|Other names |
3D model (JSmol)
|E number||E290 (preservatives)|
|UN number||1013 (gas), 1845 (solid)|
CompTox Dashboard (EPA)
|Molar mass||44.009 g·mol−1|
|Melting point||−56.6 °C; −69.8 °F; 216.6 K(triple point at 5.1 atm)|
|Critical point (T, P)||31.1 °C (304.2 K), 7.38 megapascals (73.8 bar)|
|−78.5 °C; −109.2 °F; 194.7 K (1 atm)|
|1.45 g/L at 25 °C (77 °F), 100 kPa|
|Vapor pressure||5.73 MPa (20 °C)|
|Acidity (pKa)||6.35, 10.33|
|Thermal conductivity||0.01662 W·m-1·K-1 (300 K)|
Refractive index (nD)
Heat capacity (C)
Std enthalpy of
|V03AN02 ( WHO )|
|Safety data sheet||See: data page |
|NFPA 704 (fire diamond)|
|Lethal dose or concentration (LD, LC):|
LCLo (lowest published)
|90,000 ppm (human, 5 min)|
|NIOSH (US health exposure limits):|
|TWA 5000 ppm (9000 mg/m3)|
|TWA 5000 ppm (9000 mg/m3), ST 30,000 ppm (54,000 mg/m3)|
IDLH (Immediate danger)
|Supplementary data page|
| Refractive index (n),|
Dielectric constant (εr), etc.
| Phase behaviour |
|UV, IR, NMR, MS|
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Carbon dioxide (chemical formula CO
2) is a colorless gas with a density about 60% higher than that of dry air. Carbon dioxide consists of a carbon atom covalently double bonded to two oxygen atoms. It occurs naturally in Earth's atmosphere as a trace gas. The current concentration is about 0.04% (412 ppm) by volume, having risen from pre-industrial levels of 280 ppm. Natural sources include volcanoes, hot springs and geysers, and it is freed from carbonate rocks by dissolution in water and acids. Because carbon dioxide is soluble in water, it occurs naturally in groundwater, rivers and lakes, ice caps, glaciers and seawater. It is present in deposits of petroleum and natural gas. Carbon dioxide is odorless at normally encountered concentrations, but at high concentrations, it has a sharp and acidic odor. At such concentrations it generates the taste of soda water in the mouth.
As the source of available carbon in the carbon cycle, atmospheric carbon dioxide is the primary carbon source for life on Earth and its concentration in Earth's pre-industrial atmosphere since late in the Precambrian has been regulated by photosynthetic organisms and geological phenomena. Plants, algae and cyanobacteria use light energy to photosynthesize carbohydrate from carbon dioxide and water, with oxygen produced as a waste product.
2 is produced by all aerobic organisms when they metabolize carbohydrates and lipids to produce energy by respiration. It is returned to water via the gills of fish and to the air via the lungs of air-breathing land animals, including humans. Carbon dioxide is produced during the processes of decay of organic materials and the fermentation of sugars in bread, beer and wine making. It is produced by combustion of wood and other organic materials and fossil fuels such as coal, peat, petroleum and natural gas. It is an unwanted byproduct in many large scale oxidation processes, for example, in the production of acrylic acid (over 5 million tons/year).
It is a versatile industrial material, used, for example, as an inert gas in welding and fire extinguishers, as a pressurizing gas in air guns and oil recovery, as a chemical feedstock and as a supercritical fluid solvent in decaffeination of coffee and supercritical drying. CO
2, known as dry ice is used as a refrigerant and as an abrasive in dry-ice blasting. It is a feedstock for the synthesis of fuels and chemicals.
Carbon dioxide is the most significant long-lived greenhouse gas in Earth's atmosphere. Since the Industrial Revolution anthropogenic emissions – primarily from use of fossil fuels and deforestation – have rapidly increased its concentration in the atmosphere, leading to global warming. Carbon dioxide also causes ocean acidification because it dissolves in water to form carbonic acid.
Carbon dioxide was the first gas to be described as a discrete substance. In about 1640,the Flemish chemist Jan Baptist van Helmont observed that when he burned charcoal in a closed vessel, the mass of the resulting ash was much less than that of the original charcoal. His interpretation was that the rest of the charcoal had been transmuted into an invisible substance he termed a "gas" or "wild spirit" (spiritus sylvestris).
The properties of carbon dioxide were further studied in the 1750s by the Scottish physician Joseph Black. He found that limestone (calcium carbonate) could be heated or treated with acids to yield a gas he called "fixed air." He observed that the fixed air was denser than air and supported neither flame nor animal life. Black also found that when bubbled through limewater (a saturated aqueous solution of calcium hydroxide), it would precipitate calcium carbonate. He used this phenomenon to illustrate that carbon dioxide is produced by animal respiration and microbial fermentation. In 1772, English chemist Joseph Priestley published a paper entitled Impregnating Water with Fixed Air in which he described a process of dripping sulfuric acid (or oil of vitriol as Priestley knew it) on chalk in order to produce carbon dioxide, and forcing the gas to dissolve by agitating a bowl of water in contact with the gas.
Carbon dioxide was first liquefied (at elevated pressures) in 1823 by Humphry Davy and Michael Faraday. CO
The carbon dioxide molecule is linear and centrosymmetric at equilibrium. The carbon–oxygen bond length is 116.3 pm, noticeably shorter than the bond length of a C–O single bond and even shorter than most other C–O multiply-bonded functional groups. Since it is centrosymmetric, the molecule has no electrical dipole. Consequently, only two vibrational bands are observed in the IR spectrum – an antisymmetric stretching mode at wavenumber 2349 cm−1 and a degenerate pair of bending modes at 667 cm−1 (wavelength 15 μm). There is also a symmetric stretching mode at 1388 cm−1 which is only observed in the Raman spectrum. In a gas phase sample of carbon dioxide, none of the molecules are linear as a result of the vibrational motions. This is shown both by theory and by Coulomb explosion imaging experiments.
Carbon dioxide is soluble in water, in which it reversibly forms H
3 (carbonic acid), which is a weak acid since its ionization in water is incomplete.
