List of refrigerants

Last updated

This is a list of refrigerants, sorted by their ASHRAE-designated numbers, commonly known as R numbers. Many modern refrigerants are human-made halogenated gases, especially fluorinated gases and chlorinated gases, that are frequently referred to as Freon (a registered trademark of Chemours).

Contents

Numbering scheme

According to ASHRAE standard 34, the R-number of a chemical refrigerant is assigned systematically according to its molecular structure and has between two and four digits. If there are carbon-carbon multiple bonds, there are four digits in all: the number of these bonds is the first digit and the number of carbon atoms minus one (C-1) is next. If there is more than one carbon atom but no multiple bonds, there are three digits, and the number of carbon atoms minus one is the first digit. If there is only one carbon atom, then there are only two digits. The last two digits are always the number of hydrogen atoms plus one (H+1), followed by the number of fluorine atoms. Any other atoms attached to the carbons are assumed to be chlorine atoms. For example, R-22 has one carbon atom, one hydrogen atom (2−1 = 1), two fluorine atoms, and one chlorine atom (4−2−1 = 1), so it is chlorodifluoromethane, while R-134 has two carbon atoms (2−1 = 1), two hydrogen atoms (3−1 = 2), four fluorine atoms, and no chlorine atoms (6−2−4 = 0), so it is one of the tetrafluoroethanes. This basic scheme is modified as follows:

There are separate numbering schemes for zeotropic and azeotropic blends, organic chemicals which don't fit into the scheme above, and inorganic chemicals:

Columns

The table is sortable by each of the following refrigerant properties (scroll right or reduce magnification to view more properties):

Since over 100,000 refrigerant blends are possible, [2] this list should only have notable refrigerants and refrigerant blends.

