Carbide chloride

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Carbide chlorides are mixed anion compounds containing chloride anions and anions consisting entirely of carbon. In these compounds there is no bond between chlorine and carbon. But there is a bond between a metal and carbon. Many of these compounds are cluster compounds, in which metal atoms encase a carbon core, with chlorine atoms surrounding the cluster. The chlorine may be shared between clusters to form polymers or layers. Most carbon chloride compounds contain rare earth elements. Some are known from group 4 elements. The hexatungsten carbon cluster can be oxidised and reduced, and so have different numbers of chlorine atoms included.

The carbide chlorides are a subset of the halide carbides, with related compounds including the carbide bromides, and carbide iodides. Cluster compounds similar to these carbides, may instead replace carbon with boron, hydrogen, nitrogen or phosphorus.

List

formulasystemspace groupunit cellvolumedensitycommentreference
Ca3C3Cl2orthorhombicCmcma=3.876, b=13.524, c=11.6532.47red [1]
Sc2CCl2P3m1a=3.39977 c=8.8583.24black [2]
Sc5CCl8monoclinicC12/m1a=17.8 b=3.5259 c=12.052 β=130.112.99 [2]
Sc7C2Cl10monoclinicC12/m1a=18.62 b=11.81 β=99.813.04ruby red; moisture sensitive [3] [2]
Ti6CCl14orthorhombicCmcea=12.4592 b=12.2458 c=10.95762.93black [2]
YCClC12/m1a=6.82 b=3.713 c=9.327 β=94.753.85 [2]
Y2C0.7Cl2P3m1a=3.7022 c=9.1953.91silvery grey [2]
Zr6CCl14orthorhombicCmcea=14.091 b=12.595 c=11.5063.43brown red [4] [2]
KZr6CCl15orthorhombicPnmaa=18.489 b=13.909 c=9.690 Z=42492dark red; Zr6C clusters [5]
Rb4Zr6CCl18C2/ma=10.460 b=17.239 c=9.721 β=115.05 Z=2 [6]
Rb[(Zr6C)Cl15]orthorhombicPnmaa=18.484,b= 18.962,c=9.708 Z= 42505.43.12dark red-brown [7]
Cs4[Sc6C]Cl13tetragonalI41/amda = 15.405, c = 10.179 Z=4green black [8]
Cs[(Zr6C)Cl15]orthorhombicPnmaa = 18.513 b = 13.916 c = 9.6383 Z=42483.1dark red [9]
La2CClR3ma=3.878 c=16.915.74coppery red [10]
La2C2ClmonoclinicC12/c1a=14.77 b=4.187 c=6.802 β=101.55.44gold [11] [10]
La3C3Cl2monoclinicC12/c1a=7.771 b=12.962 c=6.91 β=104.35.16gold [10]
La4C2Cl5orthorhombicImmma=3.92 b=7.945 c=19.2974.67black [10]
La4C5Cl2monoclinicC12/m1a=22.57 b=3.91 c=1.019 β=95.695.07gold [10]
La5C2Cl9triclinicP1a=8.645 b=8.706 c=11.925 α=84.97° β=85.78° γ=61.31°4.40red [10]
La6(C2)3Cl4monoclinicP21/ca = 7.770, b = 12.962, c = 6.910 and β = 104.30° Z=2674.45.158gold; sheets of octahedra [12]
