Platinum(II) iodide

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Platinum(II) iodide
Beta-PtI2 unit cell.png
beta-PtI2 (at room temperature)
Names
IUPAC name
diiodoplatinum
Other names
Platinum diiodide, platinum(2+) diiodide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.277 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 232-204-2
PubChem CID
UNII
  • InChI=1S/2HI.Pt/h2*1H;/q;;+2/p-2
    Key: ZXDJCKVQKCNWEI-UHFFFAOYSA-L
  • [Pt+2].[I-].[I-]
Properties
I2Pt
Molar mass 448.893 g·mol−1
Appearanceblack crystals
Density 6.403 g/cm3
Melting point 360 °C (680 °F; 633 K)
insoluble
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Platinum(II) iodide is a binary inorganic compound of platinum and iodine with the chemical formula PtI
2
. [1] [2] [3]

Contents

Synthesis

Production of platinum(II) iodide can be by heating of platinum(II) chloride with potassium iodide:

PtCl2 + 2KI → PtI2 + 2KCl

Chemical properties

Platinum(II) iodide decomposes when heated: [4]

Ptl2 → Pt + I2

Physical properties

Platinum(II) iodide forms black crystals [5] of several modifications. It is insoluble in water, ethanol, acetone, or ether, but is soluble in ethylamine and hydrogen iodide. [6]

Potassium tetraiodoplatinate (K2PtI4) is a soluble derivative of PtI2. [7]

Related Research Articles

<span class="mw-page-title-main">Iodine</span> Chemical element with atomic number 53 (I)

Iodine is a chemical element; it has symbol I and atomic number 53. The heaviest of the stable halogens, it exists at standard conditions as a semi-lustrous, non-metallic solid that melts to form a deep violet liquid at 114 °C (237 °F), and boils to a violet gas at 184 °C (363 °F). The element was discovered by the French chemist Bernard Courtois in 1811 and was named two years later by Joseph Louis Gay-Lussac, after the Ancient Greek Ιώδης, meaning 'violet'.

<span class="mw-page-title-main">Lead(II) iodide</span> Chemical compound

Lead(II) iodide is a chemical compound with the formula PbI
2
. At room temperature, it is a bright yellow odorless crystalline solid, that becomes orange and red when heated. It was formerly called plumbous iodide.

<span class="mw-page-title-main">Cadmium chloride</span> Chemical compound

Cadmium chloride is a white crystalline compound of cadmium and chloride, with the formula CdCl2. This salt is a hygroscopic solid that is highly soluble in water and slightly soluble in alcohol. The crystal structure of cadmium chloride (described below), is a reference for describing other crystal structures. Also known are CdCl2•H2O and the hemipentahydrate CdCl2•2.5H2O.

<span class="mw-page-title-main">Sodium iodide</span> Chemical compound

Sodium iodide (chemical formula NaI) is an ionic compound formed from the chemical reaction of sodium metal and iodine. Under standard conditions, it is a white, water-soluble solid comprising a 1:1 mix of sodium cations (Na+) and iodide anions (I) in a crystal lattice. It is used mainly as a nutritional supplement and in organic chemistry. It is produced industrially as the salt formed when acidic iodides react with sodium hydroxide. It is a chaotropic salt.

<span class="mw-page-title-main">Copper(I) iodide</span> Chemical compound

Copper(I) iodide is an inorganic compound with the chemical formula CuI. It is also known as cuprous iodide. It is useful in a variety of applications ranging from organic synthesis to cloud seeding.

<span class="mw-page-title-main">Barium iodide</span> Chemical compound

Barium iodide is an inorganic compound with the formula BaI2. The compound exists as an anhydrous and a hydrate (BaI2(H2O)2), both of which are white solids. When heated, hydrated barium iodide converts to the anhydrous salt. The hydrated form is freely soluble in water, ethanol, and acetone.

<span class="mw-page-title-main">Mercury(II) iodide</span> Chemical compound

Mercury(II) iodide is a chemical compound with the molecular formula HgI2. It is typically produced synthetically but can also be found in nature as the extremely rare mineral coccinite. Unlike the related mercury(II) chloride it is hardly soluble in water (<100 ppm).

<span class="mw-page-title-main">Potassium iodate</span> Chemical compound

Potassium iodate (KIO3) is an ionic inorganic compound with the formula KIO3. It is a white salt that is soluble in water.

<span class="mw-page-title-main">Tellurium tetraiodide</span> Chemical compound

Tellurium tetraiodide (TeI4) is an inorganic chemical compound. It has a tetrameric structure which is different from the tetrameric solid forms of TeCl4 and TeBr4. In TeI4 the Te atoms are octahedrally coordinated and edges of the octahedra are shared.