The hydration equilibrium constant of carbonic acid is (at 25 °C). Hence, the majority of the carbon dioxide is not converted into carbonic acid, but remains as CO
2 molecules, not affecting the pH.
The relative concentrations of CO
3, and the deprotonated forms HCO−
3 (bicarbonate) and CO2−
3(carbonate) depend on the pH. As shown in a Bjerrum plot, in neutral or slightly alkaline water (pH > 6.5), the bicarbonate form predominates (>50%) becoming the most prevalent (>95%) at the pH of seawater. In very alkaline water (pH > 10.4), the predominant (>50%) form is carbonate. The oceans, being mildly alkaline with typical pH = 8.2–8.5, contain about 120 mg of bicarbonate per liter.
Being diprotic, carbonic acid has two acid dissociation constants, the first one for the dissociation into the bicarbonate (also called hydrogen carbonate) ion (HCO3−):
This is the true first acid dissociation constant, defined as , where the denominator includes only covalently bound H2CO3 and does not include hydrated CO
2(aq). The much smaller and often-quoted value near 4.16×10−7 is an apparent value calculated on the (incorrect) assumption that all dissolved CO
2 is present as carbonic acid, so that . Since most of the dissolved CO
2 remains as CO
2 molecules, Ka1(apparent) has a much larger denominator and a much smaller value than the true Ka1.
The bicarbonate ion is an amphoteric species that can act as an acid or as a base, depending on pH of the solution. At high pH, it dissociates significantly into the carbonate ion (CO32−):
In organisms carbonic acid production is catalysed by the enzyme, carbonic anhydrase.
2 is a potent electrophile having an electrophilic reactivity that is comparable to benzaldehyde or strong α,β-unsaturated carbonyl compounds. However, unlike electrophiles of similar reactivity, the reactions of nucleophiles with CO
2 are thermodynamically less favored and are often found to be highly reversible. Only very strong nucleophiles, like the carbanions provided by Grignard reagents and organolithium compounds react with CO
2 to give carboxylates:
In metal carbon dioxide complexes, CO
2 serves as a ligand, which can facilitate the conversion of CO
2 to other chemicals.
The reduction of CO
2 to CO is ordinarily a difficult and slow reaction:
Photoautotrophs (i.e. plants and cyanobacteria) use the energy contained in sunlight to photosynthesize simple sugars from CO
2 absorbed from the air and water:
The redox potential for this reaction near pH 7 is about −0.53 V versus the standard hydrogen electrode. The nickel-containing enzyme carbon monoxide dehydrogenase catalyses this process.
Carbon dioxide is colorless. At low concentrations the gas is odorless; however, at sufficiently-high concentrations, it has a sharp, acidic odor. kg/m3, about 1.67 times that of air.At standard temperature and pressure, the density of carbon dioxide is around 1.98
Carbon dioxide has no liquid state at pressures below 5.1 standard atmospheres (520 kPa). At 1 atmosphere (near mean sea level pressure), the gas deposits directly to a solid at temperatures below −78.5 °C (−109.3 °F; 194.7 K) and the solid sublimes directly to a gas above −78.5 °C. In its solid state, carbon dioxide is commonly called dry ice.
Liquid carbon dioxide forms only at pressures above 5.1 atm; the triple point of carbon dioxide is about 5.1 bar (517 kPa) at 217 K (see phase diagram). The critical point is 7.38 MPa at 31.1 °C. Another form of solid carbon dioxide observed at high pressure is an amorphous glass-like solid. This form of glass, called carbonia , is produced by supercooling heated CO
2 at extreme pressure (40–48 GPa or about 400,000 atmospheres) in a diamond anvil. This discovery confirmed the theory that carbon dioxide could exist in a glass state similar to other members of its elemental family, like silicon (silica glass) and germanium dioxide. Unlike silica and germania glasses, however, carbonia glass is not stable at normal pressures and reverts to gas when pressure is released.
At temperatures and pressures above the critical point, carbon dioxide behaves as a supercritical fluid known as supercritical carbon dioxide. In this state it is starting (as of 2018) to be used for power generation.
Carbon dioxide can be obtained by distillation from air, but the method is inefficient. Industrially, carbon dioxide is predominantly an unrecovered waste product, produced by several methods which may be practiced at various scales.
The combustion of all carbon-based fuels, such as methane (natural gas), petroleum distillates (gasoline, diesel, kerosene, propane), coal, wood and generic organic matter produces carbon dioxide and, except in the case of pure carbon, water. As an example, the chemical reaction between methane and oxygen:
It is produced by thermal decomposition of limestone, CaCO
3 by heating (calcining) at about 850 °C (1,560 °F), in the manufacture of quicklime (calcium oxide, CaO), a compound that has many industrial uses:
Iron is reduced from its oxides with coke in a blast furnace, producing pig iron and carbon dioxide:
Carbon dioxide is a byproduct of the industrial production of hydrogen by steam reforming and the water gas shift reaction in ammonia production. These processes begin with the reaction of water and natural gas (mainly methane).This is a major source of food-grade carbon dioxide for use in carbonation of beer and soft drinks, and is also used for stunning animals such as poultry. In the summer of 2018 a shortage of carbon dioxide for these purposes arose in Europe due to the temporary shut-down of several ammonia plants for maintenance.
Acids liberate CO
2 from most metal carbonates. Consequently, it may be obtained directly from natural carbon dioxide springs, where it is produced by the action of acidified water on limestone or dolomite. The reaction between hydrochloric acid and calcium carbonate (limestone or chalk) is shown below:
The carbonic acid (H
3) then decomposes to water and CO
Such reactions are accompanied by foaming or bubbling, or both, as the gas is released. They have widespread uses in industry because they can be used to neutralize waste acid streams.
Carbon dioxide is a by-product of the fermentation of sugar in the brewing of beer, whisky and other alcoholic beverages and in the production of bioethanol. Yeast metabolizes sugar to produce CO
2 and ethanol, also known as alcohol, as follows:
All aerobic organisms produce CO
2 when they oxidize carbohydrates, fatty acids, and proteins. The large number of reactions involved are exceedingly complex and not described easily. Refer to (cellular respiration, anaerobic respiration and photosynthesis). The equation for the respiration of glucose and other monosaccharides is:
Anaerobic organisms decompose organic material producing methane and carbon dioxide together with traces of other compounds.Regardless of the type of organic material, the production of gases follows well defined kinetic pattern. Carbon dioxide comprises about 40–45% of the gas that emanates from decomposition in landfills (termed "landfill gas"). Most of the remaining 50–55% is methane.
