Yttrium iron garnet | |
---|---|
General | |
Category | Synthetic mineral |
Formula (repeating unit) | Y3Fe2(FeO4)3 or Y3Fe5O12 |
Identification | |
Formula mass | 737.94 [1] |
Color | Green [1] |
Density | 5.11 g/cm3 [1] |
Other characteristics | Ferrimagnetic material |
Yttrium iron garnet (YIG) is a kind of synthetic garnet, with chemical composition Y 3 Fe 2(FeO 4)3, or Y3Fe5O12. It is a ferrimagnetic material [1] with a Curie temperature of 560 K. [2] YIG may also be known as yttrium ferrite garnet, or as iron yttrium oxide or yttrium iron oxide, the latter two names usually associated with powdered forms. [3]
Several methods are utilized for synthesis of yttrium iron garnet each with their pros and cons. The solid-state reaction method is a traditional approach for YIG synthesis, involving the high-temperature firing of a mixture of yttrium and iron oxides. [4] This cost-effective technique can produce pure YIG crystals but requires careful control of temperature and atmosphere to prevent impurities. [5]
Liquid phase epitaxy (LPE) is another key method, especially for creating thin YIG films with excellent uniformity. Ideal for optical and microwave devices, LPE enables precise film growth on substrates. [6] However, its high equipment costs and complex procedures limit its use to applications where superior quality is essential. [7]
In YIG, the five iron(III) ions occupy two octahedral and three tetrahedral sites, with the yttrium(III) ions coordinated by eight oxygen ions in an irregular cube. The iron ions in the two coordination sites exhibit different spins, resulting in magnetic behavior. [2] By substituting specific sites with rare-earth elements, for example, interesting magnetic properties can be obtained. [8]
YIG has a high Verdet constant which results in the Faraday effect, [9] [10] high Q factor in microwave frequencies, [11] low absorption of infrared wavelengths down to 1200 nm, [12] and very small linewidth in electron spin resonance. These properties make it useful for MOI (magneto optical imaging) applications in superconductors. [13]
YIG is used in microwave, acoustic, optical, and magneto-optical applications, e.g. microwave YIG filters, or acoustic transmitters and transducers. [14] It is transparent for light wavelengths over 600 nm — the infrared end of the spectrum.[ citation needed ] It also finds use in solid-state lasers in Faraday rotators, in data storage, and in various nonlinear optics applications. [15]
Dysprosium is a chemical element; it has symbol Dy and atomic number 66. It is a rare-earth element in the lanthanide series with a metallic silver luster. Dysprosium is never found in nature as a free element, though, like other lanthanides, it is found in various minerals, such as xenotime. Naturally occurring dysprosium is composed of seven isotopes, the most abundant of which is 164Dy.
Holmium is a chemical element; it has symbol Ho and atomic number 67. It is a rare-earth element and the eleventh member of the lanthanide series. It is a relatively soft, silvery, fairly corrosion-resistant and malleable metal. Like many other lanthanides, holmium is too reactive to be found in native form, as pure holmium slowly forms a yellowish oxide coating when exposed to air. When isolated, holmium is relatively stable in dry air at room temperature. However, it reacts with water and corrodes readily, and also burns in air when heated.
Garnets are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives.
An optical isolator, or optical diode, is an optical component which allows the transmission of light in only one direction. It is typically used to prevent unwanted feedback into an optical oscillator, such as a laser cavity.
Gallium arsenide (GaAs) is a III-V direct band gap semiconductor with a zinc blende crystal structure.
Gallium nitride is a binary III/V direct bandgap semiconductor commonly used in blue light-emitting diodes since the 1990s. The compound is a very hard material that has a Wurtzite crystal structure. Its wide band gap of 3.4 eV affords it special properties for applications in optoelectronic, high-power and high-frequency devices. For example, GaN is the substrate that makes violet (405 nm) laser diodes possible, without requiring nonlinear optical frequency doubling.
The Faraday effect or Faraday rotation, sometimes referred to as the magneto-optic Faraday effect (MOFE), is a physical magneto-optical phenomenon. The Faraday effect causes a polarization rotation which is proportional to the projection of the magnetic field along the direction of the light propagation. Formally, it is a special case of gyroelectromagnetism obtained when the dielectric permittivity tensor is diagonal. This effect occurs in most optically transparent dielectric materials under the influence of magnetic fields.
The Verdet constant is an optical property named after the French physicist Émile Verdet. It describes the strength of the Faraday effect for a particular material. For a constant magnetic field parallel to the path of the light, it can be calculated by:
A Faraday rotator is a polarization rotator based on the Faraday effect, a magneto-optic effect involving transmission of light through a material when a longitudinal static magnetic field is present. The state of polarization is rotated as the wave traverses the device, which is explained by a slight difference in the phase velocity between the left and right circular polarizations. Thus it is an example of circular birefringence, as is optical activity, but involves a material only having this property in the presence of a magnetic field.
