beta-PtI2 (at room temperature) | |
Names | |
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IUPAC name diiodoplatinum | |
Other names Platinum diiodide, platinum(2+) diiodide | |
Identifiers | |
3D model (JSmol) | |
ChemSpider | |
ECHA InfoCard | 100.029.277 |
EC Number |
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PubChem CID | |
UNII | |
CompTox Dashboard (EPA) | |
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Properties | |
I2Pt | |
Molar mass | 448.893 g·mol−1 |
Appearance | black crystals |
Density | 6.403 g/cm3 |
Melting point | 360 °C (680 °F; 633 K) |
insoluble | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Platinum(II) iodide is a binary inorganic compound of platinum and iodine with the chemical formula PtI
2. [1] [2] [3]
Production of platinum(II) iodide can be by heating of platinum(II) chloride with potassium iodide:
Platinum(II) iodide decomposes when heated: [4]
Platinum(II) iodide forms black crystals [5] of several modifications. It is insoluble in water, ethanol, acetone, or ether, but is soluble in ethylamine and hydrogen iodide. [6]
Potassium tetraiodoplatinate (K2PtI4) is a soluble derivative of PtI2. [7]
Iodine is a chemical element; it has symbol I and atomic number 53. The heaviest of the stable halogens, it exists at standard conditions as a semi-lustrous, non-metallic solid that melts to form a deep violet liquid at 114 °C (237 °F), and boils to a violet gas at 184 °C (363 °F). The element was discovered by the French chemist Bernard Courtois in 1811 and was named two years later by Joseph Louis Gay-Lussac, after the Ancient Greek Ιώδης, meaning 'violet'.
Lead(II) iodide is a chemical compound with the formula PbI
2. At room temperature, it is a bright yellow odorless crystalline solid, that becomes orange and red when heated. It was formerly called plumbous iodide.
Cadmium chloride is a white crystalline compound of cadmium and chloride, with the formula CdCl2. This salt is a hygroscopic solid that is highly soluble in water and slightly soluble in alcohol. The crystal structure of cadmium chloride (described below), is a reference for describing other crystal structures. Also known are CdCl2•H2O and the hemipentahydrate CdCl2•2.5H2O.
Sodium iodide (chemical formula NaI) is an ionic compound formed from the chemical reaction of sodium metal and iodine. Under standard conditions, it is a white, water-soluble solid comprising a 1:1 mix of sodium cations (Na+) and iodide anions (I−) in a crystal lattice. It is used mainly as a nutritional supplement and in organic chemistry. It is produced industrially as the salt formed when acidic iodides react with sodium hydroxide. It is a chaotropic salt.
Copper(I) iodide is an inorganic compound with the chemical formula CuI. It is also known as cuprous iodide. It is useful in a variety of applications ranging from organic synthesis to cloud seeding.
Barium iodide is an inorganic compound with the formula BaI2. The compound exists as an anhydrous and a hydrate (BaI2(H2O)2), both of which are white solids. When heated, hydrated barium iodide converts to the anhydrous salt. The hydrated form is freely soluble in water, ethanol, and acetone.
Mercury(II) iodide is a chemical compound with the molecular formula HgI2. It is typically produced synthetically but can also be found in nature as the extremely rare mineral coccinite. Unlike the related mercury(II) chloride it is hardly soluble in water (<100 ppm).
Potassium iodate (KIO3) is an ionic inorganic compound with the formula KIO3. It is a white salt that is soluble in water.
Tellurium tetraiodide (TeI4) is an inorganic chemical compound. It has a tetrameric structure which is different from the tetrameric solid forms of TeCl4 and TeBr4. In TeI4 the Te atoms are octahedrally coordinated and edges of the octahedra are shared.
Magnesium iodide is an inorganic compound with the chemical formula MgI2. It forms various hydrates MgI2·xH2O. Magnesium iodide is a salt of magnesium and hydrogen iodide. These salts are typical ionic halides, being highly soluble in water.
Strontium iodide is an inorganic compound with the chemical formula SrI2. It is a salt of strontium and iodine. It forms a hexahydrate SrI2·6H2O. It is an ionic, water-soluble, and deliquescent compound that can be used in medicine as a substitute for potassium iodide. It is also used as a scintillation gamma radiation detector, typically doped with europium, due to its optical clarity, relatively high density, high effective atomic number (Z=48), and high scintillation light yield. In recent years, europium-doped strontium iodide (SrI2:Eu2+) has emerged as a promising scintillation material for gamma-ray spectroscopy with extremely high light yield and proportional response, exceeding that of the widely used high performance commercial scintillator LaBr3:Ce3+. Large diameter SrI2 crystals can be grown reliably using vertical Bridgman technique and are being commercialized by several companies.
Germanium iodides are inorganic compound with the formula GeIx. Two such compounds exist: germanium(II) iodide, GeI2, and germanium(IV) iodide GeI4.
Cobalt(II) iodide or cobaltous iodide are the inorganic compounds with the formula CoI2 and the hexahydrate CoI2(H2O)6. These salts are the principal iodides of cobalt.
Potassium hexachloroplatinate is the inorganic compound with the formula K2PtCl6. It is a yellow solid that is an example of a comparatively insoluble potassium salt. The salt features the hexachloroplatinate(IV) dianion, which has octahedral coordination geometry.
Platinum tetrafluoride is the inorganic compound with the chemical formula PtF
4. In the solid state, the compound features platinum(IV) in octahedral coordination geometry.
Praseodymium(III) iodide is an inorganic salt, consisting of the rare-earth metal praseodymium and iodine, with the chemical formula PrI3. It forms green crystals. It is soluble in water.
Dysprosium(III) iodide is a binary inorganic compound of dysprosium and iodine with the chemical formula DyI
3.
Platinum(IV) iodide is a inorganic compound with the formula PtI4. it is a dark brown diamagnetic solid and is one of several binary iodides of platinum.
Ammonium hexafluorogermanate is an inorganic chemical compound with the chemical formula (NH4)2GeF6.
Potassium tetraiodoplatinate is the inorganic compound with the formula K2PtI4·(H2O)2. It is the potassium salt of tetraiodoplatinate, a square planar complex of platinum(II). The compound crystallizes from water as the dihydrate, whereas the related chloride and bromide K2PtCl4 and K2PtBr4 are obtained only as the anhydrous salts.