Carbon dioxide is used by the food industry, the oil industry, and the chemical industry.The compound has varied commercial uses but one of its greatest uses as a chemical is in the production of carbonated beverages; it provides the sparkle in carbonated beverages such as soda water, beer and sparkling wine.
This section needs expansion. You can help by adding to it.(July 2014)
In the chemical industry, carbon dioxide is mainly consumed as an ingredient in the production of urea, with a smaller fraction being used to produce methanol and a range of other products. CO
2 by the Kolbe-Schmitt reaction.
In addition to conventional processes using CO
2 for chemical production, electrochemical methods are also being explored at a research level. In particular, the use of renewable energy for production of fuels from CO
2 (such as methanol) is attractive as this could result in fuels that could be easily transported and used within conventional combustion technologies but have no net CO
Carbon dioxide is a food additive used as a propellant and acidity regulator in the food industry. It is approved for usage in the EU(listed as E number E290), US and Australia and New Zealand (listed by its INS number 290).
A candy called Pop Rocks is pressurized with carbon dioxide gasat about 4 × 106 Pa (40 bar, 580 psi). When placed in the mouth, it dissolves (just like other hard candy) and releases the gas bubbles with an audible pop.
Leavening agents cause dough to rise by producing carbon dioxide.Baker's yeast produces carbon dioxide by fermentation of sugars within the dough, while chemical leaveners such as baking powder and baking soda release carbon dioxide when heated or if exposed to acids.
Carbon dioxide is used to produce carbonated soft drinks and soda water. Traditionally, the carbonation of beer and sparkling wine came about through natural fermentation, but many manufacturers carbonate these drinks with carbon dioxide recovered from the fermentation process. In the case of bottled and kegged beer, the most common method used is carbonation with recycled carbon dioxide. With the exception of British real ale, draught beer is usually transferred from kegs in a cold room or cellar to dispensing taps on the bar using pressurized carbon dioxide, sometimes mixed with nitrogen.
The taste of soda water (and related taste sensations in other carbonated beverages) is an effect of the dissolved carbon dioxide rather than the bursting bubbles of the gas. Carbonic anhydrase 4 converts to carbonic acid leading to a sour taste, and also the dissolved carbon dioxide induces a somatosensory response.
Carbon dioxide in the form of dry ice is often used during the cold soak phase in winemaking to cool clusters of grapes quickly after picking to help prevent spontaneous fermentation by wild yeast. The main advantage of using dry ice over water ice is that it cools the grapes without adding any additional water that might decrease the sugar concentration in the grape must, and thus the alcohol concentration in the finished wine. Carbon dioxide is also used to create a hypoxic environment for carbonic maceration, the process used to produce Beaujolais wine.
Carbon dioxide is sometimes used to top up wine bottles or other storage vessels such as barrels to prevent oxidation, though it has the problem that it can dissolve into the wine, making a previously still wine slightly fizzy. For this reason, other gases such as nitrogen or argon are preferred for this process by professional wine makers.
Carbon dioxide is often used to "stun" animals before slaughter."Stunning" may be a misnomer, as the animals are not knocked out immediately and may suffer distress.
It is one of the most commonly used compressed gases for pneumatic (pressurized gas) systems in portable pressure tools. Carbon dioxide is also used as an atmosphere for welding, although in the welding arc, it reacts to oxidize most metals. Use in the automotive industry is common despite significant evidence that welds made in carbon dioxide are more brittle than those made in more inert atmospheres.[ citation needed ] It is used as a welding gas primarily because it is much less expensive than more inert gases such as argon or helium.[ citation needed ] When used for MIG welding, CO
2 use is sometimes referred to as MAG welding, for Metal Active Gas, as CO
2 can react at these high temperatures. It tends to produce a hotter puddle than truly inert atmospheres, improving the flow characteristics. Although, this may be due to atmospheric reactions occurring at the puddle site. This is usually the opposite of the desired effect when welding, as it tends to embrittle the site, but may not be a problem for general mild steel welding, where ultimate ductility is not a major concern.
It is used in many consumer products that require pressurized gas because it is inexpensive and nonflammable, and because it undergoes a phase transition from gas to liquid at room temperature at an attainable pressure of approximately 60 bar (870 psi, 59 atm), allowing far more carbon dioxide to fit in a given container than otherwise would. Life jackets often contain canisters of pressured carbon dioxide for quick inflation. Aluminium capsules of CO
2 are also sold as supplies of compressed gas for air guns, paintball markers/guns, inflating bicycle tires, and for making carbonated water. Rapid vaporization of liquid carbon dioxide is used for blasting in coal mines.[ citation needed ] High concentrations of carbon dioxide can also be used to kill pests. Liquid carbon dioxide is used in supercritical drying of some food products and technological materials, in the preparation of specimens for scanning electron microscopy and in the decaffeination of coffee beans.
Carbon dioxide can be used to extinguish flames by flooding the environment around the flame with the gas. It does not itself react to extinguish the flame, but starves the flame of oxygen by displacing it. Some fire extinguishers, especially those designed for electrical fires, contain liquid carbon dioxide under pressure. Carbon dioxide extinguishers work well on small flammable liquid and electrical fires, but not on ordinary combustible fires, because although it excludes oxygen, it does not cool the burning substances significantly and when the carbon dioxide disperses they are free to catch fire upon exposure to atmospheric oxygen. Their desirability in electrical fire stems from the fact that, unlike water or other chemical based methods, Carbon dioxide will not cause short circuits, leading to even more damage to equipment. Because it is a gas, it is also easy to dispense large amounts of the gas automatically in IT infrastructure rooms, where the fire itself might be hard to reach with more immediate methods because it is behind rack doors and inside of cases. Carbon dioxide has also been widely used as an extinguishing agent in fixed fire protection systems for local application of specific hazards and total flooding of a protected space. CO
2 systems identified 51 incidents between 1975 and the date of the report (2000), causing 72 deaths and 145 injuries.