La8C8Cl5monoclinicP121/c1a=7.756 b=16.951 c=6.878 β=104.25.24gold [11] [10]
La8(C2)5Cl4monoclinicC2/ma = 22.570, b = 3.9300, c = 10.190 β = 95.69° Z=2899.45.071gold [12]
La11C11Cl7monoclinicP121/c1a=7.77 b=47.038 c=6.901 β=104.285.19gold [10]
La14C14Cl9monoclinicP1C1a=7.775 b=2.9963 c=6.895 β=104.215.19gold [11] [10]
La20C20Cl13monoclinicP121/c1a=7.762 b=42.941 c=6.903 β=104.265.18black [11] [10]
La36C36Cl23monoclinicP121/c1a=7.764 b=77.055 c=6.897 β=104.265.18grey [11] [10]
K[La5(C2)]Cl10monoclinicP21/ca=8.5632, b=15.074, 17.115 β=119.74 Z=41918.33.85light red [13]
Ce2C2ClmonoclinicC12/c1a=14.573, b=4.129, c=6.696, β=101.375.71gold [1]
Ce2(C2)2ClmonoclinicC2/ca = 14.573, b = 4.129, c = 6.696, β = 101.37 ° [14]
Ce3CCl5monoclinicC12/c1a=13.899, b=8.71, c=15.765, β=98.224.29orange [1]
Ce4CCl8monoclinicP1C1a=13.538, b=10.487, c=22.845, β=126.314.35black [10] [15]
Ce5C2Cl9triclinicP1a=8.57, b=8.627, c=11.869, α=84.8, β=85.5, γ=61.29red [1]
Ce6Cl10C2monoclinicC12/c1a= 13.899,b= 8.710,c= 15.765,β= 98.22° Z=41888.9 [16]
Ce8C8Cl5monoclinicP121/c1a=7.669, b=16.784, c=6.798, β=104.055.46gold [11] [1]
Ce18(C2)9Cl11triclinicP1a = 6.771, b = 7.657, c = 18.98,α = 88.90 °, β = 80.32 °, γ = 76.09 ° [14]
Ce26(C2)13Cl16monoclinicP21/ca = 7.664, b = 54.25, c = 6.796, β = 103.98 ° [14]
K[Ce5(C2)]Cl10monoclinicP21/ca=8.4739, b=15.017, c=1639 β=119.76 Z=41871.23.97red [13]
Pr3CCl5monoclinicC12/c1a=13.867 b=8.638 c=15.69 β=97.674.37yellow [2]
Pr4C2Cl5orthorhombicImmma=3.848 b=7.759 c=17.015.00black [2]
Pr5C2Cl9triclinicP1a=8.526 b=8.592 c=11.821 α=84.77 β=85.42 γ=61.264.61brown red [2]
Pr6C2Cl10monoclinicC2/ca = 13.687, b = 8.638, c = 15.690, β = 97.67°yellow to green [17]
Pr8C8Cl5monoclinicC121/c1a=7.617 b=16.689 c=6.769 β=103.945.57gold [2]
Pr11C11Cl7monoclinicP121/c1a=7.612 b=6.127 c=6.761 β=103.925.56gold [2]
Pr14C14Cl9monoclinicP1c1a=7.611 b=29.392 c=6.764 β=103.95.56gold [2]
K{Pr5(C2)}Cl10hexagonalP63/ma=8.426 c=14.894 Z=2915.9dark red [18]
Rb{Pr5(C2)}Cl10hexagonalP63/ma=8.4499, c=14.976 Z=29264.19red; trigonal bipyrmamid of Pr containing a C2 unit [19]
Rb[Nd5(C2)]Cl10hexagonala=08.398, c=14.884.33dark red [13]
Gd2C2ClP3ma=3.6902, c=20.308 [10]
Gd2C2Cl2monoclinicP3m1a=3.7633, c=9.45935.69black; contains C24− [4] [10]
Gd3CCl3cubicI4132a=10.7346.34 [10]
Gd4C2Cl3orthorhombicPnmaa=10.596, b=3.684, c=19.6276.58bronze [10] [20]
Gd5C2Cl9monoclinicP121/c1a=9.182, b=16.12, c=12.886, β=119.864.54black [10]
