Ytterbium(II) fluoride

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Ytterbium(II) fluoride
CaF2 polyhedra.png
Names
Other names
Ytterbium difluoride
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
  • InChI=1S/2FH.Yb/h2*1H;/q;;+2/p-2
    Key: DZIGMZRMIWDBCU-UHFFFAOYSA-L
  • [F-].[F-].[Yb+2]
Properties
F2Yb
Molar mass 211.042 g·mol−1
Appearancegray crystals
Density g/cm3
Melting point 1,407 °C (2,565 °F; 1,680 K)
Boiling point 2,380 °C (4,320 °F; 2,650 K)
insoluble
Structure [1]
Fluorite structure
Fm3m (No. 225)
a = 559.93 pm
4
Related compounds
Other anions
Ytterbium(II) chloride
Ytterbium(II) iodide
Other cations
Samarium(II) fluoride
Europium(II) fluoride
Thulium(II) fluoride
Related compounds
Ytterbium(III) fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Ytterbium(II) fluoride is a binary inorganic compound of ytterbium and fluorine with the chemical formula YbF2. [2] [3] [4]

Contents

Synthesis

Ytterbium(II) fluoride can be obtained by reacting ytterbium(III) fluoride with ytterbium or hydrogen.

2YbF3 + Yb → 3YbF2
2YbF3 + H2 → 2YbF2 + 2HF

Physical properties

Ytterbium(II) fluoride is a gray solid and crystallizes in the so-called fluorite type analogous to calcium fluoride with a unit cell a axis of 559.46 pm. In the crystal structure of ytterbium(II) fluoride, the Yb2+ cation is surrounded by eight F anions in the form of a cube, which is tetrahedrally surrounded by four Yb2+. [5]

Related Research Articles

<span class="mw-page-title-main">Terbium</span> Chemical element, symbol Tb and atomic number 65

Terbium is a chemical element; it has symbol Tb and atomic number 65. It is a silvery-white, rare earth metal that is malleable, and ductile. The ninth member of the lanthanide series, terbium is a fairly electropositive metal that reacts with water, evolving hydrogen gas. Terbium is never found in nature as a free element, but it is contained in many minerals, including cerite, gadolinite, monazite, xenotime and euxenite.

<span class="mw-page-title-main">Ytterbium</span> Chemical element, symbol Yb and atomic number 70

Ytterbium is a chemical element; it has symbol Yb and atomic number 70. It is a metal, the fourteenth and penultimate element in the lanthanide series, which is the basis of the relative stability of its +2 oxidation state. Like the other lanthanides, its most common oxidation state is +3, as in its oxide, halides, and other compounds. In aqueous solution, like compounds of other late lanthanides, soluble ytterbium compounds form complexes with nine water molecules. Because of its closed-shell electron configuration, its density, melting point and boiling point are much lower than those of most other lanthanides.

In chemistry, an interhalogen compound is a molecule which contains two or more different halogen atoms and no atoms of elements from any other group.

<span class="mw-page-title-main">Ytterbium(III) oxide</span> Chemical compound

Ytterbium(III) oxide is the chemical compound with the formula Yb2O3. It is one of the more commonly encountered compounds of ytterbium. It occurs naturally in trace amounts in the mineral gadolinite. It was first isolated from this in 1878 by Jean Charles Galissard de Marignac.

<span class="mw-page-title-main">Iron(II) fluoride</span> Chemical compound

Iron(II) fluoride or ferrous fluoride is an inorganic compound with the molecular formula FeF2. It forms a tetrahydrate FeF2·4H2O that is often referred to by the same names. The anhydrous and hydrated forms are white crystalline solids.

<span class="mw-page-title-main">Silver(II) fluoride</span> Chemical compound

Silver(II) fluoride is a chemical compound with the formula AgF2. It is a rare example of a silver(II) compound - silver usually exists in its +1 oxidation state. It is used as a fluorinating agent.

<span class="mw-page-title-main">Iron(III) fluoride</span> Chemical compound

Iron(III) fluoride, also known as ferric fluoride, are inorganic compounds with the formula FeF3(H2O)x where x = 0 or 3. They are mainly of interest by researchers, unlike the related iron(III) chloride. Anhydrous iron(III) fluoride is white, whereas the hydrated forms are light pink.

<span class="mw-page-title-main">Copper(II) fluoride</span> Chemical compound

Copper(II) fluoride is an inorganic compound with the chemical formula CuF2. The anhydrous form is a white, ionic, crystalline, hygroscopic salt with a distorted rutile-type crystal structure, similar to other fluorides of chemical formulae MF2 (where M is a metal). The dihydrate, CuF2·2H2O, is blue in colour.

<span class="mw-page-title-main">Cadmium fluoride</span> Chemical compound

Cadmium fluoride (CdF2) is a mostly water-insoluble source of cadmium used in oxygen-sensitive applications, such as the production of metallic alloys. In extremely low concentrations (ppm), this and other fluoride compounds are used in limited medical treatment protocols. Fluoride compounds also have significant uses in synthetic organic chemistry. The standard enthalpy has been found to be -167.39 kcal. mole−1 and the Gibbs energy of formation has been found to be -155.4 kcal. mole−1, and the heat of sublimation was determined to be 76 kcal. mole−1.