Liquid carbon dioxide is a good solvent for many lipophilic organic compounds and is used to remove caffeine from coffee.Carbon dioxide has attracted attention in the pharmaceutical and other chemical processing industries as a less toxic alternative to more traditional solvents such as organochlorides. It is also used by some dry cleaners for this reason (see green chemistry). It is used in the preparation of some aerogels because of the properties of supercritical carbon dioxide.
Plants require carbon dioxide to conduct photosynthesis. The atmospheres of greenhouses may (if of large size, must) be enriched with additional CO
2 to sustain and increase the rate of plant growth. At very high concentrations (100 times atmospheric concentration, or greater), carbon dioxide can be toxic to animal life, so raising the concentration to 10,000 ppm (1%) or higher for several hours will eliminate pests such as whiteflies and spider mites in a greenhouse.
In medicine, up to 5% carbon dioxide (130 times atmospheric concentration) is added to oxygen for stimulation of breathing after apnea and to stabilize the O
2 balance in blood.
Carbon dioxide can be mixed with up to 50% oxygen, forming an inhalable gas; this is known as Carbogen and has a variety of medical and research uses.
Carbon dioxide is used in enhanced oil recovery where it is injected into or adjacent to producing oil wells, usually under supercritical conditions, when it becomes miscible with the oil. This approach can increase original oil recovery by reducing residual oil saturation by between 7% to 23% additional to primary extraction.It acts as both a pressurizing agent and, when dissolved into the underground crude oil, significantly reduces its viscosity, and changing surface chemistry enabling the oil to flow more rapidly through the reservoir to the removal well. In mature oil fields, extensive pipe networks are used to carry the carbon dioxide to the injection points.
In enhanced coal bed methane recovery, carbon dioxide would be pumped into the coal seam to displace methane, as opposed to current methods which primarily rely on the removal of water (to reduce pressure) to make the coal seam release its trapped methane.
It has been proposed that CO
2 from power generation be bubbled into ponds to stimulate growth of algae that could then be converted into biodiesel fuel. A strain of the cyanobacterium Synechococcus elongatus has been genetically engineered to produce the fuels isobutyraldehyde and isobutanol from CO
2 using photosynthesis.
Liquid and solid carbon dioxide are important refrigerants, especially in the food industry, where they are employed during the transportation and storage of ice cream and other frozen foods. Solid carbon dioxide is called "dry ice" and is used for small shipments where refrigeration equipment is not practical. Solid carbon dioxide is always below −78.5 °C (−109.3 °F) at regular atmospheric pressure, regardless of the air temperature.
Liquid carbon dioxide (industry nomenclature R744 or R-744) was used as a refrigerant prior to the discovery of R-12 and may enjoy a renaissance due to the fact that R134a contributes to climate change more than CO
2 does. Its physical properties are highly favorable for cooling, refrigeration, and heating purposes, having a high volumetric cooling capacity. Due to the need to operate at pressures of up to 130 bar (1880 psi), CO
2 systems require highly resistant components that have already been developed for mass production in many sectors. In automobile air conditioning, in more than 90% of all driving conditions for latitudes higher than 50°, R744 operates more efficiently than systems using R134a. Its environmental advantages (GWP of 1, non-ozone depleting, non-toxic, non-flammable) could make it the future working fluid to replace current HFCs in cars, supermarkets, and heat pump water heaters, among others. Coca-Cola has fielded CO
2-based beverage coolers and the U.S. Army is interested in CO
2 refrigeration and heating technology.
The global automobile industry is expected to decide on the next-generation refrigerant in car air conditioning. CO
2 is one discussed option.(see Sustainable automotive air conditioning)
Carbon dioxide is the lasing medium in a carbon dioxide laser, which is one of the earliest type of lasers.
Carbon dioxide can be used as a means of controlling the pH of swimming pools,by continuously adding gas to the water, thus keeping the pH from rising. Among the advantages of this is the avoidance of handling (more hazardous) acids. Similarly, it is also used in the maintaining reef aquaria, where it is commonly used in calcium reactors to temporarily lower the pH of water being passed over calcium carbonate in order to allow the calcium carbonate to dissolve into the water more freely where it is used by some corals to build their skeleton.
Used as the primary coolant in the British advanced gas-cooled reactor for nuclear power generation.
Carbon dioxide induction is commonly used for the euthanasia of laboratory research animals. Methods to administer CO
2 include placing animals directly into a closed, prefilled chamber containing CO
2, or exposure to a gradually increasing concentration of CO
2. In 2013, the American Veterinary Medical Association issued new guidelines for carbon dioxide induction, stating that a displacement rate of 10% to 30% of the gas chamber volume per minute is optimal for the humane euthanization of small rodents. However, there is opposition to the practice of using carbon dioxide for this, on the grounds that it is cruel.
Carbon dioxide is also used in several related cleaning and surface preparation techniques.
Carbon dioxide in Earth's atmosphere is a trace gas, currently (start of 2020) having a global average concentration of 412 parts per million by volume(or 622 parts per million by mass). Atmospheric concentrations of carbon dioxide fluctuate slightly with the seasons, falling during the Northern Hemisphere spring and summer as plants consume the gas and rising during northern autumn and winter as plants go dormant or die and decay. Concentrations also vary on a regional basis, most strongly near the ground with much smaller variations aloft. In urban areas concentrations are generally higher and indoors they can reach 10 times background levels.
The concentration of carbon dioxide has risen due to human activities. CO
2 to increase above levels not seen in hundreds of thousands of years. Currently, about half of the carbon dioxide released from the burning of fossil fuels remains in the atmosphere and is not absorbed by vegetation and the oceans.
