Praseodymium(III) chloride is the inorganic compound with the formula PrCl3. Like other lanthanide trichlorides, it exists both in the anhydrous and hydrated forms. It is a blue-green solid that rapidly absorbs water on exposure to moist air to form a light green heptahydrate.
Neodymium(III) fluoride is an inorganic chemical compound of neodymium and fluorine with the formula NdF3. It is a purplish pink colored solid with a high melting point.
Praseodymium compounds are compounds formed by the lanthanide metal praseodymium (Pr). In these compounds, praseodymium generally exhibits the +3 oxidation state, such as PrCl3, Pr(NO3)3 and Pr(CH3COO)3. However, compounds with praseodymium in the +2 and +4 oxidation states, and unlike other lanthanides, the +5 oxidation state, are also known.
Neodymium(II) iodide or neodymium diiodide is an inorganic salt of iodine and neodymium the formula NdI2. Neodymium uses the +2 oxidation state in the compound.
Carbide chlorides are mixed anion compounds containing chloride anions and anions consisting entirely of carbon. In these compounds there is no bond between chlorine and carbon. But there is a bond between a metal and carbon. Many of these compounds are cluster compounds, in which metal atoms encase a carbon core, with chlorine atoms surrounding the cluster. The chlorine may be shared between clusters to form polymers or layers. Most carbon chloride compounds contain rare earth elements. Some are known from group 4 elements. The hexatungsten carbon cluster can be oxidised and reduced, and so have different numbers of chlorine atoms included.
Carbide bromides are mixed anion compounds containing bromide and carbide anions. Many carbide bromides are cluster compounds, containing on, two or more carbon atoms in a core, surrounded by a layer of metal atoms, encased in a shell of bromide ions. These ions may be shared between clusters to form chains, double chains or layers.
Carbide iodides are mixed anion compounds containing iodide and carbide anions. Many carbide iodides are cluster compounds, containing one, two or more carbon atoms in a core, surrounded by a layer of metal atoms, and encased in a shell of iodide ions. These ions may be shared between clusters to form chains, double chains or layers.
Germanide halides are compound that include the germanide (Ge4−) anion and a halide such as chloride (Cl−), bromide (Br−) or iodide (I−). They include germanide iodides, germanide bromides or germanide chlorides. They can be considered as mixed anion compounds. They are in the category of tetrelidehalides. Related compounds include the silicide iodides, and carbide iodides.
Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Many europium compounds fluoresce under ultraviolet light due to the excitation of electrons to higher energy levels. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.
Lanthanum(III) iodide is an inorganic compound containing lanthanum and iodine with the chemical formula LaI
3.
Lutetium(III) iodide or lutetium iodide is an inorganic compound consisting of iodine and lutetium, with the chemical formula of LuI3.
Gadolinium diiodide is an inorganic compound, with the chemical formula of GdI2. It is an electride, with the ionic formula of Gd3+(I−)2e−, and therefore not a true gadolinium(II) compound. It is ferromagnetic at 276 K with a saturation magnetization of 7.3 B; it exhibits a large negative magnetoresistance (~70%) at 7 T near room temperature. It can be obtained by reacting gadolinium and gadolinium(III) iodide at a high temperature:
Thulium(III) iodide is an iodide of thulium, with the chemical formula of TmI3. Thulium(III) iodide is used as a component of metal halide lamps.
Holmium(III) iodide is an iodide of holmium, with the chemical formula of HoI3. It is used as a component of metal halide lamps.
Cobalt compounds are chemical compounds formed by cobalt with other elements. In the compound, the most stable oxidation state of cobalt is the +2 oxidation state, and in the presence of specific ligands, there are also stable compounds with +3 valence. In addition, there are cobalt compounds in high oxidation states +4, +5 and low oxidation states -1, 0, +1.
Lutetium compounds are compounds formed by the lanthanide metal lutetium (Lu). In these compounds, lutetium generally exhibits the +3 oxidation state, such as LuCl3, Lu2O3 and Lu2(SO4)3. Aqueous solutions of most lutetium salts are colorless and form white crystalline solids upon drying, with the common exception of the iodide. The soluble salts, such as nitrate, sulfate and acetate form hydrates upon crystallization. The oxide, hydroxide, fluoride, carbonate, phosphate and oxalate are insoluble in water.
Ytterbium(III) iodide is one of ytterbium's iodides, with the chemical formula of YbI3.
Gadolinium oxalate is the oxalate of gadolinium, with the chemical formula Gd2(C2O4)3. Its hydrate can be prepared by the reaction of gadolinium nitrate and oxalic acid.
Samarium oxyiodide is an inorganic compound with the chemical formula SmOI. It can be obtained by reacting samarium(II) iodide with dry oxygen. It is oxidized when heated to 335 °C in air, and starts to generate nSmOI·Sm2O3 (n is 7, 4, 2 respectively) at 460 °C, 560 °C, and 640 °C, and completely transforms at 885 °C for samarium oxide. It can catalyze the rearrangement of propylene oxide derivatives to methyl ketones. It reacts with samarium(III) iodide, sodium iodide, and sodium at 903 K in a tantalum container to obtain black Sm4OI6.
