Strontium phosphide

Strontium phosphide

Names
Other names Tristrontium diphosphide
Identifiers
CAS Number	12504-16-4
3D model (JSmol)	Interactive image
ChemSpider	145854
ECHA InfoCard	100.032.422
EC Number	235-678-9
PubChem CID	166710
UN number	2013
CompTox Dashboard (EPA)	DTXSID30894176
InChI InChI=1S/2P.3Sr/q2*-3;3*+2 Key: ATAJSUOOOWSVGL-UHFFFAOYSA-N
SMILES [P-3].[P-3].[Sr+2].[Sr+2].[Sr+2]
Properties
Chemical formula	P2Sr3
Molar mass	324.8
Appearance	Black crystalline material
Density	2.68 g/cm3
Solubility in water	Decomposes in water
Structure
Crystal structure	cubic
Related compounds
Other anions	Calcium phosphide Barium phosphide
Other cations	Strontium nitride Strontium arsenide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Strontium phosphide is an inorganic compound of strontium and phosphorus with the chemical formula Sr
_³P
_². ^{[1] [2]} The compound looks like black crystalline material.^{[ citation needed ]}

Synthesis

Heating strontium phosphate with soot in an arc furnace:

Sr₃(PO₄)₂ + 8 C → Sr₃P₂ + 8 CO

Reaction of strontium with red phosphorus at high temperature:^{[ citation needed ]}

6 Sr + P₄ → 2 Sr₃P₂

Physical properties

Strontium phosphide forms black crystals.^{[ citation needed ]}

Thermally stable, melts at high temperatures.

Dangerous when wet, poison. ^[3]

Chemical properties

Decomposes with water releasing phosphine:^{[ citation needed ]}

Sr₃P₂ + 2 H₂O → 3 Sr(OH)₂ + 2 PH₃

Reacts with acids:

Sr₃P₂ + 6 HCl → 3 SrCl₂ + 2 PH₃

Uses

It is a highly reactive substance used as a reagent and in the manufacture of chemically reactive devices. ^[4]

References

1. "Strontium Phosphide". American Elements . Retrieved 13 December 2021.
2. Wang, Junjie; Hanzawa, Kota; Hiramatsu, Hidenori; Kim, Junghwan; Umezawa, Naoto; Iwanaka, Koki; Tada, Tomofumi; Hosono, Hideo (8 November 2017). "Exploration of Stable Strontium Phosphide-Based Electrides: Theoretical Structure Prediction and Experimental Validation" . Journal of the American Chemical Society . 139 (44): 15668–15680. doi:10.1021/jacs.7b06279. PMID   29023114 . Retrieved 13 December 2021.
3. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. U.S. Government Printing Office. 1979. p. 11. Retrieved 13 December 2021.
4. "STRONTIUM PHOSPHIDE | CAMEO Chemicals | NOAA". cameochemicals.noaa.gov. Retrieved 13 December 2021.