List

Type ASHRAE
number		 IUPAC chemical name Molecular
formula 		CAS no/
blend
name		 Atmospheric
lifetime
(years)		Semi-
empirical
ODP
(R-11 = 1)		Net
GWP
100-yr
(R-744 = 1)		 OEL/PEL
ppm (v/v) &
ASHRAE  34
safety group		RCL/IDLH
(ppm v/v, followed by g/m3)		 Molecular
mass
u 		Boiling, or
bubble/dew
/azeotropic
point(s) °C		Critical
temp.
°C		Critical
pressure,
absolute
kPa
PCCR-10 Carbon tetrachloride (Tetrachloromethane) CCl456-23-526 [3] [4] 0.73 [4] 1,400 [5] 100? B1 [6] 153.8 [7] 76.72 [8] 283.35 [9] 4,560 [9]
CFCR-11 Trichlorofluoromethane CCl3F75-69-445 [3] [4] 1.0 [4] 4,660 [10] 1,000 [11] A1 [11] 1,100 [11] 6.2 [11] 137.4 [7] 23.77 [8] 197.96 [9] 4,408 [9]
CFCR-12 Dichlorodifluoromethane CCl2F275-71-8100 [3] [4] 1.0 [4] 10,200 [10] 1,000 [11] A1 [11] 18,000 [11] 90 [11] 120.9 [7] −29.8 [8] 111.97 [9] 4,136 [9]
HR-12B1 Bromochlorodifluoromethane CBrClF2 or CF2ClBr353-59-316 [3] [4] 7.1 [4] 1,750 [5] 165.4 [7] −3.7 [8] 153.8 [9] 4,102 [9]
HR-12B2 Dibromodifluoromethane CBr2F275-61-62.9 [4] 1.7 [4] 209.8 [7] 22.8 [8] 198.11 [9] 4,130 [9]
CFCR-13 Chlorotrifluoromethane CClF375-72-9640 [3] 1 [12] 13,900 [10] 1,000 [11] A1 [11] 40,000?200?104.5 [7] −81.5 [8] 28.73 [9] 3,877 [9]
HR-13B1 Bromotrifluoromethane CBrF3 or CF3Br75-63-865 [3] [4] 16 [4] 6,290 [5] 1,000 [11] A1 [11] 148.9 [7] −57.75 [8] 67 [9] 3,964 [9]
HR-13I1 Trifluoroiodomethane CF3I2314-97-8500 [13] A1 [13] 195.9 [13] −21.9 [13]
PFCR-14 Tetrafluoromethane CF475-73-050,000 [3] 0 [14] 7,390 [3] 1,000 [11] A1 [11] 110,000 [11] 400 [11] 88 [7] −127.8 [8] −45.64 [9] 3,750 [9]
HCCR-20 Chloroform (Trichloromethane) CHCl367-66-30.51 [3] 31 [3] 119.4 [7] 61.2 [8] 262.35 [9] 5,480 [9]
HCFCR-21 Dichlorofluoromethane CHFCl275-43-41.7 [4] 0.04 [15] 148 [5] 100? B1 [11] 102.9 [7] 8.92 [8] 178.45 [9] 5,180 [9]
HCFCR-22 Chlorodifluoromethane CHClF275-45-612.0 [3] [4] 0.055 [4] [16] 1,760 [5] 1,000 [11] A1 [11] 59,000 [11] 210 [11] 86.5 [7] −40.7 [8] 96.14 [9] 4,990 [9]
HR-22B1 Bromodifluoromethane CHBrF2 or CHF2Br1511-62-25.8 [4] 0.74 [12] 404 [4] 130.9 [7] −14.6 [8] 138.83 [9] 5,132 [9]
HFCR-23 Trifluoromethane (Fluoroform) CHF375-46-7270 [3] 0 [14] 12,400 [5] 1,000 [11] A1 [11] 41,000 [11] 120 [11] 70 [7] −82.1 [8] 25.92 [9] 4,836 [9]
HCCR-30 Dichloromethane (Methylene chloride) CH2Cl275-09-20.38 [3] 0 [17] 8.7 [3] 100? B2 [11] 84.9 [7] 39.6 [8] 235.15 [9] 6,080 [9]
HCFCR-31 Chlorofluoromethane CH2FCl593-70-40.02 [15] 350? B2?10,000?20?68.5 [7] −9.1 [8] 151.76 [9] 5,131 [9]
HFCR-32 Difluoromethane CH2F275-10-54.9 [3] 0 [14] 677 [5] 1,000 [11] A2L [18] 36,000 [11] 77 [11] 52 [7] −52 [8] [19] 78.11 [9] 5,782 [9]
HCCR-40 Chloromethane CH3Cl74-87-31.0 [3] [4] 0.02 [4] 13 [3] 100? B2 [11] 50.5 [7] −24.2 [8] 143.05 [9] 6,660 [9]
HFCR-41 Fluoromethane CH3F593-53-32.4 [3] 0 [14] 116 [5] 34 [7] −78.2 [8] 44.13 [9] 5,897 [9]
HCR-50 Methane CH474-82-812 ± 3 [3] 28 [5] 1,000 [11] A3 [11] 9,000?9?16.04 [7] −162±2 [8] −82.3 [21] 4,640 [21]
PCCR-110 Hexachloroethane C2Cl667-72-1236.7 [7] 431.28 [9] 3,937 [9]
CFCR-111 Pentachlorofluoroethane C2FCl5354-56-31 [12] 220.3 [7] 135 [8]
CFCR-112 1,1,2,2-Tetrachloro-1,2-difluoroethane C2F2Cl476-12-01 [12] 203.8 [7]
CFCR-112a 1,1,1,2-Tetrachloro-2,2-difluoroethane C2F2Cl476-11-91 [lower-alpha 1] 203.8 [7]
CFCR-113 1,1,2-Trichloro-1,2,2-trifluoroethane C2F3Cl376-13-185 [3] [4] 1.0 [4] 5,820 [10] 1,000 [11] A1 [11] 2,600 [11] 20 [11] 187.4 [7] 48 [19] 214.06 [9] 3,392 [9]
CFCR-113a 1,1,1-Trichloro-2,2,2-trifluoroethane C2F3Cl3354-58-51 [lower-alpha 1] 187.4 [7]
CFCR-114 1,2-Dichlorotetrafluoroethane C2F4Cl276-14-2300 [3] [4] 1.0 [4] 8,590 [10] 1,000 [11] A1 [11] 20,000 [11] 140 [11] 170.9 [7] 3.5 [8] 145.68 [9] 3,257 [9]
CFCR-114a 1,1-Dichlorotetrafluoroethane C2F4Cl2374-07-21 [lower-alpha 1] 170.9 [7]
HR-114B2 Dibromotetrafluoroethane C2F4Br2 or CF2BrCF2Br124-73-220 [3] [4] 11.5 [4] 1,470 [5] 259.8 [7] 47.3 [8] 214.67 [9]
CFCR-115 Chloropentafluoroethane C2F5Cl76-15-31,700 [3] [4] 0.44 [4] 7,670 [5] 1,000 [11] A1 [11] 120,000 [11] 760 [11] 154.5 [7] −39.1 [8] 79.95 [9] 3,120 [9]
PFCR-116 Hexafluoroethane C2F676-16-410,000 [3] 0 [14] 12,200 [3] 1,000 [11] A1 [11] 97,000 [11] 550 [11] 138 [7] −78.2 [8] 19.88 [9] 3,042 [9]
HCCR-120 Pentachloroethane C2HCl576-01-7202.3 [7]
HCFCR-121 1,1,2,2-Tetrachloro-1-fluoroethane C2HFCl4354-14-3185.8 [7]
HCFCR-121a 1,1,1,2-Tetrachloro-2-fluoroethane C2HFCl4354-11-0185.8 [7]
HCFCR-122 1,1,2-Trichloro-2,2-difluoroethane C2HF2Cl3354-21-2169.4 [7]
HCFCR-122a 1,1,2-Trichloro-1,2-difluoroethane C2HF2Cl3354-15-4169.4 [7]
HCFCR-122b 1,1,1-Trichloro-2,2-difluoroethane C2HF2Cl3354-12-1169.4 [7]
HCFCR-123 2,2-Dichloro-1,1,1-trifluoroethane C2HF3Cl2306-83-21.3 [3] [4] 0.02 [4] 79 [5] 50 [11] B1 [11] 9,100 [11] 57 [11] 152.9 [7] 27.6 [8] 183.68 [9] 3,662 [9]
HCFCR-123a 1,2-Dichloro-1,1,2-trifluoroethane C2HF3Cl2354-23-41.3? [lower-alpha 3] 0.02? [lower-alpha 2] 77? [lower-alpha 3] 152.9 [7]
HCFCR-123b 1,1-Dichloro-1,2,2-trifluoroethane C2HF3Cl2812-04-41.3? [lower-alpha 3] 0.02? [lower-alpha 2] 77? [lower-alpha 3] 152.9 [7]
HCFCR-124 1-Chloro-1,2,2,2-tetrafluoroethane C2HF4Cl2837-89-05.8 [3] [4] 0.022 [4] 527 [5] 1,000 [11] A1 [11] 10,000 [11] 56 [11] 136.5 [7] −12 [19] 122.28 [9] 3,624 [9]
HCFCR-124a 1-Chloro-1,1,2,2-tetrafluoroethane C2HF4Cl354-25-65.8? [lower-alpha 3] 0.022? [lower-alpha 2] 609? [lower-alpha 3] 136.5 [7]
HFCR-125 Pentafluoroethane C2HF5354-33-629 [3] 0 [14] 3,170 [5] 1,000 [11] A1 [11] 75,000 [11] 370 [11] 120 [7] −48.5 [8] 66.18 [9] 3,629 [9]
HFCR- Pentafluorodimethyl ether C2F5OC2F53822-68-2136 [3] 0 [lower-alpha 4] 14,900 [3] 136 [7]
HCCR-130 1,1,2,2-Tetrachloroethane C2H2Cl479-34-5167.8 [7] 146.5 [8] 388.06 [9] 5,840 [9]
HCCR-130a 1,1,1,2-Tetrachloroethane C2H2Cl4630-20-6167.8 [7] 130.5 [8]
HCFCR-131 1,1,2-Trichloro-2-fluoroethane C2H2FCl3359-28-4151.4 [7]
HCFCR-131a 1,1,2-Trichloro-1-fluoroethane C2H2FCl3811-95-0151.4 [7]
HCFCR-131b 1,1,1-Trichloro-2-fluoroethane C2H2FCl32366-36-1151.4 [7]
HCFCR-132 1,2-Dichloro-1,2-difluoroethane C2H2F2Cl2431-06-1134.9 [7]
HCFCR-132a 1,1-Dichloro-2,2-difluoroethane C2H2F2Cl2471-43-2134.9 [7]
HCFCR-132b 1,2-Dichloro-1,1-difluoroethane C2H2F2Cl21649-08-7134.9 [7]
HCFCR-132c 1,1-Dichloro-1,2-difluoroethane C2H2F2Cl21842-05-3134.9 [7]
HR-132bB2 1,2-Dibromo-1,1-difluoroethane C2H2Br2F275-82-1223.8 [7]
HCFCR-133 1-Chloro-1,2,2-Trifluoroethane C2H2F3Cl431-07-2118.5 [7]
HCFCR-133a 1-Chloro-2,2,2-Trifluoroethane C2H2F3Cl75-88-7118.5 [7]
HCFCR-133b 1-Chloro-1,1,2-Trifluoroethane C2H2F3Cl421-04-5118.5 [7]
HFCR-134 1,1,2,2-Tetrafluoroethane C2H2F4359-35-39.6 [3] 0 [14] 1,120 [5] 102 [7]
HFCR-134a 1,1,1,2-Tetrafluoroethane C2H2F4811-97-214 [3] 0 [14] [17] 1,300 [5] 1,000 [11] A1 [11] 50,000 [11] 210 [11] 102 [7] −26.3 [8] 101.06 [9] 4,059 [9]
HFCR- Bis(difluoromethyl)ether C2H2F4O1691-17-426 [3] 0 [lower-alpha 4] 6,320 [3] 118 [7]
HCCR-140 1,1,2-Trichloroethane C2H3Cl379-00-5133.4 [7] 112.5±2.5 [8]
HCCR-140a 1,1,1-Trichloroethane (Methyl chloroform) C2H3Cl3 or CH3CCl371-55-65.0 [3] [4] 0.12 [4] 160 [5] 133.4 [7] 74 [8]
HCFCR-141 1,2-Dichloro-1-fluoroethane C2H3FCl2430-57-99.3? [lower-alpha 3] 0.12? [lower-alpha 2] 725? [lower-alpha 3] 116.9 [7]
HR-141B2 1,2-Dibromo-1-fluoroethane C2H3Br2F358-97-4205.9 [7]
HCFCR-141a 1,1-Dichloro-2-fluoroethane C2H3FCl2430-53-59.3? [lower-alpha 3] 0.12? [lower-alpha 2] 725? [lower-alpha 3] 116.9 [7]
HCFCR-141b 1,1-Dichloro-1-fluoroethane C2H3FCl21717-00-69.3 [3] [4] 0.12 [4] 725 [3] 500 [11] A2?2,600 [11] 12 [11] 116.9 [7] 32 [8] [19] 204.2 [9] 4,250 [9]
HCFCR-142a 1-Chloro-1,2-difluoroethane C2H3F2Cl338-64-717.9? [lower-alpha 3] 0.07? [lower-alpha 2] 2,310? [lower-alpha 3] 100.5 [7]
HCFCR-142b 1-Chloro-1,1-difluoroethane C2H3F2Cl75-68-317.9 [3] [4] 0.07 [4] 2,310 [3] 1,000 [11] A2 [11] 20,000 [11] 83 [11] 100.5 [7] −10 [8] [19] 137.1 [9] 4,123 [9]
HFCR-143 1,1,2-Trifluoroethane C2H3F3430-66-03.5 [3] 0 [14] 328 [5] 84 [7]
HFCR-143a 1,1,1-Trifluoroethane C2H3F3420-46-252 [3] 0 [14] 4,800 [5] 1,000 [11] A2L [18] 21,000 [11] 70 [11] 84 [7] −47.6 [8] 72.89 [9] 3,776 [9]
HFCR- Methyl trifluoromethyl ether C2H3F3O421-14-74.3 [3] 0 [lower-alpha 4] 756 [3] 100 [7]
HCCR-150 1,2-Dichloroethane C2H4Cl2107-06-299 [7] 84 [8] 292.83 [9] 5,370 [9]
HCCR-150a 1,1-Dichloroethane C2H4Cl275-34-399 [7] 57.2 [8] 249.83 [9] 5,070 [9]
HCFCR-151 1-Chloro-2-fluoroethane C2H4ClF762-50-582.5 [7]
HCFCR-151a 1-Chloro-1-fluoroethane C2H4ClF1615-75-482.5 [7]
HFCR-152 1,2-Difluoroethane C2H4F2624-72-60.60 [3] 0 [lower-alpha 4] 16 [5] 66 [7]