<span class="mw-page-title-main">Magnesium iodide</span> Chemical compound

Magnesium iodide is an inorganic compound with the chemical formula MgI2. It forms various hydrates MgI2·xH2O. Magnesium iodide is a salt of magnesium and hydrogen iodide. These salts are typical ionic halides, being highly soluble in water.

<span class="mw-page-title-main">Strontium iodide</span> Chemical compound

Strontium iodide is an inorganic compound with the chemical formula SrI2. It is a salt of strontium and iodine. It forms a hexahydrate SrI2·6H2O. It is an ionic, water-soluble, and deliquescent compound that can be used in medicine as a substitute for potassium iodide. It is also used as a scintillation gamma radiation detector, typically doped with europium, due to its optical clarity, relatively high density, high effective atomic number (Z=48), and high scintillation light yield. In recent years, europium-doped strontium iodide (SrI2:Eu2+) has emerged as a promising scintillation material for gamma-ray spectroscopy with extremely high light yield and proportional response, exceeding that of the widely used high performance commercial scintillator LaBr3:Ce3+. Large diameter SrI2 crystals can be grown reliably using vertical Bridgman technique and are being commercialized by several companies.

Germanium iodides are inorganic compound with the formula GeIx. Two such compounds exist: germanium(II) iodide, GeI2, and germanium(IV) iodide GeI4.

<span class="mw-page-title-main">Cobalt(II) iodide</span> Chemical compound

Cobalt(II) iodide or cobaltous iodide are the inorganic compounds with the formula CoI2 and the hexahydrate CoI2(H2O)6. These salts are the principal iodides of cobalt.

<span class="mw-page-title-main">Potassium hexachloroplatinate</span> Chemical compound

Potassium hexachloroplatinate is the inorganic compound with the formula K2PtCl6. It is a yellow solid that is an example of a comparatively insoluble potassium salt. The salt features the hexachloroplatinate(IV) dianion, which has octahedral coordination geometry.

<span class="mw-page-title-main">Platinum tetrafluoride</span> Chemical compound

Platinum tetrafluoride is the inorganic compound with the chemical formula PtF
4
. In the solid state, the compound features platinum(IV) in octahedral coordination geometry.

<span class="mw-page-title-main">Praseodymium(III) iodide</span> Chemical compound

Praseodymium(III) iodide is an inorganic salt, consisting of the rare-earth metal praseodymium and iodine, with the chemical formula PrI3. It forms green crystals. It is soluble in water.

<span class="mw-page-title-main">Dysprosium(III) iodide</span> Chemical compound

Dysprosium(III) iodide is a binary inorganic compound of dysprosium and iodine with the chemical formula DyI
3
.

<span class="mw-page-title-main">Platinum(IV) iodide</span> Chemical compound

Platinum(IV) iodide is a inorganic compound with the formula PtI4. it is a dark brown diamagnetic solid and is one of several binary iodides of platinum.

Ammonium hexafluorogermanate is an inorganic chemical compound with the chemical formula (NH4)2GeF6.

<span class="mw-page-title-main">Potassium tetraiodoplatinate</span> Chemical compound

Potassium tetraiodoplatinate is the inorganic compound with the formula K2PtI4·(H2O)2. It is the potassium salt of tetraiodoplatinate, a square planar complex of platinum(II). The compound crystallizes from water as the dihydrate, whereas the related chloride and bromide K2PtCl4 and K2PtBr4 are obtained only as the anhydrous salts.

References

  1. "Platinum(II) Iodide". American Elements . Retrieved 17 April 2023.
  2. "Platinum(II) iodide". Sigma Aldrich . Retrieved 17 April 2023.
  3. "Platinum(II) iodide | CAS 7790-39-8". Santa Cruz Biotechnology . Retrieved 17 April 2023.
  4. "Platinum(II) iodide, Premion , 99.99% (metals basis), Pt 43.0% min, Thermo Scientific Chemicals | Fisher Scientific". Fisher Scientific . Retrieved 17 April 2023.
  5. Lide, David R. (19 June 2003). CRC Handbook of Chemistry and Physics. CRC Press. p. 4-81. ISBN   978-0-8493-0594-8 . Retrieved 17 April 2023.
  6. "12170 Platinum(II) iodide, Premion®, 99.99% (metals basis), Pt 43.0% min". Alfa Aesar . Retrieved 17 April 2023.
  7. Olsson, Lars-Fride (1989). "Dipotassium Tetraiodoplatinate(II) Dihydrate". Inorganic Syntheses. 25: 98–100. doi:10.1002/9780470132562.ch21.