This is a list of refrigerants, sorted by their ASHRAE-designated numbers, commonly known as R numbers. Many modern refrigerants are human-made halogenated gases, especially fluorinated gases and chlorinated gases, that are frequently referred to as Freon (a registered trademark of Chemours).
Freons are responsible for the formation of the ozone hole. The Vienna Convention for the Protection of the Ozone Layer and the Montreal Protocol are international agreements that oblige signatory countries to limit the emission of ozone-depleting gases.
According to ASHRAE standard 34, the R-number of a chemical refrigerant is assigned systematically according to its molecular structure and has between two and four digits. If there are carbon-carbon multiple bonds, there are four digits in all: the number of these bonds is the first digit and the number of carbon atoms minus one (C-1) is next. If there is more than one carbon atom but no multiple bonds, there are three digits, and the number of carbon atoms minus one is the first digit. If there is only one carbon atom, then there are only two digits. The last two digits are always the number of hydrogen atoms plus one (H+1), followed by the number of fluorine atoms. Any other atoms attached to the carbons are assumed to be chlorine atoms. For example, R-22 has one carbon atom, one hydrogen atom (2−1 = 1), two fluorine atoms, and one chlorine atom (4−2−1 = 1), so it is chlorodifluoromethane, while R-134 has two carbon atoms (2−1 = 1), two hydrogen atoms (3−1 = 2), four fluorine atoms, and no chlorine atoms (6−2−4 = 0), so it is one of the tetrafluoroethanes. This basic scheme is modified as follows:
There are separate numbering schemes for zeotropic and azeotropic blends, organic chemicals which don't fit into the scheme above, and inorganic chemicals:
The table is sortable by each of the following refrigerant properties (scroll right or reduce magnification to view more properties):
Since over 100,000 refrigerant blends are possible, [2] this list should only have notable refrigerants and refrigerant blends.
Type | ASHRAE number | IUPAC chemical name | Molecular formula | CAS no/ blend name | Atmospheric lifetime (years) | Semi- empirical ODP (R-11 = 1) | Net GWP 100-yr (R-744 = 1) | OEL/PEL ppm (v/v) & ASHRAE 34 safety group | RCL/IDLH (ppm v/v, followed by g/m3) | Molecular mass u | Boiling, or bubble/dew /azeotropic point(s) °C | Critical temp. °C | Critical pressure, absolute kPa | ||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
PCC | R-10 | Carbon tetrachloride (Tetrachloromethane) | CCl4 | 56-23-5 | 26 [3] [4] | 0.73 [4] | 1,400 [5] | 100? B1 [6] | 153.8 [7] | 76.72 [8] | 283.35 [9] | 4,560 [9] | |||
CFC | R-11 | Trichlorofluoromethane | CCl3F | 75-69-4 | 45 [3] [4] | 1.0 [4] | 4,660 [10] | 1,000 [11] A1 [11] | 1,100 [11] | 6.2 [11] | 137.4 [7] | 23.77 [8] | 197.96 [9] | 4,408 [9] | |
CFC | R-12 | Dichlorodifluoromethane | CCl2F2 | 75-71-8 | 100 [3] [4] | 1.0 [4] | 10,200 [10] | 1,000 [11] A1 [11] | 18,000 [11] | 90 [11] | 120.9 [7] | −29.8 [8] | 111.97 [9] | 4,136 [9] | |
H | R-12B1 | Bromochlorodifluoromethane | CBrClF2 or CF2ClBr | 353-59-3 | 16 [3] [4] | 7.1 [4] | 1,750 [5] | 165.4 [7] | −3.7 [8] | 153.8 [9] | 4,102 [9] | ||||
H | R-12B2 | Dibromodifluoromethane | CBr2F2 | 75-61-6 | 2.9 [4] | 1.7 [4] | 209.8 [7] | 22.8 [8] | 198.11 [9] | 4,130 [9] | |||||
CFC | R-13 | Chlorotrifluoromethane | CClF3 | 75-72-9 | 640 [3] | 1 [12] | 13,900 [10] | 1,000 [11] A1 [11] | 40,000? | 200? | 104.5 [7] | −81.5 [8] | 28.73 [9] | 3,877 [9] | |
H | R-13B1 | Bromotrifluoromethane | CBrF3 or CF3Br | 75-63-8 | 65 [3] [4] | 16 [4] | 6,290 [5] | 1,000 [11] A1 [11] | 148.9 [7] | −57.75 [8] | 67 [9] | 3,964 [9] | |||
H | R-13I1 | Trifluoroiodomethane | CF3I | 2314-97-8 | 500 [13] A1 [13] | 195.9 [13] | −21.9 [13] | ||||||||
PFC | R-14 | Tetrafluoromethane | CF4 | 75-73-0 | 50,000 [3] | 0 [14] | 7,390 [3] | 1,000 [11] A1 [11] | 110,000 [11] | 400 [11] | 88 [7] | −127.8 [8] | −45.64 [9] | 3,750 [9] | |
HCC | R-20 | Chloroform (Trichloromethane) | CHCl3 | 67-66-3 | 0.51 [3] | 31 [3] | 119.4 [7] | 61.2 [8] | 262.35 [9] | 5,480 [9] | |||||
HCFC | R-21 | Dichlorofluoromethane | CHFCl2 | 75-43-4 | 1.7 [4] | 0.04 [15] | 148 [5] | 100? B1 [11] | 102.9 [7] | 8.92 [8] | 178.45 [9] | 5,180 [9] | |||
HCFC | R-22 | Chlorodifluoromethane | CHClF2 | 75-45-6 | 12.0 [3] [4] | 0.055 [4] [16] | 1,760 [5] | 1,000 [11] A1 [11] | 59,000 [11] | 210 [11] | 86.5 [7] | −40.7 [8] | 96.14 [9] | 4,990 [9] | |
H | R-22B1 | Bromodifluoromethane | CHBrF2 or CHF2Br | 1511-62-2 | 5.8 [4] | 0.74 [12] | 404 [4] | 130.9 [7] | −14.6 [8] | 138.83 [9] | 5,132 [9] | ||||
HFC | R-23 | Trifluoromethane (Fluoroform) | CHF3 | 75-46-7 | 270 [3] | 0 [14] | 12,400 [5] | 1,000 [11] A1 [11] | 41,000 [11] | 120 [11] | 70 [7] | −82.1 [8] | 25.92 [9] | 4,836 [9] | |
HCC | R-30 | Dichloromethane (Methylene chloride) | CH2Cl2 | 75-09-2 | 0.38 [3] | 0 [17] | 8.7 [3] | 100? B2 [11] | 84.9 [7] | 39.6 [8] | 235.15 [9] | 6,080 [9] | |||
HCFC | R-31 | Chlorofluoromethane | CH2FCl | 593-70-4 | 0.02 [15] | 350? B2? | 10,000? | 20? | 68.5 [7] | −9.1 [8] | 151.76 [9] | 5,131 [9] | |||
HFC | R-32 | Difluoromethane | CH2F2 | 75-10-5 | 4.9 [3] | 0 [14] | 677 [5] | 1,000 [11] A2L [18] | 36,000 [11] | 77 [11] | 52 [7] | −52 [8] [19] | 78.11 [9] | 5,782 [9] | |
HCC | R-40 | Chloromethane | CH3Cl | 74-87-3 | 1.0 [3] [4] | 0.02 [4] | 13 [3] | 100? B2 [11] | 50.5 [7] | −24.2 [8] | 143.05 [9] | 6,660 [9] | |||
HFC | R-41 | Fluoromethane | CH3F | 593-53-3 | 2.4 [3] | 0 [14] | 116 [5] | 34 [7] | −78.2 [8] | 44.13 [9] | 5,897 [9] | ||||
HC | R-50 | Methane | CH4 | 74-82-8 | 12 ± 3 [3] | <0(smog) [20] | 28 [5] | 1,000 [11] A3 [11] | 9,000? | 9? | 16.04 [7] | −162±2 [8] | −82.3 [21] | 4,640 [21] | |
PCC | R-110 | Hexachloroethane | C2Cl6 | 67-72-1 | 236.7 [7] | 431.28 [9] | 3,937 [9] | ||||||||
CFC | R-111 | Pentachlorofluoroethane | C2FCl5 | 354-56-3 | 1 [12] | 220.3 [7] | 135 [8] | ||||||||
CFC | R-112 | 1,1,2,2-Tetrachloro-1,2-difluoroethane | C2F2Cl4 | 76-12-0 | 1 [12] | 203.8 [7] | |||||||||
CFC | R-112a | 1,1,1,2-Tetrachloro-2,2-difluoroethane | C2F2Cl4 | 76-11-9 | 1 [a] | 203.8 [7] | |||||||||
CFC | R-113 | 1,1,2-Trichloro-1,2,2-trifluoroethane | C2F3Cl3 | 76-13-1 | 85 [3] [4] | 1.0 [4] | 5,820 [10] | 1,000 [11] A1 [11] | 2,600 [11] | 20 [11] | 187.4 [7] | 48 [19] | 214.06 [9] | 3,392 [9] | |
CFC | R-113a | 1,1,1-Trichloro-2,2,2-trifluoroethane | C2F3Cl3 | 354-58-5 | 1 [a] | 187.4 [7] | |||||||||
CFC | R-114 | 1,2-Dichlorotetrafluoroethane | C2F4Cl2 | 76-14-2 | 300 [3] [4] | 1.0 [4] | 8,590 [10] | 1,000 [11] A1 [11] | 20,000 [11] | 140 [11] | 170.9 [7] | 3.5 [8] | 145.68 [9] | 3,257 [9] | |
CFC | R-114a | 1,1-Dichlorotetrafluoroethane | C2F4Cl2 | 374-07-2 | 1 [a] | 170.9 [7] | |||||||||
H | R-114B2 | Dibromotetrafluoroethane | C2F4Br2 or CF2BrCF2Br | 124-73-2 | 20 [3] [4] | 11.5 [4] | 1,470 [5] | 259.8 [7] | 47.3 [8] | 214.67 [9] | |||||
CFC | R-115 | Chloropentafluoroethane | C2F5Cl | 76-15-3 | 1,700 [3] [4] | 0.44 [4] | 7,670 [5] | 1,000 [11] A1 [11] | 120,000 [11] | 760 [11] | 154.5 [7] | −39.1 [8] | 79.95 [9] | 3,120 [9] | |
PFC | R-116 | Hexafluoroethane | C2F6 | 76-16-4 | 10,000 [3] | 0 [14] | 12,200 [3] | 1,000 [11] A1 [11] | 97,000 [11] | 550 [11] | 138 [7] | −78.2 [8] | 19.88 [9] | 3,042 [9] | |
HCC | R-120 | Pentachloroethane | C2HCl5 | 76-01-7 | 202.3 [7] | ||||||||||
HCFC | R-121 | 1,1,2,2-Tetrachloro-1-fluoroethane | C2HFCl4 | 354-14-3 | 0.01–0.04 [15] | 185.8 [7] | |||||||||
HCFC | R-121a | 1,1,1,2-Tetrachloro-2-fluoroethane | C2HFCl4 | 354-11-0 | 0.01–0.04 [b] | 185.8 [7] | |||||||||
HCFC | R-122 | 1,1,2-Trichloro-2,2-difluoroethane | C2HF2Cl3 | 354-21-2 | 0.02–0.08 [15] | 169.4 [7] | |||||||||
HCFC | R-122a | 1,1,2-Trichloro-1,2-difluoroethane | C2HF2Cl3 | 354-15-4 | 0.02–0.08 [b] | 169.4 [7] | |||||||||
HCFC | R-122b | 1,1,1-Trichloro-2,2-difluoroethane | C2HF2Cl3 | 354-12-1 | 0.02–0.08 [b] | 169.4 [7] | |||||||||
HCFC | R-123 | 2,2-Dichloro-1,1,1-trifluoroethane | C2HF3Cl2 | 306-83-2 | 1.3 [3] [4] | 0.02 [4] | 79 [5] | 50 [11] B1 [11] | 9,100 [11] | 57 [11] | 152.9 [7] | 27.6 [8] | 183.68 [9] | 3,662 [9] | |
HCFC | R-123a | 1,2-Dichloro-1,1,2-trifluoroethane | C2HF3Cl2 | 354-23-4 | 1.3? [c] | 0.02? [b] | 77? [c] | 152.9 [7] | |||||||
HCFC | R-123b | 1,1-Dichloro-1,2,2-trifluoroethane | C2HF3Cl2 | 812-04-4 | 1.3? [c] | 0.02? [b] | 77? [c] | 152.9 [7] | |||||||
HCFC | R-124 | 1-Chloro-1,2,2,2-tetrafluoroethane | C2HF4Cl | 2837-89-0 | 5.8 [3] [4] | 0.022 [4] | 527 [5] | 1,000 [11] A1 [11] | 10,000 [11] | 56 [11] | 136.5 [7] | −12 [19] | 122.28 [9] | 3,624 [9] | |
