Strontium phosphide

Last updated
Strontium phosphide
Names
Other names
Tristrontium diphosphide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.032.422 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 235-678-9
PubChem CID
UN number 2013
  • InChI=1S/2P.3Sr/q2*-3;3*+2
    Key: ATAJSUOOOWSVGL-UHFFFAOYSA-N
  • [P-3].[P-3].[Sr+2].[Sr+2].[Sr+2]
Properties
P2Sr3
Molar mass 324.8
AppearanceBlack crystalline material
Density 2.68 g/cm3
Decomposes in water
Structure
cubic
Related compounds
Other anions
Calcium phosphide
Barium phosphide
Other cations
Strontium nitride
Strontium arsenide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Strontium phosphide is an inorganic compound of strontium and phosphorus with the chemical formula Sr
3
P
2
. [1] [2] The compound looks like black crystalline material.[ citation needed ]

Contents

Synthesis

Heating strontium phosphate with soot in an arc furnace:

Sr3(PO4)2 + 8 C → Sr3P2 + 8 CO

Reaction of strontium with red phosphorus at high temperature:[ citation needed ]

6 Sr + P4 → 2 Sr3P2

Physical properties

Strontium phosphide forms black crystals.[ citation needed ]

Thermally stable, melts at high temperatures.

Dangerous when wet, poison. [3]

Chemical properties

Decomposes with water releasing phosphine:[ citation needed ]

Sr3P2 + 2 H2O → 3 Sr(OH)2 + 2 PH3

Reacts with acids:

Sr3P2 + 6 HCl → 3 SrCl2 + 2 PH3

Uses

It is a highly reactive substance used as a reagent and in the manufacture of chemically reactive devices. [4]

Related Research Articles

<span class="mw-page-title-main">Strontium</span> Chemical element with atomic number 38 (Sr)

Strontium is a chemical element; it has symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is exposed to air. Strontium has physical and chemical properties similar to those of its two vertical neighbors in the periodic table, calcium and barium. It occurs naturally mainly in the minerals celestine and strontianite, and is mostly mined from these.

<span class="mw-page-title-main">Phosphine</span> Chemical compound hydrogen phosphide

Phosphine (IUPAC name: phosphane) is a colorless, flammable, highly toxic compound with the chemical formula PH3, classed as a pnictogen hydride. Pure phosphine is odorless, but technical grade samples have a highly unpleasant odor like rotting fish, due to the presence of substituted phosphine and diphosphane (P2H4). With traces of P2H4 present, PH3 is spontaneously flammable in air (pyrophoric), burning with a luminous flame. Phosphine is a highly toxic respiratory poison, and is immediately dangerous to life or health at 50 ppm. Phosphine has a trigonal pyramidal structure.

<span class="mw-page-title-main">Phosphide</span>

In chemistry, a phosphide is a compound containing the P3− ion or its equivalent. Many different phosphides are known, with widely differing structures. Most commonly encountered on the binary phosphides, i.e. those materials consisting only of phosphorus and a less electronegative element. Numerous are polyphosphides, which are solids consisting of anionic chains or clusters of phosphorus. Phosphides are known with the majority of less electronegative elements with the exception of Hg, Pb, Sb, Bi, Te, and Po. Finally, some phosphides are molecular.

<span class="mw-page-title-main">Calcium phosphide</span> Chemical compound

Calcium phosphide (CP) is the inorganic compound with the formula Ca3P2. It is one of several phosphides of calcium, being described as the salt-like material composed of Ca2+ and P3−. Other, more exotic calcium phosphides have the formula CaP / Ca2P2, CaP3, and Ca5P8.

<span class="mw-page-title-main">Sodium phosphide</span> Chemical compound

Sodium phosphide is the inorganic compound with the formula Na3P. It is a black solid. It is often described as Na+ salt of the P3− anion. Na3P is a source of the highly reactive phosphide anion. It should not be confused with sodium phosphate, Na3PO4.

