Dysprosium(III) oxide

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Dysprosium(III) oxide
Dy2O3powder.jpg
Tl2O3structure.jpg
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.013.786 OOjs UI icon edit-ltr-progressive.svg
PubChem CID
UNII
  • InChI=1S/2Dy.3O Yes check.svgY
    Key: NLQFUUYNQFMIJW-UHFFFAOYSA-N Yes check.svgY
  • InChI=1/2Dy.3O/rDy2O3/c3-1-5-2-4
    Key: NLQFUUYNQFMIJW-XDEDGNAWAZ
  • O=[Dy]O[Dy]=O
Properties
Dy2O3
Molar mass 372.998 g/mol
Appearancepastel yellowish-greenish powder.
Density 7.80 g/cm3
Melting point 2,408 °C (4,366 °F; 2,681 K) [1]
Negligible
+89,600·10−6 cm3/mol
Structure
Cubic, cI80
Ia3, No. 206 [2]
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Non-Toxic
Safety data sheet (SDS) External MSDS
Related compounds
Other anions
Dysprosium(III) chloride
Other cations
Terbium(III) oxide, Holmium(III) oxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Dysprosium oxide (Dy2O3) is a sesquioxide compound of the rare earth metal dysprosium. It is a pastel yellowish-greenish, slightly hygroscopic powder having specialized uses in ceramics, glass, phosphors, lasers, dysprosium metal halide lamps, and as a Faraday rotator [3] .

It can react with acids to produce the corresponding dysprosium(III) salts:

Dy2O3 + 6 HCl → 2 DyCl3 + 3 H2O

Related Research Articles

<span class="mw-page-title-main">Dysprosium</span> Chemical element with atomic number 66 (Dy)

Dysprosium is a chemical element; it has symbol Dy and atomic number 66. It is a rare-earth element in the lanthanide series with a metallic silver luster. Dysprosium is never found in nature as a free element, though, like other lanthanides, it is found in various minerals, such as xenotime. Naturally occurring dysprosium is composed of seven isotopes, the most abundant of which is 164Dy.

<span class="mw-page-title-main">Holmium</span> Chemical element with atomic number 67 (Ho)

Holmium is a chemical element; it has symbol Ho and atomic number 67. It is a rare-earth element and the eleventh member of the lanthanide series. It is a relatively soft, silvery, fairly corrosion-resistant and malleable metal. Like many other lanthanides, holmium is too reactive to be found in native form, as pure holmium slowly forms a yellowish oxide coating when exposed to air. When isolated, holmium is relatively stable in dry air at room temperature. However, it reacts with water and corrodes readily, and also burns in air when heated.

The lanthanide or lanthanoid series of chemical elements comprises at least the 14 metallic chemical elements with atomic numbers 57–70, from lanthanum through ytterbium. In the periodic table, they fill the 4f orbitals. Lutetium is also sometimes considered a lanthanide, despite being a d-block element and a transition metal.

<span class="mw-page-title-main">Terbium</span> Chemical element with atomic number 65 (Tb)

Terbium is a chemical element; it has the symbol Tb and atomic number 65. It is a silvery-white, rare earth metal that is malleable, and ductile. The ninth member of the lanthanide series, terbium is a fairly electropositive metal that reacts with water, evolving hydrogen gas. Terbium is never found in nature as a free element, but it is contained in many minerals, including cerite, gadolinite, monazite, xenotime and euxenite.

<span class="mw-page-title-main">Dysprosium(III) chloride</span> Chemical compound

Dysprosium(III) chloride (DyCl3), also known as dysprosium trichloride, is a compound of dysprosium and chlorine. It is a white to yellow solid which rapidly absorbs water on exposure to moist air to form a hexahydrate, DyCl3·6H2O. Simple rapid heating of the hydrate causes partial hydrolysis to an oxychloride, DyOCl.

Naturally occurring dysprosium (66Dy) is composed of 7 stable isotopes, 156Dy, 158Dy, 160Dy, 161Dy, 162Dy, 163Dy and 164Dy, with 164Dy being the most abundant. Twenty-nine radioisotopes have been characterized, with the most stable being 154Dy with a half-life of 1.4 million years, 159Dy with a half-life of 144.4 days, and 166Dy with a half-life of 81.6 hours. All of the remaining radioactive isotopes have half-lives that are less than 10 hours, and the majority of these have half-lives that are less than 30 seconds. This element also has 12 meta states, with the most stable being 165mDy, 147mDy and 145mDy.