HCFC | R-124a | 1-Chloro-1,1,2,2-tetrafluoroethane | C2HF4Cl | 354-25-6 | 5.8? [c] | 0.022? [b] | 609? [c] | 136.5 [7] | |||||||
HFC | R-125 | Pentafluoroethane | C2HF5 | 354-33-6 | 29 [3] | 0 [14] | 3,170 [5] | 1,000 [11] A1 [11] | 75,000 [11] | 370 [11] | 120 [7] | −48.5 [8] | 66.18 [9] | 3,629 [9] | |
HFC | R-E125 | Pentafluorodimethyl ether | C2F5OC2F5 | 3822-68-2 | 136 [3] | 0 [d] | 14,900 [3] | 136 [7] | |||||||
HCC | R-130 | 1,1,2,2-Tetrachloroethane | C2H2Cl4 | 79-34-5 | 167.8 [7] | 146.5 [8] | 388.06 [9] | 5,840 [9] | |||||||
HCC | R-130a | 1,1,1,2-Tetrachloroethane | C2H2Cl4 | 630-20-6 | 167.8 [7] | 130.5 [8] | |||||||||
HCFC | R-131 | 1,1,2-Trichloro-2-fluoroethane | C2H2FCl3 | 359-28-4 | 0.007–0.05 [15] | 151.4 [7] | |||||||||
HCFC | R-131a | 1,1,2-Trichloro-1-fluoroethane | C2H2FCl3 | 811-95-0 | 0.007–0.05 [b] | 151.4 [7] | |||||||||
HCFC | R-131b | 1,1,1-Trichloro-2-fluoroethane | C2H2FCl3 | 2366-36-1 | 0.007–0.05 [b] | 151.4 [7] | |||||||||
HCFC | R-132 | 1,2-Dichloro-1,2-difluoroethane | C2H2F2Cl2 | 431-06-1 | 0.008–0.05 [b] | 134.9 [7] | |||||||||
HCFC | R-132a | 1,1-Dichloro-2,2-difluoroethane | C2H2F2Cl2 | 471-43-2 | 0.008–0.05 [b] | 134.9 [7] | |||||||||
HCFC | R-132b | 1,2-Dichloro-1,1-difluoroethane | C2H2F2Cl2 | 1649-08-7 | 0.008–0.05 [15] | 134.9 [7] | |||||||||
HCFC | R-132c | 1,1-Dichloro-1,2-difluoroethane | C2H2F2Cl2 | 1842-05-3 | 0.008–0.05 [b] | 134.9 [7] | |||||||||
H | R-132bB2 | 1,2-Dibromo-1,1-difluoroethane | C2H2Br2F2 | 75-82-1 | 0.2–1.5 [12] | 223.8 [7] | |||||||||
HCFC | R-133 | 1-Chloro-1,2,2-Trifluoroethane | C2H2F3Cl | 431-07-2 | 0.02–0.06 [b] | 118.5 [7] | |||||||||
HCFC | R-133a | 1-Chloro-2,2,2-Trifluoroethane | C2H2F3Cl | 75-88-7 | 0.02–0.06 [15] | 118.5 [7] | |||||||||
HCFC | R-133b | 1-Chloro-1,1,2-Trifluoroethane | C2H2F3Cl | 421-04-5 | 0.02–0.06 [b] | 118.5 [7] | |||||||||
HFC | R-134 | 1,1,2,2-Tetrafluoroethane | C2H2F4 | 359-35-3 | 9.6 [3] | 0 [14] | 1,120 [5] | 102 [7] | |||||||
HFC | R-134a | 1,1,1,2-Tetrafluoroethane | C2H2F4 | 811-97-2 | 14 [3] | 0 [14] [17] | 1,300 [5] | 1,000 [11] A1 [11] | 50,000 [11] | 210 [11] | 102 [7] | −26.3 [8] | 101.06 [9] | 4,059 [9] | |
HFC | R-E134 | Bis(difluoromethyl)ether | C2H2F4O | 1691-17-4 | 26 [3] | 0 [d] | 6,320 [3] | 118 [7] | |||||||
HCC | R-140 | 1,1,2-Trichloroethane | C2H3Cl3 | 79-00-5 | 133.4 [7] | 112.5±2.5 [8] | |||||||||
HCC | R-140a | 1,1,1-Trichloroethane (Methyl chloroform) | C2H3Cl3 or CH3CCl3 | 71-55-6 | 5.0 [3] [4] | 0.12 [4] | 160 [5] | 133.4 [7] | 74 [8] | ||||||
HCFC | R-141 | 1,2-Dichloro-1-fluoroethane | C2H3FCl2 | 430-57-9 | 9.3? [c] | 0.12? [b] | 725? [c] | 116.9 [7] | |||||||
H | R-141B2 | 1,2-Dibromo-1-fluoroethane | C2H3Br2F | 358-97-4 | 0.1–1.7 [12] | 205.9 [7] | |||||||||
HCFC | R-141a | 1,1-Dichloro-2-fluoroethane | C2H3FCl2 | 430-53-5 | 9.3? [c] | 0.12? [b] | 725? [c] | 116.9 [7] | |||||||
HCFC | R-141b | 1,1-Dichloro-1-fluoroethane | C2H3FCl2 | 1717-00-6 | 9.3 [3] [4] | 0.12 [4] | 725 [3] | 500 [11] A2? | 2,600 [11] | 12 [11] | 116.9 [7] | 32 [8] [19] | 204.2 [9] | 4,250 [9] | |
HCFC | R-142a | 1-Chloro-1,2-difluoroethane | C2H3F2Cl | 338-64-7 | 17.9? [c] | 0.07? [b] | 2,310? [c] | 100.5 [7] | |||||||
HCFC | R-142b | 1-Chloro-1,1-difluoroethane | C2H3F2Cl | 75-68-3 | 17.9 [3] [4] | 0.07 [4] | 2,310 [3] | 1,000 [11] A2 [11] | 20,000 [11] | 83 [11] | 100.5 [7] | −10 [8] [19] | 137.1 [9] | 4,123 [9] | |
HFC | R-143 | 1,1,2-Trifluoroethane | C2H3F3 | 430-66-0 | 3.5 [3] | 0 [14] | 328 [5] | 84 [7] | |||||||
HFC | R-143a | 1,1,1-Trifluoroethane | C2H3F3 | 420-46-2 | 52 [3] | 0 [14] | 4,800 [5] | 1,000 [11] A2L [18] | 21,000 [11] | 70 [11] | 84 [7] | −47.6 [8] | 72.89 [9] | 3,776 [9] | |
HFC | R-E143a | Methyl trifluoromethyl ether | C2H3F3O | 421-14-7 | 4.3 [3] | 0 [d] | 756 [3] | 100 [7] | |||||||
HCC | R-150 | 1,2-Dichloroethane | C2H4Cl2 | 107-06-2 | 99 [7] | 84 [8] | 292.83 [9] | 5,370 [9] | |||||||
HCC | R-150a | 1,1-Dichloroethane | C2H4Cl2 | 75-34-3 | 99 [7] | 57.2 [8] | 249.83 [9] | 5,070 [9] | |||||||
HCFC | R-151 | 1-Chloro-2-fluoroethane | C2H4ClF | 762-50-5 | 82.5 [7] | ||||||||||
HCFC | R-151a | 1-Chloro-1-fluoroethane | C2H4ClF | 1615-75-4 | 82.5 [7] | ||||||||||
HFC | R-152 | 1,2-Difluoroethane | C2H4F2 | 624-72-6 | 0.60 [3] | 0 [d] | 16 [5] | 66 [7] | |||||||
HFC | R-152a | 1,1-Difluoroethane | C2H4F2 | 75-37-6 | 1.4 [3] | 0 [14] [17] | 138 [5] | 1,000 [11] A2 [11] | 12,000 [11] | 32 [11] | 66 [7] | −25 [8] [19] | 113.26 [9] | 4,517 [9] | |
HCC | R-160 | Chloroethane (ethyl chloride) | C2H5Cl | 75-00-3 | 64.5 [7] | 12.3 [8] | 187.28 [9] | 5,268 [9] | |||||||
HFC | R-161 | Fluoroethane | C2H5F | 353-36-6 | 0.3 [3] | 0 [d] | 4 [5] | 48.1 [7] | 102.22 [9] | 4,702 [9] | |||||
HC | R-170 | Ethane | C2H6 or CH3CH3 | 74-84-0 | 58 days [22] | < 0(smog) [e] | 5.5 [3] –10.2 [22] | 1,000 [11] A3 [11] | 7,000 [11] | 8.7 [11] | 30.07 [7] | −88.6 [8] [23] | 32.18 [9] | 4,872 [9] | |
HC | R-E170 | Dimethyl ether | CH3OCH3 | 115-10-6 | 0.015 [3] | < 0(smog) [e] | 1 [3] | 1,000 [11] A3 [11] | 8,500 [11] | 16 [11] | 46.1 [7] | −24 [8] | |||
CFC | R-211 | 1,1,1,2,2,3,3-Heptachloro-3-fluoropropane | C3FCl7 | 422-78-6 | 1 [12] | 303.2 [7] | |||||||||
CFC | R-212 | Hexachlorodifluoropropane | C3F2Cl6 | 134452-44-1 | 1 [12] | 286.7 [7] | |||||||||
CFC | R-213 | 1,1,1,3,3-Pentachloro-2,2,3-trifluoropropane | C3F3Cl5 | 2354-06-5 | 1 [12] | 270.3 [7] | |||||||||
CFC | R-214 | 1,2,2,3-Tetrachloro-1,1,3,3-tetrafluoropropane | C3F4Cl4 | 2268-46-4 | 1 [12] | 253.8 [7] | |||||||||
CFC | R-215 | 1,1,1-Trichloro-2,2,3,3,3-pentafluoropropane | C3F5Cl3 | 4259-43-2 | 1 [12] | 237.4 [7] | |||||||||
CFC | R-216 | 1,2-Dichloro-1,1,2,3,3,3-hexafluoropropane | C3F6Cl2 | 661-97-2 | 1 [12] | 220.9 [7] | |||||||||
CFC | R-216ca | 1,3-Dichloro-1,1,2,2,3,3-hexafluoropropane | C3F6Cl2 | 662-01-1 | 1 [a] | 220.9 [7] | |||||||||
CFC | R-217 | 1-Chloro-1,1,2,2,3,3,3-heptafluoropropane | C3F7Cl | 422-86-6 | 1 [12] | 204.5 [7] | |||||||||
CFC | R-217ba | 2-Chloro-1,1,1,2,3,3,3-heptafluoropropane | C3F7Cl | 76-18-6 | 1 [a] | 204.5 [7] | |||||||||
PFC | R-218 | Octafluoropropane | C3F8 | 76-19-7 | 2,600 [3] | 0 [14] | 8,830 [3] | 1,000 [11] A1 [11] | 90,000 [11] | 690 [11] | 188 [7] | −36.7 [8] | |||
HCFC | R-221 | 1,1,1,2,2,3-Hexachloro-3-fluoropropane | C3HFCl6 | 422-26-4 | 0.015–0.07 [15] | 268.7 [7] | |||||||||
HCFC | R-222 | Pentachlorodifluoropropane | C3HF2Cl5 | 134237-36-8 | 0.01–0.09 [b] | 252.3 [7] | |||||||||
HCFC | R-222c | 1,1,1,3,3-Pentachloro-2,2-difluoropropane | C3HF2Cl5 | 422-49-1 | 0.01–0.09 [15] | 252.3 [7] | |||||||||
HCFC | R-223 | Tetrachlorotrifluoropropane | C3HF3Cl4 | 134237-37-9 | 0.01–0.08 [b] | 235.8 [7] | |||||||||
HCFC | R-223ca | 1,1,3,3-Tetrachloro-1,2,2-trifluoropropane | C3HF3Cl4 | 422-52-6 | 0.01–0.08 [15] | 235.8 [7] | |||||||||
HCFC | R-223cb | 1,1,1,3-Tetrachloro-2,2,3-trifluoropropane | C3HF3Cl4 | 422-50-4 | 0.01–0.08 [b] | 235.8 [7] | |||||||||
HCFC | R-224 | Trichlorotetrafluoropropane | C3HF4Cl3 | 134237-38-0 | 0.01–0.09 [b] | 219.4 [7] | |||||||||
HCFC | R-224ca | 1,3,3-Trichloro-1,1,2,2-tetrafluoropropane | C3HF4Cl3 | 422-54-8 | 0.01–0.09 [15] | 219.4 [7] | |||||||||
HCFC | R-224cb | 1,1,3-Trichloro-1,2,2,3-tetrafluoropropane | C3HF4Cl3 | 422-53-7 | 0.01–0.09 [b] | 219.4 [7] | |||||||||
HCFC | R-224cc | 1,1,1-Trichloro-2,2,3,3-tetrafluoropropane | C3HF4Cl3 | 422-51-5 | 0.01–0.09 [b] | 219.4 [7] | |||||||||
HCFC | R-225 | Dichloropentafluoropropane | C3HF5Cl2 | 127564-92-5 | 0.01–0.05 [b] | 202.9 [7] | |||||||||
HCFC | R-225aa | 2,2-Dichloro-1,1,1,3,3-pentafluoropropane | C3HF5Cl2 | 128903-21-9 | 0.01–0.05 [b] | 202.9 [7] | |||||||||
HCFC | R-225ba | 2,3-Dichloro-1,1,1,2,3-pentafluoropropane | C3HF5Cl2 | 422-48-0 | 0.01–0.05 [b] | 202.9 [7] | |||||||||
HCFC | R-225bb | 1,2-Dichloro-1,1,2,3,3-pentafluoropropane | C3HF5Cl2 | 422-44-6 | 0.01–0.05 [b] | 202.9 [7] | |||||||||
HCFC | R-225ca | 3,3-Dichloro-1,1,1,2,2-pentafluoropropane | C3HF5Cl2 | 422-56-0 | 1.9 [3] [4] | 0.02 [4] | 127 [5] | 202.9 [7] | |||||||
HCFC | R-225cb | 1,3-Dichloro-1,1,2,2,3-pentafluoropropane | C3HF5Cl2 | 507-55-1 | 5.8 [3] [4] | 0.03 [4] | 525 [5] | 202.9 [7] | |||||||
HCFC | R-225cc | 1,1-Dichloro-1,2,2,3,3-pentafluoropropane | C3HF5Cl2 | 13474-88-9 | 0.01–0.05 [b] | 202.9 [7] | |||||||||
HCFC | R-225da | 1,2-Dichloro-1,1,3,3,3-pentafluoropropane | C3HF5Cl2 | 431-86-7 | 0.01–0.05 [b] | 202.9 [7] | |||||||||
HCFC | R-225ea | 1,3-Dichloro-1,1,2,3,3-pentafluoropropane | C3HF5Cl2 | 136013-79-1 | 0.01–0.05 [b] | 202.9 [7] | |||||||||
HCFC | R-225eb | 1,1-Dichloro-1,2,3,3,3-pentafluoropropane | C3HF5Cl2 | 111512-56-2 | 0.01–0.05 [b] | 202.9 [7] | |||||||||