HFCR-152a 1,1-Difluoroethane C2H4F275-37-61.4 [3] 0 [14] [17] 138 [5] 1,000 [11] A2 [11] 12,000 [11] 32 [11] 66 [7] −25 [8] [19] 113.26 [9] 4,517 [9]
HCCR-160 Chloroethane (ethyl chloride)C2H5Cl75-00-364.5 [7] 12.3 [8] 187.28 [9] 5,268 [9]
HFCR-161 Fluoroethane C2H5F353-36-60.3 [3] 0 [lower-alpha 4] 4 [5] 48.1 [7] 102.22 [9] 4,702 [9]
HCR-170 Ethane C2H6 or CH3CH374-84-058 days [22] 5.5 [3] –10.2 [22] 1,000 [11] A3 [11] 7,000 [11] 8.7 [11] 30.07 [7] −88.6 [8] [23] 32.18 [9] 4,872 [9]
HCR- Dimethyl ether CH3OCH3115-10-60.015 [3] 1 [3] 1,000 [11] A3 [11] 8,500 [11] 16 [11] 46.1 [7] −24 [8]
CFCR-211 1,1,1,2,2,3,3-Heptachloro-3-fluoropropane C3FCl7422-78-61 [12] 303.2 [7]
CFCR-212 Hexachlorodifluoropropane C3F2Cl6134452-44-11 [12] 286.7 [7]
CFCR-213 1,1,1,3,3-Pentachloro-2,2,3-trifluoropropane C3F3Cl52354-06-51 [12] 270.3 [7]
CFCR-214 1,2,2,3-Tetrachloro-1,1,3,3-tetrafluoropropane C3F4Cl42268-46-41 [12] 253.8 [7]
CFCR-215 1,1,1-Trichloro-2,2,3,3,3-pentafluoropropane C3F5Cl34259-43-21 [12] 237.4 [7]
CFCR-216 1,2-Dichloro-1,1,2,3,3,3-hexafluoropropane C3F6Cl2661-97-21 [12] 220.9 [7]
CFCR-216ca 1,3-Dichloro-1,1,2,2,3,3-hexafluoropropane C3F6Cl2662-01-11 [lower-alpha 1] 220.9 [7]
CFCR-217 1-Chloro-1,1,2,2,3,3,3-heptafluoropropane C3F7Cl422-86-61 [12] 204.5 [7]
CFCR-217ba 2-Chloro-1,1,1,2,3,3,3-heptafluoropropane C3F7Cl76-18-61 [lower-alpha 1] 204.5 [7]
PFCR-218 Octafluoropropane C3F876-19-72,600 [3] 0 [14] 8,830 [3] 1,000 [11] A1 [11] 90,000 [11] 690 [11] 188 [7] −36.7 [8]
HCFCR-221 1,1,1,2,2,3-Hexachloro-3-fluoropropane C3HFCl6422-26-4268.7 [7]
HCFCR-222 Pentachlorodifluoropropane C3HF2Cl5134237-36-8252.3 [7]
HCFCR-222c 1,1,1,3,3-Pentachloro-2,2-difluoropropane C3HF2Cl5422-49-1252.3 [7]
HCFCR-223 Tetrachlorotrifluoropropane C3HF3Cl4134237-37-9235.8 [7]
HCFCR-223ca 1,1,3,3-Tetrachloro-1,2,2-trifluoropropane C3HF3Cl4422-52-6235.8 [7]
HCFCR-223cb 1,1,1,3-Tetrachloro-2,2,3-trifluoropropane C3HF3Cl4422-50-4235.8 [7]
HCFCR-224 Trichlorotetrafluoropropane C3HF4Cl3134237-38-0219.4 [7]
HCFCR-224ca 1,3,3-Trichloro-1,1,2,2-tetrafluoropropane C3HF4Cl3422-54-8219.4 [7]
HCFCR-224cb 1,1,3-Trichloro-1,2,2,3-tetrafluoropropane C3HF4Cl3422-53-7219.4 [7]
HCFCR-224cc 1,1,1-Trichloro-2,2,3,3-tetrafluoropropane C3HF4Cl3422-51-5219.4 [7]
HCFCR-225 Dichloropentafluoropropane C3HF5Cl2127564-92-5202.9 [7]
HCFCR-225aa 2,2-Dichloro-1,1,1,3,3-pentafluoropropane C3HF5Cl2128903-21-9202.9 [7]
HCFCR-225ba 2,3-Dichloro-1,1,1,2,3-pentafluoropropane C3HF5Cl2422-48-0202.9 [7]
HCFCR-225bb 1,2-Dichloro-1,1,2,3,3-pentafluoropropane C3HF5Cl2422-44-6202.9 [7]
HCFCR-225ca 3,3-Dichloro-1,1,1,2,2-pentafluoropropane C3HF5Cl2422-56-01.9 [3] [4] 0.02 [4] 127 [5] 202.9 [7]
HCFCR-225cb 1,3-Dichloro-1,1,2,2,3-pentafluoropropane C3HF5Cl2507-55-15.8 [3] [4] 0.03 [4] 525 [5] 202.9 [7]
HCFCR-225cc 1,1-Dichloro-1,2,2,3,3-pentafluoropropane C3HF5Cl213474-88-9202.9 [7]
HCFCR-225da 1,2-Dichloro-1,1,3,3,3-pentafluoropropane C3HF5Cl2431-86-7202.9 [7]
HCFCR-225ea 1,3-Dichloro-1,1,2,3,3-pentafluoropropane C3HF5Cl2136013-79-1202.9 [7]
HCFCR-225eb 1,1-Dichloro-1,2,3,3,3-pentafluoropropane C3HF5Cl2111512-56-2202.9 [7]
HCFCR-226 Chlorohexafluoropropane C3HF6Cl134308-72-8186.5 [7]
HCFCR-226ba 2-Chloro-1,1,1,2,3,3-hexafluoropropane C3HF6Cl51346-64-6186.5 [7]
HCFCR-226ca 3-Chloro-1,1,1,2,2,3-hexafluoropropane C3HF6Cl422-57-1186.5 [7]
HCFCR-226cb 1-Chloro-1,1,2,2,3,3-hexafluoropropane C3HF6Cl422-55-9186.5 [7]
HCFCR-226da 2-Chloro-1,1,1,3,3,3-hexafluoropropane C3HF6Cl431-87-8186.5 [7]
HCFCR-226ea 1-Chloro-1,1,2,3,3,3-hexafluoropropane C3HF6Cl359-58-0186.5 [7]
HFCR-227ca 1,1,2,2,3,3,3-Heptafluoropropane C3HF72252-84-80 [lower-alpha 4] 170 [7]
HFCR-227ca2 Trifluoromethyl 1,1,2,2-tetrafluoroethyl ether C3HF7O2356-61-80 [lower-alpha 4] 186 [7]
HFCR-227ea 1,1,1,2,3,3,3-Heptafluoropropane C3HF7431-89-034.2 [3] 0 [14] [17] 3,350 [5] 1,000 [11] A1 [11] 84,000 [11] 580 [11] 170 [7] −16.4 [8] 102.8 [9] 2,980 [9]
HFCR-227me Trifluoromethyl 1,2,2,2-tetrafluoroethyl ether C3HF7O2356-62-911 [4] 0 [lower-alpha 4] 1,540 [4] 186 [7]
HCFCR-231 Pentachlorofluoropropane C3H2FCl5134190-48-0234.3 [7]
HCFCR-232 Tetrachlorodifluoropropane C3H2F2Cl4134237-39-1217.9 [7]
HCFCR-232ca 1,1,3,3-Tetrachloro-2,2-difluoropropane C3H2F2Cl41112-14-7217.9 [7]
HCFCR-232cb 1,1,1,3-Tetrachloro-2,2-difluoropropane C3H2F2Cl4677-54-3217.9 [7]
HCFCR-233 Trichlorotrifluoropropane C3H2F3Cl3134237-40-4201.4 [7]
HCFCR-233ca 1,1,3-Trichloro-2,2,3-trifluoropropane C3H2F3Cl3131221-36-8201.4 [7]
HCFCR-233cb 1,1,3-Trichloro-1,2,2-trifluoropropane C3H2F3Cl3421-99-8201.4 [7]
HCFCR-233cc 1,1,1-Trichloro-2,2,3-trifluoropropane C3H2F3Cl3131211-71-7201.4 [7]
HCFCR-234 Dichlorotetrafluoropropane C3H2F4Cl2127564-83-4184.9 [7]
HCFCR-234aa 2,2-Dichloro-1,1,3,3-tetrafluoropropane C3H2F4Cl217705-30-5184.9 [7]
HCFCR-234ab 2,2-Dichloro-1,1,1,3-tetrafluoropropane C3H2F4Cl2149329-24-8184.9 [7]
HCFCR-234ba 1,2-Dichloro-1,2,3,3-tetrafluoropropane C3H2F4Cl2425-94-5184.9 [7]
HCFCR-234bb 2,3-Dichloro-1,1,1,2-tetrafluoropropane C3H2F4Cl2149329-25-9184.9 [7]
HCFCR-234bc 1,2-Dichloro-1,1,2,3-tetrafluoropropane C3H2F4Cl2149329-26-0184.9 [7]
HCFCR-234ca 1,3-Dichloro-1,2,2,3-tetrafluoropropane C3H2F4Cl270341-81-0184.9 [7]
HCFCR-234cb 1,1-Dichloro-2,2,3,3-tetrafluoropropane C3H2F4Cl24071-01-6184.9 [7]
HCFCR-234cc 1,3-Dichloro-1,1,2,2-tetrafluoropropane C3H2F4Cl2422-00-4184.9 [7]
HCFCR-234cd 1,1-Dichloro-1,2,2,3-tetrafluoropropane C3H2F4Cl270192-63-1184.9 [7]
HCFCR-234da 2,3-Dichloro-1,1,1,3-tetrafluoropropane C3H2F4Cl2146916-90-7184.9 [7]
HCFCR-234fa 1,3-Dichloro-1,1,3,3-tetrafluoropropane C3H2F4Cl276140-39-1184.9 [7]
HCFCR-234fb 1,1-Dichloro-1,3,3,3-tetrafluoropropane C3H2F4Cl264712-27-2184.9 [7]
HCFCR-235 Chloropentafluoropropane C3H2F5Cl134237-41-5168.5 [7]
HCFCR-235ca 1-Chloro-1,2,2,3,3-pentafluoropropane C3H2F5Cl28103-66-4168.5 [7]
HCFCR-235cb 3-Chloro-1,1,1,2,3-pentafluoropropane C3H2F5Cl422-02-6168.5 [7]
HCFCR-235cc 1-Chloro-1,1,2,2,3-pentafluoropropane C3H2F5Cl679-99-2168.5 [7]
HCFCR-235da 2-Chloro-1,1,1,3,3-pentafluoropropane C3H2F5Cl134251-06-2168.5 [7]
HCFCR-235fa 1-Chloro-1,1,3,3,3-pentafluoropropane C3H2F5Cl677-55-4168.5 [7]
HFCR-236cb 1,1,1,2,2,3-Hexafluoropropane C3H2F6677-56-513.6 [3] 0 [lower-alpha 4] 1,210 [5] 152 [7] −1.5
HFCR-236ea 1,1,1,2,3,3-Hexafluoropropane C3H2F6431-63-010.7 [3] 0 [14] 1,330 [5] 152 [7] 139.29 [9] 3,502 [9]
HFCR-236fa 1,1,1,3,3,3-Hexafluoropropane C3H2F6690-39-1240 [3] 0 [14] 8,060 [5] 1,000 [11] A1 [11] 55,000 [11] 340 [11] 152 [7] −1.05±.35 [8] 124.92 [9] 3,200 [9]
HFCR-236me 1,2,2,2-Tetrafluoroethyl difluoromethyl ether C3H2F6O57041-67-55.8 [4] 0 [lower-alpha 4] 989 [4] 168 [7]
HCFCR-241 Tetrachlorofluoropropane C3H3FCl4134190-49-1199.9 [7]
HCFCR-242 Trichlorodifluoropropane C3H3F2Cl3134237-42-6183.4 [7]
HCFCR-243 Dichlorotrifluoropropane C3H3F3Cl2134237-43-7167 [7]
HCFCR-243ca 1,3-Dichloro-1,2,2-trifluoropropane C3H3F3Cl267406-68-2167 [7]
HCFCR-243cb 1,1-Dichloro-2,2,3-trifluoropropane C3H3F3Cl270192-70-0167 [7]
HCFCR-243cc 1,1-Dichloro-1,2,2-trifluoropropane C3H3F3Cl27125-99-7167 [7]
HCFCR-243da 2,3-Dichloro-1,1,1-trifluoropropane C3H3F3Cl2338-75-0167 [7]
HCFCR-243ea 1,3-Dichloro-1,2,3-trifluoropropane C3H3F3Cl2151771-08-3167 [7]
HCFCR-243ec 1,3-Dichloro-1,1,2-trifluoropropane C3H3F3Cl2149329-27-1167 [7]
HCFCR-244 Chlorotetrafluoropropane C3H3F4Cl134190-50-4150.5 [7]
HCFCR-244ba 2-Chloro-1,2,3,3-tetrafluoropropane C3H3F4Cl149329-28-2150.5 [7]
HCFCR-244bb 2-Chloro-1,1,1,2-tetrafluoropropane C3H3F4Cl421-73-8150.5 [7]
HCFCR-244ca 3-Chloro-1,1,2,2-tetrafluoropropane C3H3F4Cl679-85-6150.5 [7]
HCFCR-244cb 1-Chloro-1,2,2,3-tetrafluoropropane C3H3F4Cl67406-66-0150.5 [7]
HCFCR-244cc 1-Chloro-1,1,2,2-tetrafluoropropane C3H3F4Cl421-75-0150.5 [7]
HCFCR-244da 2-Chloro-1,1,3,3-tetrafluoropropane C3H3F4Cl19041-02-2150.5 [7]
HCFCR-244db 2-Chloro-1,1,1,3-tetrafluoropropane C3H3F4Cl117970-90-8150.5 [7]
HCFCR-244ea 3-Chloro-1,1,2,3-tetrafluoropropane C3H3F4Cl150.5 [7]
HCFCR-244eb 3-Chloro-1,1,1,2-tetrafluoropropane C3H3F4Cl151771-09-4150.5 [7]
HCFCR-244ec 1-Chloro-1,1,2,3-tetrafluoropropane C3H3F4Cl149448-09-9150.5 [7]
HCFCR-244fa 3-Chloro-1,1,1,3-tetrafluoropropane C3H3F4Cl149329-29-3150.5 [7]
HCFCR-244fb 1-Chloro-1,1,3,3-tetrafluoropropane C3H3F4Cl2730-64-5150.5 [7]
HFCR-245ca 1,1,2,2,3-Pentafluoropropane C3H3F5679-86-76.2 [3] 0 [14] 716 [5] 134 [7] 174.42 [9] 3,925 [9]
HFCR-245cb Pentafluoropropane C3H3F51814-88-60 [lower-alpha 4] 134 [7]
HFCR-245ea 1,1,2,3,3-Pentafluoropropane C3H3F524270-66-40 [lower-alpha 4] 134 [7]
HFCR-245eb 1,1,1,2,3-Pentafluoropropane C3H3F5431-31-20 [lower-alpha 4] 134 [7]
