Lithium arsenide

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Lithium arsenide
Names
Other names
Litium monoarsenide
Identifiers
PubChem CID
  • InChI=1S/As.Li
    Key: FKQOMXQAEKRXDM-UHFFFAOYSA-N
Properties
AsLi3
Molar mass 95.74 g·mol−1
Appearancered-brown
Density 3.71 g/cm3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Lithium arsenide describes inorganic compounds with the chemical formula LixAs where x can range from about 0.5 to 3. A common derivative is Li3As, which is prepared by the reduction of arsenic with a solution of lithium in ammonia. [1] It can also be produced by heating the elements. [2]

3 Li + As → Li3As

Other lithium arsenides

The arsenic-rich arsenides are often classified as zintl phases.

10.1107/S0365110X59000111[ clarification needed ]

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References

  1. E. Donges (1963). "Phosphides, Arsenides, Antimonides and Bismuthides of Alkali Metals from the Elements". In G. Brauer (ed.). Handbook of Preparative Inorganic Chemistry, 2nd Ed. Vol. 2. NY, NY: Academic Press. p. 985.
  2. Wegner, Florian; Kamm, Franziska; Pielnhofer, Florian; Pfitzner, Arno (2022). "Li3As and Li3P revisited: DFT modelling on phase stability and ion conductivity". Zeitschrift für Anorganische und Allgemeine Chemie. 648 (11). doi:10.1002/zaac.202100358.
  3. 1 2 Donnay, Joseph Désiré Hubert (1963). Crystal Data; Determinative Tables. American Crystallographic Association. p. 211. Retrieved 13 January 2022.
  4. 1 2 Hönle, W.; Buresch, J.; Peters, K.; Chang, J. H.; Schnering, H. G. von (2002). "Crystal Structure of the Low-Temperature Modification of Trilithium Heptaarsenide, LT-Li3As7". Zeitschrift für Kristallographie - New Crystal Structures. 217: 485–486. doi: 10.1524/ncrs.2002.217.jg.485 .
  5. None Available (2014). "Materials Data on Li3As7 by Materials Project". LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). doi:10.17188/1283621. OSTI   1283621.
  6. Cromer, D. T. (1 January 1959). "The crystal structure of LiAs". Acta Crystallographica . 12 (1): 36–41. Bibcode:1959AcCry..12...36C. doi: 10.1107/S0365110X59000111 . Retrieved 13 January 2022.