Gd5C6Cl3monoclinicC12/m12.1507,0.37193,1.5331,90,123.346.25bronze [10]
Gd6C3Cl5monoclinicC12/m1a=16.688,b=3.6969,c=12.824, β=128.266.18grey [10]
Gd10C4Cl17triclinicP1a=8.498, b=9.174, c=11.462, α=104.56, β=95.98, γ=111.354.70black; contains C24− [4] [10]
Gd10C4Cl18triclinicP1a = 8.498, b = 9.174, c = 11.462, α = 104.56°, β = 95.98°, γ = 111.35°, Z = 1contains C24− [21] [4]
[Gd4(C2)](Cl, I)6tetragonalP4/mbma = 13.475, c = 12.125, Z = 2black [22]
Rb2[Gd10(C2)2]Cl19orthorhombica=1.2228, b=2.2347, c=1.38964.31black [23]
Cs2[Gd10(C2)2]Cl19orthorhombica=1.2344, b=2.2434, c=1.39244.41black [23]
Cs3[Tb10(C2)2]Cl21monoclinicC2/cZ = 4; a = 23.187; b = 12.458; c = 15.02; β = 98.13°black [24]
Lu2CCl2R3ma=3.6017, c=27.167.07brown [10]
Lu2CCl2P3m1a= 3.5972, c=9.09257.05 [10]
Cs2Lu[Lu6C]Cl18R3a = 9.817, c = 27.232, Z = 3 [25]
Hf6CCl14orthorhombicCmcea=13.938, b=12.498, c=11.3995.28 [10]
W2CCl8orthorhombicPbcaa=11.96 b=12.156 c=10.95762.83black [2]
W6CCl15monoclinicC121/c1a=9.8831 b=11.8945 c=17.867 β =107.8835.47black [2]
W6CCl16orthorhombicPnmaa=16.637 b=12.958 c=9.7975.29black [2]
W6CCl18P62ca=8.923 c=17.5034.82black [2]
W30C2(Cl,Br)68triclinicP1a = 12.003, b = 14.862, c = 15.792, α = 88.75°, β = 68.85°, γ = 71.19° Z=12472.9black [26]
Li[W6CCl18]hexagonalP63/ma = 8.8648, c = 17.490 Z=21188.2black [27] [28]
(Bu4N)[W6CCl18] [29]
(Me4N)2[W6CCl18] [28]
(Bu4N)2[W6CCl18] [29]
(Bu4N)3[W6CCl18] [29]
Na[W6CCl18]hexagonalP63/ma=8.9592 c=17.5226 Z=21188.2 [28]
Ca[W6CCl18]hexagonalP63/ma=8.9384 c=17.6526 Z=21220.4 [28]
Cu[W6CCl18]triclinicP1a=8.89 b=8.929 c=17.669 α=81.85 β=80.78 γ=60.39 Z=21200.75.025black [30]
Cu(C2H6OS)6[W6CCl18]monoclinicC2/ca=17.333 b=16.011 c=18.082 β=94.61 Z=45001.73.035dark brown [30]
Cu(C2H6OS)4[W6CCl18]2triclinicP1a=9.47 b=12.630 c=13.634 α=104.69° β=90.16° γ=92.99° Z=11575.24.095dark violet [30]
Ag[W6CCl18]hexagonalP63/ma=8.874 c=17.58 Z=21199 [28]
Cs[W6CCl18]·CH3OHorthorhombicP212121a = 9.6957, b =  14.046, c = 20.238 Z=44.623black; W in trigonal prism around C [27]

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References

  1. 1 2 3 4 5 Villars, Pierre; Cenzual, Karin; Gladyshevskii, Roman (2014-12-17). Handbook of Inorganic Substances 2015. Walter de Gruyter GmbH & Co KG. p. 352. ISBN   978-3-11-031174-7.
  2. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 Villars, Pierre; Cenzual, Karin; Gladyshevskii, Roman (2014-12-17). Handbook of Inorganic Substances 2015. Walter de Gruyter GmbH & Co KG. p. 354. ISBN   978-3-11-031174-7.