HFCR-245fa 1,1,1,3,3-Pentafluoropropane C3H3F5460-73-17.6 [3] 0 [14] [17] 858 [5] 300 [11] B1 [11] 34,000 [11] 190 [11] 134 [7] 15 [19] 154.05 [9] 3,640 [9]
HFCR-245mc Methyl pentafluoroethyl ether C3H3F5O22410-44-20 [lower-alpha 4] 150 [7]
HFCR-245mf Difluoromethyl 2,2,2-trifluoroethyl ether C3H3F5O1885-48-92.2 [4] 0 [lower-alpha 4] 286 [4] 150 [7]
HFCR-245qc Difluoromethyl 1,1,2-trifluoroethyl ether C3H3F5O69948-24-90 [lower-alpha 4] 150 [7]
HCFCR-251 Trichlorofluoropropane C3H4FCl3134190-51-5165.4 [7]
HCFCR-252 Dichlorodifluoropropane C3H4F2Cl2134190-52-6149 [7]
HCFCR-252ca 1,3-Dichloro-2,2-difluoropropane C3H4F2Cl21112-36-3149 [7]
HCFCR-252cb 1,1-Dichloro-2,2-difluoropropane C3H4F2Cl21112-01-2149 [7]
HCFCR-252dc 1,2-Dichloro-1,1-difluoropropane C3H4F2Cl27126-15-0149 [7]
HCFCR-252ec 1,1-Dichloro-1,2-difluoropropane C3H4F2Cl2151771-10-7149 [7]
HCFCR-253 Chlorotrifluoropropane C3H4F3Cl134237-44-8132.5 [7]
HCFCR-253ba 2-Chloro-1,2,3-trifluoropropane C3H4F3Cl151771-11-8132.5 [7]
HCFCR-253bb 2-Chloro-1,1,2-trifluoropropane C3H4F3Cl69202-10-4132.5 [7]
HCFCR-253ca 1-Chloro-2,2,3-trifluoropropane C3H4F3Cl56758-54-4132.5 [7]
HCFCR-253cb 1-Chloro-1,2,2-trifluoropropane C3H4F3Cl70192-76-6132.5 [7]
HCFCR-253ea 3-Chloro-1,1,2-trifluoropropane C3H4F3Cl121612-65-5132.5 [7]
HCFCR-253eb 1-Chloro-1,2,3-trifluoropropane C3H4F3Cl151771-12-9132.5 [7]
HCFCR-253ec 1-Chloro-1,1,2-trifluoropropane C3H4F3Cl134251-05-1132.5 [7]
HCFCR-253fa 3-Chloro-1,3,3-trifluoropropane C3H4F3Cl132.5 [7]
HCFCR-253fb 3-Chloro-1,1,1-trifluoropropane C3H4F3Cl460-35-5132.5 [7]
HCFCR-253fc 1-Chloro-1,1,3-trifluoropropane C3H4F3Cl83124-56-5132.5 [7]
HFCR-254cb 1,1,2,2-Tetrafluoropropane C3H4F440723-63-50 [lower-alpha 4] 116.1 [7]
HFCR-254pc Methyl 1,1,2,2-tetrafluoroethyl ether C3H4F4O425-88-72.6 [3] 0 [lower-alpha 4] 359 [3] 132.1 [7]
HCFCR-261 Dichlorofluoropropane C3H5FCl2134237-45-9131 [7]
HCFCR-261ba 1,2-Dichloro-2-fluoropropane C3H5FCl2420-97-3131 [7]
HCFCR-262 Chlorodifluoropropane C3H5F2Cl134190-53-7114.5 [7]
HCFCR-262ca 1-Chloro-2,2-difluoropropane C3H5F2Cl420-99-5114.5 [7]
HCFCR-262fa 3-Chloro-1,1-difluoropropane C3H5F2Cl83124-57-6114.5 [7]
HCFCR-262fb 1-Chloro-1,3-difluoropropane C3H5F2Cl151771-13-0114.5 [7]
HFCR-263 Trifluoropropane C3H5F394458-05-60 [lower-alpha 4] 98.1 [7]
HCFCR-271 Chlorofluoropropane C3H6FCl134190-54-896.5 [7]
HCFCR-271b 2-Chloro-2-fluoropropane C3H6FCl420-44-096.5 [7]
HCFCR-271d 2-Chloro-1-fluoropropane C3H6FCl20372-78-596.5 [7]
HCFCR-271fb 1-Chloro-1-fluoropropane C3H6FCl430-55-796.5 [7]
HFCR-272 Difluoropropane C3H6F294458-04-50 [lower-alpha 4] 80.1 [7]
HFCR-281 Fluoropropane C3H7F106857-11-80 [lower-alpha 4] 62.1 [7]
HCR-290 Propane C3H8 or CH3CH2CH374-98-613 days [22] 3.3 [3] –9.5 [22] 1,000 [11] A3 [11] 5,300 [11] 9.5 [11] 44.1 [7] −42.1±.2 [8] 96.7 [9] 4,248 [9]
CFCR- Dichlorohexafluorocyclobutane C4Cl2F6356-18-374.6 ± 3(E),114.1 ± 10 (Z) [24] 0.40(E), 0.49(Z) [24] 4,160(E), 5,400(Z) [24] 232.9 [7]
CFCR- Chloroheptafluorocyclobutane C4ClF7377-41-3216.5 [7]
PFCR- Octafluorocyclobutane (Perfluorocyclobutane) C4F8 or -(CF2)4-115-25-33,200 [3] 0 [14] 10,300 [3] 1,000 [11] A1 [11] 69,000 [11] 570 [11] 200 [7] −6 [8] [19] 115.23 [9] 2,777 [9]
PFCR- Decafluorobutane (Perfluorobutane) C4F10355-25-92,600 [3] 0 [14] 8,860 [3] 238 [7] −1.7 [8]
HFCR-329ccb 1,1,1,2,2,3,3,4,4-Nonafluorobutane C4HF9375-17-70 [lower-alpha 4] 220 [7]
HFCR-338eea1,1,1,2,3,4,4,4-OctafluorobutaneC4H2F875995-72-10 [lower-alpha 4] 202 [7]
HFCR-347ccd 1,1,1,2,2,3,3-Heptafluorobutane C4H3F7662-00-00 [lower-alpha 4] 184.1 [7]
HFCR-347mcc Perfluoropropyl methyl ether C4H3F7O375-03-15.2 [3] 0 [lower-alpha 4] 575 [3] 200.1 [7]
HFCR-347mmy Perfluoroisopropyl methyl ether C4H3F7O22052-84-23.4 [4] 0 [lower-alpha 4] 343 [4] 200.1 [7]
HFCR-365mfc 1,1,1,3,3-Pentafluorobutane C4H5F5406-58-68.6 [3] 0 [14] [17] 804 [3] 148.1 [7]
PFCR- Dodecafluoropentane (Perfluoropentane) C5F12678-26-24,100 [3] 0 [14] 9,160 [3] 288 [7]
PFCR- Tetradecafluorohexane (Perfluorohexane) C6F14355-42-03,200 [3] 0 [14] 9,300 [3] 338 [7] 56 [8]
CFCR-400R-12/114(50/50 wt%) OR
(60/40)(must be specified)		50% CCl2F2 ·50% C2F4Cl2 OR
60% CCl2F2 ·40% C2F4Cl2		1.0 [note 2] 1,000 [11] A1 [11]
1,000 [11] A1 [11]
HCFCR-401AR-22/152a/124 (53±2/13+.5,-1.5/34±1)53±2% CHClF2 ·13+.5,-1.5% C2H4F2 ·34±1% C2HF4ClMP-39 [9] [26] 8.514 [note 1] 0.03398 [note 2] 1,182 [note 1] 1,000 [11] A1 [11] 27,000 [11] 110 [11] 94.4 [7] 105.27 [9] 4,613 [9]
HCFCR-401BR-22/152a/124 (61±2/11+.5,-1.5/28±1)61±2% CHClF2 ·11+.5,-1.5% C2H4F2 ·28±1% C2HF4ClMP-66 [9] [26] 9.098 [note 1] 0.03666 [note 2] 1,288 [note 1] 1,000 [11] A1 [11] 30,000 [11] 120 [11] 92.8 [7] 103.54 [9] 4,682 [9]
HCFCR-401CR-22/152a/124 (33±2/15+.5,-1.5/52±1)33±2% CHClF2 ·15+.5,-1.5% C2H4F2 ·52±1% C2HF4ClMP-52 [26] 7.186 [note 1] 0.02794 [note 2] 933 [note 1] 1,000 [11] A1 [11] 20,000 [11] 84 [11] 101 [7]
HCFCR-402AR-125/290/22 (60±2/2±1/38±2)60±2% C2HF5 ·2±1% C3H8 ·38±2%  CHClF2HP-80 [9] [26] 22.2? [note 1] 0.019 [note 2] 2,788 [note 1] 1,000 [11] A1 [11] 33,000 [11] 140 [11] 101.5 [7] 76.03 [9] 4,234 [9]
HCFCR-402BR-125/290/22 (38±2/2±1/60±2)38±2% C2HF5 ·2±1% C3H8 ·60±2% CHClF2HP-81 [9] [26] 18.46? [note 1] 0.03 [note 2] 2,416 [note 1] 1,000 [11] A1 [11] 63,000 [11] 240 [11] 94.7 [7] 83.03 [9] 4,525 [9]
HCFCR-403AR-290/22/218 (5+.2,-2/75±2/20±0)5+.2,-2% C3H8 ·75±2% CHClF2 ·20±0% C3F8ISCEON 69-S [9] 529.6? [note 1] 0.0375 [note 2] 3,124 [note 1] 1,000 [11] A2 [27] 33,000 [11] 120 [11] 92 [7] 91.22 [9] 4,688 [9]
HCFCR-403BR-290/22/218 (5+.2,-2/56±2/39±0)5+.2,-2% C3H8 ·56±2% CHClF2 ·39±0% C3F8ISCEON 69-L [9] 1,021.32? [note 1] 0.028 [note 2] 4,457 [note 1] 1,000 [11] A1 [11] 70,000 [11] 290 [11] 103.3 [7] 88.72 [9] 4,399 [9]
HFCR-404AR-125/143a/134a (44±2/52±1/4±2)44±2% C2HF5 ·52±1% C2H3F3 ·4±2% C2H2F4HP-62, [9] [26] FX-70 [9] [26] 40.36 [note 1] 0 [note 2] 3,922 [note 1] 1,000 [11] A1 [11] 130,000 [11] 500 [11] 97.6 [7] 72.14 [9] 3,735 [9]
HCFCR-405AR-22/152a/142b/C318 (45±0/7±1/5.5±1/42.5±2)45±0% CHClF2 ·7±1% C2H4F2 ·5.5±1% C2H3F2Cl ·42.5±2% C4F8GREENCOOL G2015 [9] 1,366.4825 [note 1] 0.02635 [note 2] 5,328 [note 1] 1,000 [11] A1?57,000 [11] 260 [11] 111.9 [7] 106 [9] 4,289 [9]
HCFC R-406A R-22/600a/142b (55±2/4±1/41±0)55±2% CHClF2 ·4±1% C4H10 ·41±0% C2H3F2ClGHG [9] [26] 14.419? [note 1] 0.0562 [note 2] 1,943 [note 1] 1,000 [11] A2 [11] 21,000 [11] 25 [11] 89.9 [7] 116.5 [9] 4,881 [9]
HCFCR-406BR-22/600a/142b (65±2/4±1/31±0)65±2% CHClF2 ·4±1% C4H10 ·31±0% C2H3F2ClGHG-HP [9] 13.829? [note 1] 0.0542 [note 2] 1,893 [note 1] 1,000? A2?21,000?25?88.6 [7]
HFC R-407A R-32/125/134a (20±2/40±2/40±2)20±2% CH2F2 ·40±2% C2HF5 ·40±2% C2H2F4Klea 60 [9] [26] 18.18 [note 1] 0 [note 2] 2,107 [note 1] 1,000 [11] A1 [11] 83,000 [28] 300 [28] 90.1 [7] 81.91 [9] 4,487 [9]
HFCR-407BR-32/125/134a (10±2/70±2/20±2)10±2% CH2F2 ·70±2% C2HF5 ·20±2% C2H2F4Klea 61 [9] 23.59 [note 1] 0 [note 2] 2,804 [note 1] 1,000 [11] A1 [11] 79,000 [28] 330 [28] 102.9 [7] 74.38 [9] 4,083 [9]
HFC R-407C R-32/125/134a (23±2/25±2/52±2)23±2% CH2F2 ·25±2% C2HF5 ·52±2% C2H2F4Klea 66, [9] AC9000 [26] 15.657 [note 1] 0 [note 2] 1,774 [note 1] 1,000 [11] A1 [11] 81,000 [28] 290 [28] 86.2 [7] 86.05 [9] 4,634 [9]
HFCR-407DR-32/125/134a (15±2/15±2/70±2)15±2% CH2F2 ·15±2% C2HF5 ·70±2% C2H2F414.885 [note 1] 0 [note 2] 1,627 [note 1] 1,000 [11] A1 [11] 68,000 [28] 250 [28] 91 [7] 91.57 [9] 4,483 [9]
HFCR-407ER-32/125/134a (25±2/15±2/60±2)25±2% CH2F2 ·15±2% C2HF5 ·60±2% C2H2F413.975 [note 1] 0 [note 2] 1,552 [note 1] 1,000 [11] A1 [11] 80,000 [28] 280 [28] 83.8 [7] 88.77 [9] 4,734 [9]
HFCR-407FR-32/125/134a (30±2/30±2/40±2)30±2% CH2F2 ·30±2% C2HF5 ·40±2% C2H2F4Genetron Performax LT [26] 15.77 [note 1] 0 [note 2] 1,825 [note 1] 1,000 [29] A1 [29] 95,000 [28] 320 [28] 82.1 [7]
HCFCR-408AR-125/143a/22 (7±2/46±1/47±2)7±2% C2HF5 ·46±1% C2H3F3 ·47±2% CHClF2FX-10 [9] [26] 31.59 [note 1] 0.0235 [note 2] 3,152 [note 1] 1,000 [11] A1 [11] 95,000 [11] 340 [11] 87 [7] 83.5 [9] 4,340 [9]
HCFCR-409AR-22/124/142b (60±2/25±2/15±1)60±2% CHClF2 ·25±2% C2HF4Cl ·15±1% C2H3F2ClFX-56 [9] [26] 11.335 [note 1] 0.046 [note 2] 1,585 [note 1] 1,000 [11] A1 [11] 29,000 [11] 110 [11] 97.4 [7] 106.92 [9] 4,600 [9]
HCFCR-409BR-22/124/142b (65±2/25±2/10±1)65±2% CHClF2 ·25±2% C2HF4Cl ·10±1% C2H3F2ClFX-57 [9] 11.04 [note 1] 0.045 [note 2] 1,560 [note 1] 1,000 [11] A1 [11] 30,000 [11] 120 [11] 96.7 [7] 104.36 [9] 4,711 [9]
HFC R-410A R-32/125 (50+.5,–1.5/50+1.5,–.5)50+.5,–1.5% CH2F2 ·50+1.5,–.5% CHF2CF3 [30] AZ-20, [9] Puron, [9] Suva 9100 [9] 16.95 [note 1] 0 [note 2] 2,088 [note 1] 1,000 [11] A1 [11] 140,000 [28] 420 [28] 72.6 [7] 70.17 [9] 4,770 [9]
