Dysprosium titanate

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Dysprosium titanate
Fragment of pyrochlore lattice in spin ice state.png
Names
IUPAC name
Dysprosium titanate
Identifiers
3D model (JSmol)
  • InChI=1S/2Dy.7O.2Ti/q2*+3;7*-2;2*+4
  • [Dy+3].[Dy+3].[Ti+4].[Ti+4].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2]
Properties
Dy2O7Ti2
Molar mass 532.727 g·mol−1
Density 6.8 g/cm3 [1]
Structure [1]
Pyrochlore
Fd3m, cF88, No. 227
a = 1.0136 nm
8
Related compounds
Other cations
Holmium titanate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Dysprosium titanate (Dy 2 Ti 2 O 7) is an inorganic compound, a ceramic of the titanate family, with pyrochlore structure.

Dysprosium titanate, like holmium titanate and holmium stannate, is a spin ice material. In 2009, quasiparticles resembling magnetic monopoles were observed at low temperature and high magnetic field. [2] [3]

Dysprosium titanate (Dy 2 Ti O 5) is used since 1995 as material for control rods of commercial nuclear reactor. [4]

Related Research Articles

<span class="mw-page-title-main">Dysprosium</span> Chemical element, symbol Dy and atomic number 66

Dysprosium is a chemical element; it has symbol Dy and atomic number 66. It is a rare-earth element in the lanthanide series with a metallic silver luster. Dysprosium is never found in nature as a free element, though, like other lanthanides, it is found in various minerals, such as xenotime. Naturally occurring dysprosium is composed of seven isotopes, the most abundant of which is 164Dy.

<span class="mw-page-title-main">Holmium</span> Chemical element, symbol Ho and atomic number 67

Holmium is a chemical element; it has symbol Ho and atomic number 67. It is a rare-earth element and the eleventh member of the lanthanide series. It is a relatively soft, silvery, fairly corrosion-resistant and malleable metal. Like many other lanthanides, holmium is too reactive to be found in native form, as pure holmium slowly forms a yellowish oxide coating when exposed to air. When isolated, holmium is relatively stable in dry air at room temperature. However, it reacts with water and corrodes readily, and also burns in air when heated.

<span class="mw-page-title-main">Pyrochlore</span> Niobium mineral of A2B2O7 general formula

Pyrochlore2Nb2O6(OH,F) is a mineral group of the niobium end member of the pyrochlore supergroup. Pyrochlore is also a term for the crystal structure Fd3m. The name is from the Greek πῦρ, fire, and χλωρός, green because it typically turns green on ignition in classic blowpipe analysis.

<span class="mw-page-title-main">Magnetic monopole</span> Hypothetical particle with one magnetic pole

In particle physics, a magnetic monopole is a hypothetical elementary particle that is an isolated magnet with only one magnetic pole. A magnetic monopole would have a net north or south "magnetic charge". Modern interest in the concept stems from particle theories, notably the grand unified and superstring theories, which predict their existence. The known elementary particles that have electric charge are electric monopoles.

<span class="mw-page-title-main">Control rod</span> Device used to regulate the power of a nuclear reactor

Control rods are used in nuclear reactors to control the rate of fission of the nuclear fuel – uranium or plutonium. Their compositions include chemical elements such as boron, cadmium, silver, hafnium, or indium, that are capable of absorbing many neutrons without themselves decaying. These elements have different neutron capture cross sections for neutrons of various energies. Boiling water reactors (BWR), pressurized water reactors (PWR), and heavy-water reactors (HWR) operate with thermal neutrons, while breeder reactors operate with fast neutrons. Each reactor design can use different control rod materials based on the energy spectrum of its neutrons. Control rods have been used in nuclear aircraft engines like Project Pluto as a method of control.

