Holmium(III) chloride

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Holmium(III) chloride
Aluminium-trichloride-crystal-3D-balls.png
Names
Other names
Holmium trichloride
Holmiumchlorid
Identifiers
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PubChem CID
UNII
Properties
HoCl3
Molar mass 271.289 g/mol
Appearanceyellow crystals
hygroscopic
Density 3.7 g/cm3
Melting point 720 °C (1,328 °F; 993 K) [1]
Boiling point 1,500 °C (2,730 °F; 1,770 K) (decomposes)
dissolves
Structure
Monoclinic, mS16
C12/m1, No. 12
Related compounds
Other anions
Holmium(III) oxide
Other cations
Dysprosium(III) chloride, Erbium(III) chloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Holmium(III) chloride is the inorganic compound with the formula Ho Cl3. It is a common salt but is mainly used in research. It can be used to produce pure holmium. [2] It exhibits the same color-changing behavior seen in holmium oxide, being a yellow in natural lighting and a bright pink color in fluorescent lighting.

Contents

Preparation

The most commonly used method to obtain holmium(III) chloride involves heating a mixture of holmium(III) oxide and ammonium chloride at 200-250 °C: [3]

Ho2O3 + 6 NH4Cl → 2 HoCl3 + 6 NH3 + 2 H2O

The hexahydrate of holmium(III) chloride can be obtained by reaction between holmium and hydrochloric acid: [3]

2 Ho + 6 HCl → 2 HoCl3 + 3 H2

It can also be prepared by the direct reaction between holmium and chlorine: [4]

2 Ho + 3 Cl2 → 2 HoCl3

Properties

Holmium(III) chloride and its hexahydrate are light yellow solids in daylight that are soluble in water. The hexahydrate starts to release water of crystallization at 64 °C. [5] Holmium(III) chloride has a monoclinic crystal structure analogous to that of aluminum(III) chloride. [3] In the solid state it has the YCl3 layer structure. [6]

Related Research Articles

<span class="mw-page-title-main">Holmium</span> Chemical element, symbol Ho and atomic number 67

Holmium is a chemical element with the symbol Ho and atomic number 67. It is a rare-earth element and the eleventh member of the lanthanide series. It is a relatively soft, silvery, fairly corrosion-resistant and malleable metal. Like a lot of other lanthanides, holmium is too reactive to be found in native form, as pure holmium slowly forms a yellowish oxide coating when exposed to air. When isolated, holmium is relatively stable in dry air at room temperature. However, it reacts with water and corrodes readily, and also burns in air when heated.

Iron(III) chloride describes the inorganic compounds with the formula FeCl3(H2O)x. Also called ferric chloride, these compounds are available both in anhydrous and hydrated forms which are both hygroscopic. They are common sources of iron in its +3 oxidation state. The anhydrous derivative is a Lewis acid, while the hydrate is a mild oxidizing agent. It is used as a water cleaner and as an etchant for metals.

Neodymium(III) chloride or neodymium trichloride is a chemical compound of neodymium and chlorine with the formula NdCl3. This anhydrous compound is a mauve-colored solid that rapidly absorbs water on exposure to air to form a purple-colored hexahydrate, NdCl3·6H2O. Neodymium(III) chloride is produced from minerals monazite and bastnäsite using a complex multistage extraction process. The chloride has several important applications as an intermediate chemical for production of neodymium metal and neodymium-based lasers and optical fibers. Other applications include a catalyst in organic synthesis and in decomposition of waste water contamination, corrosion protection of aluminium and its alloys, and fluorescent labeling of organic molecules (DNA).

<span class="mw-page-title-main">Samarium(III) chloride</span> Chemical compound

Samarium(III) chloride, also known as samarium trichloride, is an inorganic compound of samarium and chloride. It is a pale yellow salt that rapidly absorbs water to form a hexahydrate, SmCl3.6H2O. The compound has few practical applications but is used in laboratories for research on new compounds of samarium.