HFCR-410BR-32/125 (45±1/55±1)45±1% CH2F2 ·55±1% CHF2CF3 [30] AC9100 [26] 18.155 [note 1] 0 [note 2] 2,229 [note 1] 1,000? A1 [11] 140,000 [28] 430 [28] 75.6 [7]
HCFOR-411AR-1270/22/152a (1.5+0,–1/87.5+2,–0/11+0,–1)1.5+0,–1% C3H6 ·87.5+2,–0% CHClF2 ·11+0,–1% C2H4F2GREENCOOL G2018a [9] 10.834 [note 1] 0.04375 [note 2] 1,597 [note 1] 990 [11] A2 [11] 14,000 [11] 46 [11] 82.4 [7] 99.06 [9] 4,954 [9]
HCFOR-411BR-1270/22/152a (3+0,–1/94+2,–0/3+0,–1)3+0,–1% C3H6 ·94+2,–0% CHClF2 ·3+0,–1% C2H4F2GREENCOOL G2018b [9] 11.682 [note 1] 0.047 [note 2] 1,705 [note 1] 980 [11] A2 [11] 13,000 [11] 45 [11] 83.1 [7] 95.95 [9] 4,947 [9]
HCFOR-411CR-1270/22/152a (3+0,–1/95.5+2,–0/1.5+0,–1)3+0,–1% C3H6 ·95.5+2,–0% CHClF2 ·1.5+0,–1% C2H4F2GREENCOOL G2018c [9] 11.841 [note 1] 0.04775 [note 2] 1,730 [note 1] 970? A2?12,000?44?83.4 [7] 95.5 [9] 4,950 [9]
HCFCR-412AR-22/218/142b (70±2/5±2/25±1)70±2% CHClF2 ·5±2% C3F8 ·25±1% C2H3F2ClArcton TP5R [9] 142.875 [note 1] 0.0525 [note 2] 2,286 [note 1] 1,000 [11] A2 [11] 22,000 [11] 82 [11] 92.2 [7] 107.5 [9] 4,881 [9]
HFCR-413AR-218/134a/600a (9±1/88±2/3+0,–1)9±1% C3F8 ·88±2% C2H2F4 ·3+0,–1% C4H10ISCEON 49 [9] 246.68? [note 1] 0 [note 2] 2,053 [note 1] 1,000 [11] A2 [11] 22,000 [11] 94 [11] 104 [7] 101.39 [9] 4,240 [9]
HCFCR-414AR-22/124/600a/142b (51±2/28.5±2/4±.5/16.5+.5,–1)51±2% CHClF2 ·28.5±2% C2HF4Cl ·4±.5% C4H10 ·16.5+.5,–1% C2H3F2ClGHG-X4, [9] Autofrost, [9] Chill-It [9] 11.2065? [note 1] 0.04332 [note 2] 1,478 [note 1] 1,000 [11] A1 [11] 26,000 [11] 100 [11] 96.9 [7] 110.72 [9] 4,702 [9]
HCFCR-414BR-22/124/600a/142b (50±2/39±2/1.5±.5/9.5+.5,–1)50±2% CHClF2 ·39±2% C2HF4Cl ·1.5±.5% C4H10 ·9.5+.5,–1% C2H3F2ClHot Shot, [9] [26] Kar Kool [9] 10.1425? [note 1] 0.04023 [note 2] 1,362 [note 1] 1,000 [11] A1 [11] 23,000 [11] 95 [11] 101.5 [7] 108 [9] 4,592 [9]
HCFCR-415AR-22/152a (82±1/18±1)82±1% CHClF2 ·18±1% C2H4F210.092 [note 1] 0.041 [note 2] 1,507 [note 1] 1,000 [11] A2 [11] 57,000 [11] 190 [11] 81.9 [7]
HCFCR-415BR-22/152a (25±1/75±1)25±1% CHClF2 ·75±1% C2H4F24.05 [note 1] 0.0125 [note 2] 546 [note 1] 1,000 [11] A2 [11] 52,000 [11] 120 [11] 70.2 [7]
HCFCR-416AR-134a/124/600 (59+.5,–1/39.5+1,–.5/1.5+1,–.2)59+.5,-1% C2H2F4 ·39.5+1,–.5% C2HF4Cl ·1.5+1,–.2% C4H10FRIGC (FR-12) [9] 10.731? [note 1] 0.00869 [note 2] 1,084 [note 1] 1,000 [11] A1 [11] 14,000 [11] 62 [11] 111.9 [7] 108.22 [9] 4,020 [9]
HFCR-417AR-125/134a/600 (46.6±1.1/50±1/3.4+.1,–.4)46.6±1.1% C2HF5 ·50±1% C2H2F4 ·3.4+.1,–.4% C4H10ISCEON 59, [9] NU-22 [9] 20.922? [note 1] 0 [note 2] 2,346 [note 1] 1,000 [11] A1 [11] 13,000 [11] 56 [11] 106.7 [7] 89.89 [9] 4,102 [9]
HFCR-417BR-125/134a/600 (79±1/18.3±1/2.7+.1,–.5)79±1% C2HF5 ·18.3±1% C2H2F4 ·2.7+.1,–.5% C4H1025.796? [note 1] 0 [note 2] 3,027 [note 1] 1,000 [29] A1 [29] 15,000 [29] 70 [29] 113.1 [7]
HCFCR-418AR-290/22/152a (1.5±.5/96±1/2.5±.5)1.5±.5% C3H8 ·96±1% CHClF2 ·2.5±.5% C2H4F211.735? [note 1] 0.048 [note 2] 1,741 [note 1] 1,000 [11] A2 [11] 59,000 [11] 200 [11] 84.6 [7]
HFCR-419AR-125/134a/E170 (77±1/19±1/4±1)77±1% C2HF5 ·19±1% C2H2F4 ·4±1% C2H6O24.9906 [note 1] 0 [note 2] 2,967 [note 1] 1,000 [11] A2 [11] 70,000 [11] 310 [11] 109.3 [7]
HCFCR-420AR-134a/142b (88+1,–0/12+0,–1)88+1,–0% C2H2F4 ·12+0,–1% C2H3F2ClChoice Refrigerant [26] 14.468 [note 1] 0.0084 [note 2] 1,548 [note 1] 1,000 [11] A1 [11] 45,000 [11] 190 [11] 101.8 [7]
HFCR-421AR-125/134a (58±1/42±1)58±1% C2HF5 ·42±1% C2H2F4Choice R421A [26] 22.7 [note 1] 0 [note 2] 2,631 [note 1] 1,000 [11] A1 [11] 61,000 [11] 280 [11] 111.7 [7]
HFCR-421BR-125/134a (85±1/15±1)85±1% C2HF5 ·15±1% C2H2F4Choice 421B [26] 26.75 [note 1] 0 [note 2] 3,190 [note 1] 1,000 [11] A1 [11] 69,000 [11] 330 [11] 116.9 [7]
HFCR-422AR-125/134a/600a (85.1±1/11.5±1/3.4+.1,–.4)85.1±1% C2HF5 ·11.5±1% C2H2F4 ·3.4+.1,–.4% C4H10ISCEON 79 [26] 26.697? [note 1] 0 [note 2] 3,143 [note 1] 1,000 [11] A1 [11] 63,000 [11] 290 [11] 113.6 [7]
HFCR-422B (NU-22B)R-125/134a/600a (55±1/42±1/3+.1,–.5)55±1% C2HF5 ·42±1% C2H2F4 ·3+.1,–.5% C4H10ICOR XAC1 [26] 22.19? [note 1] 0 [note 2] 2,526 [note 1] 1,000 [11] A1 [11] 56,000 [11] 250 [11] 108.5 [7]
HFCR-422CR-125/134a/600a (82±1/15±1/3+.1,–.5)82±1% C2HF5 ·15±1% C2H2F4 ·3+.1,–.5% C4H10ICOR XLT1 [26] 26.24? [note 1] 0 [note 2] 3,085 [note 1] 1,000 [11] A1 [11] 62,000 [11] 290 [11] 113.4 [7]
HFCR-422DR-125/134a/600a (65.1+.9,–1.1/31.5±1/3.4+.1,–.4)65.1+.9,–1.1% C2HF5 ·31.5±1% C2H2F4 ·3.4+.1,–.4% C4H10ISCEON MO29 [26] 23.697? [note 1] 0 [note 2] 2,729 [note 1] 1,000 [11] A1 [11] 58,000 [11] 260 [11] 109.9 [7]
HFCR-423AR-134a/227ea (52.5±1/47.5±1)52.5±1% C2H2F4 ·47.5±1% C3HF723.595 [note 1] 0 [note 2] 2,280 [note 1] 1,000 [11] A1 [11] 59,000 [11] 310 [11] 126 [7]
HFCR-424AR-125/134a/600a/600/601a (50.5±1/47±1/.9+.1,–.2/1+.1,+.2/.6+.1,–.2)50.5±1% C2HF5 ·47±1% C2H2F4 ·1.9+.3,–.1% C4H10 ·.6+.1,–.2% C5H12RS-44 (new comp.) [26] 21.525? [note 1] 0 [note 2] 2,440? [note 1] 970 [11] A1 [11] 23,000 [11] 100 [11] 108.4 [7]
HFCR-425AR-32/134a/227ea (18.5±.5/69.5±.5/12±.5)18.5±.5% CH2F2 ·69.5±.5% C2H2F4 ·12±.5% C3HF714.7405 [note 1] 0 [note 2] 1,505 [note 1] 1,000 [11] A1 [11] 72,000 [28] 260 [28] 90.3 [7]
HFCR-426AR-125/134a/600/601a (5.1±1/93±1/1.3+.1,–.2/.6+.1,–.2)5.1±1% C2HF5 ·93±1% C2H2F4 ·1.3+.1,–.2% C4H10 ·.6+.1,–.2% C5H12RS-24 (new comp.) [26] 14.727? [note 1] 0 [note 2] 1,508? [note 1] 990 [11] A1 [11] 20,000 [11] 83 [11] 101.6 [7]
HFCR-427AR-32/125/143a/134a (15±2/25±2/10±2/50±2)15±2% CH2F2 ·25±2% C2HF5 ·10±2% C2H3F3 ·50±2% C2H2F4Forane 427A [26] 20.185 [note 1] 0 [note 2] 2,138 [note 1] 1,000 [11] A1 [11] 79,000 [28] 290 [28] 90.4 [7]
HFCR-428AR-125/143a/290/600a (77.5±1/20±1/.6+.1,–.2/1.9+.1,–.2)77.5±1% C2HF5 ·20±1% C2H3F3 ·.6+.1,–.2% C3H8 ·1.9+.1,–.2% C4H10RS-52 [26] 33.175? [note 1] 3,607 [note 1] 1,000 [11] A1 [11] 83,000 [31] 370 [31] 107.5 [7]
HFCR-429AR-E170/152a/600a (60±1/10±1/30±1)60±1% C2H6O ·10±1% C2H4F2 ·30±1% C4H103.749? [note 1] 13.9 [note 1] 1,000 [11] A3 [11] 6,300 [11] 13 [11] 50.8 [7]
HFCR-430AR-152a/600a (76±1/24±1)76±1% C2H4F2 ·24±1% C4H103.944? [note 1] 0 [note 2] 95 [note 1] 1,000 [11] A3 [11] 8,000 [11] 21 [11] 64 [7]
HFCR-431AR-290/152a (71±1/29±1)71±1% C3H8 ·29±1% C2H4F28.926? [note 1] 38.3 [note 1] 1,000 [11] A3 [11] 5,500 [11] 11 [11] 48.8 [7]
HOR-432AR-1270/E170 (80±1/20±1)80±1% C3H6 ·20±1% C2H6O9.603? [note 1] 1.64 [note 1] 710 [11] A3 [11] 1,200 [11] 2.1 [11] 42.8 [7]
HOR-433AR-1270/290 (30±1/70±1)30±1% C3H6 ·70±1% C3H812 ± 3 [lower-alpha 5] 2.85 [note 1] 880 [11] A3 [11] 3,100 [11] 5.5 [11] 43.5 [7]
HOR-433BR-1270/290 (5±1/95±1)5±1% C3H6 ·95±1% C3H812 ± 3 [lower-alpha 5] 3.23 [note 1] 950 [32] A3 [32] 4,500 [32] 8.1 [32] 44 [7]
HOR-433CR-1270/290 (25±1/75±1)25±1% C3H6 ·75±1% C3H812 ± 3 [lower-alpha 5] 2.93 [note 1] 790 [32] A3 [32] 3,600 [32] 6.6 [32] 43.6 [7]
HFCR-434AR-125/143a/134a/600a (63.2±1/18±1/16±1/2.8+.1,–.2)63.2±1% C2HF5 ·18±1% C2H3F3 ·16±1% C2H2F4 ·2.8+.1,–.2% C4H10RS-45 [26] 30.264? [note 1] 0 [note 2] 3,245 [note 1] 1,000 [11] A1 [11] 73,000 [11] 320 [11] 105.7 [7]
HFCR-435AR-E170/152a (80±1/20±1)80±1% C2H6O ·20±1% C2H4F20.292 [note 1] 25.6 [note 1] 1,000 [11] A3 [11] 8,500 [11] 17 [11] 49 [7]
HCR-436AR-290/600a (56±1/44±1)56±1% C3H8 ·44±1% C4H1012 ± 3 [lower-alpha 5] 3.17 [note 1] 1,000 [11] A3 [11] 4,000 [11] 8 [11] 49.3 [7]
HCR-436BR-290/600a (52±1/48±1)52±1% C3H8 ·48±1% C4H1012 ± 3 [lower-alpha 5] 3.16 [note 1] 1,000 [11] A3 [11] 4,000 [11] 8 [11] 49.9 [7]
HFCR-437AR-125/134a/600/601 (19.5+.5,–1.8/78.5+1.5,–.7/1.4+.1,–.2/.6+.1,–.2)19.5+.5,–1.8% C2HF5 ·78.5+1.5,–.7% C2H2F4 ·1.4+.1,–.2% C4H10 ·.6+.1,–.2% C5H1216.885? [note 1] 0 [note 2] 1,805? [note 1] 990 [11] A1 [11] 19,000 [11] 81 [11] 103.7 [7]
HFCR-438AR-32/125/134a/600/601a (8.5+.5,-1.5/45±1.5/44.2±1.5/1.7+.1,-.2/.6+.1,-.2)8.5+.5,-1.5% CH2F2 ·45±1.5% C2HF5 ·44.2±1.5% C2H2F4 ·1.7+.1,-.2% C4H10 ·.6+.1,-.2% C5H12KDD5, [26] ISCEON MO99 [26] 19.9305? [note 1] 0 [note 2] 2,265? [note 1] 990 [27] A1 [27] 20,000 [28] 79 [28] 99.1 [7]
HFCR-439AR-32/125/600a (50±1/47±1/3±.5)50±1% CH2F2 ·47±1% C2HF5 ·3±.5% C4H1016.44? [note 1] 0 [note 2] 1,983 [note 1] 990 [18] A2 [18] 26,000 [18] 76 [18] 71.2 [7]
HFCR-440AR-290/134a/152a (.6±.1/1.6±.6/97.8±.5).6±.1% C3H8 ·1.6±.6% C2H2F4 ·97.8±.5% C2H4F21.6652? [note 1] 144 [note 1] 1,000 [18] A2 [18] 12,000 [18] 31 [18] 66.2 [7]
HCR-441AR-170/290/600a/600 (3.1±.3/54.8±2/6±.6/36.1±2)3.1±.3% C2H6 ·54.8±2% C3H8 ·42.1±2.6% C4H10HCR-188C [26] 12 ± 3 [lower-alpha 5] 3.6 [note 1] 1,000 [18] A3 [18] 3,200 [18] 6.3 [18] 48.3 [7]
HFC /