HCFC | R-226 | Chlorohexafluoropropane | C3HF6Cl | 134308-72-8 | 0.02–0.1 [b] | 186.5 [7] | |||||||||
HCFC | R-226ba | 2-Chloro-1,1,1,2,3,3-hexafluoropropane | C3HF6Cl | 51346-64-6 | 0.02–0.1 [b] | 186.5 [7] | |||||||||
HCFC | R-226ca | 3-Chloro-1,1,1,2,2,3-hexafluoropropane | C3HF6Cl | 422-57-1 | 0.02–0.1 [b] | 186.5 [7] | |||||||||
HCFC | R-226cb | 1-Chloro-1,1,2,2,3,3-hexafluoropropane | C3HF6Cl | 422-55-9 | 0.02–0.1 [b] | 186.5 [7] | |||||||||
HCFC | R-226da | 2-Chloro-1,1,1,3,3,3-hexafluoropropane | C3HF6Cl | 431-87-8 | 0.02–0.1 [15] | 186.5 [7] | |||||||||
HCFC | R-226ea | 1-Chloro-1,1,2,3,3,3-hexafluoropropane | C3HF6Cl | 359-58-0 | 0.02–0.1 [b] | 186.5 [7] | |||||||||
HFC | R-227ca | 1,1,2,2,3,3,3-Heptafluoropropane | C3HF7 | 2252-84-8 | 0 [d] | 170 [7] | |||||||||
HFC | R-227ca2 | Trifluoromethyl 1,1,2,2-tetrafluoroethyl ether | C3HF7O | 2356-61-8 | 0 [d] | 186 [7] | |||||||||
HFC | R-227ea | 1,1,1,2,3,3,3-Heptafluoropropane | C3HF7 | 431-89-0 | 34.2 [3] | 0 [14] [17] | 3,350 [5] | 1,000 [11] A1 [11] | 84,000 [11] | 580 [11] | 170 [7] | −16.4 [8] | 102.8 [9] | 2,980 [9] | |
HFC | R-227me | Trifluoromethyl 1,2,2,2-tetrafluoroethyl ether | C3HF7O | 2356-62-9 | 11 [4] | 0 [d] | 1,540 [4] | 186 [7] | |||||||
HCFC | R-231 | Pentachlorofluoropropane | C3H2FCl5 | 134190-48-0 | 0.05–0.09 [15] | 234.3 [7] | |||||||||
HCFC | R-232 | Tetrachlorodifluoropropane | C3H2F2Cl4 | 134237-39-1 | 0.008–0.1 [15] | 217.9 [7] | |||||||||
HCFC | R-232ca | 1,1,3,3-Tetrachloro-2,2-difluoropropane | C3H2F2Cl4 | 1112-14-7 | 0.008–0.1 [b] | 217.9 [7] | |||||||||
HCFC | R-232cb | 1,1,1,3-Tetrachloro-2,2-difluoropropane | C3H2F2Cl4 | 677-54-3 | 0.008–0.1 [b] | 217.9 [7] | |||||||||
HCFC | R-233 | Trichlorotrifluoropropane | C3H2F3Cl3 | 134237-40-4 | 0.007–0.23 [15] | 201.4 [7] | |||||||||
HCFC | R-233ca | 1,1,3-Trichloro-2,2,3-trifluoropropane | C3H2F3Cl3 | 131221-36-8 | 0.007–0.23 [b] | 201.4 [7] | |||||||||
HCFC | R-233cb | 1,1,3-Trichloro-1,2,2-trifluoropropane | C3H2F3Cl3 | 421-99-8 | 0.007–0.23 [b] | 201.4 [7] | |||||||||
HCFC | R-233cc | 1,1,1-Trichloro-2,2,3-trifluoropropane | C3H2F3Cl3 | 131211-71-7 | 0.007–0.23 [b] | 201.4 [7] | |||||||||
HCFC | R-234 | Dichlorotetrafluoropropane | C3H2F4Cl2 | 127564-83-4 | 0.01–0.28 [b] | 184.9 [7] | |||||||||
HCFC | R-234aa | 2,2-Dichloro-1,1,3,3-tetrafluoropropane | C3H2F4Cl2 | 17705-30-5 | 0.01–0.28 [b] | 184.9 [7] | |||||||||
HCFC | R-234ab | 2,2-Dichloro-1,1,1,3-tetrafluoropropane | C3H2F4Cl2 | 149329-24-8 | 0.01–0.28 [b] | 184.9 [7] | |||||||||
HCFC | R-234ba | 1,2-Dichloro-1,2,3,3-tetrafluoropropane | C3H2F4Cl2 | 425-94-5 | 0.01–0.28 [15] | 184.9 [7] | |||||||||
HCFC | R-234bb | 2,3-Dichloro-1,1,1,2-tetrafluoropropane | C3H2F4Cl2 | 149329-25-9 | 0.01–0.28 [b] | 184.9 [7] | |||||||||
HCFC | R-234bc | 1,2-Dichloro-1,1,2,3-tetrafluoropropane | C3H2F4Cl2 | 149329-26-0 | 0.01–0.28 [b] | 184.9 [7] | |||||||||
HCFC | R-234ca | 1,3-Dichloro-1,2,2,3-tetrafluoropropane | C3H2F4Cl2 | 70341-81-0 | 0.01–0.28 [b] | 184.9 [7] | |||||||||
HCFC | R-234cb | 1,1-Dichloro-2,2,3,3-tetrafluoropropane | C3H2F4Cl2 | 4071-01-6 | 0.01–0.28 [b] | 184.9 [7] | |||||||||
HCFC | R-234cc | 1,3-Dichloro-1,1,2,2-tetrafluoropropane | C3H2F4Cl2 | 422-00-4 | 0.01–0.28 [b] | 184.9 [7] | |||||||||
HCFC | R-234cd | 1,1-Dichloro-1,2,2,3-tetrafluoropropane | C3H2F4Cl2 | 70192-63-1 | 0.01–0.28 [b] | 184.9 [7] | |||||||||
HCFC | R-234da | 2,3-Dichloro-1,1,1,3-tetrafluoropropane | C3H2F4Cl2 | 146916-90-7 | 0.01–0.28 [b] | 184.9 [7] | |||||||||
HCFC | R-234fa | 1,3-Dichloro-1,1,3,3-tetrafluoropropane | C3H2F4Cl2 | 76140-39-1 | 0.01–0.28 [b] | 184.9 [7] | |||||||||
HCFC | R-234fb | 1,1-Dichloro-1,3,3,3-tetrafluoropropane | C3H2F4Cl2 | 64712-27-2 | 0.01–0.28 [b] | 184.9 [7] | |||||||||
HCFC | R-235 | Chloropentafluoropropane | C3H2F5Cl | 134237-41-5 | 0.03–0.52 [15] | 168.5 [7] | |||||||||
HCFC | R-235ca | 1-Chloro-1,2,2,3,3-pentafluoropropane | C3H2F5Cl | 28103-66-4 | 0.03–0.52 [b] | 168.5 [7] | |||||||||
HCFC | R-235cb | 3-Chloro-1,1,1,2,3-pentafluoropropane | C3H2F5Cl | 422-02-6 | 0.03–0.52 [b] | 168.5 [7] | |||||||||
HCFC | R-235cc | 1-Chloro-1,1,2,2,3-pentafluoropropane | C3H2F5Cl | 679-99-2 | 0.03–0.52 [b] | 168.5 [7] | |||||||||
HCFC | R-235da | 2-Chloro-1,1,1,3,3-pentafluoropropane | C3H2F5Cl | 134251-06-2 | 0.03–0.52 [b] | 168.5 [7] | |||||||||
HCFC | R-235fa | 1-Chloro-1,1,3,3,3-pentafluoropropane | C3H2F5Cl | 677-55-4 | 0.03–0.52 [b] | 168.5 [7] | |||||||||
HFC | R-236cb | 1,1,1,2,2,3-Hexafluoropropane | C3H2F6 | 677-56-5 | 13.6 [3] | 0 [d] | 1,210 [5] | 152 [7] | −1.5 | ||||||
HFC | R-236ea | 1,1,1,2,3,3-Hexafluoropropane | C3H2F6 | 431-63-0 | 10.7 [3] | 0 [14] | 1,330 [5] | 152 [7] | 139.29 [9] | 3,502 [9] | |||||
HFC | R-236fa | 1,1,1,3,3,3-Hexafluoropropane | C3H2F6 | 690-39-1 | 240 [3] | 0 [14] | 8,060 [5] | 1,000 [11] A1 [11] | 55,000 [11] | 340 [11] | 152 [7] | −1.05±.35 [8] | 124.92 [9] | 3,200 [9] | |
HFC | R-236me | 1,2,2,2-Tetrafluoroethyl difluoromethyl ether | C3H2F6O | 57041-67-5 | 5.8 [4] | 0 [d] | 989 [4] | 168 [7] | |||||||
HCFC | R-241 | Tetrachlorofluoropropane | C3H3FCl4 | 134190-49-1 | 0.004–0.09 [15] | 199.9 [7] | |||||||||
HCFC | R-242 | Trichlorodifluoropropane | C3H3F2Cl3 | 134237-42-6 | 0.005–0.13 [15] | 183.4 [7] | |||||||||
HCFC | R-243 | Dichlorotrifluoropropane | C3H3F3Cl2 | 134237-43-7 | 0.007–0.12 [15] | 167 [7] | |||||||||
HCFC | R-243ca | 1,3-Dichloro-1,2,2-trifluoropropane | C3H3F3Cl2 | 67406-68-2 | 0.007–0.12 [b] | 167 [7] | |||||||||
HCFC | R-243cb | 1,1-Dichloro-2,2,3-trifluoropropane | C3H3F3Cl2 | 70192-70-0 | 0.007–0.12 [b] | 167 [7] | |||||||||
HCFC | R-243cc | 1,1-Dichloro-1,2,2-trifluoropropane | C3H3F3Cl2 | 7125-99-7 | 0.007–0.12 [b] | 167 [7] | |||||||||
HCFC | R-243da | 2,3-Dichloro-1,1,1-trifluoropropane | C3H3F3Cl2 | 338-75-0 | 0.007–0.12 [b] | 167 [7] | |||||||||
HCFC | R-243ea | 1,3-Dichloro-1,2,3-trifluoropropane | C3H3F3Cl2 | 151771-08-3 | 0.007–0.12 [b] | 167 [7] | |||||||||
HCFC | R-243ec | 1,3-Dichloro-1,1,2-trifluoropropane | C3H3F3Cl2 | 149329-27-1 | 0.007–0.12 [b] | 167 [7] | |||||||||
HCFC | R-244 | Chlorotetrafluoropropane | C3H3F4Cl | 134190-50-4 | 0.009–0.14 [15] | 150.5 [7] | |||||||||
HCFC | R-244ba | 2-Chloro-1,2,3,3-tetrafluoropropane | C3H3F4Cl | 149329-28-2 | 0.009–0.14 [b] | 150.5 [7] | |||||||||
HCFC | R-244bb | 2-Chloro-1,1,1,2-tetrafluoropropane | C3H3F4Cl | 421-73-8 | 0.009–0.14 [b] | 150.5 [7] | |||||||||
HCFC | R-244ca | 3-Chloro-1,1,2,2-tetrafluoropropane | C3H3F4Cl | 679-85-6 | 0.009–0.14 [b] | 150.5 [7] | |||||||||
HCFC | R-244cb | 1-Chloro-1,2,2,3-tetrafluoropropane | C3H3F4Cl | 67406-66-0 | 0.009–0.14 [b] | 150.5 [7] | |||||||||
HCFC | R-244cc | 1-Chloro-1,1,2,2-tetrafluoropropane | C3H3F4Cl | 421-75-0 | 0.009–0.14 [b] | 150.5 [7] | |||||||||
HCFC | R-244da | 2-Chloro-1,1,3,3-tetrafluoropropane | C3H3F4Cl | 19041-02-2 | 0.009–0.14 [b] | 150.5 [7] | |||||||||
HCFC | R-244db | 2-Chloro-1,1,1,3-tetrafluoropropane | C3H3F4Cl | 117970-90-8 | 0.009–0.14 [b] | 150.5 [7] | |||||||||
HCFC | R-244ea | 3-Chloro-1,1,2,3-tetrafluoropropane | C3H3F4Cl | 0.009–0.14 [b] | 150.5 [7] | ||||||||||
HCFC | R-244eb | 3-Chloro-1,1,1,2-tetrafluoropropane | C3H3F4Cl | 151771-09-4 | 0.009–0.14 [b] | 150.5 [7] | |||||||||
HCFC | R-244ec | 1-Chloro-1,1,2,3-tetrafluoropropane | C3H3F4Cl | 149448-09-9 | 0.009–0.14 [b] | 150.5 [7] | |||||||||
HCFC | R-244fa | 3-Chloro-1,1,1,3-tetrafluoropropane | C3H3F4Cl | 149329-29-3 | 0.009–0.14 [b] | 150.5 [7] | |||||||||
HCFC | R-244fb | 1-Chloro-1,1,3,3-tetrafluoropropane | C3H3F4Cl | 2730-64-5 | 0.009–0.14 [b] | 150.5 [7] | |||||||||
HFC | R-245ca | 1,1,2,2,3-Pentafluoropropane | C3H3F5 | 679-86-7 | 6.2 [3] | 0 [14] | 716 [5] | 134 [7] | 174.42 [9] | 3,925 [9] | |||||
HFC | R-245cb | Pentafluoropropane | C3H3F5 | 1814-88-6 | 0 [d] | 134 [7] | |||||||||
HFC | R-245ea | 1,1,2,3,3-Pentafluoropropane | C3H3F5 | 24270-66-4 | 0 [d] | 134 [7] | |||||||||
HFC | R-245eb | 1,1,1,2,3-Pentafluoropropane | C3H3F5 | 431-31-2 | 0 [d] | 134 [7] | |||||||||
HFC | R-245fa | 1,1,1,3,3-Pentafluoropropane | C3H3F5 | 460-73-1 | 7.6 [3] | 0 [14] [17] | 858 [5] | 300 [11] B1 [11] | 34,000 [11] | 190 [11] | 134 [7] | 15 [19] | 154.05 [9] | 3,640 [9] | |
HFC | R-245mc | Methyl pentafluoroethyl ether | C3H3F5O | 22410-44-2 | 0 [d] | 150 [7] | |||||||||
HFC | R-245mf | Difluoromethyl 2,2,2-trifluoroethyl ether | C3H3F5O | 1885-48-9 | 2.2 [4] | 0 [d] | 286 [4] | 150 [7] | |||||||
HFC | R-245qc | Difluoromethyl 1,1,2-trifluoroethyl ether | C3H3F5O | 69948-24-9 | 0 [d] | 150 [7] | |||||||||
HCFC | R-251 | Trichlorofluoropropane | C3H4FCl3 | 134190-51-5 | 0.001–0.01 [15] | 165.4 [7] | |||||||||