<span class="mw-page-title-main">Europium(III) chloride</span> Chemical compound

Europium(III) chloride is an inorganic compound with the formula EuCl3. The anhydrous compound is a yellow solid. Being hygroscopic it rapidly absorbs water to form a white crystalline hexahydrate, EuCl3·6H2O, which is colourless. The compound is used in research.

<span class="mw-page-title-main">Aluminium chloride</span> Chemical compound

Aluminium chloride, also known as aluminium trichloride, is an inorganic compound with the formula AlCl3. It forms a hexahydrate with the formula [Al(H2O)6]Cl3, containing six water molecules of hydration. Both the anhydrous form and the hexahydrate are colourless crystals, but samples are often contaminated with iron(III) chloride, giving them a yellow colour.

<span class="mw-page-title-main">Cobalt(II) chloride</span> Chemical compound

Cobalt(II) chloride is an inorganic compound of cobalt and chlorine, with the formula CoCl
2
. The compound forms several hydrates CoCl
2
·nH
2
O
, for n = 1, 2, 6, and 9. Claims of the formation of tri- and tetrahydrates have not been confirmed. The anhydrous form is a blue crystalline solid; the dihydrate is purple and the hexahydrate is pink. Commercial samples are usually the hexahydrate, which is one of the most commonly used cobalt compounds in the lab.

<span class="mw-page-title-main">Chromium(III) chloride</span> Chemical compound

Chromium(III) chloride (also called chromic chloride) is an inorganic chemical compound with the chemical formula CrCl3. It forms several hydrates with the formula CrCl3·nH2O, among which are hydrates where n can be 5 (chromium(III) chloride pentahydrate CrCl3·5H2O) or 6 (chromium(III) chloride hexahydrate CrCl3·6H2O). The anhydrous compound with the formula CrCl3 are violet crystals, while the most common form of the chromium(III) chloride are the dark green crystals of hexahydrate, CrCl3·6H2O. Chromium chlorides find use as catalysts and as precursors to dyes for wool.

<span class="mw-page-title-main">Terbium(III,IV) oxide</span> Chemical compound

Terbium(III,IV) oxide, occasionally called tetraterbium heptaoxide, has the formula Tb4O7, though some texts refer to it as TbO1.75. There is some debate as to whether it is a discrete compound, or simply one phase in an interstitial oxide system. Tb4O7 is one of the main commercial terbium compounds, and the only such product containing at least some Tb(IV) (terbium in the +4 oxidation state), along with the more stable Tb(III). It is produced by heating the metal oxalate, and it is used in the preparation of other terbium compounds. Terbium forms three other major oxides: Tb2O3, TbO2, and Tb6O11.

<span class="mw-page-title-main">Erbium(III) chloride</span> Chemical compound

Erbium(III) chloride is a violet solid with the formula ErCl3. It is used in the preparation of erbium metal.

<span class="mw-page-title-main">Gadolinium(III) chloride</span> Chemical compound

Gadolinium(III) chloride, also known as gadolinium trichloride, is GdCl3. It is a colorless, hygroscopic, water-soluble solid. The hexahydrate GdCl3∙6H2O is commonly encountered and is sometimes also called gadolinium trichloride. Gd3+ species are of special interest because the ion has the maximum number of unpaired spins possible, at least for known elements. With seven valence electrons and seven available f-orbitals, all seven electrons are unpaired and symmetrically arranged around the metal. The high magnetism and high symmetry combine to make Gd3+ a useful component in NMR spectroscopy and MRI.

<span class="mw-page-title-main">Holmium(III) oxide</span> Chemical compound

Holmium(III) oxide, or holmium oxide is a chemical compound of a rare-earth element holmium and oxygen with the formula Ho2O3. Together with dysprosium(III) oxide (Dy2O3), holmium oxide is one of the most powerfully paramagnetic substances known. The oxide, also called holmia, occurs as a component of the related erbium oxide mineral called erbia. Typically, the oxides of the trivalent lanthanides coexist in nature, and separation of these components requires specialized methods. Holmium oxide is used in making specialty colored glasses. Glass containing holmium oxide and holmium oxide solutions have a series of sharp optical absorption peaks in the visible spectral range. They are therefore traditionally used as a convenient calibration standard for optical spectrophotometers.

