Platinum(II) fluoride

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Platinum(II) fluoride
Names
Other names
Platinum difluoride, difluoroplatinum
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
  • InChI=1S/2FH.Pt/h2*1H;/q;;+2/p-2
    Key: FXGFZZYDXMUETH-UHFFFAOYSA-L
  • F[Pt]F
Properties
F2Pt
Molar mass 233.081 g·mol−1
Appearanceyellow crystals
insoluble
Related compounds
Related compounds
 Palladium difluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Platinum(II) fluoride is a binary chemical compound of platinum and fluorine with the chemical formula PtF
2. [1] [2] Some sources claim that its existence is uncertain. [3] [4]

Contents

Synthesis

Effect of fluorine on heated platinum wire at 500-600 °C: [5]

Pt + F2 → PtF2

Physical properties

The compound forms yellow crystals. Insoluble in water.

Chemical properties

Platinum difluoride decomposes under strong heating:

PtF2 → Pt + F2

References

  1. ↑ "Platinum difluoride". NIST . Retrieved 3 May 2023.
  2. ↑ Nikitin, M. I. (1 August 2008). "Thermal behavior of platinum fluorides: III. Platinum difluoride and trifluoride" . Russian Journal of Inorganic Chemistry. 53 (8): 1292–1296. doi:10.1134/S0036023608080238. ISSN   1531-8613. S2CID   93184337 . Retrieved 3 May 2023.
  3. ↑ Macintyre, Jane E. (23 July 1992). Dictionary of Inorganic Compounds. CRC Press. p. 3158. ISBN   978-0-412-30120-9 . Retrieved 3 May 2023.
  4. ↑ McAvoy, J.; Moss, K. C.; Sharp, D. W. A. (1 January 1965). "240. Phosphine and phosphite complexes of platinum(II) fluoride" . Journal of the Chemical Society (Resumed): 1376–1379. doi:10.1039/JR9650001376. ISSN   0368-1769 . Retrieved 3 May 2023.
  5. ↑ "Journal of the Society of Chemical Industry". Society of Chemical Industry (Great Britain). Society of Chemical Industry.: 186 28 February 1890. Retrieved 3 May 2023.
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