HFO [34]

R-448AR-32/125/134a/1234ze/1234yf

(26%/26%/21%/7%/20%) [34]

26% CH2F2 ·
26% C2HF5 ·
21% C2H2F4 ·

7% C3H2F4 ·
20% C3H2F4 [34]

Solistice N-40 [34] 0 [34] 1273 [34] A1 [34] 86.3 [35] −45.9 [35] 83.7 [34] 4,660 [34]
HFOR-449AR-32/R-125/134a/1234yf
(24.3%/24.7%/25.7%/25.3%)		24.3% CH2F2 ·
24.7% C2HF5 ·
25.7% C2H2F4 ·
25.3% C3H2F4		Forane 449a [36] 01,282 [36] A1 [36] 87.2 [36] −45.9 [36] 81.5 [36]
HFOR-452AR-32/R-125/1234yf
(11%/59%/30%)		11% CH2F2 ·
59% C2HF5 ·
30% C3H2F4		Opteon™️ XP44, Solstice® R452A
HFOR-452BR-32/R-125/1234yf
(67.0%/7.0%/26.0%)		67.0% CH2F2 ·
7.0% C2HF5 ·
26.0% C3H2F4		Opteon XL55, [37] Solstice L41y [38] 0676 [37] [38] A2L [38] 63.5 [38] 76.0 [38] 5,220 [38]
HFCR-453AR-32/125/134a/227ea/600/601a
(20%/20%/53.8%/5%/0.6%/0.6%)		20.0% CH2F2 ·
20.0% C2HF5 ·
53.8% C2H2F4 ·
5.0% C3HF7 ·
0.6% C4H10 ·
0.6% C5H12		RS-70 [39] 01,765 [39] 1,000 [39] A1 [39] 88.8 [39] −42.2 [39] 87.9 [39] 4,530 [39]
HFOR-454AR-32/1234yf (35.0%/65.0%)35.0% CH2F2 ·
65.0% C3H2F4		Opteon XL40 [40] 0239 [40] A2L [40] 80.5 [40] −48.3 [40] 78.9 [40]
HFO R-454B R-32/1234yf (68.9%/31.1%)68.9% CH2F2 ·
31.1% C3H2F4		Opteon XL41, [41] Puron Advance [42] 0466 [41] A2L [41] 62.6 [41] −50.9 [41] 77.0 [41]
HFOR-454CR-32/1234yf (21.5%/78.5%)21.5% CH2F2 ·
78.5% C3H2F4		Opteon XL20 [43] 0148 [43] A2L [43] 90.8 [43] −45.9 [43] 82.4 [43]
HFOR-455AR-32/1234yf/744 (75.5%/21.5%/3%)21.5% CH2F2 ·
75.5% C3H2F4 ·
3% CO2		Solstice L40x [44] 0146 [44] A2L [44] 87.5 [44] 85.6 [44] 4,660 [44]
HFOR-456AR-32/134a/1234ze(E) (6.0%/45.0%/49.0%)6.0% CH2F2 ·
45.0% C2H2F4 ·
49.0% C3H2F4		0687102.4
HFOR-457AR-32/152a/1234yf
(18.0%/12.0%/70.0%)		18.0% CH2F2 ·
12.0% C2H4F2 ·
70.0% C3H2F4		Forane 457a [45] 0139 [46] A2L [46] 92.6
HFCR-458AR-32/125/134a/227ea/236fa (20.5%/4.0%/61.4%/13.5%/0.6%)20.5% CH2F2 ·
4.0% C2HF5 ·
61.4% C2H3F3 ·
13.5% C3HF7 ·
0.6% C3H2F6		01,650 [47] 92.0
HFOR-459AR-32/1234yf(E)/1234ze(E) (68.0%/26.0%/6.0%)68.0% CH2F2 ·
26.0% C3H2F4 ·
6.0% C3H2F4		Forane 459a [45] 0460
HFC/HR-466AR-32/125/13I1 (49/11.5/39.5)49% CH2F2 ·
11.5% C2HF5 ·
39.5% CIF3		Solstice N41 [48] 0 [48] 733 [48] A1 [48] −51.7 [48] 76.5 [48] 5144 [48]
HCFCR-500R-12/152a (73.8/26.2)73.8% CCl2F2 ·26.2% C2H4F2Carrene #7 [9] 74.1668 [note 1] 0.738 [note 2] 8,077 [note 1] 1,000 [11] A1 [11] 30,000 [11] 120 [11] 99.3 [7] 102.15 [9] 4,173 [9]
HCFCR-501R-22/12 (75/25)75% CHClF2 ·25% CCl2F234 [note 1] 0.2875 [note 2] 4,083 [note 1] 1,000 [11] A1 [11] 54,000 [11] 210 [11] 93.1 [7] −41/−41 [19] 96.19 [9] 4,764 [9]
HCFCR-502R-22/115 (48.8/51.2)48.8% CHClF2 ·51.2% C2F5Cl876.256 [note 1] 0.24968 [note 2] 4,657 [note 1] 1,000 [11] A1 [11] 73,000 [11] 330 [11] 111.6 [7] −45/19 [19] 80.73 [9] 4,019 [9]
HCFCR-503R-23/13 (40.1/59.9)40.1% CHF3 ·59.9% CClF3491.63 [note 1] 0.599 [note 2] 14,560 [note 1] 1,000 [11] A1?40,000?200?87.2 [7] −88/88 [19] 18.43 [9] 4,265 [9]
HCFCR-504R-32/115 (48.2/51.8)48.2% CH2F2 ·51.8% C2F5Cl882.9618 [note 1] 0.22792 [note 2] 4,143 [note 1] 1,000 [11] A1?140,000 [28] 450 [28] 79.2 [7] −57/17 [19] 62.13 [9] 4,439 [9]
HCFCR-505R-12/31 (78/22)78% CCl2F2 ·22% CH2FCl78.0836+ [note 1] 0.7844 [note 2] 8,504+ [note 1] 350? B2?10,000?20?103.5 [7] −30/115 [19] 117.78 [9] 4,730 [9]
HCFCR-506R-31/114 (55.1/44.9)55.1% CH2FCl ·44.9% C2F4Cl2134.90938+ [note 1] 0.46002 [note 2] 4,495+ [note 1] 350? B2?10,000?20?93.7 [7] −12/18 [19] 142.22 [9] 5,157 [9]
HFCR-507[A]R-125/143a (50/50)50% C2HF5 ·50% C2H3F3AZ-50 [9] [26] 40.5 [note 1] 0 [note 2] 3,985 [note 1] 1,000 [11] A1 [11] 130,000 [11] 520 [11] 98.9 [7] −46.7/−40 [19] 70.74 [9] 3,715 [9]
HFCR-508[A]R-23/116 (39/61)39% CHF3 ·61% C2F6Klea 5R3 [9] [26] 6,205.3 [note 1] 0 [note 2] 13,214 [note 1] 1,000 [11] A1 [11] 55,000 [11] 220 [11] 100.1 [7] −86/−86 [19] 11.01 [9] 3,701 [9]
HFCR-508BR-23/116 (46/54)46% CHF3 ·54% C2F6Suva 95 [9] [26] 5,524.2 [note 1] 0 [note 2] 13,396 [note 1] 1,000 [11] A1 [11] 52,000 [11] 200 [11] 95.4 [7] 12.06 [9] 3,834 [9]
HCFCR-509[A]R-22/218 (44/56)44% CHClF2 ·56% C3F8Arcton TP5R2 [9] 1,461.28 [note 1] 0.022 [note 2] 5,741 [note 1] 1,000 [11] A1 [11] 75,000 [11] 390 [11] 124 [7] −47/0 [19] 87.22 [9] 4,033 [9]
HCR-510[A]R-E170/600a (88±.5/12±.5)88±.5% C2H6O ·12±.5% C4H101.4532? [note 1] 1.24 [note 1] 1,000 [11] A3 [11] 7,300 [11] 14 [11] 47.2 [7] −25.2/−25.2 [11]
HCR-511[A]R-290/E170 (95±1/5±1)95±1% C3H8 ·5±1% C2H6O11.40075? [note 1] 3.19 [note 1] 1,000 [28] A3 [28] 5,300 [28] 9.5 [28] 44.2 [7] −42.1/−20-40 [28]
HFOR-513AR-1234yf/134a (56%/44%)56% C3H2F4  ·44% C2H2F40 [49] 573 [49] A1 [49] 108.4 [49] −29.4 [49] 96.5 [49] 3,766 [46]
HFOR-514AR-1336mzz-Z/trans-1,2-Dichloroethene(t-DCE)(74.7%/25.3%) [50] 74.7% C4H2F6  ·25.3% C2H2CL2 [51] 02B1139.629.196.53,520
HFOR-515BR-1234ze/227ea299 [52]
HCR-600 Butane C4H10 or CH3CH2CH2CH3106-97-86.8 days [22] 0 [17] 4.0 [3] –6.5 [22] 1,000 [11] A3 [11] 4,000?9.6?58.1 [7] 0 [19] ±1 [8] 152.01 [9] 3,796 [9]
HCR-600a Isobutane C4H10 or CH(CH3)2CH375-28-512 ± 3 [53] [lower-alpha 5] 0 [17] [54] 3 [54] 1,000 [11] A3 [11] 4,000 [11] 9.6 [11] 58.1 [7] −11.7 [8] 134.7 [9] 3,640 [9]
HCR-601 Pentane C5H12 or CH3CH2CH2CH2CH3109-66-012 ± 3 [lower-alpha 5] 0 [17] 4 ± 2 [lower-alpha 6] 600 [11] A3 [33] 1,000 [33] 2.9 [33] 72.1 [7] 36.1 [33] ±.2 [8] 196.56 [9] 3,358 [9]
HCR-601a Isopentane C5H12 or (CH3)2CHCH2CH378-78-412 ± 3 [lower-alpha 5] 0 [17] 4 ± 2 [lower-alpha 6] 600 [11] A3 [11] 1,000 [11] 2.9 [11] 72.1 [7] 27.7 [8] 187.78 [9] 3,378 [9]
HCR-610 Ethoxyethane (Diethyl ether) CH3CH2OCH2CH360-29-712 ± 3 [lower-alpha 5] 4 ± 2 [lower-alpha 6] 400 [11] A3?74.1 [7] 34.6 [8] 193.65 [9] 3,640 [9]
HCR-611 Methyl formate HCOOCH3107-31-312 ± 3 [lower-alpha 5] 0 [17] [54] 100 [11] B2 [11] 60.1 [7] 32 [8] [19] 213.55 [9] 6,000 [9]
HCPropane/isobutane [55] 40–70% C3H8 · 30–60% C4H6 (by volume)−33
HCPropane [55] C3H8 98% by volume−42
HCPropane/ethane [55] C3H8 60–100% · C2H6 3-7% (by volume)−49
HFC / HFO415−20.4110.73,960
HFCR-134a (98.5%)C2H2F4 (98.5%)
R-630 Methylamine CH3NH274-89-531.1 [7] −6 [8] 156.89 [9] 7,460 [9]
R-631 Ethylamine CH3CH2(NH2)75-04-745.1 [7] 16.6 [8] 183 [9] 5,620 [9]
R-702 Hydrogen H21333-74-05.8 [3] 2.016 [7] −252.87 [8] −239.95 [21] 1,300 [21]
R-704 Helium He7440-59-70 [lower-alpha 7] 0 [lower-alpha 7] 9,340? A1 [11] 4.002 [7] −268.93 [8] −267.96 [21] 227 [21]
R-717 Ammonia NH37664-41-70 [58] 0 [58] 25 [11] B2L [18] 320 [11] 0.22 [11] 17.03 [7] −33.34 [8] 132.4 [59] 11,280 [59]
R-718 Water/Steam H2O7732-18-50.0260 [60] 0.2 ± 0.2 [3] 18.02 [7] 100 [19] 373.946 [21] 22,060 [21]
R-720 Neon Ne7440-01-90 [lower-alpha 7] 0 [lower-alpha 7] 9,340? A1 [11] 20.18 [7] −246.08 [8] −228.75 [21] 2,760 [21]
R-728 Nitrogen N27727-37-90 [lower-alpha 7] 0 [lower-alpha 7] 28.01 [7] −195.79 [8] −146.9 [21] 3,390 [21]
R-729 Air N2/O2/Ar (78.082/20.945/.934 vol%)78.082% N2 ·20.945% O2 ·.934% Ar0 [60] [lower-alpha 7] 0.00054+ [3] 28.97 [7] −192.97?−140.53 [9] 3,785 [9]
R-732 Oxygen O27782-44-70 [lower-alpha 7] 32 [7] −182.95 [8] −118.6 [21] 5,050 [21]
R-740 Argon Ar7440-37-10 [lower-alpha 7] 0 [lower-alpha 7] 9,340? A1 [11] 39.95 [7] −185.85 [8] −122.4 [21] 4,870 [21]
R-744 Carbon dioxide CO2124-38-90 [17] 1 [3] 5,000 [11] A1 [11] 40,000 [11] 72 [11] 44 [7] −56.56 at 518 kPa [note 3] [62] 31.04 [21] 7,380 [21]
R-744A Nitrous oxide N2O10024-97-2114 [3] 0.017 [20] 265 [5] 44 [7] −88.48 [8] 36.4 [21] 7,240 [21]
R-764 Sulfur dioxide SO27446-09-55 [63] B1 [11] 100 [63] 0.262 [63] 64.1 [7] −10 [8] [19] 157.65 [9] 7,880 [9]
R-784 Krypton Kr7439-90-90 [lower-alpha 7] 0 [lower-alpha 7] 9,340? A1?83.80 [7] −153.22 [8] −63.8 [21] 5,500 [21]
CFOR-1112a 1,1-Dichloro-2,2-difluoroethylene C2Cl2F279-35-6132.9 [7]
CFOR-1113 Chlorotrifluoroethylene C2ClF379-38-9116.5 [7] −27.8 [8]
PFOR-1114 Tetrafluoroethylene C2F4116-14-30 [lower-alpha 4] 100 [7] −76.3 [8]
HCOR-1120 Trichloroethylene (trielene)C2HCl379-01-6131.4 [7] 87.2 [8] 297.78 [9] 4,909 [9]
HCOR-1130(E) trans-1,2-Dichloroethylene C2H2Cl2156-60-50 [17] 96.9 [7] 48.5 [8] 243.28 [9] 5,481 [9]
HFOR-1132a 1,1-Difluoroethylene C2H2F275-38-70 [lower-alpha 4] 64 [7] −83 [64] 29.7 [9] 4,458 [9]
HCOR-1140 Chloroethylene (vinyl chloride)C2H3Cl75-01-4100? B3 [6] 62.5 [7] −13.4 [8] 151.83 [9] 5,150 [9]
HFOR-1141 Fluoroethylene (vinyl fluoride)C2H3F75-02-50 [lower-alpha 4] 46 [7] −72.2 [8]
HOR-1150 Ethene (Ethylene) CH2=CH274-85-112 ± 3 [lower-alpha 5] 3.7 [3] 200 [11] A3 [11] 28.05 [7] −103.7 [8] 9.19 [9] 5,040 [9]
PFOR-1216 Hexafluoropropylene C3F6116-15-41,000+ [3] [4] 0 [lower-alpha 4] 17,340+ [3] 150 [7] −28 [8]
PFOR-1218 Hexafluoropropene trimer (C3F6)36792-31-00 [lower-alpha 4] 450.1 [7]
HCFOR-1224yd(Z)(Z)-2,3,3,3,-Tetrafluoro-1-Chloropropene [65] [66] [67] (Z)-CF3-CF=CHCl111512-60-80.032 (21 days) [68] 0.00012 [68] <1 [68] 148.5 [68] 14°C [68] 156°C [68] 3330 [68]
HCFOR-1233zd(E) trans-1-chloro-3,3,3-trifluoropropene C3H2ClF3102687-65-00.0712328 [69] 0 [69] 1 [69] 130.5 [7] 19
HFOR-1234yf 2,3,3,3-Tetrafluoropropene C3H2F4754-12-10.030116 [70] 0 [54] <1 [54] [71] [70] 500 [72] A2L [18] 16,000 [73] 75 [73] 114 [7] −29.4 [73]
HFOR-1234ze(E) trans-1,3,3,3-tetrafluoropropene C3H2F429118-24-90 [54] <1 [54] [71] 800 [28] A2L [28] 16,000 [28] 75 [28] 114 [7] −19.0 [8] [28]
HOR-1270 Propene (Propylene) C3H6 or CH3CH=CH2115-07-112 ± 3 [lower-alpha 5] 1.8 [3] 500 [11] A3 [11] 1,000 [11] 1.7 [11] 42.1 [7] −47.6 [8] 92.42 [9] 4,665 [9]
HFOR-1336mzz(E) [56] trans-1,1,1,4,4,4-hexafluoro-2-buteneC4H2F666711-86-20187.5137.73,150
HFOR-1336mzz(Z) (DR-2) [56] [74] cis-1,1,1,4,4,4-hexafluoro-2-buteneCF3CH=CHCF3(Z)692-49-902A137.4171.32,900
T
y
p
e 		ASHRAE
number		 IUPAC chemical name Molecular
formula 		CAS no/
blend
name		 Atmospheric
lifetime
(years)		Semi-
empirical
ODP 		Net
GWP
100-yr		 OEL/PEL
ppm (v/v) &
ASHRAE  34
safety group		RCL/IDLH Molecular
mass
u 		Boiling, or
bubble/dew
/azeotropic
point(s) °C		Critical
temp.
°C		Critical
pressure,
absolute
kPa
ppm
(v/v)		g/m3

Type and flammability

Legends
Types / Prefixes [75]
TypeMeaningAtoms in the Molecule
CFC Chlorofluorocarbon Cl, F, C
CFO Chlorofluoroolefin
HCFC Hydrochlorofluorocarbon H, Cl, F, C
HCFO Hydrochlorofluoroolefin
HFC Hydrofluorocarbon H, F, C
HFO Hydrofluoroolefin
HCC Hydrochlorocarbon H, Cl, C
HCO Hydrochloroolefin
HC Hydrocarbon H, C
HO Olefin (Alkene)
PFC Perfluorocarbon F, C
PFO Perfluoroolefin
PCC Perchlorocarbon Cl, C
H Halon/Haloalkane Br, Cl (in some but not all), F, H (in some but not all), C
Safety Classification of Refrigerants [76]
Flammability in Air @ 60 °C & 101.3 kPa ASHRAE 34 Safety group
Higher Flammability
LFL or ETFL60 = 100 g/m3 OR HOC = 19 MJ/kg [77] 		A3B3
Lower Flammability
LFL or ETFL60 > 100 g/m3 & HOC < 19 MJ/kg [77] 		A2B2
Lower Flammability
LFL or ETFL60 > 100 g/m3 & HOC < 19 MJ/kg [77]
with a maximum burning velocity of = 10 cm/s		A2LB2L
No flame PropagationA1B1
Flammability in Air @ 60 °C & 101.3 kPaLower Toxicity
OEL ≥ 400 ppm [29] 		Higher Toxicity
OEL < 400 ppm [29]

LFL = Lower Flammability Limit
ETFL60 = Elevated Temperature Flame Limit @ 60 °C
HOC = Heat Of Combustion

Compounds used as refrigerants may be described using either the appropriate prefix above or with the prefixes "R-" or "Refrigerant." Thus, CFC-12 may also be written as R-12 or Refrigerant 12.
An alkene, olefin, or olefine is an unsaturated compound containing at least one carbon-carbon double bond. [78]

Educated Estimates
  1. 1 2 3 4 5 Some CFCs are assumed to be similar in terms of Semi-Empirical ODP being one. [4] [12]
  2. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 Some HCFCs are assumed to be similar in terms of Semi-Empirical ODP. [4] [15]
  3. 1 2 3 4 5 6 7 8 9 10 11 12 Some HCFCs are assumed to be similar in terms of Atmospheric Lifetime [3] [4] & net GWP over a 100-year time horizon. [3] [4]
  4. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 All HFCs, HFOs, PFCs & PFOs are assumed to be similar in terms of Semi-Empirical ODP being zero. [14] [17]
  5. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 Most hydrocarbons are assumed to be similar to Methane in terms of Atmospheric Lifetime being 12 ± 3 years [3] & Semi-Empirical ODP being < 0(smog chemistry). [20]
  6. 1 2 3 Pentane, Isopentane & Ethoxyethane (Diethyl ether) is assumed to have a net GWP over 100-yr to be 4 ± 2.
  7. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 Air, nitrogen, oxygen & the noble gases are assumed to have an unlimited Atmospheric Lifetime, a Semi-Empirical ODP of zero (except oxygen being slightly less than zero) & net GWP over 100-yr to be zero (except air being the sum of its parts).