<span class="mw-page-title-main">Ytterbium(III) chloride</span> Chemical compound

Ytterbium(III) chloride (YbCl3) is an inorganic chemical compound. It reacts with NiCl2 to form a very effective catalyst for the reductive dehalogenation of aryl halides. It is poisonous if injected, and mildly toxic by ingestion. It is an experimental teratogen, known to irritate the skin and eyes.

<span class="mw-page-title-main">Ytterbium(II) chloride</span> Chemical compound

Ytterbium(II) chloride (YbCl2) is an inorganic chemical compound. It was first prepared in 1929 by W. K. Klemm and W. Schuth, by reduction of ytterbium(III) chloride, YbCl3, using hydrogen.

Fluorine forms a great variety of chemical compounds, within which it always adopts an oxidation state of −1. With other atoms, fluorine forms either polar covalent bonds or ionic bonds. Most frequently, covalent bonds involving fluorine atoms are single bonds, although at least two examples of a higher order bond exist. Fluoride may act as a bridging ligand between two metals in some complex molecules. Molecules containing fluorine may also exhibit hydrogen bonding. Fluorine's chemistry includes inorganic compounds formed with hydrogen, metals, nonmetals, and even noble gases; as well as a diverse set of organic compounds. For many elements the highest known oxidation state can be achieved in a fluoride. For some elements this is achieved exclusively in a fluoride, for others exclusively in an oxide; and for still others the highest oxidation states of oxides and fluorides are always equal.

Samarium(II) fluoride is one of fluorides of samarium with a chemical formula SmF2. The compound crystalizes in the fluorite structure, and is significantly nonstoichiometric. Along with europium(II) fluoride and ytterbium(II) fluoride, it is one of three known rare earth difluorides, the rest are unstable.

Europium(II) fluoride is an inorganic compound with a chemical formula EuF2. It was first synthesized in 1937.

Ytterbium(III) phosphide is an inorganic compound of ytterbium and phosphorus with the chemical formula YbP. This is one of the phosphides of ytterbium.

<span class="mw-page-title-main">Europium compounds</span> Compounds with at least one europium atom

Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Many europium compounds fluoresce under ultraviolet light due to the excitation of electrons to higher energy levels. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.

Ytterbium compounds are chemical compounds that contain the element ytterbium (Yb). The chemical behavior of ytterbium is similar to that of the rest of the lanthanides. Most ytterbium compounds are found in the +3 oxidation state, and its salts in this oxidation state are nearly colorless. Like europium, samarium, and thulium, the trihalides of ytterbium can be reduced to the dihalides by hydrogen, zinc dust, or by the addition of metallic ytterbium. The +2 oxidation state occurs only in solid compounds and reacts in some ways similarly to the alkaline earth metal compounds; for example, ytterbium(II) oxide (YbO) shows the same structure as calcium oxide (CaO).

Actinium oxyfluoride is an inorganic compound, with the chemical formula AcOF. It is radioactive. It crystallises in a calcium fluoride structure. It can be obtained by reacting actinium fluoride with ammonia and water:

Einsteinium fluoride is a binary inorganic chemical compound of einsteinium and fluorine with the chemical formula EsF3.

Einsteinium(II) chloride is a binary inorganic chemical compound of einsteinium and chlorine with the chemical formula EsCl2.

References

  1. Greis, Ortwin; Haschke, John M. (1982). "Chapter 45 Rare earth fluorides". Handbook on the Physics and Chemistry of Rare Earths Volume 5. Vol. 5. Elsevier. pp. 387–460. doi:10.1016/s0168-1273(82)05008-9. ISBN   9780444863751. ISSN   0168-1273.
  2. Meyer, G.; Morss, L. R. (6 December 2012). Synthesis of Lanthanide and Actinide Compounds. Springer Science & Business Media. p. 57. ISBN   978-94-011-3758-4 . Retrieved 5 April 2023.
  3. Yaws, Carl (6 January 2015). The Yaws Handbook of Physical Properties for Hydrocarbons and Chemicals: Physical Properties for More Than 54,000 Organic and Inorganic Chemical Compounds, Coverage for C1 to C100 Organics and Ac to Zr Inorganics. Gulf Professional Publishing. p. 807. ISBN   978-0-12-801146-1 . Retrieved 5 April 2023.
  4. Macintyre, Jane E. (23 July 1992). Dictionary of Inorganic Compounds. CRC Press. p. 3160. ISBN   978-0-412-30120-9 . Retrieved 5 April 2023.
  5. Reckeweg, Olaf; DiSalvo, Francis J. (1 December 2017). "Single-crystal structure refinement of YbF2 with a remark about YbH2". Zeitschrift für Naturforschung B . 72 (12): 995–998. doi:10.1515/znb-2017-0147. ISSN   1865-7117. S2CID   102902501 . Retrieved 5 April 2023.