HCFC | R-252 | Dichlorodifluoropropane | C3H4F2Cl2 | 134190-52-6 | 0.005–0.04 [15] | 149 [7] | |||||||||
HCFC | R-252ca | 1,3-Dichloro-2,2-difluoropropane | C3H4F2Cl2 | 1112-36-3 | 0.005–0.04 [b] | 149 [7] | |||||||||
HCFC | R-252cb | 1,1-Dichloro-2,2-difluoropropane | C3H4F2Cl2 | 1112-01-2 | 0.005–0.04 [b] | 149 [7] | |||||||||
HCFC | R-252dc | 1,2-Dichloro-1,1-difluoropropane | C3H4F2Cl2 | 7126-15-0 | 0.005–0.04 [b] | 149 [7] | |||||||||
HCFC | R-252ec | 1,1-Dichloro-1,2-difluoropropane | C3H4F2Cl2 | 151771-10-7 | 0.005–0.04 [b] | 149 [7] | |||||||||
HCFC | R-253 | Chlorotrifluoropropane | C3H4F3Cl | 134237-44-8 | 0.003–0.03 [15] | 132.5 [7] | |||||||||
HCFC | R-253ba | 2-Chloro-1,2,3-trifluoropropane | C3H4F3Cl | 151771-11-8 | 0.003–0.03 [b] | 132.5 [7] | |||||||||
HCFC | R-253bb | 2-Chloro-1,1,2-trifluoropropane | C3H4F3Cl | 69202-10-4 | 0.003–0.03 [b] | 132.5 [7] | |||||||||
HCFC | R-253ca | 1-Chloro-2,2,3-trifluoropropane | C3H4F3Cl | 56758-54-4 | 0.003–0.03 [b] | 132.5 [7] | |||||||||
HCFC | R-253cb | 1-Chloro-1,2,2-trifluoropropane | C3H4F3Cl | 70192-76-6 | 0.003–0.03 [b] | 132.5 [7] | |||||||||
HCFC | R-253ea | 3-Chloro-1,1,2-trifluoropropane | C3H4F3Cl | 121612-65-5 | 0.003–0.03 [b] | 132.5 [7] | |||||||||
HCFC | R-253eb | 1-Chloro-1,2,3-trifluoropropane | C3H4F3Cl | 151771-12-9 | 0.003–0.03 [b] | 132.5 [7] | |||||||||
HCFC | R-253ec | 1-Chloro-1,1,2-trifluoropropane | C3H4F3Cl | 134251-05-1 | 0.003–0.03 [b] | 132.5 [7] | |||||||||
HCFC | R-253fa | 3-Chloro-1,3,3-trifluoropropane | C3H4F3Cl | 0.003–0.03 [b] | 132.5 [7] | ||||||||||
HCFC | R-253fb | 3-Chloro-1,1,1-trifluoropropane | C3H4F3Cl | 460-35-5 | 0.003–0.03 [b] | 132.5 [7] | |||||||||
HCFC | R-253fc | 1-Chloro-1,1,3-trifluoropropane | C3H4F3Cl | 83124-56-5 | 0.003–0.03 [b] | 132.5 [7] | |||||||||
HFC | R-254cb | 1,1,2,2-Tetrafluoropropane | C3H4F4 | 40723-63-5 | 0 [d] | 116.1 [7] | |||||||||
HFC | R-254pc | Methyl 1,1,2,2-tetrafluoroethyl ether | C3H4F4O | 425-88-7 | 2.6 [3] | 0 [d] | 359 [3] | 132.1 [7] | |||||||
HCFC | R-261 | Dichlorofluoropropane | C3H5FCl2 | 134237-45-9 | 0.002–0.02 [b] | 131 [7] | |||||||||
HCFC | R-261ba | 1,2-Dichloro-2-fluoropropane | C3H5FCl2 | 420-97-3 | 0.002–0.02 [15] | 131 [7] | |||||||||
HCFC | R-262 | Chlorodifluoropropane | C3H5F2Cl | 134190-53-7 | 0.002–0.02 [15] | 114.5 [7] | |||||||||
HCFC | R-262ca | 1-Chloro-2,2-difluoropropane | C3H5F2Cl | 420-99-5 | 0.002–0.02 [b] | 114.5 [7] | |||||||||
HCFC | R-262fa | 3-Chloro-1,1-difluoropropane | C3H5F2Cl | 83124-57-6 | 0.002–0.02 [b] | 114.5 [7] | |||||||||
HCFC | R-262fb | 1-Chloro-1,3-difluoropropane | C3H5F2Cl | 151771-13-0 | 0.002–0.02 [b] | 114.5 [7] | |||||||||
HFC | R-263 | Trifluoropropane | C3H5F3 | 94458-05-6 | 0 [d] | 98.1 [7] | |||||||||
HCFC | R-271 | Chlorofluoropropane | C3H6FCl | 134190-54-8 | 0.001–0.03 [15] | 96.5 [7] | |||||||||
HCFC | R-271b | 2-Chloro-2-fluoropropane | C3H6FCl | 420-44-0 | 0.001–0.03 [b] | 96.5 [7] | |||||||||
HCFC | R-271d | 2-Chloro-1-fluoropropane | C3H6FCl | 20372-78-5 | 0.001–0.03 [b] | 96.5 [7] | |||||||||
HCFC | R-271fb | 1-Chloro-1-fluoropropane | C3H6FCl | 430-55-7 | 0.001–0.03 [b] | 96.5 [7] | |||||||||
HFC | R-272 | Difluoropropane | C3H6F2 | 94458-04-5 | 0 [d] | 80.1 [7] | |||||||||
HFC | R-281 | Fluoropropane | C3H7F | 106857-11-8 | 0 [d] | 62.1 [7] | |||||||||
HC | R-290 | Propane | C3H8 or CH3CH2CH3 | 74-98-6 | 13 days [22] | < 0(smog) [e] | 3.3 [3] –9.5 [22] | 1,000 [11] A3 [11] | 5,300 [11] | 9.5 [11] | 44.1 [7] | −42.1±.2 [8] | 96.7 [9] | 4,248 [9] | |
CFC | R-C316 | Dichlorohexafluorocyclobutane | C4Cl2F6 | 356-18-3 | 74.6 ± 3(E),114.1 ± 10 (Z) [24] | 0.40(E), 0.49(Z) [24] | 4,160(E), 5,400(Z) [24] | 232.9 [7] | |||||||
CFC | R-C317 | Chloroheptafluorocyclobutane | C4ClF7 | 377-41-3 | 216.5 [7] | ||||||||||
PFC | R-C318 | Octafluorocyclobutane (Perfluorocyclobutane) | C4F8 or -(CF2)4- | 115-25-3 | 3,200 [3] | 0 [14] | 10,300 [3] | 1,000 [11] A1 [11] | 69,000 [11] | 570 [11] | 200 [7] | −6 [8] [19] | 115.23 [9] | 2,777 [9] | |
PFC | R-3-1-10 | Decafluorobutane (Perfluorobutane) | C4F10 | 355-25-9 | 2,600 [3] | 0 [14] | 8,860 [3] | 238 [7] | −1.7 [8] | ||||||
HFC | R-329ccb | 1,1,1,2,2,3,3,4,4-Nonafluorobutane | C4HF9 | 375-17-7 | 0 [d] | 220 [7] | |||||||||
HFC | R-338eea | 1,1,1,2,3,4,4,4-Octafluorobutane | C4H2F8 | 75995-72-1 | 0 [d] | 202 [7] | |||||||||
HFC | R-347ccd | 1,1,1,2,2,3,3-Heptafluorobutane | C4H3F7 | 662-00-0 | 0 [d] | 184.1 [7] | |||||||||
HFC | R-347mcc | Perfluoropropyl methyl ether | C4H3F7O | 375-03-1 | 5.2 [3] | 0 [d] | 575 [3] | 200.1 [7] | |||||||
HFC | R-347mmy | Perfluoroisopropyl methyl ether | C4H3F7O | 22052-84-2 | 3.4 [4] | 0 [d] | 343 [4] | 200.1 [7] | |||||||
HFC | R-365mfc | 1,1,1,3,3-Pentafluorobutane | C4H5F5 | 406-58-6 | 8.6 [3] | 0 [14] [17] | 804 [3] | 148.1 [7] | |||||||
PFC | R-4-1-12 | Dodecafluoropentane (Perfluoropentane) | C5F12 | 678-26-2 | 4,100 [3] | 0 [14] | 9,160 [3] | 288 [7] | |||||||
PFC | R-5-1-14 | Tetradecafluorohexane (Perfluorohexane) | C6F14 | 355-42-0 | 3,200 [3] | 0 [14] | 9,300 [3] | 338 [7] | 56 [8] | ||||||
CFC | R-400 | R-12/114(50/50 wt%) OR (60/40)(must be specified) | 50% CCl2F2 ·50% C2F4Cl2 OR 60% CCl2F2 ·40% C2F4Cl2 | 200 [note 1] OR 180 [note 1] | 1.0 [note 2] | 10,450 [note 1] 10,540 [note 1] | 1,000 [11] A1 [11] 1,000 [11] A1 [11] | 28,000 [11] 30,000 [11] | 160 [11] 170 [11] | 141.6 [7] 136.9 [7] | |||||
HCFC | R-401A | R-22/152a/124 (53±2/13+.5,-1.5/34±1) | 53±2% CHClF2 ·13+.5,-1.5% C2H4F2 ·34±1% C2HF4Cl | MP-39 [9] [26] | 8.514 [note 1] | 0.03398 [note 2] | 1,182 [note 1] | 1,000 [11] A1 [11] | 27,000 [11] | 110 [11] | 94.4 [7] | −34.4/−28.8 [19] | 105.27 [9] | 4,613 [9] | |
HCFC | R-401B | R-22/152a/124 (61±2/11+.5,-1.5/28±1) | 61±2% CHClF2 ·11+.5,-1.5% C2H4F2 ·28±1% C2HF4Cl | MP-66 [9] [26] | 9.098 [note 1] | 0.03666 [note 2] | 1,288 [note 1] | 1,000 [11] A1 [11] | 30,000 [11] | 120 [11] | 92.8 [7] | −35.7/−30.8 [19] | 103.54 [9] | 4,682 [9] | |
HCFC | R-401C | R-22/152a/124 (33±2/15+.5,-1.5/52±1) | 33±2% CHClF2 ·15+.5,-1.5% C2H4F2 ·52±1% C2HF4Cl | MP-52 [26] | 7.186 [note 1] | 0.02794 [note 2] | 933 [note 1] | 1,000 [11] A1 [11] | 20,000 [11] | 84 [11] | 101 [7] | −30.5/−23.8 [19] | |||
HCFC | R-402A | R-125/290/22 (60±2/2±1/38±2) | 60±2% C2HF5 ·2±1% C3H8 ·38±2% CHClF2 | HP-80 [9] [26] | 22.2? [note 1] | 0.019 [note 2] | 2,788 [note 1] | 1,000 [11] A1 [11] | 33,000 [11] | 140 [11] | 101.5 [7] | −49.2/−47.0 [19] | 76.03 [9] | 4,234 [9] | |
HCFC | R-402B | R-125/290/22 (38±2/2±1/60±2) | 38±2% C2HF5 ·2±1% C3H8 ·60±2% CHClF2 | HP-81 [9] [26] | 18.46? [note 1] | 0.03 [note 2] | 2,416 [note 1] | 1,000 [11] A1 [11] | 63,000 [11] | 240 [11] | 94.7 [7] | −47.2/−44.9 [19] | 83.03 [9] | 4,525 [9] | |
HCFC | R-403A | R-290/22/218 (5+.2,-2/75±2/20±0) | 5+.2,-2% C3H8 ·75±2% CHClF2 ·20±0% C3F8 | ISCEON 69-S [9] | 529.6? [note 1] | 0.0375 [note 2] | 3,124 [note 1] | 1,000 [11] A2 [27] | 33,000 [11] | 120 [11] | 92 [7] | −44.0/−42.3 [19] | 91.22 [9] | 4,688 [9] | |
HCFC | R-403B | R-290/22/218 (5+.2,-2/56±2/39±0) | 5+.2,-2% C3H8 ·56±2% CHClF2 ·39±0% C3F8 | ISCEON 69-L [9] | 1,021.32? [note 1] | 0.028 [note 2] | 4,457 [note 1] | 1,000 [11] A1 [11] | 70,000 [11] | 290 [11] | 103.3 [7] | −43.8/−42.3 [19] | 88.72 [9] | 4,399 [9] | |
HFC | R-404A | R-125/143a/134a (44±2/52±1/4±2) | 44±2% C2HF5 ·52±1% C2H3F3 ·4±2% C2H2F4 | HP-62, [9] [26] FX-70 [9] [26] | 40.36 [note 1] | 0 [note 2] | 3,922 [note 1] | 1,000 [11] A1 [11] | 130,000 [11] | 500 [11] | 97.6 [7] | −46.6/−45.8 [19] | 72.14 [9] | 3,735 [9] | |
HCFC | R-405A | R-22/152a/142b/C318 (45±0/7±1/5.5±1/42.5±2) | 45±0% CHClF2 ·7±1% C2H4F2 ·5.5±1% C2H3F2Cl ·42.5±2% C4F8 | GREENCOOL G2015 [9] | 1,366.4825 [note 1] | 0.02635 [note 2] | 5,328 [note 1] | 1,000 [11] A1? | 57,000 [11] | 260 [11] | 111.9 [7] | −32.9/−24.5 [19] | 106 [9] | 4,289 [9] | |
HCFC | R-406A | R-22/600a/142b (55±2/4±1/41±0) | 55±2% CHClF2 ·4±1% C4H10 ·41±0% C2H3F2Cl | GHG [9] [26] | 14.419? [note 1] | 0.0562 [note 2] | 1,943 [note 1] | 1,000 [11] A2 [11] | 21,000 [11] | 25 [11] | 89.9 [7] | −32.7/−23.5 [19] | 116.5 [9] | 4,881 [9] | |
HCFC | R-406B | R-22/600a/142b (65±2/4±1/31±0) | 65±2% CHClF2 ·4±1% C4H10 ·31±0% C2H3F2Cl | GHG-HP [9] | 13.829? [note 1] | 0.0542 [note 2] | 1,893 [note 1] | 1,000? A2? | 21,000? | 25? | 88.6 [7] | ||||
HFC | R-407A | R-32/125/134a (20±2/40±2/40±2) | 20±2% CH2F2 ·40±2% C2HF5 ·40±2% C2H2F4 | Klea 60 [9] [26] | 18.18 [note 1] | 0 [note 2] | 2,107 [note 1] | 1,000 [11] A1 [11] | 83,000 [28] | 300 [28] | 90.1 [7] | −45.2/−38.7 [19] | 81.91 [9] | 4,487 [9] | |
