Dysprosium stannate

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Dysprosium stannate
Fragment of pyrochlore lattice in spin ice state.png
Names
IUPAC name
Dysprosium stannate
Identifiers
3D model (JSmol)
  • InChI=1S/2Dy.7O.2Sn/q2*+3;7*-2;2*+4
    Key: NQAJIAKVXPCJHB-UHFFFAOYSA-N
  • [Dy+3].[Dy+3].[Sn+4].[Sn+4].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2]
Properties
Dy2O7Sn2
Molar mass 674.413 g·mol−1
Density 7.97 g/cm3 [1]
Structure [1]
Pyrochlore
Fd3m, cF88, No. 227
a = 1.0396 nm
8
Related compounds
Other anions
Dysprosium titanate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Dysprosium stannate (Dy 2 Sn 2 O 7) is an inorganic compound, a ceramic of the stannate family, with pyrochlore structure.

Dysprosium stannate, like dysprosium titanate and holmium stannate, is a spin ice material. In 2009, quasiparticles resembling magnetic monopoles were observed at low temperature and high magnetic field. [2] [3]

Related Research Articles

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Spin ice

A spin ice is a magnetic substance that does not have a single minimal-energy state. It has magnetic moments (i.e. "spin") as elementary degrees of freedom which are subject to frustrated interactions. By their nature, these interactions prevent the moments from exhibiting a periodic pattern in their orientation down to a temperature much below the energy scale set by the said interactions. Spin ices show low-temperature properties, residual entropy in particular, closely related to those of common crystalline water ice. The most prominent compounds with such properties are dysprosium titanate (Dy2Ti2O7) and holmium titanate (Ho2Ti2O7). The orientation of the magnetic moments in spin ice resembles the positional organization of hydrogen atoms (more accurately, ionized hydrogen, or protons) in conventional water ice (see figure 1).

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References

  1. 1 2 Mel'chenko G.G., Serebrennikov V.V. (1973) Russ. J. Inorg. Chem., 18 618–621
  2. "Magnetic Monopoles Detected In A Real Magnet For The First Time". Science Daily . 2009-09-04. Retrieved 2009-09-04.
  3. Morris, D. J. P.; Tennant, D. A.; Grigera, S. A.; Klemke, B.; Castelnovo, C.; Moessner, R.; Czternasty, C.; Meissner, M.; Rule, K. C.; Hoffmann, J.-U.; Kiefer, K.; Gerischer, S.; Slobinsky, D.; Perry, R. S. (2009-09-03). "Dirac Strings and Magnetic Monopoles in Spin Ice Dy2Ti2O7". Science . 326 (5951): 411–4. arXiv: 1011.1174 . Bibcode:2009Sci...326..411M. doi:10.1126/science.1178868. PMID   19729617. S2CID   206522398.