Yttrium aluminium garnet (YAG, Y3Al5O12) is a synthetic crystalline material of the garnet group. It is a cubic yttrium aluminium oxide phase, with other examples being YAlO3 (YAP) in a hexagonal or an orthorhombic, perovskite-like form, and the monoclinic Y4Al2O9 (YAM).
Yttrium oxide, also known as yttria, is Y2O3. It is an air-stable, white solid substance.
Yttrium iron garnet spheres serve as magnetically tunable filters and resonators for microwave frequencies. YIG filters are used for their high Q factors, typically between 100 and 200. A sphere made from a single crystal of synthetic yttrium iron garnet acts as a resonator.
Lutetium aluminum garnet (commonly abbreviated LuAG, molecular formula Lu3Al5O12) is an inorganic compound with a unique crystal structure primarily known for its use in high-efficiency laser devices. LuAG is also useful in the synthesis of transparent ceramics.
Bismuth ferrite (BiFeO3, also commonly referred to as BFO in materials science) is an inorganic chemical compound with perovskite structure and one of the most promising multiferroic materials. The room-temperature phase of BiFeO3 is classed as rhombohedral belonging to the space group R3c. It is synthesized in bulk and thin film form and both its antiferromagnetic (G type ordering) Néel temperature (approximately 653 K) and ferroelectric Curie temperature are well above room temperature (approximately 1100K). Ferroelectric polarization occurs along the pseudocubic direction () with a magnitude of 90–95 μC/cm2.
An optical modulator is an optical device which is used to modulate a beam of light with a perturbation device. It is a kind of transmitter to convert information to optical binary signal through optical fiber or transmission medium of optical frequency in fiber optic communication. There are several methods to manipulate this device depending on the parameter of a light beam like amplitude modulator (majority), phase modulator, polarization modulator etc. The easiest way to obtain modulation is modulation of intensity of a light by the current driving the light source. This sort of modulation is called direct modulation, as opposed to the external modulation performed by a light modulator. For this reason, light modulators are called external light modulators. According to manipulation of the properties of material modulators are divided into two groups, absorptive modulators and refractive modulators. Absorption coefficient can be manipulated by Franz-Keldysh effect, Quantum-Confined Stark Effect, excitonic absorption, or changes of free carrier concentration. Usually, if several such effects appear together, the modulator is called electro-absorptive modulator. Refractive modulators most often make use of electro-optic effect, other modulators are made with acousto-optic effect, magneto-optic effect such as Faraday and Cotton-Mouton effects. The other case of modulators is spatial light modulator (SLM) which is modified two dimensional distribution of amplitude & phase of an optical wave.
A tunable metamaterial is a metamaterial with a variable response to an incident electromagnetic wave. This includes remotely controlling how an incident electromagnetic wave interacts with a metamaterial. This translates into the capability to determine whether the EM wave is transmitted, reflected, or absorbed. In general, the lattice structure of the tunable metamaterial is adjustable in real time, making it possible to reconfigure a metamaterial device during operation. It encompasses developments beyond the bandwidth limitations in left-handed materials by constructing various types of metamaterials. The ongoing research in this domain includes electromagnetic band gap metamaterials (EBG), also known as photonic band gap (PBG), and negative refractive index material (NIM).
Gadolinium Gallium Garnet is a synthetic crystalline material of the garnet group, with good mechanical, thermal, and optical properties. It is typically colorless. It has a cubic lattice, a density of 7.08 g/cm3 and its Mohs hardness is variously noted as 6.5 and 7.5. Its crystals are produced with the Czochralski method. During production, various dopants can be added for colour modification. The material is also used in fabrication of various optical components and as a substrate material for magneto–optical films. It also finds use in jewelry as a diamond simulant. GGG can also be used as a seed substrate for the growth of other garnets such as yttrium iron garnet.
Terbium gallium garnet (TGG) is a kind of synthetic garnet, with the chemical composition Tb3Ga5O12. This is a Faraday rotator material with excellent transparency properties and is very resistant to laser damage. TGG can be used in optical isolators for laser systems, in optical circulators for fiber optic systems, in optical modulators, and in current and magnetic field sensors.
A complex oxide is a chemical compound that contains oxygen and at least two other elements. Complex oxide materials are notable for their wide range of magnetic and electronic properties, such as ferromagnetism, ferroelectricity, and high-temperature superconductivity. These properties often come from their strongly correlated electrons in d or f orbitals.