  3. ↑ Hwu, Shiou-Jyh; Corbett, John D.; Poeppelmeier, Kenneth R. (March 1985). "Interstitial atoms in metal-metal bonded arrays: The synthesis and characterization of heptascandium decachlorodicarbide, Sc7Cl10C2, and comparison with the interstitial-free Sc7Cl10". Journal of Solid State Chemistry. 57 (1): 43–58. doi:10.1016/S0022-4596(85)80059-1.
  4. 1 2 3 4 Miller, Gordon J.; Burdett, Jeremy K.; Schwarz, Christine; Simon, Arndt (November 1986). "Molecular interstitials: an analysis of the gadolinium carbide chloride, Gd2C2Cl2". Inorganic Chemistry. 25 (24): 4437–4444. doi:10.1021/ic00244a031. ISSN   0020-1669.
  5. ↑ Ziebarth, Robin P.; Corbett, John D. (August 1987). "Cation distributions within a cluster framework. Synthesis and structure of the carbon- and boron-centered zirconium cluster compounds KZr6Cl15C and CsKZr6Cl15B". Journal of the American Chemical Society. 109 (16): 4844–4850. doi:10.1021/ja00250a015. ISSN   0002-7863.
  6. ↑ Zhang, Jie; Ziebarth, Robin P.; Corbett, John D. (February 1992). "Two novel phases containing centered, isolated zirconium clusters, Rb4Zr6Cl18C and Li6Zr6Cl18H". Inorganic Chemistry. 31 (4): 614–619. doi:10.1021/ic00030a017. ISSN   0020-1669.
  7. ↑ Rohm, Henning W.; Köckerling, Martin (2008-05-01). "Synthesis and Structure of and Cation Distribution in the Zirconium Cluster Rb[(Zr 6 C)Cl 15 ]". Zeitschrift für Naturforschung B. 63 (5): 507–512. doi: 10.1515/znb-2008-0505 . ISSN   1865-7117. S2CID   197327959.
  8. ↑ Artelt, Holger M.; Schleid, Thomas; Meyer, Gerd (September 1994). "Cs4[Sc6C]Cl13 und Cs4[Pr6(C2)]I13 ? zwei Beispiele für das fehlende Bindeglied bei der Verknüpfung der Baueinheiten [M6Z]X12iX6a". Zeitschrift für anorganische und allgemeine Chemie (in German). 620 (9): 1521–1526. doi:10.1002/zaac.19946200905. ISSN   0044-2313.
  9. ↑ Rohm, Henning W.; Köckerling, Martin (2006-02-15). "Cation distribution in the zirconium chloride cluster phase Cs[(Zr 6 C)Cl 15 ]". Acta Crystallographica Section C Crystal Structure Communications. 62 (2): i19–i20. doi:10.1107/S0108270105043076. ISSN   0108-2701. PMID   16456264.
  10. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 Villars, Pierre; Cenzual, Karin; Gladyshevskii, Roman (2014-12-17). Handbook of Inorganic Substances 2015. Walter de Gruyter GmbH & Co KG. p. 353. ISBN   978-3-11-031174-7.
  11. 1 2 3 4 5 6 Mattausch, Hansjürgen; Simon, Arndt; Kienle, Lorenz; Köhler, Jürgen; Hoch, Constantin; Nuss, Jürgen (December 2008). "Gewellt und eben - La 6 (C 2 )-Oktaederschichten in Lanthancarbidchloriden". Zeitschrift für anorganische und allgemeine Chemie. 634 (15): 2765–2776. doi:10.1002/zaac.200800264.
  12. 1 2 Mattausch, Hansjürgen; Hoch, Constantin; Zheng, Chong; Simon, Arndt (February 2007). "La6(C2)3Cl4 und La8(C2)5Cl4: Schichten und Kanäle aus La6(C2)-Clustern". Zeitschrift für anorganische und allgemeine Chemie (in German). 633 (2): 239–245. doi:10.1002/zaac.200600289.
