It has been suggested that this article should be split into articles titled lithium titanate , lithium titanate spinel and lithium metatitanate . (discuss) (May 2022) |
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Names | |
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Other names Lithium metatitanate | |
Identifiers | |
3D model (JSmol) | |
ECHA InfoCard | 100.031.586 |
PubChem CID | |
CompTox Dashboard (EPA) | |
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Properties | |
Li2TiO3 | |
Molar mass | 109.76 |
Appearance | White powder [1] |
Density | 3.43 g/cm3 [2] |
Melting point | 1,533 °C (2,791 °F; 1,806 K) [1] |
Structure [3] | |
Monoclinic, mS48, No. 15 | |
C2/c | |
a = 0.505 nm, b = 0.876 nm, c = 0.968 nm α = 90°°, β = 100°°, γ = 90°° | |
Lattice volume (V) | 0.4217 nm3 |
Formula units (Z) | 8 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Lithium titanates are chemical compounds of lithium, titanium and oxygen. They are mixed oxides and belong to the titanates. The most important lithium titanates are:
Other lithium titanates, i.e. mixed oxides of the system Li2O–TiO2, are:
Lithium metatitanate is a compound with the chemical formula Li2TiO3. It is a white powder with a melting point of 1,533 °C (2,791 °F). [4] It is also used as an additive in porcelain enamels and ceramic insulating bodies based on titanates. It is frequently utilized as a flux due to its good stability. [6] In recent years, along with other lithium ceramics, metatitanate pebbles have been the subject of research efforts towards tritium breeding materials in nuclear fusion applications. [7]
The most stable lithium titanate phase is β-Li2TiO3 that belongs to the monoclinic system. [8] A high-temperature cubic phase exhibiting solid-solution type behavior is referred to as γ-Li2TiO3 and is known to form reversibly above temperatures in the range 1150-1250 °C. [9] A metastable cubic phase, isostructural with γ-Li2TiO3 is referred to as α-Li2TiO3; it is formed at low temperatures, and transforms to the more stable β-phase upon heating to 400 °C. [10]
The sintering process is taking a powder, putting it into a mold and heating it to below its melting point. Sintering is based on atomic diffusion, the atoms in the powder particle diffuse into surrounding particles eventually forming a solid or porous material.
It has been discovered that Li2TiO3 powders have a high purity and good sintering ability. [11]
Lithium titanate is used as a cathode in layer one of a double layer cathode for molten carbonate fuel cells. These fuel cells have two material layers, layer 1 and layer 2, which allow for the production of high power molten carbonate fuel cells that work more efficiently. [12]
Li2TiO3 is used in the cathode of some lithium-ion batteries, along with an aqueous binder and a conducting agent. Li2TiO3 is used because it is capable of stabilizing the high capacity cathode conducting agents; LiMO2 (M=Fe, Mn, Cr, Ni). Li2TiO3 and the conduction agents (LiMO2) are layered in order to create the cathode material. These layers allow for the occurrence of lithium diffusion.
The lithium-titanate battery is a rechargeable battery that is much faster to charge than other lithium-ion batteries. It differs from other lithium-ion batteries because it uses lithium-titanate on the anode surface rather than carbon. This is advantageous because it does not create a solid electrolyte interface layer, which acts as a barrier to the ingress and egress of Li-ion to and from the anode. This allows lithium-titanate batteries to be recharged more quickly and provide higher currents when necessary. A disadvantage of the lithium-titanate battery is a much lower capacity and voltage than the conventional lithium-ion battery. The lithium-titanate battery is currently being used in battery electric vehicles[ citation needed ] and other specialist applications.