While transparent to visible light, carbon dioxide is a greenhouse gas, absorbing and emitting infrared radiation at its two infrared-active vibrational frequencies (see the section "Structure and bonding" above). Light emission from the earth's surface is most intense in the infrared region between 200 and 2500 cm−1, as opposed to light emission from the much hotter sun which is most intense in the visible region. Absorption of infrared light at the vibrational frequencies of atmospheric carbon dioxide traps energy near the surface, warming the surface and the lower atmosphere. Less energy reaches the upper atmosphere, which is therefore cooler because of this absorption. Increases in atmospheric concentrations of CO
2 and other long-lived greenhouse gases such as methane, nitrous oxide and ozone have correspondingly strengthened their absorption and emission of infrared radiation, causing the rise in average global temperature since the mid-20th century. Carbon dioxide is of greatest concern because it exerts a larger overall warming influence than all of these other gases combined and because it has a long atmospheric lifetime (hundreds to thousands of years).
Not only do increasing carbon dioxide concentrations lead to increases in global surface temperature, but increasing global temperatures also cause increasing concentrations of carbon dioxide. This produces a positive feedback for changes induced by other processes such as orbital cycles.Five hundred million years ago the carbon dioxide concentration was 20 times greater than today, decreasing to 4–5 times during the Jurassic period and then slowly declining with a particularly swift reduction occurring 49 million years ago.
Local concentrations of carbon dioxide can reach high values near strong sources, especially those that are isolated by surrounding terrain. At the Bossoleto hot spring near Rapolano Terme in Tuscany, Italy, situated in a bowl-shaped depression about 100 m (330 ft) in diameter, concentrations of CO
2 rise to above 75% overnight, sufficient to kill insects and small animals. After sunrise the gas is dispersed by convection. High concentrations of CO
2 produced by disturbance of deep lake water saturated with CO
2 are thought to have caused 37 fatalities at Lake Monoun, Cameroon in 1984 and 1700 casualties at Lake Nyos, Cameroon in 1986.
Carbon dioxide dissolves in the ocean to form carbonic acid (H2CO3), bicarbonate (HCO3−) and carbonate (CO32−). There is about fifty times as much carbon dioxide dissolved in the oceans as exists in the atmosphere. The oceans act as an enormous carbon sink, and have taken up about a third of CO
2 emitted by human activity.
As the concentration of carbon dioxide increases in the atmosphere, the increased uptake of carbon dioxide into the oceans is causing a measurable decrease in the pH of the oceans, which is referred to as ocean acidification. This reduction in pH affects biological systems in the oceans, primarily oceanic calcifying organisms. These effects span the food chain from autotrophs to heterotrophs and include organisms such as coccolithophores, corals, foraminifera, echinoderms, crustaceans and mollusks. Under normal conditions, calcium carbonate is stable in surface waters since the carbonate ion is at supersaturating concentrations. However, as ocean pH falls, so does the concentration of this ion, and when carbonate becomes undersaturated, structures made of calcium carbonate are vulnerable to dissolution. CO
Gas solubility decreases as the temperature of water increases (except when both pressure exceeds 300 bar and temperature exceeds 393 K, only found near deep geothermal vents)and therefore the rate of uptake from the atmosphere decreases as ocean temperatures rise.
Most of the CO
2 taken up by the ocean, which is about 30% of the total released into the atmosphere, forms carbonic acid in equilibrium with bicarbonate. Some of these chemical species are consumed by photosynthetic organisms that remove carbon from the cycle. Increased CO
2 in the atmosphere has led to decreasing alkalinity of seawater, and there is concern that this may adversely affect organisms living in the water. In particular, with decreasing alkalinity, the availability of carbonates for forming shells decreases, although there's evidence of increased shell production by certain species under increased CO
NOAA states in their May 2008 "State of the science fact sheet for ocean acidification" that:
"The oceans have absorbed about 50% of the carbon dioxide (CO
2) released from the burning of fossil fuels, resulting in chemical reactions that lower ocean pH. This has caused an increase in hydrogen ion (acidity) of about 30% since the start of the industrial age through a process known as "ocean acidification." A growing number of studies have demonstrated adverse impacts on marine organisms, including:
Also, the Intergovernmental Panel on Climate Change (IPCC) writes in their Climate Change 2007: Synthesis Report:
"The uptake of anthropogenic carbon since 1750 has led to the ocean becoming more acidic with an average decrease in pH of 0.1 units. Increasing atmospheric CO
2 concentrations lead to further acidification ... While the effects of observed ocean acidification on the marine biosphere are as yet undocumented, the progressive acidification of oceans is expected to have negative impacts on marine shell-forming organisms (e.g. corals) and their dependent species."
Some marine calcifying organisms (including coral reefs) have been singled out by major research agencies, including NOAA, OSPAR commission, NANOOS and the IPCC, because their most current research shows that ocean acidification should be expected to impact them negatively.
Carbon dioxide is also introduced into the oceans through hydrothermal vents. The Champagne hydrothermal vent, found at the Northwest Eifuku volcano in the Marianas Trench, produces almost pure liquid carbon dioxide, one of only two known sites in the world as of 2004, the other being in the Okinawa Trough.The finding of a submarine lake of liquid carbon dioxide in the Okinawa Trough was reported in 2006.
Carbon dioxide is an end product of cellular respiration in organisms that obtain energy by breaking down sugars, fats and amino acids with oxygen as part of their metabolism. This includes all plants, algae and animals and aerobic fungi and bacteria. In vertebrates, the carbon dioxide travels in the blood from the body's tissues to the skin (e.g., amphibians) or the gills (e.g., fish), from where it dissolves in the water, or to the lungs from where it is exhaled. During active photosynthesis, plants can absorb more carbon dioxide from the atmosphere than they release in respiration.
Carbon fixation is a biochemical process by which atmospheric carbon dioxide is incorporated by plants, algae and (cyanobacteria) into energy-rich organic molecules such as glucose, thus creating their own food by photosynthesis. Photosynthesis uses carbon dioxide and water to produce sugars from which other organic compounds can be constructed, and oxygen is produced as a by-product.
Ribulose-1,5-bisphosphate carboxylase oxygenase, commonly abbreviated to RuBisCO, is the enzyme involved in the first major step of carbon fixation, the production of two molecules of 3-phosphoglycerate from CO
2 and ribulose bisphosphate, as shown in the diagram at left.
RuBisCO is thought to be the single most abundant protein on Earth.