  13. 1 2 3 Uhrlandt, Stefan; Meyer, Gerd (November 1994). "Trigonal-bipyramidale Cluster mit interstitiellen C2-Hanteln in den Chloriden K[M5(C2)]Cl10 (M = La, Ce, Pr) und Rb[M5(C2)]Cl10 (M = Pr, Nd)". Zeitschrift für anorganische und allgemeine Chemie (in German). 620 (11): 1872–1878. doi:10.1002/zaac.19946201107. ISSN   0044-2313.
  14. 1 2 3 Mattausch, Hansjürgen; Simon, Arndt (July 2011). "Variationen modulo 4-4+, 4+3-3+4-, 4-5+, 5-4+4-5+4-4+ bei Seltenerdcarbidhalogeniden". Zeitschrift für anorganische und allgemeine Chemie. 637 (9): 1093–1100. doi:10.1002/zaac.201100055.
  15. ↑ Schaloske, Manuel C.; Kienle, Lorenz; Hoch, Constantin; Mattausch, Hansjürgen; Kremer, Reinhard K.; Simon, Arndt (May 2009). "The First Structure with Isolated Carbon-Centered Tetrahedra of Rare-Earth Metals - the New Compound Ce 4 CCl 8". Zeitschrift für anorganische und allgemeine Chemie. 635 (6–7): 1023–1029. doi:10.1002/zaac.200801391.
  16. ↑ Schaloske, Manuel C.; Mattausch, Hansjürgen; Simon, Arndt (September 2008). "Crystal structure of hexacerium decachloride dicarbide, Ce6Cl10C2". Zeitschrift für Kristallographie - New Crystal Structures. 223 (3): 189–190. doi: 10.1524/ncrs.2008.0079 . S2CID   93416923.
  17. ↑ Schaloske, Manuel C.; Mattausch, Hansjürgen; Kienle, Lorenz; Simon, Arndt (August 2008). "Pr6C2-Doppeltetraeder in Pr6C2Cl10 und Pr6C2Cl5Br5". Zeitschrift für anorganische und allgemeine Chemie. 634 (9): 1493–1500. doi:10.1002/zaac.200800026.
  18. ↑ Uhrlandt, Stefan; Meyer, Gerd (November 1994). "Trigonal-bipyramidale Cluster mit interstitiellen C2-Hanteln in den Chloriden K[M5(C2)]Cl10 (M = La, Ce, Pr) und Rb[M5(C2)]Cl10 (M = Pr, Nd)". Zeitschrift für anorganische und allgemeine Chemie (in German). 620 (11): 1872–1878. doi:10.1002/zaac.19946201107. ISSN   0044-2313.
  19. ↑ Meyer, Gerd; Uhrlandt, Stefan (September 1993). "The First Trigonal-Bipyramidal Cluster with an Interstitial C2 Unit: [Rb{Pr5(C2)}Cl10]". Angewandte Chemie International Edition in English. 32 (9): 1318–1319. doi:10.1002/anie.199313181. ISSN   0570-0833.
  20. ↑ Bauhofer, Christine; Mattausch, Hansjürgen; Kremer, Reinhard K.; Simon, Arndt (September 1995). "Die Gadoliniumcarbidhalogenide Gd4C2X3 (X = Cl, Br)". Zeitschrift für anorganische und allgemeine Chemie (in German). 621 (9): 1501–1507. doi:10.1002/zaac.19956210911. ISSN   0044-2313.
  21. ↑ Warkentin, E.; Masse, R.; Simon, A. (August 1982). "Gd10C4Cl18 und Gd10C4Cl17, zwei Seltenerdmetall-Clusterverbindungen mit interstitiellen C2-Gruppen". Zeitschrift für anorganische und allgemeine Chemie (in German). 491 (1): 323–336. doi:10.1002/zaac.19824910142. ISSN   0044-2313.
  22. ↑ Ließ, Henning; Meyer, H.-Jürgen; Meyer, Gerd (March 1996). "[Gd4(C2)](Cl, I)6, an Interstitially Stabilized Heteroleptic Gadolinium Sesquihalide". Zeitschrift für anorganische und allgemeine Chemie (in German). 622 (3): 494–500. doi:10.1002/zaac.19966220318. ISSN   0044-2313.
