 8.137 [59]
hexa(triethylenetriammonium) tetrasamarium tetradecasulfate difluoride[C4H16N3]6[Sm4F2(SO4)14]2621.4314:2triclinicP1a = 11.1988 b = 11.4073 c = 16.2666 α = 89.901°, β = 82.406°, γ = 67.757° Z=11903.92.286colourless [61]
TbFSO4·H2O292.001:1monoclinicP21/na = 5.0014 b = 7.377 c = 11.651 β = 96.692° Z=4426.94.543colourless [61]
gadolinium fluoride sulfateGdF[SO4]1:1orthorhombicPnmaa=8.436 b=7.0176 c=6.4338 Z=4 [63]
γ-K2HfF2(SO4)2 · 2H2O2:2 [36]
K2HfF2(SO4)2 · 2.5H2O2:2 [36]
Na6Pb4(SO4)6F26:2 [64]
ThSO4F2.H2O1:2monoclinicP21na = 6.9065 b = 6.9256 c = 10.589 β = 96.755° Z = 4502.98colourless [65]
potassium catena-di—fluoro-difluorotetraoxo-di—sulphato-diuranate(VI) hydrateK2UF2O2(SO4)·H2O1:2monoclinicP21/ca = 9.263 b = 8.672 c = 11.019 β= 101.60° Z = 4867.13.83greenish yellow [66] [67]
(NH4)2[UO2F2(SO4)]triclinicP1a=9.73 b=10.28 c=11.37 α = 107.4°, β = 111.9°, γ =106.9 Z=2greenish yellow [67]
(NH4)6[(UO2)2F4(SO4)3]triclinicP1a=9.35 b=9.85 c=11.25 α = 109.2°, β = 113.1°, γ =102.5 Z=1greenish yellow [67]
Cs2[(UO2)2F4(SO4)]greenish yellow [67]
(NH4)[UO2F(SO4)]triclinicP1a=8.99 b=7.12 c=7.42 α = 114.5°, β = 117.4°, γ =103.2 Z=11.92greenish yellow [67]
RbUO2SO4ForthorhombicPca21a=25.353 b=6.735 c=11.496 Z=12 [68] [69]
[N2C6H16][UO2F2(SO4)]520.291:2triclinicP1a=6.9105 b=9.6605 =10.1033 α=72.6594(14) β=87.068 γ=77.9568 Z=2629.622.744yellow [70]
[N2C6H16][UO2F(SO4)]2884.372:2orthorhombicPmmna=6.9503 b=17.2147 c=7.0867 Z=2847.903.464yellow [70]
[N2C3H12][UO2F(SO4)]2·H2O862.322:2orthorhombicPnmaa=13.5775 b=14.6180 c=8.1168 Z=41610.993.555yellow [70]
[N2C5H14][UO2F(H2O)(SO4)]2907.382:2monoclinicP121/n1a=8.4354 b=15.5581 c=14.8442 β =96.666 Z=41935.03.115yellow [70]
[N2C6H18]2[UO2F(SO4)]4·H2O1792.804:4triclinicP1a=10.8832 b=10.9386 c=16.5325 α=75.6604 β=73.6101 γ=89.7726 Z=21824.733.263yellow [70]
[N2C3H12][UO2F(SO4)]2·H2O864.342:2monoclinicP121/n1a=6.7745 b=8.1589 c=14.3661 β =94.556 Z=2791.543.626yellow [70]
diammonium hydrazinium triuranium(IV) tetrafluoride hexasulfateU4+3F4(SO4)6·2NH4·H3N-NH31436.66:4monoclinicC2/ca=15.2309 b=8.77998 c=18.8590 β=105.5030 Z=42432.694.392green [71]

References

  1. ↑ Avdontceva, Margarita S.; Zolotarev, Andrey A.; Krivovichev, Sergey V. (November 2015). "Order–disorder phase transition in the antiperovskite-type structure of synthetic kogarkoite, Na3SO4F". Journal of Solid State Chemistry. 231: 42–46. Bibcode:2015JSSCh.231...42A. doi:10.1016/j.jssc.2015.07.033.
  2. ↑ de Marignac, Jean Charles (1859). Recherches sur les formes cristallines et la composition chimique de divers sels. p. 221.{{cite book}}: |work= ignored (help)
  3. ↑ "Chukhrovite-(Ca): Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  4. ↑ "Chukhrovite-(Ce): Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  5. ↑ "Chukhrovite-(Y): Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  6. ↑ "Chukhrovite-(Nd): Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  7. ↑ "Pseudograndreefite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  8. ↑ "Creedite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  9. ↑ "Grandreefite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  10. ↑ Yakubovich, O. V.; Steele, I. M.; Chernyshev, V. V.; Zayakina, N. V.; Gamyanin, G. N.; Karimova, O. V. (August 2014). "The crystal structure of arangasite, Al 2 F(PO 4 )(SO 4 )·9H 2 O determined using low-temperature synchrotron data" . Mineralogical Magazine. 78 (4): 889–903. Bibcode:2014MinM...78..889Y. doi:10.1180/minmag.2014.078.4.09. ISSN   0026-461X. S2CID   94078023.
  11. ↑ "Arangasite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-16.
  12. ↑ "Khademite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-16.
  13. ↑ "Kogarkoite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  14. ↑ Pekov, Igor V.; Krzhizhanovskaya, Maria G.; Yapaskurt, Vasiliy O.; Belakovskiy, Dmitry I.; Chukanov, Nikita V.; Lykova, Inna S.; Sidorov, Evgeny G. (2015-07-27). "Kononovite, NaMg(SO4)F, a new mineral from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia" . European Journal of Mineralogy. 27 (4): 575–580. Bibcode:2015EJMin..27..575P. doi:10.1127/ejm/2015/0027-2457. ISSN   0935-1221.
  15. ↑ "Lannonite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  16. ↑ "Sulphohalite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  17. ↑ "Uklonskovite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  18. ↑ "Vlodavetsite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  19. ↑ "Schairerite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  20. ↑ "Galeite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-03.
  21. ↑ "Fluorellestadite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-16.
  22. ↑ "Straßmannite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-16.
  23. ↑ "Svyazhinite: Mineral information, data and localities". www.mindat.org. Retrieved 2020-06-16.
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