See also

Related Research Articles

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Chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs) are fully or partly halogenated hydrocarbons that contain carbon (C), hydrogen (H), chlorine (Cl), and fluorine (F), produced as volatile derivatives of methane, ethane, and propane.

<span class="mw-page-title-main">Heating, ventilation, and air conditioning</span> Technology of indoor and vehicular environmental comfort

Heating, ventilation, and air conditioning (HVAC) is the use of various technologies to control the temperature, humidity, and purity of the air in an enclosed space. Its goal is to provide thermal comfort and acceptable indoor air quality. HVAC system design is a subdiscipline of mechanical engineering, based on the principles of thermodynamics, fluid mechanics, and heat transfer. "Refrigeration" is sometimes added to the field's abbreviation as HVAC&R or HVACR, or "ventilation" is dropped, as in HACR.

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A refrigerant is a working fluid used in the refrigeration cycle of air conditioning systems and heat pumps where in most cases they undergo a repeated phase transition from a liquid to a gas and back again. Refrigerants are heavily regulated because of their toxicity and flammability and the contribution of CFC and HCFC refrigerants to ozone depletion and that of HFC refrigerants to climate change.

<span class="mw-page-title-main">Chlorodifluoromethane</span> Chemical propellant and refrigerant

Chlorodifluoromethane or difluoromonochloromethane is a hydrochlorofluorocarbon (HCFC). This colorless gas is better known as HCFC-22, or R-22, or CHClF
2. It was commonly used as a propellant and refrigerant. These applications were phased out under the Montreal Protocol in developed countries in 2020 due to the compound's ozone depletion potential (ODP) and high global warming potential (GWP), and in developing countries this process will be completed by 2030. R-22 is a versatile intermediate in industrial organofluorine chemistry, e.g. as a precursor to tetrafluoroethylene.

R-410A is a refrigerant used in air conditioning and heat pump applications. It is a zeotropic but near-azeotropic mixture of difluoromethane (CH2F2, called R-32) and pentafluoroethane (CHF2CF3, called R-125). R-410A is sold under the trademarked names AZ-20, EcoFluor R410, Forane 410A, Genetron R410A, Puron, and Suva 410A.

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Vapour-compression refrigeration or vapor-compression refrigeration system (VCRS), in which the refrigerant undergoes phase changes, is one of the many refrigeration cycles and is the most widely used method for air conditioning of buildings and automobiles. It is also used in domestic and commercial refrigerators, large-scale warehouses for chilled or frozen storage of foods and meats, refrigerated trucks and railroad cars, and a host of other commercial and industrial services. Oil refineries, petrochemical and chemical processing plants, and natural gas processing plants are among the many types of industrial plants that often utilize large vapor-compression refrigeration systems. Cascade refrigeration systems may also be implemented using two compressors.

Natural refrigerants are considered substances that serve as refrigerants in refrigeration systems. They are alternatives to synthetic refrigerants such as chlorofluorocarbon (CFC), hydrochlorofluorocarbon (HCFC), and hydrofluorocarbon (HFC) based refrigerants. Unlike other refrigerants, natural refrigerants can be found in nature and are commercially available thanks to physical industrial processes like fractional distillation, chemical reactions such as Haber process and spin-off gases. The most prominent of these include various natural hydrocarbons, carbon dioxide, ammonia, and water. Natural refrigerants are preferred actually in new equipment to their synthetic counterparts for their presumption of higher degrees of sustainability. With the current technologies available, almost 75 percent of the refrigeration and air conditioning sector has the potential to be converted to natural refrigerants.

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2H
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1-Chloro-1,1-difluoroethane (HCFC-142b) is a haloalkane with the chemical formula CH3CClF2. It belongs to the hydrochlorofluorocarbon (HCFC) family of man-made compounds that contribute significantly to both ozone depletion and global warming when released into the environment. It is primarily used as a refrigerant where it is also known as R-142b and by trade names including Freon-142b.

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<span class="mw-page-title-main">Hydrofluoroolefin</span> Class of chemical compounds

Hydrofluoroolefins (HFOs) are unsaturated organic compounds composed of hydrogen, fluorine and carbon. These organofluorine compounds are of interest as refrigerants. Unlike traditional hydrofluorocarbons (HFCs) and chlorofluorocarbons (CFCs), which are saturated, HFOs are olefins, otherwise known as alkenes.