Organophosphorus chemistry is the scientific study of the synthesis and properties of organophosphorus compounds, which are organic compounds containing phosphorus. They are used primarily in pest control as an alternative to chlorinated hydrocarbons that persist in the environment. Some organophosphorus compounds are highly effective insecticides, although some are extremely toxic to humans, including sarin and VX nerve agents.

<span class="mw-page-title-main">Zinc phosphide</span> Chemical compound

Zinc phosphide (Zn3P2) is an inorganic chemical compound. It is a grey solid, although commercial samples are often dark or even black. It is used as a rodenticide. Zn3P2 is a II-V semiconductor with a direct band gap of 1.5 eV and may have applications in photovoltaic cells. A second compound exists in the zinc-phosphorus system, zinc diphosphide (ZnP2).

A pyrotechnic composition is a substance or mixture of substances designed to produce an effect by heat, light, sound, gas/smoke or a combination of these, as a result of non-detonative self-sustaining exothermic chemical reactions. Pyrotechnic substances do not rely on oxygen from external sources to sustain the reaction.

<span class="mw-page-title-main">Strontium carbonate</span> Chemical compound

Strontium carbonate (SrCO3) is the carbonate salt of strontium that has the appearance of a white or grey powder. It occurs in nature as the mineral strontianite.

Iron phosphide is a chemical compound of iron and phosphorus, with a formula of FeP.< Its physical appearance is grey needles.

Lithium phosphide is an inorganic compound of lithium and phosphorus with the chemical formula Li3P. This dark colored compound is formally the lithium salt of phosphine, consisting of lithium cations Li+ and phosphide anions P3−. It is hazardous to handle because of its high reactivity toward air.

Lutetium phosphide is an inorganic compound of lutetium and phosphorus with the chemical formula LuP. The compound forms dark crystals, does not dissolve in water.

Neodymium phosphide is an inorganic compound of neodymium and phosphorus with the chemical formula NdP.

Europium phosphide is an inorganic compound of europium and phosphorus with the chemical formula EuP. Other phosphides are also known.

Samarium(III) phosphide is an inorganic compound of samarium and phosphorus with the chemical formula SmP.

<span class="mw-page-title-main">Lanthanum phosphide</span> Chemical compound

Lanthanum phosphide is an inorganic compound of lanthanum and phosphorus with the chemical formula LaP.

Ytterbium(III) phosphide is an inorganic compound of ytterbium and phosphorus with the chemical formula YbP. This is one of the phosphides of ytterbium.

Holmium phosphide is a binary inorganic compound of holmium and phosphorus with the chemical formula HoP. The compound forms dark crystals, is stable in air, and does not dissolve in water.

Phosphide bromides or bromide phosphides are compounds containing anions composed of bromide (Br) and phosphide (P3−) anions. Usually phosphorus is covalently connected into more complex structures. They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the phosphide chlorides, phosphide iodides, nitride bromides, arsenide bromides, and antimonide bromides.

Gold phosphide is a hypothetical binary inorganic compound of gold metal and phosphorus with the chemical formula AuP. No compound of composition AuP has been probed by X-ray crystallography. The only known gold phosphide is the metastable Au2P3.

References

  1. "Strontium Phosphide". American Elements . Retrieved 13 December 2021.
  2. Wang, Junjie; Hanzawa, Kota; Hiramatsu, Hidenori; Kim, Junghwan; Umezawa, Naoto; Iwanaka, Koki; Tada, Tomofumi; Hosono, Hideo (8 November 2017). "Exploration of Stable Strontium Phosphide-Based Electrides: Theoretical Structure Prediction and Experimental Validation". Journal of the American Chemical Society . 139 (44): 15668–15680. doi:10.1021/jacs.7b06279. PMID   29023114 . Retrieved 13 December 2021.
  3. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. U.S. Government Printing Office. 1979. p. 11. Retrieved 13 December 2021.
  4. "STRONTIUM PHOSPHIDE | CAMEO Chemicals | NOAA". cameochemicals.noaa.gov. Retrieved 13 December 2021.