<span class="mw-page-title-main">Vanadium(III) chloride</span> Chemical compound

Vanadium(III) chloride is the inorganic compound with the formula VCl3 which forms the hexahydrate, [VCl2(H2O)4]Cl·2H2O. This hygroscopic purple salt is a common precursor to other vanadium(III) complexes.

Terbium(III) chloride (TbCl3) is a chemical compound. In the solid state TbCl3 has the YCl3 layer structure. Terbium(III) chloride frequently forms a hexahydrate.

<span class="mw-page-title-main">Lutetium(III) chloride</span> Chemical compound

Lutetium(III) chloride or lutetium trichloride is the chemical compound composed of lutetium and chlorine with the formula LuCl3. It forms hygroscopic white monoclinic crystals and also a hydroscopic hexahydrate LuCl3·6H2O. Anhydrous lutetium(III) chloride has the YCl3 (AlCl3) layer structure with octahedral lutetium ions.

<span class="mw-page-title-main">Thulium(III) chloride</span> Chemical compound

Thulium(III) chloride or thulium trichloride is as an inorganic salt composed of thulium and chlorine with the formula TmCl3. It forms yellow crystals. Thulium(III) chloride has the YCl3 (AlCl3) layer structure with octahedral thulium ions. It has been used as a starting material for some exotic nanostructures prepared for NIR photocatalysis.

<span class="mw-page-title-main">Chromium(III) perchlorate</span> Chemical compound

Chromium(III) perchlorate is an inorganic compound with the chemical formula Cr(ClO4)3. It's hexahydrate Cr(ClO4)3·6H2O is a cyan solid that dissolves in water.

<span class="mw-page-title-main">Neodymium compounds</span> Chemical compounds with at least one neodymium atom

Neodymium compounds are compounds formed by the lanthanide metal neodymium (Nd). In these compounds, neodymium generally exhibits the +3 oxidation state, such as NdCl3, Nd2(SO4)3 and Nd(CH3COO)3. Compounds with neodymium in the +2 oxidation state are also known, such as NdCl2 and NdI2. Some neodymium compounds have colors that vary based upon the type of lighting.

Cobalt compounds are chemical compounds formed by cobalt with other elements. In the compound, the most stable oxidation state of cobalt is the +2 oxidation state, and in the presence of specific ligands, there are also stable compounds with +3 valence. In addition, there are cobalt compounds in high oxidation states +4, +5 and low oxidation states -1, 0, +1.

Erbium compounds are compounds containing the element erbium (Er). These compounds are usually dominated by erbium in the +3 oxidation state, although the +2, +1 and 0 oxidation states have also been reported.

References

  1. Lide, David R., ed. (2006). CRC Handbook of Chemistry and Physics (87th ed.). Boca Raton, FL: CRC Press. ISBN   0-8493-0487-3.
  2. Emsley, John (2003). Nature's building blocks: an A-Z guide to the elements (Reprinted with corrections ed.). Oxford: Oxford Univ. Press. ISBN   978-0-19-850340-8.
  3. 1 2 3 Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY.
  4. Webelements: Holmium
  5. Ans, Jan d'; Ans, Jan d' (1998). Elemente, anorganische Verbindungen und Materialien. Taschenbuch für Chemiker und Physiker / D'Ans (4., neubearb. u. rev. Aufl ed.). Ort nicht ermittelbar: Verlag nicht ermittelbar. ISBN   978-3-540-60035-0.
  6. Wells A.F. (1984) Structural Inorganic Chemistry 5th edition Oxford. ISBN   0-19-855370-6