HFC | R-407B | R-32/125/134a (10±2/70±2/20±2) | 10±2% CH2F2 ·70±2% C2HF5 ·20±2% C2H2F4 | Klea 61 [9] | 23.59 [note 1] | 0 [note 2] | 2,804 [note 1] | 1,000 [11] A1 [11] | 79,000 [28] | 330 [28] | 102.9 [7] | −46.8/−42.4 [19] | 74.38 [9] | 4,083 [9] | |
HFC | R-407C | R-32/125/134a (23±2/25±2/52±2) | 23±2% CH2F2 ·25±2% C2HF5 ·52±2% C2H2F4 | Klea 66, [9] AC9000 [26] | 15.657 [note 1] | 0 [note 2] | 1,774 [note 1] | 1,000 [11] A1 [11] | 81,000 [28] | 290 [28] | 86.2 [7] | −43.8/−36.7 [19] | 86.05 [9] | 4,634 [9] | |
HFC | R-407D | R-32/125/134a (15±2/15±2/70±2) | 15±2% CH2F2 ·15±2% C2HF5 ·70±2% C2H2F4 | 14.885 [note 1] | 0 [note 2] | 1,627 [note 1] | 1,000 [11] A1 [11] | 68,000 [28] | 250 [28] | 91 [7] | −39.4/−32.7 [19] | 91.57 [9] | 4,483 [9] | ||
HFC | R-407E | R-32/125/134a (25±2/15±2/60±2) | 25±2% CH2F2 ·15±2% C2HF5 ·60±2% C2H2F4 | 13.975 [note 1] | 0 [note 2] | 1,552 [note 1] | 1,000 [11] A1 [11] | 80,000 [28] | 280 [28] | 83.8 [7] | −42.8/−35.6 [19] | 88.77 [9] | 4,734 [9] | ||
HFC | R-407F | R-32/125/134a (30±2/30±2/40±2) | 30±2% CH2F2 ·30±2% C2HF5 ·40±2% C2H2F4 | Genetron Performax LT [26] | 15.77 [note 1] | 0 [note 2] | 1,825 [note 1] | 1,000 [29] A1 [29] | 95,000 [28] | 320 [28] | 82.1 [7] | −46.1/−39.7 [29] | |||
HCFC | R-408A | R-125/143a/22 (7±2/46±1/47±2) | 7±2% C2HF5 ·46±1% C2H3F3 ·47±2% CHClF2 | FX-10 [9] [26] | 31.59 [note 1] | 0.0235 [note 2] | 3,152 [note 1] | 1,000 [11] A1 [11] | 95,000 [11] | 340 [11] | 87 [7] | −45.5/−45.0 [19] | 83.5 [9] | 4,340 [9] | |
HCFC | R-409A | R-22/124/142b (60±2/25±2/15±1) | 60±2% CHClF2 ·25±2% C2HF4Cl ·15±1% C2H3F2Cl | FX-56 [9] [26] | 11.335 [note 1] | 0.046 [note 2] | 1,585 [note 1] | 1,000 [11] A1 [11] | 29,000 [11] | 110 [11] | 97.4 [7] | −35.4/−27.5 [19] | 106.92 [9] | 4,600 [9] | |
HCFC | R-409B | R-22/124/142b (65±2/25±2/10±1) | 65±2% CHClF2 ·25±2% C2HF4Cl ·10±1% C2H3F2Cl | FX-57 [9] | 11.04 [note 1] | 0.045 [note 2] | 1,560 [note 1] | 1,000 [11] A1 [11] | 30,000 [11] | 120 [11] | 96.7 [7] | −36.5/−29.7 [19] | 104.36 [9] | 4,711 [9] | |
HFC | R-410A | R-32/125 (50+.5,–1.5/50+1.5,–.5) | 50+.5,–1.5% CH2F2 ·50+1.5,–.5% CHF2CF3 [30] | AZ-20, [9] Puron, [9] Suva 9100 [9] | 16.95 [note 1] | 0 [note 2] | 2,088 [note 1] | 1,000 [11] A1 [11] | 140,000 [28] | 420 [28] | 72.6 [7] | −51.6/−51.5 [19] | 70.17 [9] | 4,770 [9] | |
HFC | R-410B | R-32/125 (45±1/55±1) | 45±1% CH2F2 ·55±1% CHF2CF3 [30] | AC9100 [26] | 18.155 [note 1] | 0 [note 2] | 2,229 [note 1] | 1,000? A1 [11] | 140,000 [28] | 430 [28] | 75.6 [7] | −51.5/−51.4 [19] | |||
HCFO | R-411A | R-1270/22/152a (1.5+0,–1/87.5+2,–0/11+0,–1) | 1.5+0,–1% C3H6 ·87.5+2,–0% CHClF2 ·11+0,–1% C2H4F2 | GREENCOOL G2018a [9] | 10.834 [note 1] | 0.04375 [note 2] | 1,597 [note 1] | 990 [11] A2 [11] | 14,000 [11] | 46 [11] | 82.4 [7] | −39.7/−37.2 [19] | 99.06 [9] | 4,954 [9] | |
HCFO | R-411B | R-1270/22/152a (3+0,–1/94+2,–0/3+0,–1) | 3+0,–1% C3H6 ·94+2,–0% CHClF2 ·3+0,–1% C2H4F2 | GREENCOOL G2018b [9] | 11.682 [note 1] | 0.047 [note 2] | 1,705 [note 1] | 980 [11] A2 [11] | 13,000 [11] | 45 [11] | 83.1 [7] | −41.6/−41.3 [19] | 95.95 [9] | 4,947 [9] | |
HCFO | R-411C | R-1270/22/152a (3+0,–1/95.5+2,–0/1.5+0,–1) | 3+0,–1% C3H6 ·95.5+2,–0% CHClF2 ·1.5+0,–1% C2H4F2 | GREENCOOL G2018c [9] | 11.841 [note 1] | 0.04775 [note 2] | 1,730 [note 1] | 970? A2? | 12,000? | 44? | 83.4 [7] | 95.5 [9] | 4,950 [9] | ||
HCFC | R-412A | R-22/218/142b (70±2/5±2/25±1) | 70±2% CHClF2 ·5±2% C3F8 ·25±1% C2H3F2Cl | Arcton TP5R [9] | 142.875 [note 1] | 0.0525 [note 2] | 2,286 [note 1] | 1,000 [11] A2 [11] | 22,000 [11] | 82 [11] | 92.2 [7] | −36.4/−28.8 [19] | 107.5 [9] | 4,881 [9] | |
HFC | R-413A | R-218/134a/600a (9±1/88±2/3+0,–1) | 9±1% C3F8 ·88±2% C2H2F4 ·3+0,–1% C4H10 | ISCEON 49 [9] | 246.68? [note 1] | 0 [note 2] | 2,053 [note 1] | 1,000 [11] A2 [11] | 22,000 [11] | 94 [11] | 104 [7] | −29.3/−27.6 [19] | 101.39 [9] | 4,240 [9] | |
HCFC | R-414A | R-22/124/600a/142b (51±2/28.5±2/4±.5/16.5+.5,–1) | 51±2% CHClF2 ·28.5±2% C2HF4Cl ·4±.5% C4H10 ·16.5+.5,–1% C2H3F2Cl | GHG-X4, [9] Autofrost, [9] Chill-It [9] | 11.2065? [note 1] | 0.04332 [note 2] | 1,478 [note 1] | 1,000 [11] A1 [11] | 26,000 [11] | 100 [11] | 96.9 [7] | −34.0/−25.8 [19] | 110.72 [9] | 4,702 [9] | |
HCFC | R-414B | R-22/124/600a/142b (50±2/39±2/1.5±.5/9.5+.5,–1) | 50±2% CHClF2 ·39±2% C2HF4Cl ·1.5±.5% C4H10 ·9.5+.5,–1% C2H3F2Cl | Hot Shot, [9] [26] Kar Kool [9] | 10.1425? [note 1] | 0.04023 [note 2] | 1,362 [note 1] | 1,000 [11] A1 [11] | 23,000 [11] | 95 [11] | 101.5 [7] | −34.4/−26.1 [19] | 108 [9] | 4,592 [9] | |
HCFC | R-415A | R-22/152a (82±1/18±1) | 82±1% CHClF2 ·18±1% C2H4F2 | 10.092 [note 1] | 0.041 [note 2] | 1,507 [note 1] | 1,000 [11] A2 [11] | 57,000 [11] | 190 [11] | 81.9 [7] | −37.5/−34.7 [19] | ||||
HCFC | R-415B | R-22/152a (25±1/75±1) | 25±1% CHClF2 ·75±1% C2H4F2 | 4.05 [note 1] | 0.0125 [note 2] | 546 [note 1] | 1,000 [11] A2 [11] | 52,000 [11] | 120 [11] | 70.2 [7] | −23.4/−21.8 [19] | ||||
HCFC | R-416A | R-134a/124/600 (59+.5,–1/39.5+1,–.5/1.5+1,–.2) | 59+.5,-1% C2H2F4 ·39.5+1,–.5% C2HF4Cl ·1.5+1,–.2% C4H10 | FRIGC (FR-12) [9] | 10.731? [note 1] | 0.00869 [note 2] | 1,084 [note 1] | 1,000 [11] A1 [11] | 14,000 [11] | 62 [11] | 111.9 [7] | −38.0/−32.9 [19] | 108.22 [9] | 4,020 [9] | |
HFC | R-417A | R-125/134a/600 (46.6±1.1/50±1/3.4+.1,–.4) | 46.6±1.1% C2HF5 ·50±1% C2H2F4 ·3.4+.1,–.4% C4H10 | ISCEON 59, [9] NU-22 [9] | 20.922? [note 1] | 0 [note 2] | 2,346 [note 1] | 1,000 [11] A1 [11] | 13,000 [11] | 56 [11] | 106.7 [7] | −41.2/−40.1 [19] | 89.89 [9] | 4,102 [9] | |
HFC | R-417B | R-125/134a/600 (79±1/18.3±1/2.7+.1,–.5) | 79±1% C2HF5 ·18.3±1% C2H2F4 ·2.7+.1,–.5% C4H10 | 25.796? [note 1] | 0 [note 2] | 3,027 [note 1] | 1,000 [29] A1 [29] | 15,000 [29] | 70 [29] | 113.1 [7] | −44.9/−41.5 [29] | ||||
HCFC | R-418A | R-290/22/152a (1.5±.5/96±1/2.5±.5) | 1.5±.5% C3H8 ·96±1% CHClF2 ·2.5±.5% C2H4F2 | 11.735? [note 1] | 0.048 [note 2] | 1,741 [note 1] | 1,000 [11] A2 [11] | 59,000 [11] | 200 [11] | 84.6 [7] | −42.6/−36.0 [19] | ||||
HFC | R-419A | R-125/134a/E170 (77±1/19±1/4±1) | 77±1% C2HF5 ·19±1% C2H2F4 ·4±1% C2H6O | 24.9906 [note 1] | 0 [note 2] | 2,967 [note 1] | 1,000 [11] A2 [11] | 70,000 [11] | 310 [11] | 109.3 [7] | −25.0/−24.2 [19] | ||||
HCFC | R-420A | R-134a/142b (88+1,–0/12+0,–1) | 88+1,–0% C2H2F4 ·12+0,–1% C2H3F2Cl | Choice Refrigerant [26] | 14.468 [note 1] | 0.0084 [note 2] | 1,548 [note 1] | 1,000 [11] A1 [11] | 45,000 [11] | 190 [11] | 101.8 [7] | −34.4/−28.8 [19] | |||
HFC | R-421A | R-125/134a (58±1/42±1) | 58±1% C2HF5 ·42±1% C2H2F4 | Choice R421A [26] | 22.7 [note 1] | 0 [note 2] | 2,631 [note 1] | 1,000 [11] A1 [11] | 61,000 [11] | 280 [11] | 111.7 [7] | ||||
HFC | R-421B | R-125/134a (85±1/15±1) | 85±1% C2HF5 ·15±1% C2H2F4 | Choice 421B [26] | 26.75 [note 1] | 0 [note 2] | 3,190 [note 1] | 1,000 [11] A1 [11] | 69,000 [11] | 330 [11] | 116.9 [7] | ||||
HFC | R-422A | R-125/134a/600a (85.1±1/11.5±1/3.4+.1,–.4) | 85.1±1% C2HF5 ·11.5±1% C2H2F4 ·3.4+.1,–.4% C4H10 | ISCEON 79 [26] | 26.697? [note 1] | 0 [note 2] | 3,143 [note 1] | 1,000 [11] A1 [11] | 63,000 [11] | 290 [11] | 113.6 [7] | ||||
HFC | R-422B (NU-22B) | R-125/134a/600a (55±1/42±1/3+.1,–.5) | 55±1% C2HF5 ·42±1% C2H2F4 ·3+.1,–.5% C4H10 | ICOR XAC1 [26] | 22.19? [note 1] | 0 [note 2] | 2,526 [note 1] | 1,000 [11] A1 [11] | 56,000 [11] | 250 [11] | 108.5 [7] | ||||
HFC | R-422C | R-125/134a/600a (82±1/15±1/3+.1,–.5) | 82±1% C2HF5 ·15±1% C2H2F4 ·3+.1,–.5% C4H10 | ICOR XLT1 [26] | 26.24? [note 1] | 0 [note 2] | 3,085 [note 1] | 1,000 [11] A1 [11] | 62,000 [11] | 290 [11] | 113.4 [7] | ||||
HFC | R-422D | R-125/134a/600a (65.1+.9,–1.1/31.5±1/3.4+.1,–.4) | 65.1+.9,–1.1% C2HF5 ·31.5±1% C2H2F4 ·3.4+.1,–.4% C4H10 | ISCEON MO29 [26] | 23.697? [note 1] | 0 [note 2] | 2,729 [note 1] | 1,000 [11] A1 [11] | 58,000 [11] | 260 [11] | 109.9 [7] | ||||
HFC | R-423A | R-134a/227ea (52.5±1/47.5±1) | 52.5±1% C2H2F4 ·47.5±1% C3HF7 | 23.595 [note 1] | 0 [note 2] | 2,280 [note 1] | 1,000 [11] A1 [11] | 59,000 [11] | 310 [11] | 126 [7] | |||||
HFC | R-424A | R-125/134a/600a/600/601a (50.5±1/47±1/.9+.1,–.2/1+.1,+.2/.6+.1,–.2) | 50.5±1% C2HF5 ·47±1% C2H2F4 ·1.9+.3,–.1% C4H10 ·.6+.1,–.2% C5H12 | RS-44 (new comp.) [26] | 21.525? [note 1] | 0 [note 2] | 2,440? [note 1] | 970 [11] A1 [11] | 23,000 [11] | 100 [11] | 108.4 [7] | ||||
HFC | R-425A | R-32/134a/227ea (18.5±.5/69.5±.5/12±.5) | 18.5±.5% CH2F2 ·69.5±.5% C2H2F4 ·12±.5% C3HF7 | 14.7405 [note 1] | 0 [note 2] | 1,505 [note 1] | 1,000 [11] A1 [11] | 72,000 [28] | 260 [28] | 90.3 [7] | |||||
HFC | R-426A | R-125/134a/600/601a (5.1±1/93±1/1.3+.1,–.2/.6+.1,–.2) | 5.1±1% C2HF5 ·93±1% C2H2F4 ·1.3+.1,–.2% C4H10 ·.6+.1,–.2% C5H12 | RS-24 (new comp.) [26] | 14.727? [note 1] | 0 [note 2] | 1,508? [note 1] | 990 [11] A1 [11] | 20,000 [11] | 83 [11] | 101.6 [7] | ||||
