Amblygonite | |
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General | |
Category | Phosphate minerals |
Formula (repeating unit) | (Li,Na)AlPO4(F,OH) |
IMA symbol | Aby [1] |
Strunz classification | 8.BB.05 |
Crystal system | Triclinic |
Crystal class | Pinacoidal (1) (same H-M symbol) |
Space group | C1 |
Identification | |
Color | Generally white or creamy, but can also be colorless or pale yellow, green, blue, beige, gray, brown or pink. |
Crystal habit | Prismatic to columnar form |
Twinning | Microscopic polysynthetic twinning common |
Cleavage | [100] Perfect, [110] good, [011] distinct |
Fracture | Irregular/ineven, sub-Conchoidal |
Mohs scale hardness | 5.5–6 [2] |
Luster | Vitreous to pearly [2] |
Specific gravity | 2.98–3.11 |
Polish luster | greasy to vitreous (in gem material) [2] |
Optical properties | Double refractive, biaxial, may be either positive or negative [2] |
Refractive index | na=1.577 – 1.591, nb=1.592 – 1.605, nc=1.596 – 1.613 |
Birefringence | .020 – .027 [2] |
Pleochroism | weak to none [2] |
Ultraviolet fluorescence | very weak green in long wave, light blue phosphorescence in long wave and short wave [2] |
Amblygonite ( /æmˈblɪɡəˌnaɪt/ ) is a fluorophosphate mineral, (Li,Na)AlPO4(F,OH), composed of lithium, sodium, aluminium, phosphate, fluoride and hydroxide. The mineral occurs in pegmatite deposits and is easily mistaken for albite and other feldspars. Its density, cleavage and flame test for lithium are diagnostic. Amblygonite forms a series with montebrasite, the low fluorine endmember. Geologic occurrence is in granite pegmatites, high-temperature tin veins, and greisens. Amblygonite occurs with spodumene, apatite, lepidolite, tourmaline, and other lithium-bearing minerals in pegmatite veins. It contains about 10% lithium, and has been utilized as a source of lithium. The chief commercial sources have historically been the deposits of California and France.
The mineral was first discovered in Saxony by August Breithaupt in 1817, and named by him from the Greek amblus, blunt, and gonia, angle, because of the obtuse angle between the cleavages. Later it was found at Montebras, Creuse, France, and at Hebron in Maine; and because of slight differences in optical character and chemical composition the names montebrasite and hebronite have been applied to the mineral from these localities.The term amblygonite has been used interchangeably in mining, whether this mineral or montebrasite was extracted. In fact, montebrasite is much more common than amblygonite, which is a rare mineral. [3] It has been discovered in considerable quantity at Pala in San Diego county, California; Caceres, Spain; and the Black Hills of South Dakota. A blue form of amblygonite-montebrasite has been described from Rwanda. The largest documented single crystal of amblygonite measured 7.62 × 2.44 × 1.83 m and weighed about 102 tons. [4]
Transparent amblygonite has been faceted and used as a gemstone. As a gemstone set into jewelry it is vulnerable to breakage and abrasion from general wear, as its hardness and toughness are poor. [2] The main sources for gem material are Brazil and the United States. Australia, France, Germany, Namibia, and Norway, and Spain have also produced gem quality amblygonite. [2]
Beryl ( BERR-əl) is a mineral composed of beryllium aluminium silicate with the chemical formula Be3Al2Si6O18. Well-known varieties of beryl include emerald and aquamarine. Naturally occurring hexagonal crystals of beryl can be up to several meters in size, but terminated crystals are relatively rare. Pure beryl is colorless, but it is frequently tinted by impurities; possible colors are green, blue, yellow, pink, and red (the rarest). It is an ore source of beryllium.
Topaz is a silicate mineral made of aluminum and fluorine with the chemical formula Al2SiO4(F, OH)2. It is used as a gemstone in jewelry and other adornments. Common topaz in its natural state is colorless, though trace element impurities can make it pale blue or golden brown to yellow-orange. Topaz is often treated with heat or radiation to make it a deep blue, reddish-orange, pale green, pink, or purple.
Tourmaline is a crystalline silicate mineral group in which boron is compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. This gemstone comes in a wide variety of colors.
A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than 1 cm (0.4 in) and sometimes greater than 1 meter (3 ft). Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic composition to granite. However, rarer intermediate composition and mafic pegmatites are known.