In condensed matter physics, the term geometrical frustration refers to a phenomenon where atoms tend to stick to non-trivial positions or where, on a regular crystal lattice, conflicting inter-atomic forces lead to quite complex structures. As a consequence of the frustration in the geometry or in the forces, a plenitude of distinct ground states may result at zero temperature, and usual thermal ordering may be suppressed at higher temperatures. Much studied examples are amorphous materials, glasses, or dilute magnets.

Magnetic semiconductors are semiconductor materials that exhibit both ferromagnetism and useful semiconductor properties. If implemented in devices, these materials could provide a new type of control of conduction. Whereas traditional electronics are based on control of charge carriers, practical magnetic semiconductors would also allow control of quantum spin state. This would theoretically provide near-total spin polarization, which is an important property for spintronics applications, e.g. spin transistors.

Naturally occurring dysprosium (66Dy) is composed of 7 stable isotopes, 156Dy, 158Dy, 160Dy, 161Dy, 162Dy, 163Dy and 164Dy, with 164Dy being the most abundant. Twenty-nine radioisotopes have been characterized, with the most stable being 154Dy with a half-life of 1.4 million years, 159Dy with a half-life of 144.4 days, and 166Dy with a half-life of 81.6 hours. All of the remaining radioactive isotopes have half-lives that are less than 10 hours, and the majority of these have half-lives that are less than 30 seconds. This element also has 12 meta states, with the most stable being 165mDy, 147mDy and 145mDy.

Montonen–Olive duality or electric–magnetic duality is the oldest known example of strong–weak duality or S-duality according to current terminology. It generalizes the electro-magnetic symmetry of Maxwell's equations by stating that magnetic monopoles, which are usually viewed as emergent quasiparticles that are "composite", can in fact be viewed as "elementary" quantized particles with electrons playing the reverse role of "composite" topological solitons; the viewpoints are equivalent and the situation dependent on the duality. It was later proven to hold true when dealing with a N = 4 supersymmetric Yang–Mills theory. It is named after Finnish physicist Claus Montonen and British physicist David Olive after they proposed the idea in their academic paper Magnetic monopoles as gauge particles? where they state:

There should be two "dual equivalent" field formulations of the same theory in which electric (Noether) and magnetic (topological) quantum numbers exchange roles.

<span class="mw-page-title-main">Spin ice</span>

A spin ice is a magnetic substance that does not have a single minimal-energy state. It has magnetic moments (i.e. "spin") as elementary degrees of freedom which are subject to frustrated interactions. By their nature, these interactions prevent the moments from exhibiting a periodic pattern in their orientation down to a temperature much below the energy scale set by the said interactions. Spin ices show low-temperature properties, residual entropy in particular, closely related to those of common crystalline water ice. The most prominent compounds with such properties are dysprosium titanate (Dy2Ti2O7) and holmium titanate (Ho2Ti2O7). The orientation of the magnetic moments in spin ice resembles the positional organization of hydrogen atoms (more accurately, ionized hydrogen, or protons) in conventional water ice (see figure 1).

<span class="mw-page-title-main">Helimagnetism</span>

Helimagnetism is a form of magnetic ordering where spins of neighbouring magnetic moments arrange themselves in a spiral or helical pattern, with a characteristic turn angle of somewhere between 0 and 180 degrees. It results from the competition between ferromagnetic and antiferromagnetic exchange interactions. It is possible to view ferromagnetism and antiferromagnetism as helimagnetic structures with characteristic turn angles of 0 and 180 degrees respectively. Helimagnetic order breaks spatial inversion symmetry, as it can be either left-handed or right-handed in nature.

Gallium manganese arsenide, chemical formula (Ga,Mn)As is a magnetic semiconductor. It is based on the world's second most commonly used semiconductor, gallium arsenide,, and readily compatible with existing semiconductor technologies. Differently from other dilute magnetic semiconductors, such as the majority of those based on II-VI semiconductors, it is not paramagnetic but ferromagnetic, and hence exhibits hysteretic magnetization behavior. This memory effect is of importance for the creation of persistent devices. In (Ga,Mn)As, the manganese atoms provide a magnetic moment, and each also acts as an acceptor, making it a p-type material. The presence of carriers allows the material to be used for spin-polarized currents. In contrast, many other ferromagnetic magnetic semiconductors are strongly insulating and so do not possess free carriers. (Ga,Mn)As is therefore a candidate as a spintronic material.