HFC | R-427A | R-32/125/143a/134a (15±2/25±2/10±2/50±2) | 15±2% CH2F2 ·25±2% C2HF5 ·10±2% C2H3F3 ·50±2% C2H2F4 | Forane 427A [26] | 20.185 [note 1] | 0 [note 2] | 2,138 [note 1] | 1,000 [11] A1 [11] | 79,000 [28] | 290 [28] | 90.4 [7] | ||||
HFC | R-428A | R-125/143a/290/600a (77.5±1/20±1/.6+.1,–.2/1.9+.1,–.2) | 77.5±1% C2HF5 ·20±1% C2H3F3 ·.6+.1,–.2% C3H8 ·1.9+.1,–.2% C4H10 | RS-52 [26] | 33.175? [note 1] | <0(smog) [note 2] | 3,607 [note 1] | 1,000 [11] A1 [11] | 83,000 [31] | 370 [31] | 107.5 [7] | ||||
HFC | R-429A | R-E170/152a/600a (60±1/10±1/30±1) | 60±1% C2H6O ·10±1% C2H4F2 ·30±1% C4H10 | 3.749? [note 1] | <0(smog) [note 2] | 13.9 [note 1] | 1,000 [11] A3 [11] | 6,300 [11] | 13 [11] | 50.8 [7] | |||||
HFC | R-430A | R-152a/600a (76±1/24±1) | 76±1% C2H4F2 ·24±1% C4H10 | 3.944? [note 1] | 0 [note 2] | 95 [note 1] | 1,000 [11] A3 [11] | 8,000 [11] | 21 [11] | 64 [7] | |||||
HFC | R-431A | R-290/152a (71±1/29±1) | 71±1% C3H8 ·29±1% C2H4F2 | 8.926? [note 1] | <0(smog) [note 2] | 38.3 [note 1] | 1,000 [11] A3 [11] | 5,500 [11] | 11 [11] | 48.8 [7] | |||||
HO | R-432A | R-1270/E170 (80±1/20±1) | 80±1% C3H6 ·20±1% C2H6O | 9.603? [note 1] | <0(smog) [note 2] | 1.64 [note 1] | 710 [11] A3 [11] | 1,200 [11] | 2.1 [11] | 42.8 [7] | |||||
HO | R-433A | R-1270/290 (30±1/70±1) | 30±1% C3H6 ·70±1% C3H8 | 12 ± 3 [e] | < 0(smog) [e] | 2.85 [note 1] | 880 [11] A3 [11] | 3,100 [11] | 5.5 [11] | 43.5 [7] | −44.6/−44.2? | ||||
HO | R-433B | R-1270/290 (5±1/95±1) | 5±1% C3H6 ·95±1% C3H8 | 12 ± 3 [e] | < 0(smog) [e] | 3.23 [note 1] | 950 [32] A3 [32] | 4,500 [32] | 8.1 [32] | 44 [7] | −42.7/−42.5 [32] | ||||
HO | R-433C | R-1270/290 (25±1/75±1) | 25±1% C3H6 ·75±1% C3H8 | 12 ± 3 [e] | < 0(smog) [e] | 2.93 [note 1] | 790 [32] A3 [32] | 3,600 [32] | 6.6 [32] | 43.6 [7] | −44.3/−43.9 [32] | ||||
HFC | R-434A | R-125/143a/134a/600a (63.2±1/18±1/16±1/2.8+.1,–.2) | 63.2±1% C2HF5 ·18±1% C2H3F3 ·16±1% C2H2F4 ·2.8+.1,–.2% C4H10 | RS-45 [26] | 30.264? [note 1] | 0 [note 2] | 3,245 [note 1] | 1,000 [11] A1 [11] | 73,000 [11] | 320 [11] | 105.7 [7] | −45.0/−42.3 [33] | |||
HFC | R-435A | R-E170/152a (80±1/20±1) | 80±1% C2H6O ·20±1% C2H4F2 | 0.292 [note 1] | <0(smog) [note 2] | 25.6 [note 1] | 1,000 [11] A3 [11] | 8,500 [11] | 17 [11] | 49 [7] | −26.1/−25.9 [11] | ||||
HC | R-436A | R-290/600a (56±1/44±1) | 56±1% C3H8 ·44±1% C4H10 | 12 ± 3 [e] | <0(smog) [note 2] | 3.17 [note 1] | 1,000 [11] A3 [11] | 4,000 [11] | 8 [11] | 49.3 [7] | −34.3/−26.2 [11] | ||||
HC | R-436B | R-290/600a (52±1/48±1) | 52±1% C3H8 ·48±1% C4H10 | 12 ± 3 [e] | <0(smog) [note 2] | 3.16 [note 1] | 1,000 [11] A3 [11] | 4,000 [11] | 8 [11] | 49.9 [7] | −33.4/−25.0 [11] | ||||
HFC | R-437A | R-125/134a/600/601 (19.5+.5,–1.8/78.5+1.5,–.7/1.4+.1,–.2/.6+.1,–.2) | 19.5+.5,–1.8% C2HF5 ·78.5+1.5,–.7% C2H2F4 ·1.4+.1,–.2% C4H10 ·.6+.1,–.2% C5H12 | 16.885? [note 1] | 0 [note 2] | 1,805? [note 1] | 990 [11] A1 [11] | 19,000 [11] | 81 [11] | 103.7 [7] | −32.9/−29.2 [11] | ||||
HFC | R-438A | R-32/125/134a/600/601a (8.5+.5,-1.5/45±1.5/44.2±1.5/1.7+.1,-.2/.6+.1,-.2) | 8.5+.5,-1.5% CH2F2 ·45±1.5% C2HF5 ·44.2±1.5% C2H2F4 ·1.7+.1,-.2% C4H10 ·.6+.1,-.2% C5H12 | KDD5, [26] ISCEON MO99 [26] | 19.9305? [note 1] | 0 [note 2] | 2,265? [note 1] | 990 [27] A1 [27] | 20,000 [28] | 79 [28] | 99.1 [7] | −43.0/−36.4 [27] | |||
HFC | R-439A | R-32/125/600a (50±1/47±1/3±.5) | 50±1% CH2F2 ·47±1% C2HF5 ·3±.5% C4H10 | 16.44? [note 1] | 0 [note 2] | 1,983 [note 1] | 990 [18] A2 [18] | 26,000 [18] | 76 [18] | 71.2 [7] | −52.0/−51.8 [18] | ||||
HFC | R-440A | R-290/134a/152a (.6±.1/1.6±.6/97.8±.5) | .6±.1% C3H8 ·1.6±.6% C2H2F4 ·97.8±.5% C2H4F2 | 1.6652? [note 1] | <0(smog) [note 2] | 144 [note 1] | 1,000 [18] A2 [18] | 12,000 [18] | 31 [18] | 66.2 [7] | −25.5/−24.3 [18] | ||||
HC | R-441A | R-170/290/600a/600 (3.1±.3/54.8±2/6±.6/36.1±2) | 3.1±.3% C2H6 ·54.8±2% C3H8 ·42.1±2.6% C4H10 | HCR-188C [26] | 12 ± 3 [e] | <0(smog) [note 2] | 3.6 [note 1] | 1,000 [18] A3 [18] | 3,200 [18] | 6.3 [18] | 48.3 [7] | −41.9/−20.4 [18] | |||
HFC / HFO [34] | R-448A | R-32/125/134a/1234ze/1234yf (26%/26%/21%/7%/20%) [34] | 26% CH2F2 · 26% C2HF5 · 21% C2H2F4 · 7% C3H2F4 · | Solistice N-40 [34] | 0 [34] | 1273 [34] | A1 [34] | 86.3 [35] | −45.9 [35] | 83.7 [34] | 4,660 [34] | ||||
HFO | R-449A | R-32/R-125/134a/1234yf (24.3%/24.7%/25.7%/25.3%) | 24.3% CH2F2 · 24.7% C2HF5 · 25.7% C2H2F4 · 25.3% C3H2F4 | Forane 449a [36] | 0 | 1,282 [36] | A1 [36] | 87.2 [36] | −45.9 [36] | 81.5 [36] | |||||
HFO | R-452A | R-32/R-125/1234yf (11%/59%/30%) | 11% CH2F2 · 59% C2HF5 · 30% C3H2F4 | Opteon™️ XP44, Solstice® R452A | |||||||||||
HFO | R-452B | R-32/R-125/1234yf (67.0%/7.0%/26.0%) | 67.0% CH2F2 · 7.0% C2HF5 · 26.0% C3H2F4 | Opteon XL55, [37] Solstice L41y [38] | 0 | 676 [37] [38] | A2L [38] | 63.5 [38] | −50.9/−50.1 [38] | 76.0 [38] | 5,220 [38] | ||||
HFC | R-453A | R-32/125/134a/227ea/600/601a (20%/20%/53.8%/5%/0.6%/0.6%) | 20.0% CH2F2 · 20.0% C2HF5 · 53.8% C2H2F4 · 5.0% C3HF7 · 0.6% C4H10 · 0.6% C5H12 | RS-70 [39] | 0 | 1,765 [39] | 1,000 [39] A1 [39] | 88.8 [39] | −42.2 [39] | 87.9 [39] | 4,530 [39] | ||||
HFO | R-454A | R-32/1234yf (35.0%/65.0%) | 35.0% CH2F2 · 65.0% C3H2F4 | Opteon XL40 [40] | 0 | 239 [40] | A2L [40] | 80.5 [40] | −48.3 [40] | 78.9 [40] | |||||
HFO | R-454B | R-32/1234yf (68.9%/31.1%) | 68.9% CH2F2 · 31.1% C3H2F4 | Opteon XL41, [41] Puron Advance [42] | 0 | 466 [41] | A2L [41] | 62.6 [41] | −50.9 [41] | 77.0 [41] | |||||
HFO | R-454C | R-32/1234yf (21.5%/78.5%) | 21.5% CH2F2 · 78.5% C3H2F4 | Opteon XL20 [43] | 0 | 148 [43] | A2L [43] | 90.8 [43] | −45.9 [43] | 82.4 [43] | |||||
HFO | R-455A | R-32/1234yf/744 (75.5%/21.5%/3%) | 21.5% CH2F2 · 75.5% C3H2F4 · 3% CO2 | Solstice L40x [44] | 0 | 146 [44] | A2L [44] | 87.5 [44] | −52.3/−39.4 [44] | 85.6 [44] | 4,660 [44] | ||||
HFO | R-456A | R-32/134a/1234ze(E) (6.0%/45.0%/49.0%) | 6.0% CH2F2 · 45.0% C2H2F4 · 49.0% C3H2F4 | 0 | 687 | 102.4 | |||||||||
HFO | R-457A | R-32/152a/1234yf (18.0%/12.0%/70.0%) | 18.0% CH2F2 · 12.0% C2H4F2 · 70.0% C3H2F4 | Forane 457a [45] | 0 | 139 [46] | A2L [46] | 92.6 | |||||||
HFC | R-458A | R-32/125/134a/227ea/236fa (20.5%/4.0%/61.4%/13.5%/0.6%) | 20.5% CH2F2 · 4.0% C2HF5 · 61.4% C2H3F3 · 13.5% C3HF7 · 0.6% C3H2F6 | 0 | 1,650 [47] | 92.0 | |||||||||
HFO | R-459A | R-32/1234yf(E)/1234ze(E) (68.0%/26.0%/6.0%) | 68.0% CH2F2 · 26.0% C3H2F4 · 6.0% C3H2F4 | Forane 459a [45] | 0 | 460 | |||||||||
HFC/H | R-466A | R-32/125/13I1 (49/11.5/39.5) | 49% CH2F2 · 11.5% C2HF5 · 39.5% CIF3 | Solstice N41 [48] | 0 [48] | 733 [48] | A1 [48] | −51.7 [48] | 76.5 [48] | 5144 [48] | |||||
HCFC | R-500 | R-12/152a (73.8/26.2) | 73.8% CCl2F2 ·26.2% C2H4F2 | Carrene #7 [9] | 74.1668 [note 1] | 0.738 [note 2] | 8,077 [note 1] | 1,000 [11] A1 [11] | 30,000 [11] | 120 [11] | 99.3 [7] | −33/0 [19] | 102.15 [9] | 4,173 [9] | |
HCFC | R-501 | R-22/12 (75/25) | 75% CHClF2 ·25% CCl2F2 | 34 [note 1] | 0.2875 [note 2] | 4,083 [note 1] | 1,000 [11] A1 [11] | 54,000 [11] | 210 [11] | 93.1 [7] | −41/−41 [19] | 96.19 [9] | 4,764 [9] | ||
HCFC | R-502 | R-22/115 (48.8/51.2) | 48.8% CHClF2 ·51.2% C2F5Cl | 876.256 [note 1] | 0.24968 [note 2] | 4,657 [note 1] | 1,000 [11] A1 [11] | 73,000 [11] | 330 [11] | 111.6 [7] | −45/19 [19] | 80.73 [9] | 4,019 [9] | ||
HCFC | R-503 | R-23/13 (40.1/59.9) | 40.1% CHF3 ·59.9% CClF3 | 491.63 [note 1] | 0.599 [note 2] | 14,560 [note 1] | 1,000 [11] A1? | 40,000? | 200? | 87.2 [7] | −88/88 [19] | 18.43 [9] | 4,265 [9] | ||
HCFC | R-504 | R-32/115 (48.2/51.8) | 48.2% CH2F2 ·51.8% C2F5Cl | 882.9618 [note 1] | 0.22792 [note 2] | 4,143 [note 1] | 1,000 [11] A1? | 140,000 [28] | 450 [28] | 79.2 [7] | −57/17 [19] | 62.13 [9] | 4,439 [9] | ||
HCFC | R-505 | R-12/31 (78/22) | 78% CCl2F2 ·22% CH2FCl | 78.0836+ [note 1] | 0.7844 [note 2] | 8,504+ [note 1] | 350? B2? | 10,000? | 20? | 103.5 [7] | −30/115 [19] | 117.78 [9] | 4,730 [9] | ||
HCFC | R-506 | R-31/114 (55.1/44.9) | 55.1% CH2FCl ·44.9% C2F4Cl2 | 134.90938+ [note 1] | 0.46002 [note 2] | 4,495+ [note 1] | 350? B2? | 10,000? | 20? | 93.7 [7] | −12/18 [19] | 142.22 [9] | 5,157 [9] | ||
HFC | R-507[A] | R-125/143a (50/50) | 50% C2HF5 ·50% C2H3F3 | AZ-50 [9] [26] | 40.5 [note 1] | 0 [note 2] | 3,985 [note 1] | 1,000 [11] A1 [11] | 130,000 [11] | 520 [11] | 98.9 [7] | −46.7/−40 [19] | 70.74 [9] | 3,715 [9] | |
HFC | R-508[A] | R-23/116 (39/61) | 39% CHF3 ·61% C2F6 | Klea 5R3 [9] [26] | 6,205.3 [note 1] | 0 [note 2] | 13,214 [note 1] | 1,000 [11] A1 [11] | 55,000 [11] | 220 [11] | 100.1 [7] | −86/−86 [19] | 11.01 [9] | 3,701 [9] | |