Phototrophs use the products of their photosynthesis as internal food sources and as raw material for the biosynthesis of more complex organic molecules, such as polysaccharides, nucleic acids and proteins. These are used for their own growth, and also as the basis of the food chains and webs that feed other organisms, including animals such as ourselves. Some important phototrophs, the coccolithophores synthesise hard calcium carbonate scales.A globally significant species of coccolithophore is Emiliania huxleyi whose calcite scales have formed the basis of many sedimentary rocks such as limestone, where what was previously atmospheric carbon can remain fixed for geological timescales.
Plants can grow as much as 50 percent faster in concentrations of 1,000 ppm CO
2 when compared with ambient conditions, though this assumes no change in climate and no limitation on other nutrients. Elevated CO
2 levels cause increased growth reflected in the harvestable yield of crops, with wheat, rice and soybean all showing increases in yield of 12–14% under elevated CO
2 in FACE experiments.
Increased atmospheric CO
2 concentrations result in fewer stomata developing on plants which leads to reduced water usage and increased water-use efficiency. Studies using FACE have shown that CO
2 enrichment leads to decreased concentrations of micronutrients in crop plants. This may have knock-on effects on other parts of ecosystems as herbivores will need to eat more food to gain the same amount of protein.
The concentration of secondary metabolites such as phenylpropanoids and flavonoids can also be altered in plants exposed to high concentrations of CO
Plants also emit CO
2 during respiration, and so the majority of plants and algae, which use C3 photosynthesis, are only net absorbers during the day. Though a growing forest will absorb many tons of CO
2 each year, a mature forest will produce as much CO
2 from respiration and decomposition of dead specimens (e.g., fallen branches) as is used in photosynthesis in growing plants. Contrary to the long-standing view that they are carbon neutral, mature forests can continue to accumulate carbon and remain valuable carbon sinks, helping to maintain the carbon balance of Earth's atmosphere. Additionally, and crucially to life on earth, photosynthesis by phytoplankton consumes dissolved CO
2 in the upper ocean and thereby promotes the absorption of CO
2 from the atmosphere.
Carbon dioxide content in fresh air (averaged between sea-level and 10 kPa level, i.e., about 30 km (19 mi) altitude) varies between 0.036% (360 ppm) and 0.041% (412 ppm), depending on the location. [ clarification needed ]
2 is an asphyxiant gas and not classified as toxic or harmful in accordance with Globally Harmonized System of Classification and Labelling of Chemicals standards of United Nations Economic Commission for Europe by using the OECD Guidelines for the Testing of Chemicals. In concentrations up to 1% (10,000 ppm), it will make some people feel drowsy and give the lungs a stuffy feeling. Concentrations of 7% to 10% (70,000 to 100,000 ppm) may cause suffocation, even in the presence of sufficient oxygen, manifesting as dizziness, headache, visual and hearing dysfunction, and unconsciousness within a few minutes to an hour. The physiological effects of acute carbon dioxide exposure are grouped together under the term hypercapnia, a subset of asphyxiation.
Because it is heavier than air, in locations where the gas seeps from the ground (due to sub-surface volcanic or geothermal activity) in relatively high concentrations, without the dispersing effects of wind, it can collect in sheltered/pocketed locations below average ground level, causing animals located therein to be suffocated. Carrion feeders attracted to the carcasses are then also killed. Children have been killed in the same way near the city of Goma by CO
2 emissions from the nearby volcano Mt. Nyiragongo. The Swahili term for this phenomenon is 'mazuku'.
Adaptation to increased concentrations of CO
2 occurs in humans, including modified breathing and kidney bicarbonate production, in order to balance the effects of blood acidification (acidosis). Several studies suggested that 2.0 percent inspired concentrations could be used for closed air spaces (e.g. a submarine) since the adaptation is physiological and reversible, as deterioration in performance or in normal physical activity does not happen at this level of exposure for five days. Yet, other studies show a decrease in cognitive function even at much lower levels. Also, with ongoing respiratory acidosis, adaptation or compensatory mechanisms will be unable to reverse such condition.
There are few studies of the health effects of long-term continuous CO
2 exposure on humans and animals at levels below 1%. Occupational CO
2 exposure limits have been set in the United States at 0.5% (5000 ppm) for an eight-hour period. At this CO
2 concentration, International Space Station crew experienced headaches, lethargy, mental slowness, emotional irritation, and sleep disruption. Studies in animals at 0.5% CO
2 have demonstrated kidney calcification and bone loss after eight weeks of exposure. A study of humans exposed in 2.5 hour sessions demonstrated significant negative effects on cognitive abilities at concentrations as low as 0.1% (1000 ppm) CO
2 likely due to CO
2 induced increases in cerebral blood flow. Another study observed a decline in basic activity level and information usage at 1000 ppm, when compared to 500 ppm.
Poor ventilation is one of the main causes of excessive CO
2 concentrations in closed spaces. Carbon dioxide differential above outdoor concentrations at steady state conditions (when the occupancy and ventilation system operation are sufficiently long that CO
2 concentration has stabilized) are sometimes used to estimate ventilation rates per person.[ citation needed ] Higher CO
2 concentrations are associated with occupant health, comfort and performance degradation. ASHRAE Standard 62.1–2007 ventilation rates may result in indoor concentrations up to 2,100 ppm above ambient outdoor conditions. Thus if the outdoor concentration is 400 ppm, indoor concentrations may reach 2,500 ppm with ventilation rates that meet this industry consensus standard. Concentrations in poorly ventilated spaces can be found even higher than this (range of 3,000 or 4,000).
Miners, who are particularly vulnerable to gas exposure due to an insufficient ventilation, referred to mixtures of carbon dioxide and nitrogen as "blackdamp," "choke damp" or "stythe." Before more effective technologies were developed, miners would frequently monitor for dangerous levels of blackdamp and other gases in mine shafts by bringing a caged canary with them as they worked. The canary is more sensitive to asphyxiant gases than humans, and as it became unconscious would stop singing and fall off its perch. The Davy lamp could also detect high levels of blackdamp (which sinks, and collects near the floor) by burning less brightly, while methane, another suffocating gas and explosion risk, would make the lamp burn more brightly.