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References

  1. 1 2 "ANSI/ASHRAE Standard 34-2022 : Designation and Safety Classification of Refrigerants". Atlanta, GA: American Society of Heating, Refrigerating and Air-Conditioning Engineers. 2022. ISSN   1041-2336 . Retrieved 2024-01-09.
  2. ↑ "Refrigerant blends to challenge hydrocarbon efficiencies". 22 December 2019.
  3. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 P. Forster; V. Ramaswamy; P. Artaxo; T. Berntsen; R. Betts; D.W. Fahey; J. Haywood; J. Lean; D.C. Lowe; G. Myhre; J. Nganga; R. Prinn; G. Raga; M. Schulz; R. Van Dorland (2007). "Chapter 2: Changes in Atmospheric Constituents and in Radiative Forcing". In Solomon, S.; Miller, H.L.; Tignor, M.; Averyt, K.B.; Marquis, M.; Chen, Z.; Manning, M.; Qin, D. (eds.). Climate Change 2007: The Physical Science Basis. Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change. Cambridge, United Kingdom and New York, NY, US: Cambridge University Press. Archived from the original on 1 December 2016. Retrieved 9 October 2016.
  4. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 John S. Daniel; Guus J.M. Velders; A.R. Douglass; P.M.D. Forster; D.A. Hauglustaine; I.S.A. Isaksen; L.J.M. Kuijpers; A. McCulloch; T.J. Wallington (2006). "Chapter 8. Halocarbon Scenarios, Ozone Depletion Potentials, and Global Warming Potentials" (PDF). Scientific Assessment of Ozone Depletion: 2006. Geneva, Switzerland: World Meteorological Organization . Retrieved 9 October 2016.
  5. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 Myhre, G., D. Shindell, F.‐M. Bréon, W. Collins, J. Fuglestvedt, J. Huang, D. Koch, J.‐F. Lamarque, D. Lee, B. Mendoza, T. Nakajima, A. Robock, G. Stephens, T. Takemura and H. Zhang, 2013: Anthropogenic and Natural Radiative Forcing. In: Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change [Stocker, T.F., D. Qin, G.‐K. Plattner, M. Tignor, S.K. Allen, J. Boschung, A. Nauels, Y. Xia, V. Bex and P.M. Midgley (eds.)]. Cambridge University Press, Cambridge, United Kingdom and New York, NY, US.
  6. 1 2 "Addenda to ANSI/ASHRAE Standard 34-1997". ANSI/ASHRAE Standard 34-1997, Designation and Safety Classification of Refrigerants. Atlanta, GA: American Society of Heating, Refrigerating and Air-Conditioning Engineers. 2000-11-15. ISSN   1041-2336. Archived from the original (PDF) on 2016-10-10. Retrieved 2016-10-10.
  7. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200 201 202 203 204 205 206 207 208 209 210 211 212 213 214 215 216 217 218 219 220 221 222 223 224 225 226 227 228 229 230 231 232 233 234 235 236 237 238 239 240 241 242 243 244 245 246 247 248 249 250 251 252 253 254 255 256 257 258 259 260 261 262 263 264 265 266 267 268 269 270 271 272 273 274 275 276 277 278 279 280 281 282 283 284 285 286 287 288 289 290 291 292 293 294 295 296 297 298 299 300 301 302 303 304 305 306 307 308 309 310 311 312 313 314 315 316 317 318 319 320 321 322 323 324 325 326 327 328 329 330 331 332 333 334 335 336 337 338 339 340 341 342 Wieser, Michael E.; Coplen, Tyler B. (2010-12-12). "Atomic weights of the elements 2009 (IUPAC Technical Report)". Pure and Applied Chemistry. 83 (2): 359–396. doi: 10.1351/PAC-REP-10-09-14 . ISSN   1365-3075. S2CID   95898322.
  8. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 Wikipedia:Chemical infobox#References
  9. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200 201 202 203 204 205 206 207 208 209 210 211 212 213 214 215 216 217 218 219 220 221 222 223 224 225 226 227 228 229 230 231 232 233 234 235 Schoen, J. Andrew, "Listing of Refrigerants" (PDF), Andy's HVAC/R Web Page, archived from the original (PDF) on 2009-03-19, retrieved 2011-12-17
  10. 1 2 3 4 5 Intergovernmental Panel on Climate Change, ed. (2014), "Anthropogenic and Natural Radiative Forcing", Climate Change 2013 - the Physical Science Basis, Cambridge University Press, pp. 659–740, doi:10.1017/cbo9781107415324.018, ISBN   9781107415324
  11. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200 201 202 203 204 205 206 207 208 209 210 211 212 213 214 215 216 217 218 219 220 221 222 223 224 225 226 227 228 229 230 231 232 233 234 235 236 237 238 239 240 241 242 243 244 245 246 247 248 249 250 251 252 253 254 255 256 257 258 259 260 261 262 263 264 265 266 267 268 269 270 271 272 273 274 275 276 277 278 279 280 281 282 283 284 285 286 287 288 289 290 291 292 293 294 295 296 297 298 299 300 301 302 303 304 305 306 307 308 309 310 311 312 313 314 315 316 317 318 319 320 321 322 323 324 325 326 327 328 329 330 331 332 333 334 335 336 337 338 339 340 341 342 343 344 345 346 347 348 349 350 351 352 353 354 355 356 357 358 359 360 361 362 363 364 365 366 367 368 369 370 371 372 373 374 375 376 377 378 379 380 381 382 383 384 385 386 387 388 "Addenda m, n, o, p, q, r, s, t, u, and v to ANSI/ASHRAE Standard 34-2007" (PDF). ANSI/ASHRAE Standard 34-2007, Designation and Safety Classification of Refrigerants. Atlanta, GA: American Society of Heating, Refrigerating and Air-Conditioning Engineers. 2008-06-26. ISSN   1041-2336. Archived from the original (PDF) on 2011-10-12. Retrieved 2011-12-18.
  12. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 "Class I Ozone-depleting Substances". Science - Ozone Layer Protection. US EPA. 2007. Archived from the original on 2010-12-10. Retrieved 2010-12-16.
  13. 1 2 3 4 "ANSI/ASHRAE Addendum t to ANSI/ASHRAE Standard 34-2019: Designation and Safety Classification of Refrigerants" (PDF). ANSI/ASHRAE Standard 34-2019: Designation and Safety Classification of Refrigerants. Atlanta, GA: American Society of Heating, Refrigerating and Air-Conditioning Engineers. July 25, 2019. ISSN   1041-2336 . Retrieved 2024-01-08.
  14. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 "Global Warming Potentials of ODS Substitutes". Science - Ozone Layer Protection. US EPA. 2007. Archived from the original on 2010-10-16. Retrieved 2010-12-16.
  15. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 "Class II Ozone-depleting Substances". Science - Ozone Layer Protection. US EPA. 2007. Archived from the original on 2010-12-09. Retrieved 2010-12-16.
  16. ↑ The Montreal Protocol on Substances that Deplete the Ozone Layer. UNEP, 2000. ISBN   92-807-1888-6
  17. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 Montreal Protocol on Substances that Deplete the Ozone Layer: 2006 Report of the Rigid and Flexible Foams Technical Options Committee (FTOC); 2006 Assessment (PDF), Nairobi, Kenya: United Nations Environment Programme (UNEP) Ozone Secretariat, March 2007, ISBN   978-92-807-2826-2 , retrieved 2010-12-16
  18. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 "Addenda e, f, g, and h to ANSI/ASHRAE Standard 34-2010" (PDF). ANSI/ASHRAE Standard 34-2010, Designation and Safety Classification of Refrigerants. Atlanta, GA: American Society of Heating, Refrigerating and Air-Conditioning Engineers. 2011-02-03. ISSN   1041-2336 . Retrieved 2011-12-18.[ permanent dead link ]
  19. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 "Addenda d, j, l, m, and t to ANSI/ASHRAE Standard 34-2004" (PDF). ANSI/ASHRAE Standard 34-2004, Designation and Safety Classification of Refrigerants. Atlanta, GA: American Society of Heating, Refrigerating and Air-Conditioning Engineers. 2007-03-03. ISSN   1041-2336. Archived from the original (PDF) on 2011-10-12. Retrieved 2011-12-18.
  20. 1 2 3 Ravishankara, A. R.; Daniel, John S.; Portmann, Robert W. (2009-08-27), "Supporting Online Material for - Nitrous Oxide (N2O): The Dominant Ozone-Depleting Substance Emitted in the 21st Century" (PDF), Science, 326 (5949), Washington, DC: 123–125, Bibcode:2009Sci...326..123R, doi:10.1126/science.1176985, PMID   19713491, S2CID   2100618, Methane's influence on ozone is very dependent on altitude. In the troposphere and lower stratosphere it induces ozone production via "smog chemistry"(10), while at higher altitudes it causes ozone losses [...] The net effect is generally a gain in column ozone due to methane increases, both in the stratospheric column and total column(11). Thus, unlike for N2O, a calculated ODP for methane would likely be negative.
  21. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 Critical point (thermodynamics)#Table of liquid–vapor critical temperature and pressure for selected substances
  22. 1 2 3 4 5 6 Hodnebrog, ∅.; Dalsøren, S.; Myhre, G. (2018), "Lifetimes, direct and indirect radiative forcing, and global warming potentials of ethane (C2H6), propane (C3H8), and butane (C4H10)", Atmos. Sci. Lett., 2018, 19:e804 (2): e804, Bibcode:2018AtScL..19E.804H, doi: 10.1002/asl.804
  23. ↑ Lide, D. R., ed. (2005). CRC Handbook of Chemistry and Physics (86th ed.). Boca Raton (FL): CRC Press. p. 3.22. ISBN   978-0-8493-0486-6.
  24. 1 2 3 Papadimitriou, Vassileios C.; McGillen, Max R.; Smith, Shona C.; Jubb, Aaron M.; Portmann, Robert W.; Hall, Bradley D.; Fleming, Eric L.; Jackman, Charles H.; Burkholder, James B. (2013). "1,2-Dichlorohexafluoro-cyclobutane (1,2-c-C4F6Cl2, R-316c) a Potent Ozone Depleting Substance and Greenhouse Gas: Atmospheric Loss Processes, Lifetimes, and Ozone Depletion and Global Warming Potentials for the (E) and (Z) Stereoisomers". The Journal of Physical Chemistry A. 117 (43): 11049–11065. Bibcode:2013JPCA..11711049P. doi:10.1021/jp407823k. hdl: 2060/20140012685 . PMID   24079521. S2CID   25162740.
  25. ↑ Hydrocarbons are assumed to be similar to Methane in terms of Semi-Empirical ODP being < 0(smog chemistry)
  26. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 Composition of Refrigerant Blends, US EPA, 18 November 2014, retrieved 2022-07-19
  27. 1 2 3 4 "Addenda af and ag to ANSI/ASHRAE Standard 34-2007" (PDF). ANSI/ASHRAE Standard 34-2007, Designation and Safety Classification of Refrigerants. Atlanta, GA: American Society of Heating, Refrigerating and Air-Conditioning Engineers. 2009-06-25. ISSN   1041-2336. Archived from the original (PDF) on 2011-10-12. Retrieved 2011-12-18.
  28. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 "Addenda i, j, k, l, n, and o to ANSI/ASHRAE Standard 34-2010" (PDF). ANSI/ASHRAE Standard 34-2010, Designation and Safety Classification of Refrigerants. Atlanta, GA: American Society of Heating, Refrigerating and Air-Conditioning Engineers. 2011-06-30. ISSN   1041-2336 . Retrieved 2011-12-18.[ permanent dead link ]
  29. 1 2 3 4 5 6 7 8 9 10 "Addenda a, b, and d to ANSI/ASHRAE Standard 34-2010" (PDF). ANSI/ASHRAE Standard 34-2010, Designation and Safety Classification of Refrigerants. Atlanta, GA: American Society of Heating, Refrigerating and Air-Conditioning Engineers. 2010-07-01. ISSN   1041-2336. Archived from the original (PDF) on 2011-10-12. Retrieved 2011-12-18.
  30. 1 2 IPCC Assessment Report 4 (AR4) 2007, Table 2.14, page 212
  31. 1 2 "Addenda a, b, c, d, e, f, g, and h to ANSI/ASHRAE Standard 34-2007" (PDF). ANSI/ASHRAE Standard 34-2007, Designation and Safety Classification of Refrigerants. Atlanta, GA: American Society of Heating, Refrigerating and Air-Conditioning Engineers. 2007-06-28. ISSN   1041-2336. Archived from the original (PDF) on 2011-10-12. Retrieved 2011-12-18.
  32. 1 2 3 4 5 6 7 8 9 10 "Addenda x, y, aa, ab, ac, ad, and ae to ANSI/ASHRAE Standard 34-2007" (PDF). ANSI/ASHRAE Standard 34-2007, Designation and Safety Classification of Refrigerants. Atlanta, GA: American Society of Heating, Refrigerating and Air-Conditioning Engineers. 2009-01-29. ISSN   1041-2336. Archived from the original (PDF) on 2011-10-12. Retrieved 2011-12-18.
  33. 1 2 3 4 5 "Addenda i, j, and k to ANSI/ASHRAE Standard 34-2007" (PDF). ANSI/ASHRAE Standard 34-2007, Designation and Safety Classification of Refrigerants. Atlanta, GA: American Society of Heating, Refrigerating and Air-Conditioning Engineers. 2008-01-24. ISSN   1041-2336. Archived from the original (PDF) on 2011-10-12. Retrieved 2011-12-18.
  34. 1 2 3 4 5 6 7 8 9 "Solstice® N40 (R-448A) | European Refrigerants". www.honeywell-refrigerants.com. Retrieved 2020-12-13.
  35. 1 2 "Solstice N40 TDS" (PDF).
  36. 1 2 3 4 5 6 "Forane® 449A (XP40) Refrigerant - Product Information". Arkema. Archived from the original on 2020-10-16. Retrieved 2020-10-14.
  37. 1 2 "Opteon™ XL55 Refrigerant - Product Information" (PDF). Chemours. Retrieved 2020-10-13.[ permanent dead link ]
  38. 1 2 3 4 5 6 7 "Solstice® L41y (R-452B) Refrigerant - Brochure" (PDF). Honeywell. Retrieved 2020-10-13.
  39. 1 2 3 4 5 6 7 8 "Features and uses of RS-70" (PDF). Gas Servei. Retrieved 2022-07-19.
  40. 1 2 3 4 5 6 "Opteon™ XL40 Refrigerant - Product Information" (PDF). Chemours. Retrieved 2020-10-13.[ permanent dead link ]
  41. 1 2 3 4 5 6 "Opteon™ XL41 Refrigerant - Product Information" (PDF). Chemours. Retrieved 2020-10-13.
  42. ↑ "Carrier Introduces Puron Advance™". Carrier. 19 December 2018. Retrieved 2020-10-13.
  43. 1 2 3 4 5 6 "Opteon™ XL20 Refrigerant - Product Information" (PDF). Chemours. Retrieved 2020-10-13.[ permanent dead link ]
  44. 1 2 3 4 5 6 7 "Solstice® L40X (R-455A) | European Refrigerants" (PDF). www.honeywell-refrigerants.com. Retrieved 2018-09-24.
  45. 1 2 "Fluorinated alternatives in residential and light commercial applications - Forane Refrigerants" (PDF). Arkema. Retrieved 2020-10-13.
  46. 1 2 3 "Protection of Stratospheric Ozone: Listing of Substitutes Under the Significant New Alternatives Policy Program". Federal Register. 2020-06-12. Retrieved 2020-07-01.
  47. ↑ "Federal Register :: Protection of Stratospheric Ozone: Determination 33 for Significant New Alternatives Policy Program". www.federalregister.gov. Retrieved 2019-08-16.
  48. 1 2 3 4 5 6 7 "Solstice® N41 (R-466A)". advancedmaterials.honeywell.com. Retrieved 2024-03-17.
  49. 1 2 3 4 5 6 "Opteon™ XP10 (R-513A) refrigerant". www.chemours.com. Retrieved 2018-12-12.
  50. ↑ https://www.opteon.com/en/-/media/files/opteon/opteon-xp30-product-information.pdf?la=en&rev=dbb567acf6554988840dff8d3c725d97 [ bare URL PDF ]
  51. ↑ "Trane adopts new low GWP refrigerant R514A". 15 June 2016.
  52. ↑ "Honeywell launches R515B, its latest nonflammable HFO, as R134a replacement". 4 February 2020.
  53. ↑ PRODUCT SAFETY DATA SHEET - PRODUCT: RS-45 (R434A) (PDF), Refrigerant Solutions Limited, 2001-10-01, archived from the original (PDF) on 2011-07-03, retrieved 2011-12-16
  54. 1 2 3 4 5 6 7 8 TRANSITIONING TO LOW-GWP - ALTERNATIVES IN DOMESTIC REFRIGERATION (PDF), US EPA, October 2010, retrieved 2011-12-17
  55. 1 2 3 "HC Refrigerant".
  56. 1 2 3 http://hpc2017.org/wp-content/uploads/2017/05/O.3.3.4-Novel-Working-Fluid-HFO-1336mzzE-for-Use-in-Waste-Heat-Recovery-Applications.pdf [ bare URL PDF ]
  57. ↑ "EPA Adds SP34E to SNAP Program".
  58. 1 2 3 "II. ADVANTAGES OF AMMONIA AS A REFRIGERANT". Ammonia: The Natural Refrigerant of Choice (An IIAR Green Paper). International Institute of Ammonia Refrigeration. Archived from the original on 2011-07-26. Retrieved 2010-12-21.
  59. 1 2 "Ammonia - NH3 - Properties". Engineering Toolbox. Retrieved 2011-12-18.
  60. 1 2 "Refrigerants - Environment Properties". Engineering ToolBox. Archived from the original on 2013-03-14. Retrieved 2011-12-27.
  61. ↑ Archer, David (2005). "Fate of fossil fuel CO
    2     in geologic time"     (PDF). Journal of Geophysical Research . 110 (C9): C09S05.1–6. Bibcode:2005JGRC..110.9S05A. doi: 10.1029/2004JC002625 . Retrieved 27 July 2007.
  62. ↑ Span R, Wagner W (1996-11-01). "A New Equation of State for Carbon Dioxide Covering the Fluid Region from the Triple-Point Temperature to 1100 K at Pressures up to 800 MPa". Journal of Physical and Chemical Reference Data. 25 (6): 1519. Bibcode:1996JPCRD..25.1509S. doi:10.1063/1.555991.
  63. 1 2 3 "CDC - NIOSH Pocket Guide to Chemical Hazards - Sulfur dioxide", National Institute for Occupational Safety and Health , Centers for Disease Control and Prevention 1600 Clifton Rd. Atlanta, GA 30333, USA, 2010-11-18, retrieved 2012-02-06
  64. ↑ "ICSC 0687 - VINYLIDENE FLUORIDE". www.ilo.org. Retrieved 2018-06-18.
  65. ↑ "New HCFO refrigerant is ASHRAE listed". Cooling Post. 2017-10-23. Retrieved 2021-02-06.
  66. ↑ "NEC develops cooling technology for data centers that reduces air conditioning power by 50%". NEC. Retrieved 2021-02-06.
  67. ↑ "NEC, NTT develop data center cooling system using new low pressure refrigerant". www.datacenterdynamics.com. Retrieved 2021-02-06.
  68. 1 2 3 4 5 6 7 https://www.coolingpost.com/world-news/new-hcfo-refrigerant-ashrae-listed/ [ bare URL ]
  69. 1 2 3 "Solstice® LBA Technical Brochure | Blowing Agents". www.honeywell-blowingagents.com. Retrieved 2016-07-05.
  70. 1 2 GM First to Market Greenhouse Gas-Friendly Air Conditioning Refrigerant in U.S., Warren, Michigan: General Motors, 2010-07-23, retrieved 2010-12-27
  71. 1 2 Everitt, Neil (2014-02-03). "IPCC confirms HFO GWPs are less than 1". Cooling Post. Retrieved 2024-09-16.
  72. ↑ "ANSI/ASHRAE Addendum c to ANSI/ASHRAE Standard 34-2010: Designation and Safety Classification of Refrigerants" (PDF). ASHRAE. 2011-07-27.
  73. 1 2 3 "Addendum w to ANSI/ASHRAE Standard 34-2007" (PDF). ANSI/ASHRAE Standard 34-2007, Designation and Safety Classification of Refrigerants. Atlanta, GA: American Society of Heating, Refrigerating and Air-Conditioning Engineers. 2008-11-18. ISSN   1041-2336. Archived from the original (PDF) on 2011-10-12. Retrieved 2011-12-18.
  74. ↑ https://docs.lib.purdue.edu/cgi/viewcontent.cgi?article=2524&context=iracc [ bare URL PDF ]
  75. ↑ "Numbering Scheme for Ozone-Depleting Substances and their Substitutes". Science - Ozone Layer Protection. US EPA. 2007. Retrieved 2011-12-18.
  76. ↑ "ANSI/ASHRAE Addendum ak to ANSI/ASHRAE Standard 34-2007" (PDF). ANSI/ASHRAE Standard 34-2007, Designation and Safety Classification of Refrigerants. Atlanta, GA: American Society of Heating, Refrigerating and Air-Conditioning Engineers. 2010-02-24. ISSN   1041-2336. Archived from the original (PDF) on 2011-10-12. Retrieved 2011-12-18.
  77. 1 2 3 "ANSI/ASHRAE Addenda z, ah, ai, and aj to ANSI/ASHRAE Standard 34-2007" (PDF). ANSI/ASHRAE Standard 34-2007, Designation and Safety Classification of Refrigerants. Atlanta, GA: American Society of Heating, Refrigerating and Air-Conditioning Engineers. 2010-01-28. ISSN   1041-2336. Archived from the original (PDF) on 2011-10-12. Retrieved 2011-12-18.
  78. ↑ Wade, Leroy G. Jr. (2006). Organic Chemistry (Sixth ed.). Upper Saddle River, New Jersey: Pearson Prentice Hall. pp.  279. ISBN   978-0-13-147871-8. OCLC   56876670.


Notes

  1. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 Blend Calculation using the following information: (a) Hydrocarbons are assumed to be similar to Methane in terms of Atmospheric Lifetime being 12 ± 3 years, (b) Pentane & Isopentane is assumed to have a net GWP over 100-yr to be 4 ± 2
  2. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 Blend Calculation using the following information: [4] [12] [15] [14] [17] [25]
  3. ↑ Triple point; substance sublimes at atmospheric pressure.
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