HFC | R-508B | R-23/116 (46/54) | 46% CHF3 ·54% C2F6 | Suva 95 [9] [26] | 5,524.2 [note 1] | 0 [note 2] | 13,396 [note 1] | 1,000 [11] A1 [11] | 52,000 [11] | 200 [11] | 95.4 [7] | -88.3/−45.6 [19] | 12.06 [9] | 3,834 [9] | |
HCFC | R-509[A] | R-22/218 (44/56) | 44% CHClF2 ·56% C3F8 | Arcton TP5R2 [9] | 1,461.28 [note 1] | 0.022 [note 2] | 5,741 [note 1] | 1,000 [11] A1 [11] | 75,000 [11] | 390 [11] | 124 [7] | −47/0 [19] | 87.22 [9] | 4,033 [9] | |
HC | R-510[A] | R-E170/600a (88±.5/12±.5) | 88±.5% C2H6O ·12±.5% C4H10 | 1.4532? [note 1] | <0(smog) [note 2] | 1.24 [note 1] | 1,000 [11] A3 [11] | 7,300 [11] | 14 [11] | 47.2 [7] | −25.2/−25.2 [11] | ||||
HC | R-511[A] | R-290/E170 (95±1/5±1) | 95±1% C3H8 ·5±1% C2H6O | 11.40075? [note 1] | < 0(smog) [e] | 3.19 [note 1] | 1,000 [28] A3 [28] | 5,300 [28] | 9.5 [28] | 44.2 [7] | −42.1/−20-40 [28] | ||||
HFO | R-513A | R-1234yf/134a (56%/44%) | 56% C3H2F4 ·44% C2H2F4 | 0 [49] | 573 [49] | A1 [49] | 108.4 [49] | −29.4 [49] | 96.5 [49] | 3,766 [46] | |||||
HFO | R-514A | R-1336mzz-Z/trans-1,2-Dichloroethene(t-DCE)(74.7%/25.3%) [50] | 74.7% C4H2F6 ·25.3% C2H2CL2 [51] | 0 | 2 | B1 | 139.6 | 29.1 | 96.5 | 3,520 | |||||
HFO | R-515B | R-1234ze/227ea | 299 [52] | ||||||||||||
HC | R-600 | Butane | C4H10 or CH3CH2CH2CH3 | 106-97-8 | 6.8 days [22] | 0 [17] | 4.0 [3] –6.5 [22] | 1,000 [11] A3 [11] | 4,000? | 9.6? | 58.1 [7] | 0 [19] ±1 [8] | 152.01 [9] | 3,796 [9] | |
HC | R-600a | Isobutane | C4H10 or CH(CH3)2CH3 | 75-28-5 | 12 ± 3 [53] [e] | 0 [17] [54] | 3 [54] | 1,000 [11] A3 [11] | 4,000 [11] | 9.6 [11] | 58.1 [7] | −11.7 [8] | 134.7 [9] | 3,640 [9] | |
HC | R-601 | Pentane | C5H12 or CH3CH2CH2CH2CH3 | 109-66-0 | 12 ± 3 [e] | 0 [17] | 4 ± 2 [f] | 600 [11] A3 [33] | 1,000 [33] | 2.9 [33] | 72.1 [7] | 36.1 [33] ±.2 [8] | 196.56 [9] | 3,358 [9] | |
HC | R-601a | Isopentane | C5H12 or (CH3)2CHCH2CH3 | 78-78-4 | 12 ± 3 [e] | 0 [17] | 4 ± 2 [f] | 600 [11] A3 [11] | 1,000 [11] | 2.9 [11] | 72.1 [7] | 27.7 [8] | 187.78 [9] | 3,378 [9] | |
HC | R-610 | Ethoxyethane (Diethyl ether) | CH3CH2OCH2CH3 | 60-29-7 | 12 ± 3 [e] | < 0(smog) [e] | 4 ± 2 [f] | 400 [11] A3? | 74.1 [7] | 34.6 [8] | 193.65 [9] | 3,640 [9] | |||
HC | R-611 | Methyl formate | HCOOCH3 | 107-31-3 | 12 ± 3 [e] | 0 [17] [54] | < 25 [17] [54] | 100 [11] B2 [11] | 60.1 [7] | 32 [8] [19] | 213.55 [9] | 6,000 [9] | |||
HC | HC-12a | Propane/isobutane [55] | 40–70% C3H8 · 30–60% C4H6 (by volume) | −33 | |||||||||||
HC | HC-22a | Propane [55] | C3H8 98% by volume | −42 | |||||||||||
HC | HC-502a | Propane/ethane [55] | C3H8 60–100% · C2H6 3-7% (by volume) | −49 | |||||||||||
HFC / HFO | DR-14A [56] | 415 | −20.4 | 110.7 | 3,960 | ||||||||||
HFC | SP34E [57] | R-134a (98.5%) | C2H2F4 (98.5%) | ||||||||||||
R-630 | Methylamine | CH3NH2 | 74-89-5 | 31.1 [7] | −6 [8] | 156.89 [9] | 7,460 [9] | ||||||||
R-631 | Ethylamine | CH3CH2(NH2) | 75-04-7 | 45.1 [7] | 16.6 [8] | 183 [9] | 5,620 [9] | ||||||||
R-702 | Hydrogen | H2 | 1333-74-0 | 5.8 [3] | A3 [11] | 2.016 [7] | −252.87 [8] | −239.95 [21] | 1,300 [21] | ||||||
R-704 | Helium | He | 7440-59-7 | Unlimited [g] | 0 [g] | 0 [g] | 9,340? A1 [11] | 4.002 [7] | −268.93 [8] | −267.96 [21] | 227 [21] | ||||
R-717 | Ammonia | NH3 | 7664-41-7 | < 0.019165 [58] | 0 [58] | 0 [58] | 25 [11] B2L [18] | 320 [11] | 0.22 [11] | 17.03 [7] | −33.34 [8] | 132.4 [59] | 11,280 [59] | ||
R-718 | Water/Steam | H2O | 7732-18-5 | 0.026 | 0 [60] | 0.2 ± 0.2 [3] | A1 [11] | 18.02 [7] | 100 [19] | 373.946 [21] | 22,060 [21] | ||||
R-720 | Neon | Ne | 7440-01-9 | Unlimited [g] | 0 [g] | 0 [g] | 9,340? A1 [11] | 20.18 [7] | −246.08 [8] | −228.75 [21] | 2,760 [21] | ||||
R-728 | Nitrogen | N2 | 7727-37-9 | Unlimited [g] | 0 [g] | 0 [g] | A1 [11] | 28.01 [7] | −195.79 [8] | −146.9 [21] | 3,390 [21] | ||||
R-729 | Air N2/O2/Ar (78.082/20.945/.934 vol%) | 78.082% N2 ·20.945% O2 ·.934% Ar | Unlimited [g] | 0 [60] [g] | 0.00054+ [3] | A1? | 28.97 [7] | −192.97? | −140.53 [9] | 3,785 [9] | |||||
R-732 | Oxygen | O2 | 7782-44-7 | Unlimited [g] | < 0 [g] | 0 [g] | A1? | 32 [7] | −182.95 [8] | −118.6 [21] | 5,050 [21] | ||||
R-740 | Argon | Ar | 7440-37-1 | Unlimited [g] | 0 [g] | 0 [g] | 9,340? A1 [11] | 39.95 [7] | −185.85 [8] | −122.4 [21] | 4,870 [21] | ||||
R-744 | Carbon dioxide | CO2 | 124-38-9 | 29,300-36,100 [61] | 0 [17] | 1 [3] | 5,000 [11] A1 [11] | 40,000 [11] | 72 [11] | 44 [7] | −56.56 at 518 kPa [note 3] [62] | 31.04 [21] | 7,380 [21] | ||
R-744A | Nitrous oxide | N2O | 10024-97-2 | 114 [3] | 0.017 [20] | 265 [5] | A1? | 44 [7] | −88.48 [8] | 36.4 [21] | 7,240 [21] | ||||
R-764 | Sulfur dioxide | SO2 | 7446-09-5 | 5 [63] B1 [11] | 100 [63] | 0.262 [63] | 64.1 [7] | −10 [8] [19] | 157.65 [9] | 7,880 [9] | |||||
R-784 | Krypton | Kr | 7439-90-9 | Unlimited [g] | 0 [g] | 0 [g] | 9,340? A1? | 83.80 [7] | −153.22 [8] | −63.8 [21] | 5,500 [21] | ||||
CFO | R-1112a | 1,1-Dichloro-2,2-difluoroethylene | C2Cl2F2 | 79-35-6 | 132.9 [7] | ||||||||||
CFO | R-1113 | Chlorotrifluoroethylene | C2ClF3 | 79-38-9 | 116.5 [7] | −27.8 [8] | |||||||||
PFO | R-1114 | Tetrafluoroethylene | C2F4 | 116-14-3 | 0 [d] | 100 [7] | −76.3 [8] | ||||||||
HCO | R-1120 | Trichloroethylene (trielene) | C2HCl3 | 79-01-6 | 131.4 [7] | 87.2 [8] | 297.78 [9] | 4,909 [9] | |||||||
HCO | R-1130(E) | trans-1,2-Dichloroethylene | C2H2Cl2 | 156-60-5 | 0 [17] | < 25 [17] | 96.9 [7] | 48.5 [8] | 243.28 [9] | 5,481 [9] | |||||
HFO | R-1132a | 1,1-Difluoroethylene | C2H2F2 | 75-38-7 | 0 [d] | 64 [7] | −83 [64] | 29.7 [9] | 4,458 [9] | ||||||
HCO | R-1140 | Chloroethylene (vinyl chloride) | C2H3Cl | 75-01-4 | 100? B3 [6] | 62.5 [7] | −13.4 [8] | 151.83 [9] | 5,150 [9] | ||||||
HFO | R-1141 | Fluoroethylene (vinyl fluoride) | C2H3F | 75-02-5 | 0 [d] | 46 [7] | −72.2 [8] | ||||||||
HO | R-1150 | Ethene (Ethylene) | CH2=CH2 | 74-85-1 | 12 ± 3 [e] | < 0(smog) [e] | 3.7 [3] | 200 [11] A3 [11] | 28.05 [7] | −103.7 [8] | 9.19 [9] | 5,040 [9] | |||
PFO | R-1216 | Hexafluoropropylene | C3F6 | 116-15-4 | 1,000+ [3] [4] | 0 [d] | 17,340+ [3] | 150 [7] | −28 [8] | ||||||
PFO | R-1218 | Hexafluoropropene trimer | (C3F6)3 | 6792-31-0 | 0 [d] | 450.1 [7] | |||||||||
HCFO | R-1224yd(Z) | (Z)-2,3,3,3,-Tetrafluoro-1-Chloropropene [65] [66] [67] | (Z)-CF3-CF=CHCl | 111512-60-8 | 0.032 (21 days) [68] | 0.00012 [68] | <1 [68] | 148.5 [68] | 14°C [68] | 156°C [68] | 3330 [68] | ||||
HCFO | R-1233zd(E) | trans-1-chloro-3,3,3-trifluoropropene | C3H2ClF3 | 102687-65-0 | 0.0712328 [69] | 0 [69] | 1 [69] | 130.5 [7] | 19 | ||||||
HFO | R-1234yf | 2,3,3,3-Tetrafluoropropene | C3H2F4 | 754-12-1 | 0.030116 [70] | 0 [54] | <1 [54] [71] [70] | 500 [72] A2L [18] | 16,000 [73] | 75 [73] | 114 [7] | −29.4 [73] | |||
HFO | R-1234ze(E) | trans-1,3,3,3-tetrafluoropropene | C3H2F4 | 29118-24-9 | 0 [54] | <1 [54] [71] | 800 [28] A2L [28] | 16,000 [28] | 75 [28] | 114 [7] | −19.0 [8] [28] | ||||
HO | R-1270 | Propene (Propylene) | C3H6 or CH3CH=CH2 | 115-07-1 | 12 ± 3 [e] | < 0(smog) [e] | 1.8 [3] | 500 [11] A3 [11] | 1,000 [11] | 1.7 [11] | 42.1 [7] | −47.6 [8] | 92.42 [9] | 4,665 [9] | |
HFO | R-1336mzz(E) [56] | trans-1,1,1,4,4,4-hexafluoro-2-butene | C4H2F6 | 66711-86-2 | 0 | 18 | 7.5 | 137.7 | 3,150 | ||||||
HFO | R-1336mzz(Z) (DR-2) [56] [74] | cis-1,1,1,4,4,4-hexafluoro-2-butene | CF3CH=CHCF3(Z) | 692-49-9 | 0 | 2 | A1 | 37.4 | 171.3 | 2,900 | |||||
T y p e | ASHRAE number | IUPAC chemical name | Molecular formula | CAS no/ blend name | Atmospheric lifetime (years) | Semi- empirical ODP | Net GWP 100-yr | OEL/PEL ppm (v/v) & ASHRAE 34 safety group | RCL/IDLH | Molecular mass u | Boiling, or bubble/dew /azeotropic point(s) °C | Critical temp. °C | Critical pressure, absolute kPa | ||
ppm (v/v) | g/m3 |
|
LFL = Lower Flammability Limit |
Compounds used as refrigerants may be described using either the appropriate prefix above or with the prefixes "R-" or "Refrigerant." Thus, CFC-12 may also be written as R-12 or Refrigerant 12.
An alkene, olefin, or olefine is an unsaturated compound containing at least one carbon-carbon double bond. [78]
Chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs) are fully or partly halogenated hydrocarbons that contain carbon (C), hydrogen (H), chlorine (Cl), and fluorine (F), produced as volatile derivatives of methane, ethane, and propane.
A refrigerant is a working fluid used in cooling, heating or reverse cooling and heating of air conditioning systems and heat pumps where they undergo a repeated phase transition from a liquid to a gas and back again. Refrigerants are heavily regulated because of their toxicity and flammability and the contribution of CFC and HCFC refrigerants to ozone depletion and that of HFC refrigerants to climate change.