In February 2020, three people died from suffocation at a party in Moscow when dry ice (frozen CO2) was added to a swimming pool to cool it down.
|Venous blood carbon dioxide||5.5–6.8||41–51|
|Arterial blood carbon dioxide||4.7–6.0||35–45|
The body produces approximately 2.3 pounds (1.0 kg) of carbon dioxide per day per person, containing 0.63 pounds (290 g) of carbon. In humans, this carbon dioxide is carried through the venous system and is breathed out through the lungs, resulting in lower concentrations in the arteries. The carbon dioxide content of the blood is often given as the partial pressure, which is the pressure which carbon dioxide would have had if it alone occupied the volume. In humans, the blood carbon dioxide contents is shown in the adjacent table:
2 is carried in blood in three different ways. (The exact percentages vary depending whether it is arterial or venous blood).
Hemoglobin, the main oxygen-carrying molecule in red blood cells, carries both oxygen and carbon dioxide. However, the CO
2 bound to hemoglobin does not bind to the same site as oxygen. Instead, it combines with the N-terminal groups on the four globin chains. However, because of allosteric effects on the hemoglobin molecule, the binding of CO
2 decreases the amount of oxygen that is bound for a given partial pressure of oxygen. This is known as the Haldane Effect, and is important in the transport of carbon dioxide from the tissues to the lungs. Conversely, a rise in the partial pressure of CO
2 or a lower pH will cause offloading of oxygen from hemoglobin, which is known as the Bohr effect.
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Carbon dioxide is one of the mediators of local autoregulation of blood supply. If its concentration is high, the capillaries expand to allow a greater blood flow to that tissue.
Bicarbonate ions are crucial for regulating blood pH. A person's breathing rate influences the level of CO
2 in their blood. Breathing that is too slow or shallow causes respiratory acidosis, while breathing that is too rapid leads to hyperventilation, which can cause respiratory alkalosis.
Although the body requires oxygen for metabolism, low oxygen levels normally do not stimulate breathing. Rather, breathing is stimulated by higher carbon dioxide levels. As a result, breathing low-pressure air or a gas mixture with no oxygen at all (such as pure nitrogen) can lead to loss of consciousness without ever experiencing air hunger. This is especially perilous for high-altitude fighter pilots. It is also why flight attendants instruct passengers, in case of loss of cabin pressure, to apply the oxygen mask to themselves first before helping others; otherwise, one risks losing consciousness.
The respiratory centers try to maintain an arterial CO
2 pressure of 40 mm Hg. With intentional hyperventilation, the CO
2 content of arterial blood may be lowered to 10–20 mm Hg (the oxygen content of the blood is little affected), and the respiratory drive is diminished. This is why one can hold one's breath longer after hyperventilating than without hyperventilating. This carries the risk that unconsciousness may result before the need to breathe becomes overwhelming, which is why hyperventilation is particularly dangerous before free diving.
In chemistry, a carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula of CO2−
3. The name may also refer to a carbonate ester, an organic compound containing the carbonate group C(=O)(O–)2.
Calcium carbonate is a chemical compound with the formula CaCO3. It is a common substance found in rocks as the minerals calcite and aragonite (most notably as limestone, which is a type of sedimentary rock consisting mainly of calcite) and is the main component of pearls and the shells of marine organisms, snails, and eggs. Calcium carbonate is the active ingredient in agricultural lime and is created when calcium ions in hard water react with carbonate ions to create limescale. It is medicinally used as a calcium supplement or as an antacid, but excessive consumption can be hazardous and cause poor digestion.
The carbon cycle is the biogeochemical cycle by which carbon is exchanged among the biosphere, pedosphere, geosphere, hydrosphere, and atmosphere of the Earth. Carbon is the main component of biological compounds as well as a major component of many minerals such as limestone. Along with the nitrogen cycle and the water cycle, the carbon cycle comprises a sequence of events that are key to make Earth capable of sustaining life. It describes the movement of carbon as it is recycled and reused throughout the biosphere, as well as long-term processes of carbon sequestration to and release from carbon sinks.
Carbonic acid is a chemical compound with the chemical formula H2CO3 (equivalently: OC(OH)2). It is also a name sometimes given to solutions of carbon dioxide in water (carbonated water), because such solutions contain small amounts of H2CO3. In physiology, carbonic acid is described as volatile acid or respiratory acid because it is the only acid excreted as a gas by the lungs. It plays an important role in the bicarbonate buffer system to maintain acid–base homeostasis.
The lysocline is the depth in the ocean dependent upon the calcite compensation depth (CCD), usually around 3.5 km, below which the rate of dissolution of calcite increases dramatically because of a pressure effect. While the lysocline is the upper bound of this transition zone of calcite saturation, the CCD is the lower bound of this zone.
The biological pump, in its simplest form, is the ocean's biologically driven sequestration of carbon from the atmosphere to the ocean interior and seafloor sediments. It is the part of the oceanic carbon cycle responsible for the cycling of organic matter formed mainly by phytoplankton during photosynthesis (soft-tissue pump), as well as the cycling of calcium carbonate (CaCO3) formed into shells by certain organisms such as plankton and mollusks (carbonate pump).
Alkalinity is the capacity of water to resist changes in pH that would make the water more acidic. Alkalinity is the strength of a buffer solution composed of weak acids and their conjugate bases. It is measured by titrating the solution with a monoprotic acid such as HCl until its pH changes abruptly, or it reaches a known endpoint where that happens. Alkalinity is expressed in units of meq/L, which corresponds to the amount of monoprotic acid added as a titrant in millimoles per liter.
In oceanic biogeochemistry, the solubility pump is a physico-chemical process that transports carbon from the ocean's surface to its interior.
Carbonyl sulfide is the chemical compound with the linear formula OCS. Normally written as COS as a chemical formula that does not imply its structure, it is a colourless flammable gas with an unpleasant odor. It is a linear molecule consisting of a carbonyl group double bonded to a sulfur atom. Carbonyl sulfide can be considered to be intermediate between carbon dioxide and carbon disulfide, both of which are valence isoelectronic with it.
