Strontium oxide

Last updated
Strontium oxide [1]
SrOpowder.jpg
Strontium-oxide-unit-cell-3D-SF.png
Names
IUPAC name
Strontium oxide
Other names
Strontia
Identifiers
3D model (JSmol)
ECHA InfoCard 100.013.837 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 215-219-9
PubChem CID
UNII
  • InChI=1S/O.Sr/q-2;+2
  • [O-2].[Sr+2]
Properties
SrO
Molar mass 103.619 g/mol
Appearancecolorless cubic crystals
Density 4.70 g/cm3
Melting point 2,531 °C (4,588 °F; 2,804 K)
Boiling point 3,200 °C (5,790 °F; 3,470 K) (decomposes)
reacts, forms Sr(OH)2
Solubility miscible with potassium hydroxide
slightly soluble in alcohol
insoluble in acetone and ether
35.0·10−6 cm3/mol
1.810 [2]
Structure
Halite (cubic), cF8
Fm3m, No. 225
Octahedral (Sr2+); octahedral (O2−)
Thermochemistry
44.3 J·mol−1·K−1
Std molar
entropy
(S298)
57.2 J·mol−1·K−1
-592.0 kJ·mol−1
Hazards
Flash point Non-flammable
Related compounds
Other anions
Strontium sulfide
Other cations
Beryllium oxide
Magnesium oxide
Calcium oxide
Barium oxide
Related compounds
Strontium hydroxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
X mark.svgN  verify  (what is  Yes check.svgYX mark.svgN ?)

Strontium oxide or strontia, SrO, is formed when strontium reacts with oxygen. Burning strontium in air results in a mixture of strontium oxide and strontium nitride. It also forms from the decomposition of strontium carbonate SrCO3. It is a strongly basic oxide.

Contents

Uses

About 8% by weight of cathode ray tubes is strontium oxide, which has been the major use of strontium since 1970. [3] [4] Color televisions and other devices containing color cathode ray tubes sold in the United States are required by law to use strontium in the faceplate to block X-ray emission (these X-ray emitting TVs are no longer in production). Lead(II) oxide can be used in the neck and funnel, but causes discoloration when used in the faceplate. [5]

Reactions

Elemental strontium is formed when strontium oxide is heated with aluminium in a vacuum. [1]

Related Research Articles

<span class="mw-page-title-main">Barium</span> Chemical element, symbol Ba and atomic number 56

Barium is a chemical element; it has symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element.

<span class="mw-page-title-main">Cathode-ray tube</span> Vacuum tube often used to display images

A cathode-ray tube (CRT) is a vacuum tube containing one or more electron guns, which emit electron beams that are manipulated to display images on a phosphorescent screen. The images may represent electrical waveforms on an oscilloscope, a frame of video on an analog television set (TV), digital raster graphics on a computer monitor, or other phenomena like radar targets. A CRT TV is commonly called a picture tube. CRTs have also been used as memory devices, in which case the screen is not intended to be visible to an observer. The term cathode ray was used to describe electron beams when they were first discovered, before it was understood that what was emitted from the cathode was a beam of electrons.

<span class="mw-page-title-main">Rubidium</span> Chemical element, symbol Rb and atomic number 37

Rubidium is a chemical element; it has symbol Rb and atomic number 37. It is a very soft, whitish-grey solid in the alkali metal group, similar to potassium and caesium. Rubidium is the first alkali metal in the group to have a density higher than water. On Earth, natural rubidium comprises two isotopes: 72% is a stable isotope 85Rb, and 28% is slightly radioactive 87Rb, with a half-life of 48.8 billion years—more than three times as long as the estimated age of the universe.

<span class="mw-page-title-main">Strontium</span> Chemical element, symbol Sr and atomic number 38

Strontium is a chemical element; it has symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is exposed to air. Strontium has physical and chemical properties similar to those of its two vertical neighbors in the periodic table, calcium and barium. It occurs naturally mainly in the minerals celestine and strontianite, and is mostly mined from these.

<span class="mw-page-title-main">Alkaline earth metal</span> Group of chemical elements

The alkaline earth metals are six chemical elements in group 2 of the periodic table. They are beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), and radium (Ra). The elements have very similar properties: they are all shiny, silvery-white, somewhat reactive metals at standard temperature and pressure.