Dichlorodifluoromethane (R-12) is a colorless gas popularly known by the genericized brand name Freon. It is a chlorofluorocarbon halomethane (CFC) used as a refrigerant and aerosol spray propellant. In compliance with the Montreal Protocol, its manufacture was banned in developed countries in 1996, and in developing countries in 2010 out of concerns about its damaging effect on the ozone layer. Its only allowed usage is as a fire retardant in submarines and aircraft. It is soluble in many organic solvents. R-12 cylinders are colored white.
Chlorodifluoromethane or difluoromonochloromethane is a hydrochlorofluorocarbon (HCFC). This colorless gas is better known as HCFC-22, or R-22, or CHClF
2. It was commonly used as a propellant and refrigerant. These applications were phased out under the Montreal Protocol in developed countries in 2020 due to the compound's ozone depletion potential (ODP) and high global warming potential (GWP), and in developing countries this process will be completed by 2030. R-22 is a versatile intermediate in industrial organofluorine chemistry, e.g. as a precursor to tetrafluoroethylene.
R-410A is a refrigerant used in air conditioning and heat pump applications. It is a zeotropic but near-azeotropic mixture of difluoromethane (CH2F2, called R-32) and pentafluoroethane (CHF2CF3, called R-125). R-410A is sold under the trademarked names AZ-20, EcoFluor R410, Forane 410A, Genetron R410A, Puron, and Suva 410A.
Natural refrigerants are considered substances that serve as refrigerants in refrigeration systems. They are alternatives to synthetic refrigerants such as chlorofluorocarbon (CFC), hydrochlorofluorocarbon (HCFC), and hydrofluorocarbon (HFC) based refrigerants. Unlike other refrigerants, natural refrigerants can be found in nature and are commercially available thanks to physical industrial processes like fractional distillation, chemical reactions such as Haber process and spin-off gases. The most prominent of these include various natural hydrocarbons, carbon dioxide, ammonia, and water. Natural refrigerants are preferred actually in new equipment to their synthetic counterparts for their presumption of higher degrees of sustainability. With the current technologies available, almost 75 percent of the refrigeration and air conditioning sector has the potential to be converted to natural refrigerants.
2,3,3,3-Tetrafluoropropene, HFO-1234yf, is a hydrofluoroolefin (HFO) with molecular formula CH2=CFCF3. Its primary application is as a refrigerant with low global warming potential (GWP).
Air changes per hour, abbreviated ACPH or ACH, or air change rate is the number of times that the total air volume in a room or space is completely removed and replaced in an hour. If the air in the space is either uniform or perfectly mixed, air changes per hour is a measure of how many times the air within a defined space is replaced each hour. Perfectly mixed air refers to a theoretical condition where supply air is instantly and uniformly mixed with the air already present in a space, so that conditions such as age of air and concentration of pollutants are spatially uniform.
1,1-Dichloro-1-fluoroethane is a haloalkane with the formula C
2H
3Cl
2F. It is one of the three isomers of dichlorofluoroethane. It belongs to the hydrochlorofluorocarbon (HCFC) family of man-made compounds that contribute significantly to both ozone depletion and global warming when released into the environment.
R-407C is a mixture of hydrofluorocarbons used as a refrigerant. It is a zeotropic blend of difluoromethane (R-32), pentafluoroethane (R-125), and 1,1,1,2-tetrafluoroethane (R-134a). Difluoromethane serves to provide the heat capacity, pentafluoroethane decreases flammability, tetrafluoroethane reduces pressure. R-407C cylinders are colored burnt orange.
1-Chloro-1,1-difluoroethane (HCFC-142b) is a haloalkane with the chemical formula CH3CClF2. It belongs to the hydrochlorofluorocarbon (HCFC) family of man-made compounds that contribute significantly to both ozone depletion and global warming when released into the environment. It is primarily used as a refrigerant where it is also known as R-142b and by trade names including Freon-142b.
SRF Limited is an Indian multi-business chemicals conglomerate engaged in the manufacturing of industrial and specialty intermediates. The company’s business portfolio covers fluorochemicals, specialty chemicals, packaging films, technical textiles, coated and laminated fabrics. It has a workforce of more than 8,000 employees across eleven manufacturing plants in India Thailand, South Africa and Hungary. The company exports to more than 90 countries.
Hydrofluoroolefins (HFOs) are unsaturated organic compounds composed of hydrogen, fluorine and carbon. These organofluorine compounds are of interest as refrigerants. Unlike traditional hydrofluorocarbons (HFCs) and chlorofluorocarbons (CFCs), which are saturated, HFOs are olefins, otherwise known as alkenes.
trans-1,3,3,3-Tetrafluoropropene (HFO-1234ze(E), R-1234ze(E)) is a hydrofluoroolefin. It was developed as a "fourth generation" refrigerant to replace fluids such as R-134a, as a blowing agent for foam and aerosol applications, and in air horns and gas dusters. The use of R-134a is being phased out because of its high global warming potential (GWP). HFO-1234ze(E) itself has zero ozone-depletion potential (ODP=0), a very low global warming potential (GWP < 1 ), even lower than CO2, and it is classified by ANSI/ASHRAE as class A2L refrigerant (lower flammability (see below) and lower toxicity).
The American Society of Heating, Refrigerating and Air-Conditioning Engineers is an American professional association seeking to advance heating, ventilation, air conditioning and refrigeration (HVAC&R) systems design and construction. ASHRAE has over 50,000 members in more than 130 countries worldwide.
Barbara Haviland Minor is an American chemical engineer, known for the development of refrigerants. She was technical leader for chemical company DuPont in the development of R-1234yf, a refrigerant which, as of 2018, was used in 50% of all new vehicles produced by original equipment manufacturers, and which represented an important contribution to countering global warming.
R-454B, also known by the trademarked names Opteon XL41, Solstice 454B, and Puron Advance, is a zeotropic blend of 68.9 percent difluoromethane (R-32), a hydrofluorocarbon, and 31.1 percent 2,3,3,3-tetrafluoropropene (R-1234yf), a hydrofluoroolefin. Because of its reduced global warming potential (GWP), R-454B is intended to be an alternative to refrigerant R-410A in new equipment. R-454B has a GWP of 466, which is 78 percent lower than R-410A's GWP of 2088.
Life Cycle Climate Performance (LCCP) is an evolving method to evaluate the carbon footprint and global warming impact of heating, ventilation, air conditioning (AC), refrigeration systems, and potentially other applications such as thermal insulating foam. It is calculated as the sum of direct, indirect, and embodied greenhouse gas (GHG) emissions generated over the lifetime of the system “from cradle to grave,” i.e. from manufacture to disposal. Direct emissions include all climate forcing effects from the release of refrigerants into the atmosphere, including annual leakage and losses during service and disposal of the unit. Indirect emissions include the climate forcing effects of GHG emissions from the electricity powering the equipment. The embodied emissions include the climate forcing effects of the manufacturing processes, transport, and installation for the refrigerant, materials, and equipment, and for recycle or other disposal of the product at end of its useful life.
R-469A is a refrigerant blend consisting of 35% carbon dioxide (R-744), 32.5% difluoromethane (R-32), and 32.5% pentafluoroethane (R-125).
The Significant New Alternatives Policy is a program of the EPA to determine acceptable chemical substitutes, and establish which are prohibited or regulated by the EPA. It also establishes a program by which new alternatives may be accepted, and promulgates timelines to the industry regarding phase-outs of substitutes.
Methane's influence on ozone is very dependent on altitude. In the troposphere and lower stratosphere it induces ozone production via "smog chemistry"(10), while at higher altitudes it causes ozone losses [...] The net effect is generally a gain in column ozone due to methane increases, both in the stratospheric column and total column(11). Thus, unlike for N2O, a calculated ODP for methane would likely be negative.