Fusion reactions, such as those in the proposed ITER thermonuclear demonstrator reactor, are fueled by tritium and deuterium. Tritium resources are extremely limited in their availability, with total resources currently estimated at twenty kilograms. Lithium-containing ceramic pebbles can be used as solid breeder materials in a component known as a helium-cooled breeder blanket for the production of tritium. [13] The breeding blanket constitutes a key component of the ITER reactor design. In such reactor designs tritium is produced by neutrons leaving the plasma and interacting with lithium in the blanket. Li2TiO3 along with Li4SiO4 are attractive as tritium breeding materials because they exhibit high tritium release, low activation, and chemical stability. [7]
Li2TiO3 powder is most commonly prepared by the mixing of lithium carbonate, Ti-nitrate solution, and citric acid followed by calcination, compaction, and sintering. The nanocrystalline material created is used as a breeder powder due to its high purity and activity. [14] [12] [15]
An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit. Electrodes are essential parts of batteries that can consist of a variety of materials depending on the type of battery.
Tritium or hydrogen-3 is a rare and radioactive isotope of hydrogen with half-life ~12.3 years. The nucleus of tritium contains one proton and two neutrons, whereas the nucleus of the common isotope hydrogen-1 (protium) contains one proton and zero neutrons, and that of a non-radioactive hydrogen-2 (deuterium) contains one proton and one neutron.
In chemistry, titanate usually refers to inorganic compounds composed of titanium oxides, or oxides containing the titanium element. Together with niobate, titanate salts form the Perovskite group.
Strontium titanate is an oxide of strontium and titanium with the chemical formula SrTiO3. At room temperature, it is a centrosymmetric paraelectric material with a perovskite structure. At low temperatures it approaches a ferroelectric phase transition with a very large dielectric constant ~104 but remains paraelectric down to the lowest temperatures measured as a result of quantum fluctuations, making it a quantum paraelectric. It was long thought to be a wholly artificial material, until 1982 when its natural counterpart—discovered in Siberia and named tausonite—was recognised by the IMA. Tausonite remains an extremely rare mineral in nature, occurring as very tiny crystals. Its most important application has been in its synthesized form wherein it is occasionally encountered as a diamond simulant, in precision optics, in varistors, and in advanced ceramics.
John Bannister Goodenough was an American materials scientist, a solid-state physicist, and a Nobel laureate in chemistry. From 1986 he was a professor of Materials Science, Electrical Engineering and Mechanical Engineering, at the University of Texas at Austin. He is credited with identifying the Goodenough–Kanamori rules of the sign of the magnetic superexchange in materials, with developing materials for computer random-access memory and with inventing cathode materials for lithium-ion batteries.
Barium titanate (BTO) is an inorganic compound with chemical formula BaTiO3. Barium titanate appears white as a powder and is transparent when prepared as large crystals. It is a ferroelectric, pyroelectric, and piezoelectric ceramic material that exhibits the photorefractive effect. It is used in capacitors, electromechanical transducers and nonlinear optics.
Lithium cobalt oxide, sometimes called lithium cobaltate or lithium cobaltite, is a chemical compound with formula LiCoO
2. The cobalt atoms are formally in the +3 oxidation state, hence the IUPAC name lithium cobalt(III) oxide.
The lithium–air battery (Li–air) is a metal–air electrochemical cell or battery chemistry that uses oxidation of lithium at the anode and reduction of oxygen at the cathode to induce a current flow.
Sodium-ion batteries (NIBs, SIBs, or Na-ion batteries) are several types of rechargeable batteries, which use sodium ions (Na+) as its charge carriers. In some cases, its working principle and cell construction are similar to those of lithium-ion battery (LIB) types, but it replaces lithium with sodium as the intercalating ion. Sodium belongs to the same group in the periodic table as lithium and thus has similar chemical properties. However, in some cases, such as aqueous batteries, SIBs can be quite different from LIBs.
Titanium disulfide is an inorganic compound with the formula TiS2. A golden yellow solid with high electrical conductivity, it belongs to a group of compounds called transition metal dichalcogenides, which consist of the stoichiometry ME2. TiS2 has been employed as a cathode material in rechargeable batteries.
