Yttrium phosphide

Last updated
Yttrium phosphide
NaCl polyhedra.svg
Names
IUPAC name
Phosphanylidyneyttrium
Other names
Yttrium phosphide, yttrium(III) phosphide.
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.032.318 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 235-563-3
PubChem CID
  • InChI=1S/P.Y
    Key: DWDQAMUKGDBIGM-UHFFFAOYSA-N
  • P#[Y]
Properties
PY
Molar mass 119.879600
AppearanceColourless solid
Density 4.35 g/cm3 [1]
Melting point 200.78 °C (393.40 °F; 473.93 K)
Boiling point 511.30 °C (952.34 °F; 784.45 K)
Structure [2]
Rock salt structure
Fm3m
a = 0.5661 nm
4
Octahedral at Y3+, Octahedral at P3-
Related compounds
Other anions
Yttrium nitride
Yttrium(III) arsenide
Yttrium(III) antimonide
Other cations
Scandium phosphide
Lutetium phosphide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Yttrium phosphide is an inorganic compound of yttrium and phosphorus with the chemical formula YP. [3] [4] [5] The compound may be also classified as yttrium(III) phosphide.

Contents

Synthesis

Heating (500–1000 °C) of pure substances in a vacuum: [6]

4 Y + P4 → 4 YP

Properties

Yttrium phosphide forms cubic crystals. [1]

Uses

Ytttium phosphide is a semiconductor used in laser diodes, and in high power and frequency applications.

Related Research Articles

<span class="mw-page-title-main">Cubic crystal system</span> Crystallographic system where the unit cell is in the shape of a cube

In crystallography, the cubiccrystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals.

Tin(IV) iodide, also known as stannic iodide, is the chemical compound with the formula SnI4. This tetrahedral molecule crystallizes as a bright orange solid that dissolves readily in nonpolar solvents such as benzene.

<span class="mw-page-title-main">Scandium dodecaboride</span> Chemical compound

Scandium dodecaboride is a refractory metal boride.

<span class="mw-page-title-main">Yttrium borides</span> Chemical compound

Yttrium boride refers to a crystalline material composed of different proportions of yttrium and boron, such as YB2, YB4, YB6, YB12, YB25, YB50 and YB66. They are all gray-colored, hard solids having high melting temperatures. The most common form is the yttrium hexaboride YB6. It exhibits superconductivity at relatively high temperature of 8.4 K and, similar to LaB6, is an electron cathode. Another remarkable yttrium boride is YB66. It has a large lattice constant (2.344 nm), high thermal and mechanical stability, and therefore is used as a diffraction grating for low-energy synchrotron radiation (1–2 keV).

<span class="mw-page-title-main">Calcium titanate</span> Chemical compound

Calcium titanate is an inorganic compound with the chemical formula CaTiO3. As a mineral, it is called perovskite, named after Russian mineralogist, L. A. Perovski (1792-1856). It is a colourless, diamagnetic solid, although the mineral is often coloured owing to impurities.

Langbeinites are a family of crystalline substances based on the structure of langbeinite with general formula M2M'2(SO4)3, where M is a large univalent cation, and M' is a small divalent cation. The sulfate group, SO2−4, can be substituted by other tetrahedral anions with a double negative charge such as tetrafluoroberyllate, selenate, chromate, molybdate, or tungstates. Although monofluorophosphates are predicted, they have not been described. By redistributing charges other anions with the same shape such as phosphate also form langbeinite structures. In these the M' atom must have a greater charge to balance the extra three negative charges.

Yttrium hydride is a compound of hydrogen and yttrium. It is considered to be a part of the class of rare-earth metal hydrides. It exists in several forms, the most common being a metallic compound with formula YH2. YH2 has a face-centred cubic structure, and is a metallic compound. Under great pressure, extra hydrogen can combine to yield an insulator with a hexagonal structure, with a formula close to YH3. Hexagonal YH3 has a band gap of 2.6 eV. Under pressure of 12 GPa YH3 transforms to an intermediate state, and when the pressure increases to 22 GPa another metallic face-centred cubic phase is formed.

Yttrium oxyfluoride is an inorganic chemical compound with the formula YOF. Under normal conditions, the compound is a colorless solid.