<span class="mw-page-title-main">Magnetic structure</span>

The term magnetic structure of a material pertains to the ordered arrangement of magnetic spins, typically within an ordered crystallographic lattice. Its study is a branch of solid-state physics.

<span class="mw-page-title-main">Lithium titanate</span> Chemical compound

Lithium titanates are chemical compounds of lithium, titanium and oxygen. They are mixed oxides and belong to the titanates. The most important lithium titanates are:

In magnetism, a nanomagnet is a nanoscopic scale system that presents spontaneous magnetic order (magnetization) at zero applied magnetic field (remanence).

In quantum mechanics, fractionalization is the phenomenon whereby the quasiparticles of a system cannot be constructed as combinations of its elementary constituents. One of the earliest and most prominent examples is the fractional quantum Hall effect, where the constituent particles are electrons but the quasiparticles carry fractions of the electron charge. Fractionalization can be understood as deconfinement of quasiparticles that together are viewed as comprising the elementary constituents. In the case of spin–charge separation, for example, the electron can be viewed as a bound state of a 'spinon' and a 'chargon', which under certain conditions can become free to move separately.

<span class="mw-page-title-main">Steven T. Bramwell</span> British scientist

Steven T. Bramwell is a British physicist and chemist who works at the London Centre for Nanotechnology and the Department of Physics and Astronomy, University College London. He is known for his experimental discovery of spin ice with M. J. Harris and his calculation of a critical exponent observed in two-dimensional magnets with P. C. W. Holdsworth. A probability distribution for global quantities in complex systems, the "Bramwell-Holdsworth-Pinton (BHP) distribution", is named after him.

Roderich Moessner is a theoretical physicist at the Max Planck Institute for the Physics of Complex Systems in Dresden, Germany. His research interests are in condensed matter and materials physics, especially concerning new and topological forms of order, as well as the study of classical and quantum many-body dynamics in and out of equilibrium.

<span class="mw-page-title-main">Holmium titanate</span> Chemical compound

Holmium titanate is an inorganic compound with the chemical formula Ho2Ti2O7.

<span class="mw-page-title-main">Dysprosium stannate</span> Chemical compound

Dysprosium stannate (Dy2Sn2O7) is an inorganic compound, a ceramic of the stannate family, with pyrochlore structure.

References

  1. 1 2 Dolgikh V.A., Lavat E.A. (1991). "Preparation of new oxide nitrides with the pyrochlore structure". Russ. J. Inorg. Chem. 36: 1389–1392.
  2. "Magnetic Monopoles Detected In A Real Magnet For The First Time". Science Daily . 2009-09-04. Retrieved 2009-09-04.
  3. Morris, D. J. P.; Tennant, D. A.; Grigera, S. A.; Klemke, B.; Castelnovo, C.; Moessner, R.; Czternasty, C.; Meissner, M.; Rule, K. C.; Hoffmann, J.-U.; Kiefer, K.; Gerischer, S.; Slobinsky, D.; Perry, R. S. (2009-09-03). "Dirac Strings and Magnetic Monopoles in Spin Ice Dy2Ti2O7". Science . 326 (5951): 411–4. arXiv: 1011.1174 . Bibcode:2009Sci...326..411M. doi:10.1126/science.1178868. PMID   19729617. S2CID   206522398.
  4. Risovany, V.D.; Varlashova, E.E.; Suslov, D.N. (2000). "Dysprosium titanate as an absorber material for control rods". Journal of Nuclear Materials. 281 (1): 84–89. Bibcode:2000JNuM..281...84R. doi:10.1016/S0022-3115(00)00129-X.