A lithium ion manganese oxide battery (LMO) is a lithium-ion cell that uses manganese dioxide, MnO
2, as the cathode material. They function through the same intercalation/de-intercalation mechanism as other commercialized secondary battery technologies, such as LiCoO
2. Cathodes based on manganese-oxide components are earth-abundant, inexpensive, non-toxic, and provide better thermal stability.
Abnormal or discontinuous grain growth, also referred to as exaggerated or secondary recrystallisation grain growth, is a grain growth phenomenon in which certain energetically favorable grains (crystallites) grow rapidly in a matrix of finer grains, resulting in a bimodal grain-size distribution.
Research in lithium-ion batteries has produced many proposed refinements of lithium-ion batteries. Areas of research interest have focused on improving energy density, safety, rate capability, cycle durability, flexibility, and cost.
Magnesium batteries are batteries that utilize magnesium cations as charge carriers and possibly in the anode in electrochemical cells. Both non-rechargeable primary cell and rechargeable secondary cell chemistries have been investigated. Magnesium primary cell batteries have been commercialised and have found use as reserve and general use batteries.
Mixed conductors, also known as mixed ion-electron conductors(MIEC), are a single-phase material that has significant conduction ionically and electronically. Due to the mixed conduction, a formally neutral species can transport in a solid and therefore mass storage and redistribution are enabled. Mixed conductors are well known in conjugation with high-temperature superconductivity and are able to capacitate rapid solid-state reactions.
Lithium iridate, Li2IrO3, is a chemical compound of lithium, iridium and oxygen. It forms black crystals with three slightly different layered atomic structures, α, β, and sometimes γ. Lithium iridate exhibits metal-like, temperature-independent electrical conductivity, and changes its magnetic ordering from paramagnetic to antiferromagnetic upon cooling to 15 K.
The tritium breeding blanket, is a key part of many proposed fusion reactor designs. It serves several purposes; primarily it is to produce further tritium fuel for the nuclear fusion reaction, which owing to the scarcity of tritium would not be available in sufficient quantities, through the reaction of neutrons with lithium in the blanket. The blanket may also act as a cooling mechanism, absorbing the energy from the neutrons produced by the reaction between deuterium and tritium ("D-T"), and further serves as shielding, preventing the high-energy neutrons from escaping to the area outside the reactor and protecting the more radiation-susceptible portions, such as ohmic or superconducting magnets, from damage.
Anthony Roy West FRSE, FRSC, FInstP, FIMMM is a British chemist and materials scientist, and Professor of Electroceramics and Solid State Chemistry at the Department of Materials Science and Engineering at the University of Sheffield.
Lithium orthosilicate is a compound with the chemical formula Li4SiO4. It is a white ceramic compound, which melts congruently at a temperature of 1,258 °C (2,296 °F).
Lithium aluminium germanium phosphate, typically known with the acronyms LAGP or LAGPO, is an inorganic ceramic solid material whose general formula is Li
1+xAl
xGe
2-x(PO
4)
3. LAGP belongs to the NASICON family of solid conductors and has been applied as a solid electrolyte in all-solid-state lithium-ion batteries. Typical values of ionic conductivity in LAGP at room temperature are in the range of 10–5 - 10–4 S/cm, even if the actual value of conductivity is strongly affected by stoichiometry, microstructure, and synthesis conditions. Compared to lithium aluminium titanium phosphate (LATP), which is another phosphate-based lithium solid conductor, the absence of titanium in LAGP improves its stability towards lithium metal. In addition, phosphate-based solid electrolytes have superior stability against moisture and oxygen compared to sulfide-based electrolytes like Li
10GeP
2S
12 (LGPS) and can be handled safely in air, thus simplifying the manufacture process. Since the best performances are encountered when the stoichiometric value of x is 0.5, the acronym LAGP usually indicates the particular composition of Li
1.5Al
0.5Ge
1.5(PO
4)
3, which is also the typically used material in battery applications.