Ocean acidification is the ongoing decrease in the pH of the Earth's oceans, caused by the uptake of carbon dioxide (CO
2) from the atmosphere. Seawater is slightly basic (meaning pH > 7), and ocean acidification involves a shift towards pH-neutral conditions rather than a transition to acidic conditions (pH < 7). An estimated 30–40% of the carbon dioxide from human activity released into the atmosphere dissolves into oceans, rivers and lakes. Some of it reacts with the water to form carbonic acid. Some of the resulting carbonic acid molecules dissociate into a bicarbonate ion and a hydrogen ion, thus increasing ocean acidity (H+ ion concentration). Between 1751 and 1996, surface ocean pH is estimated to have decreased from approximately 8.25 to 8.14, representing an increase of almost 30% in H+ ion concentration in the world's oceans. Earth System Models project that, by around 2008, ocean acidity exceeded historical analogues and, in combination with other ocean biogeochemical changes, could undermine the functioning of marine ecosystems and disrupt the provision of many goods and services associated with the ocean beginning as early as 2100.
Carbon dioxide is an important trace gas in Earth's atmosphere. It is an integral part of the carbon cycle, a biogeochemical cycle in which carbon is exchanged between the Earth's oceans, soil, rocks and the biosphere. Plants and other photoautotrophs use solar energy to produce carbohydrate from atmospheric carbon dioxide and water by photosynthesis. Almost all other organisms depend on carbohydrate derived from photosynthesis as their primary source of energy and carbon compounds. CO
2 absorbs and emits infrared radiation at wavelengths of 4.26 µm and 14.99 µm and consequently is a greenhouse gas that plays a significant role in influencing Earth's surface temperature through the greenhouse effect.
The carbonate–silicate geochemical cycle, also known as the inorganic carbon cycle, describes the long-term transformation of silicate rocks to carbonate rocks by weathering and sedimentation, and the transformation of carbonate rocks back into silicate rocks by metamorphism and volcanism. Carbon dioxide is removed from the atmosphere during burial of weathered minerals and returned to the atmosphere through volcanism. On million-year time scales, the carbonate-silicate cycle is a key factor in controlling Earth's climate because it regulates carbon dioxide levels and therefore global temperature.
Enhanced weathering refers to geoengineering approaches that use the dissolution of natural or artificially created minerals to remove carbon dioxide from the atmosphere. Since the carbon dioxide is usually first removed from ocean water, these approaches would attack the problem by first reducing ocean acidification.
The Revelle factor (buffer factor) is the ratio of instantaneous change in carbon dioxide (CO
2) to the change in total dissolved inorganic carbon (DIC), and is a measure of the resistance to atmospheric CO2 being absorbed by the ocean surface layer. The buffer factor is used to examine the distribution of CO2 between the atmosphere and the ocean, and measures the amount of CO2 that can be dissolved in the mixed surface layer. It is named after the oceanographer Roger Revelle. The Revelle factor describes the oceans ability to uptake atmospheric CO2, and is typically referenced in global carbon budget analysis and anthropogenic climate change studies.
The oceanic carbon cycle is composed of processes that exchange carbon between various pools within the ocean as well as between the atmosphere, Earth interior, and the seafloor. The carbon cycle is a result of many interacting forces across multiple time and space scales that circulates carbon around the planet, ensuring that carbon is available globally. The Oceanic carbon cycle is a central process to the global carbon cycle and contains both inorganic carbon and organic carbon. Part of the marine carbon cycle transforms carbon between non-living and living matter.
Estuarine acidification happens when the pH balance of water in coastal marine ecosystems, specifically those of estuaries, decreases. Water, generally considered neutral on the pH scale, normally perfectly balanced between alkalinity and acidity.While ocean acidification occurs due to the ongoing decrease in the pH of the Earth's oceans, caused by the absorption of carbon dioxide (CO2) from the atmosphere, pH change in estuaries is more complicated than in the open ocean due to direct impacts from land run-off, human impact, and coastal current dynamics. In the ocean, wave and wind movement allows carbon dioxide (CO2) to mixes with water (H2O) forming carbonic acid (H2CO3). Through wave motion this chemical bond is mixed up, allowing for the further break of the bond, eventually becoming carbonate (CO3) which is basic and helps form shells for ocean creatures, and two hydron molecules. This creates the potential for acidic threat since hydron ions readily bond with any Lewis Structure to form an acidic bond. This is referred to as an oxidation-reduction reaction.
Ocean acidification threatens the Great Barrier Reef by reducing the viability and strength of coral reefs. The Great Barrier Reef, considered one of the seven natural wonders of the world and a biodiversity hotspot, is located in Australia. Similar to other coral reefs, it is experiencing degradation due to ocean acidification. Ocean acidification results from a rise in atmospheric carbon dioxide, which is taken up by the ocean. This process can increase sea surface temperature, decrease aragonite, and lower the pH of the ocean.
The Southern Ocean Carbon and Climate Observations and Modeling (SOCCOM) project is a large scale National Science Foundation funded research project based at Princeton University that started in September 2014. The project aims to increase the understanding of the Southern Ocean and the role it plays in factors such as climate, as well as educate new scientists with oceanic observation.
Ocean storage of carbon dioxide (CO2) is a method of carbon sequestration. The concept of storing carbon dioxide in the ocean was first proposed by Italian physicist Cesare Marchetti in his 1976 paper "On Geoengineering and the carbon dioxide problem." Since then, the concept of sequestering atmospheric carbon dioxide in the world's oceans has been investigated by scientists, engineers, and environmental activists. 39,000 GtC (gigatonnes of carbon) currently reside in the oceans while only 750 GtC are in the atmosphere.
The Arctic ocean covers an area of 14,056,000 squared kilometers, and supports a diverse and important socioeconomic food web of organisms, despite its average water temperature being 32 degrees Fahrenheit. Over the last three decades, the Arctic Ocean has experienced drastic changes due to climate change. One of the changes is in the acidity levels of the ocean, which have been consistently increasing at twice the rate of the Pacific and Atlantic oceans. Arctic Ocean acidification is a result of feedback from climate system mechanisms, and is having negative impacts on Arctic Ocean ecosystems and the organisms that live within them.
(Rubisco) is the most prevalent enzyme on this planet, accounting for 30–50% of total soluble protein in the chloroplast;
This new title is an essential guide for engineers, managers, procurement specialists and designers working on global carbon capture and storage projects.
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