<span class="mw-page-title-main">Durward William John Cruickshank</span> British crystallographer

Durward William John Cruickshank, often known as D. W. J. Cruickshank, was a British crystallographer whose work transformed the precision of determining molecular structures from X-ray crystal structure analysis. He developed the theoretical framework for anisotropic displacement parameters, also known as the thermal ellipsoid, for crystal structure determination in a series of papers published in 1956 in Acta Crystallographica.

Actinium(III) sulfide is the radioactive compound of actinium with the formula Ac2S3. This salt was prepared by heating actinium(III) oxalate at 1400°C for 6 minutes in a mixture of carbon disulfide and hydrogen sulfide. The result was conformed to be actinium(III) sulfide by x-ray diffraction.

<span class="mw-page-title-main">Yttrium oxalate</span> Chemical compound

Yttrium oxalate is an inorganic compound, a salt of yttrium and oxalic acid with the chemical formula Y2(C2O4)3. The compound does not dissolve in water and forms crystalline hydrates—colorless crystals.

Yttrium iodide is a binary inorganic compound, a salt of yttrium and hydroiodic acid with the formula YI
3
. The compound forms colorless crystals, soluble in water.

Lithium phosphide is an inorganic compound of lithium and phosphorus with the chemical formula Li
3
P
.

<span class="mw-page-title-main">Scandium phosphide</span> Chemical compound

Scandium phosphide is an inorganic compound of scandium and phosphorus with the chemical formula ScP.

Plutonium(III) phosphide is a binary inorganic compound of plutonium and phosphorus with the formula PuP.

Arsenide bromides or bromide arsenides are compounds containing anions composed of bromide (Br) and arsenide (As3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide chlorides, arsenide iodides, phosphide bromides, and antimonide bromides.

<span class="mw-page-title-main">Terbium compounds</span> Chemical compounds with at least one terbium atom

Terbium compounds are compounds formed by the lanthanide metal terbium (Tb). Terbium generally exhibits the +3 oxidation state in these compounds, such as in TbCl3, Tb(NO3)3 and Tb(CH3COO)3. Compounds with terbium in the +4 oxidation state are also known, such as TbO2 and BaTbF6. Terbium can also form compounds in the 0, +1 and +2 oxidation states.

Erbium compounds are compounds containing the element erbium (Er). These compounds are usually dominated by erbium in the +3 oxidation state, although the +2, +1 and 0 oxidation states have also been reported.

Ytterbium compounds are chemical compounds that contain the element ytterbium (Yb). The chemical behavior of ytterbium is similar to that of the rest of the lanthanides. Most ytterbium compounds are found in the +3 oxidation state, and its salts in this oxidation state are nearly colorless. Like europium, samarium, and thulium, the trihalides of ytterbium can be reduced to the dihalides by hydrogen, zinc dust, or by the addition of metallic ytterbium. The +2 oxidation state occurs only in solid compounds and reacts in some ways similarly to the alkaline earth metal compounds; for example, ytterbium(II) oxide (YbO) shows the same structure as calcium oxide (CaO).

Indium(I) chloride is the chemical compound with the formula InCl. Indium monochloride occurs as a yellow cubic form below 120 °C and above this temperature as a red orthorhombic form. InCl is one of three known indium chlorides.

References

  1. 1 2 "mp-994: YP (cubic, Fm-3m, 225)". materialsproject.org . Retrieved 8 December 2021.
  2. Parthé, E. (1963-01-01). "Note on the structure of ScP and YP". Acta Crystallographica. International Union of Crystallography (IUCr). 16 (1): 71. Bibcode:1963AcCry..16...71P. doi:10.1107/s0365110x63000141. ISSN   0365-110X.
  3. "Yttrium Phosphide". American Elements . Retrieved 8 December 2021.
  4. "Substance Name: Yttrium phosphide (YP)". TOXNET . chem.nlm.nih.gov. Retrieved 15 June 2017.
  5. "Yttrium: yttrium phosphide". Webelements. webelements.com. Retrieved 15 June 2017.
  6. Parthé, E. (10 January 1963). "Note on the structure of ScP and YP". Acta Crystallographica . 16: 71. Bibcode:1963AcCry..16...71P. doi:10.1107/S0365110X63000141 . Retrieved 12 December 2021.