<span class="mw-page-title-main">Baryte</span> Barium sulfate mineral

Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate (BaSO4). Baryte is generally white or colorless, and is the main source of the element barium. The baryte group consists of baryte, celestine (strontium sulfate), anglesite (lead sulfate), and anhydrite (calcium sulfate). Baryte and celestine form a solid solution (Ba,Sr)SO4.

<span class="mw-page-title-main">Phosphor</span> Luminescent substance

A phosphor is a substance that exhibits the phenomenon of luminescence; it emits light when exposed to some type of radiant energy. The term is used both for fluorescent or phosphorescent substances which glow on exposure to ultraviolet or visible light, and cathodoluminescent substances which glow when struck by an electron beam in a cathode-ray tube.

<span class="mw-page-title-main">Magnesium oxide</span> Chemical compound naturally occurring as periclase

Magnesium oxide (MgO), or magnesia, is a white hygroscopic solid mineral that occurs naturally as periclase and is a source of magnesium (see also oxide). It has an empirical formula of MgO and consists of a lattice of Mg2+ ions and O2− ions held together by ionic bonding. Magnesium hydroxide forms in the presence of water (MgO + H2O → Mg(OH)2), but it can be reversed by heating it to remove moisture.

<span class="mw-page-title-main">Vacuum fluorescent display</span> Display used in consumer electronics

A vacuum fluorescent display (VFD) is a display device once commonly used on consumer electronics equipment such as video cassette recorders, car radios, and microwave ovens.

<span class="mw-page-title-main">Strontium titanate</span> Chemical compound

Strontium titanate is an oxide of strontium and titanium with the chemical formula SrTiO3. At room temperature, it is a centrosymmetric paraelectric material with a perovskite structure. At low temperatures it approaches a ferroelectric phase transition with a very large dielectric constant ~104 but remains paraelectric down to the lowest temperatures measured as a result of quantum fluctuations, making it a quantum paraelectric. It was long thought to be a wholly artificial material, until 1982 when its natural counterpart—discovered in Siberia and named tausonite—was recognised by the IMA. Tausonite remains an extremely rare mineral in nature, occurring as very tiny crystals. Its most important application has been in its synthesized form wherein it is occasionally encountered as a diamond simulant, in precision optics, in varistors, and in advanced ceramics.

A television set or television receiver is an electronic device for the purpose of viewing and hearing television broadcasts, or as a computer monitor. It combines a tuner, display, and loudspeakers. Introduced in the late 1920s in mechanical form, television sets became a popular consumer product after World War II in electronic form, using cathode ray tube (CRT) technology. The addition of color to broadcast television after 1953 further increased the popularity of television sets in the 1960s, and an outdoor antenna became a common feature of suburban homes. The ubiquitous television set became the display device for the first recorded media for consumer use in the 1970s, such as Betamax, VHS; these were later succeeded by DVD. It has been used as a display device since the first generation of home computers and dedicated video game consoles in the 1980s. By the early 2010s, flat-panel television incorporating liquid-crystal display (LCD) technology, especially LED-backlit LCD technology, largely replaced CRT and other display technologies. Modern flat panel TVs are typically capable of high-definition display and can also play content from a USB device. Starting in the late 2010s, most flat panel TVs began to offer 4K and 8K resolutions.

<span class="mw-page-title-main">Zinc sulfide</span> Inorganic compound

Zinc sulfide is an inorganic compound with the chemical formula of ZnS. This is the main form of zinc found in nature, where it mainly occurs as the mineral sphalerite. Although this mineral is usually black because of various impurities, the pure material is white, and it is widely used as a pigment. In its dense synthetic form, zinc sulfide can be transparent, and it is used as a window for visible optics and infrared optics.

<span class="mw-page-title-main">Barium oxide</span> Chemical compound used in cathode ray tubes

Barium oxide, also known as baria, is a white hygroscopic non-flammable compound with the formula BaO. It has a cubic structure and is used in cathode ray tubes, crown glass, and catalysts. It is harmful to human skin and if swallowed in large quantity causes irritation. Excessive quantities of barium oxide may lead to death.