  23. 1 2 Ließ, Henning; Steffen, Frank; Meyer, Gerd (January 1997). "Quaternary chlorides and bromides with interstitially stabilized double octahedra, A2[Gd10(C2)2]Cl19 (A = Rb, Cs), A2[Gd10(C2)2]Br19 (A = K,Rb), Rb2[Tb10(C2)2]Br19, and K2[Gd10(C2)2]Br20". Journal of Alloys and Compounds. 246 (1–2): 242–247. doi:10.1016/S0925-8388(96)02476-0.
  24. ↑ Artelt, Holger M.; Meyer, Gerd (September 1994). "Cs3[Tb10(C2)2]Cl21, ein neuer Formel- und Strukturtyp mit isolierten, dimeren Clustern". Zeitschrift für anorganische und allgemeine Chemie (in German). 620 (9): 1527–1531. doi:10.1002/zaac.19946200906. ISSN   0044-2313.
  25. ↑ Meyer, Gerd (December 1992). "Cs[Er6C]I12 und Cs2Lu[Lu6C]Cl18: Beispiele für quaternäre reduzierte Halogenide der Lanthanide mit isolierten "Clustern"". Zeitschrift für anorganische und allgemeine Chemie (in German). 618 (12): 18–25. doi:10.1002/zaac.19926180104. ISSN   0044-2313.
  26. ↑ Ströbele, Markus; Meyer, H.-Jürgen (2010-07-05). "The Trigonal Prismatic Cluster Compound W 6 CCl 15 and a Carambolage of Tungsten Clusters in the Structure of the Heteroleptic Cluster Compound W 30 C 2 (Cl,Br) 68". Inorganic Chemistry. 49 (13): 5986–5991. doi:10.1021/ic100516t. ISSN   0020-1669. PMID   20521794.
  27. 1 2 Weisser, Martina; Ströbele, Markus; Meyer, H.-Jürgen (November 2005). "A synthesis route for carbon-centered triprismo-hexatungsten cluster compounds and the crystal structure of Cs[W6CCl18]·CH3OH". Comptes Rendus Chimie. 8 (11–12): 1820–1826. doi:10.1016/j.crci.2005.02.034.
  28. 1 2 3 4 5 Weisser, Martina; Burgert, Ralf; Schnöckel, Hansgeorg; Meyer, H.-Jürgen (April 2008). "Synthese und Untersuchung von kohlenstoff- und stickstoffzentrierten (Z) trigonal-prismatischen Wolframclustern des Formeltyps A[W6ZCl18]". Zeitschrift für anorganische und allgemeine Chemie (in German). 634 (4): 633–640. doi:10.1002/zaac.200700474.
  29. 1 2 3 Welch, Eric J.; Crawford, Nathan R. M.; Bergman, Robert G.; Long, Jeffrey R. (2003-09-01). "New Routes to Transition Metal-Carbido Species: Synthesis and Characterization of the Carbon-Centered Trigonal Prismatic Clusters [W 6 CCl 18 ] n - ( n = 1, 2, 3)". Journal of the American Chemical Society. 125 (38): 11464–11465. doi:10.1021/ja035962v. ISSN   0002-7863. PMID   13129326.
  30. 1 2 3 Mos, Agnieszka; Ströbele, Markus; Meyer, H.-Jürgen (October 2015). "Carbon Centered Trigonal Prismatic Tungsten Clusters [W 6 CCl 18 ] n- ( n = 1, 2) containing Copper(I) and Copper(II): Tungsten Clusters [W 6 CCl 18 ] n- ( n = 1, 2) with Copper(I) and (II)". Zeitschrift für anorganische und allgemeine Chemie. 641 (12–13): 2245–2249. doi:10.1002/zaac.201500571.
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