<span class="mw-page-title-main">Holmium(III) oxide</span> Chemical compound

Holmium(III) oxide, or holmium oxide is a chemical compound of the rare-earth element holmium and oxygen with the formula Ho2O3. Together with dysprosium(III) oxide (Dy2O3), holmium oxide is one of the most powerfully paramagnetic substances known. The oxide, also called holmia, occurs as a component of the related erbium oxide mineral called erbia. Typically, the oxides of the trivalent lanthanides coexist in nature, and separation of these components requires specialized methods. Holmium oxide is used in making specialty colored glasses. Glass containing holmium oxide and holmium oxide solutions have a series of sharp optical absorption peaks in the visible spectral range. They are therefore traditionally used as a convenient calibration standard for optical spectrophotometers.

<span class="mw-page-title-main">Yttrium iron garnet</span> Synthetic garnet

Yttrium iron garnet (YIG) is a kind of synthetic garnet, with chemical composition Y3Fe2(FeO4)3, or Y3Fe5O12. It is a ferrimagnetic material with a Curie temperature of 560 K. YIG may also be known as yttrium ferrite garnet, or as iron yttrium oxide or yttrium iron oxide, the latter two names usually associated with powdered forms.

A block of the periodic table is a set of elements unified by the atomic orbitals their valence electrons or vacancies lie in. The term seems to have been first used by Charles Janet. Each block is named after its characteristic orbital: s-block, p-block, d-block, f-block and g-block.

<span class="mw-page-title-main">Cerium(III) fluoride</span> Chemical compound

Cerium(III) fluoride (or cerium trifluoride), CeF3, is an ionic compound of the rare earth metal cerium and fluorine.

Dysprosium(III) fluoride is an inorganic compound of dysprosium with a chemical formula DyF3.

<span class="mw-page-title-main">Dysprosium(III) hydroxide</span> Chemical compound

Dysprosium(III) hydroxide is an inorganic compound with the chemical formula Dy(OH)3.

Dysprosium(II) chloride (DyCl2), also known as dysprosium dichloride, is an ionic chemical compound of dysprosium and chlorine. This salt is a reduced compound, as the normal oxidation state of dysprosium in dysprosium compounds is +3.

<span class="mw-page-title-main">Dysprosium(III) nitrate</span> Chemical compound

Dysprosium(III) nitrate is an inorganic compound, a salt of dysprosium and nitric acid with the chemical formula Dy(NO3)3. The compound forms yellowish crystals, dissolves in water, forms a crystalline hydrate.

<span class="mw-page-title-main">Dysprosium phosphide</span> Erbium compound

Dysprosium phosphide is an inorganic compound of dysprosium and phosphorus with the chemical formula DyP.

<span class="mw-page-title-main">Dysprosium(III) acetate</span> Chemical compound

Dysprosium acetate is a hypothetical salt of dysprosium and acetate. Its proposed chemical formula is Dy(CH3COO)3.

<span class="mw-page-title-main">Terbium compounds</span> Chemical compounds with at least one terbium atom

Terbium compounds are compounds formed by the lanthanide metal terbium (Tb). Terbium generally exhibits the +3 oxidation state in these compounds, such as in TbCl3, Tb(NO3)3 and Tb(CH3COO)3. Compounds with terbium in the +4 oxidation state are also known, such as TbO2 and BaTbF6. Terbium can also form compounds in the 0, +1 and +2 oxidation states.

<span class="mw-page-title-main">Dysprosium(III) bromide</span> Chemical compound

Dysprosium(III) bromide is an inorganic compound of bromine and dysprosium, with the chemical formula of DyBr3.

Dysprosium(III) selenide is one of the selenides of dysprosium, with the chemical formula of Dy2Se3.

<span class="mw-page-title-main">Dysprosium(III) phosphate</span> Chemical compound

Dysprosium(III) phosphate is an inorganic compound with the chemical formula DyPO4.

References

  1. Webelements Dysprosium trioxide
  2. Curzon A.E., Chlebek H.G. (1973). "The observation of face centred cubic Gd, Tb, Dy, Ho, Er and Tm in the form of thin films and their oxidation". J. Phys. F. 3 (1): 1–5. Bibcode:1973JPhF....3....1C. doi:10.1088/0305-4608/3/1/009.
  3. Vojna, David; Slezák, Ondřej; Yasuhara, Ryo; Furuse, Hiroaki; Lucianetti, Antonio; Mocek, Tomáš (2020). "Faraday Rotation of Dy2O3, CeF3 and Y3Fe5O12 at the Mid-Infrared Wavelengths". Materials. 13 (23): 5324. Bibcode:2020Mate...13.5324V. doi: 10.3390/ma13235324 . PMC   7727863 . PMID   33255447.