<span class="mw-page-title-main">Lead(II) oxide</span> Chemical compound

Lead(II) oxide, also called lead monoxide, is the inorganic compound with the molecular formula PbO. PbO occurs in two polymorphs: litharge having a tetragonal crystal structure, and massicot having an orthorhombic crystal structure. Modern applications for PbO are mostly in lead-based industrial glass and industrial ceramics, including computer components. It is an amphoteric oxide.

<span class="mw-page-title-main">Hot cathode</span> Type of electrode

In vacuum tubes and gas-filled tubes, a hot cathode or thermionic cathode is a cathode electrode which is heated to make it emit electrons due to thermionic emission. This is in contrast to a cold cathode, which does not have a heating element. The heating element is usually an electrical filament heated by a separate electric current passing through it. Hot cathodes typically achieve much higher power density than cold cathodes, emitting significantly more electrons from the same surface area. Cold cathodes rely on field electron emission or secondary electron emission from positive ion bombardment, and do not require heating. There are two types of hot cathode. In a directly heated cathode, the filament is the cathode and emits the electrons. In an indirectly heated cathode, the filament or heater heats a separate metal cathode electrode which emits the electrons.

<span class="mw-page-title-main">Mercury battery</span>

A mercury battery is a non-rechargeable electrochemical battery, a primary cell. Mercury batteries use a reaction between mercuric oxide and zinc electrodes in an alkaline electrolyte. The voltage during discharge remains practically constant at 1.35 volts, and the capacity is much greater than that of a similarly sized zinc-carbon battery. Mercury batteries were used in the shape of button cells for watches, hearing aids, cameras and calculators, and in larger forms for other applications.

<span class="mw-page-title-main">Strontium carbonate</span> Chemical compound

Strontium carbonate (SrCO3) is the carbonate salt of strontium that has the appearance of a white or grey powder. It occurs in nature as the mineral strontianite.

<span class="mw-page-title-main">Strontium sulfate</span> Chemical compound

Strontium sulfate (SrSO4) is the sulfate salt of strontium. It is a white crystalline powder and occurs in nature as the mineral celestine. It is poorly soluble in water to the extent of 1 part in 8,800. It is more soluble in dilute HCl and nitric acid and appreciably soluble in alkali chloride solutions (e.g. sodium chloride).

Lanthanum strontium cobalt ferrite (LSCF), also called lanthanum strontium cobaltite ferrite is a specific ceramic oxide derived from lanthanum cobaltite of the ferrite group. It is a phase containing lanthanum(III) oxide, strontium oxide, cobalt oxide and iron oxide with the formula La
x
Sr
1-x
Co
y
Fe
1-y
O
3
, where 0.1≤x≤0.4 and 0.2≤y≤0.8.

<span class="mw-page-title-main">Yttrium</span> Chemical element, symbol Y and atomic number 39

Yttrium is a chemical element; it has symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a "rare-earth element". Yttrium is almost always found in combination with lanthanide elements in rare-earth minerals and is never found in nature as a free element. 89Y is the only stable isotope and the only isotope found in the Earth's crust.

References

  1. 1 2 Lide, David R. (1998). Handbook of Chemistry and Physics (87 ed.). Boca Raton, Florida: CRC Press. pp. 4–87. ISBN   0-8493-0594-2.
  2. Pradyot Patnaik. Handbook of Inorganic Chemicals. McGraw-Hill, 2002, ISBN   0-07-049439-8
  3. Ober, Joyce A.; Polyak, Désirée E. "Mineral Yearbook 2007:Strontium" (PDF). United States Geological Survey. Retrieved 2009-09-14.
  4. Minerals Yearbook. Bureau of Mines. May 8, 2011. ISBN   9781411332270 via Google Books.
  5. Méar, F; Yot, P; Cambon, M; Ribes, M (2006). "The characterization of waste cathode-ray tube glass". Waste Management. 26 (12): 1468–76. Bibcode:2006WaMan..26.1468M. doi:10.1016/j.wasman.2005.11.017. ISSN   0956-053X. PMID   16427267.