Lepidolite is a lilac-gray or rose-colored member of the mica group of minerals with chemical formula K(Li,Al)3(Al,Si,Rb)4O10(F,OH)2. It is the most abundant lithium-bearing mineral and is a secondary source of this metal. It is the major source of the alkali metal rubidium.
Spodumene is a pyroxene mineral consisting of lithium aluminium inosilicate, LiAl(SiO3)2, and is a commercially important source of lithium. It occurs as colorless to yellowish, purplish, or lilac kunzite (see below), yellowish-green or emerald-green hiddenite, prismatic crystals, often of great size. Single crystals of 14.3 m (47 ft) in size are reported from the Black Hills of South Dakota, United States.
Petalite, also known as castorite, is a lithium aluminum tektosilicate mineral LiAlSi4O10, crystallizing in the monoclinic system. Petalite occurs as colorless, pink, grey, yellow, yellow grey, to white tabular crystals and columnar masses. It occurs in lithium-bearing pegmatites with spodumene, lepidolite, and tourmaline. Petalite is an important ore of lithium, and is converted to spodumene and quartz by heating to ~500 °C and under 3 kbar of pressure in the presence of a dense hydrous alkali borosilicate fluid with a minor carbonate component. Petalite (and secondary spodumene formed from it) is lower in iron than primary spodumene, making it a more useful source of lithium in, e.g., the production of glass. The colorless varieties are often used as gemstones.
Cassiterite is a tin oxide mineral, SnO2. It is generally opaque, but it is translucent in thin crystals. Its luster and multiple crystal faces produce a desirable gem. Cassiterite was the chief tin ore throughout ancient history and remains the most important source of tin today.
Vivianite (Fe(II)
3(PO
4)
2·8H
2O) is a hydrated iron(II) phosphate mineral found in a number of geological environments. Small amounts of manganese Mn2+, magnesium Mg2+, and calcium Ca2+ may substitute for iron Fe2+ in its structure. Pure vivianite is colorless, but the mineral oxidizes very easily, changing the color, and it is usually found as deep blue to deep bluish green prismatic to flattened crystals. Vivianite crystals are often found inside fossil shells, such as those of bivalves and gastropods, or attached to fossil bone. Vivianite can also appear on the iron coffins or on the corpses of humans as a result of a chemical reaction of the decomposing body with the iron enclosure.
Jadeite is a pyroxene mineral with composition NaAlSi2O6. It is hard (Mohs hardness of about 6.5 to 7.0), very tough, and dense, with a specific gravity of about 3.4. It is found in a wide range of colors, but is most often found in shades of green or white. Jadeite is formed only in the subduction zones of continental margins, where rock undergoes metamorphism at high pressure but relatively low temperature.
Wardite is a hydrous sodium aluminium phosphate hydroxide mineral with formula: NaAl3(PO4)2(OH)4·2(H2O). Wardite is of interest for its rare crystallography. It crystallizes in the tetragonal trapezohedral class and is one of only a few minerals in that class. Wardite forms vitreous green to bluish green to white to colorless crystals, with pyramidal {102} or {114} faces and with {001} usually present masses. Also appera as fibrous encrustations. It has a Mohs hardness of 5 and a specific gravity of 2.81–2.87.
Brazilianite, whose name derives from its country of origin, Brazil, is a typically yellow-green phosphate mineral, most commonly found in phosphate-rich pegmatites.
Cordierite (mineralogy) or iolite (gemology) is a magnesium iron aluminium cyclosilicate. Iron is almost always present, and a solid solution exists between Mg-rich cordierite and Fe-rich sekaninaite with a series formula: (Mg,Fe)2Al3(Si5AlO18) to (Fe,Mg)2Al3(Si5AlO18). A high-temperature polymorph exists, indialite, which is isostructural with beryl and has a random distribution of Al in the (Si,Al)6O18 rings. Cordierite is also synthesized and used in high temperature applications such as catalytic converters and pizza stones.
Phenakite or phenacite is a fairly rare nesosilicate mineral consisting of beryllium orthosilicate, Be2SiO4. Occasionally used as a gemstone, phenakite occurs as isolated crystals, which are rhombohedral with parallel-faced hemihedrism, and are either lenticular or prismatic in habit: the lenticular habit is determined by the development of faces of several obtuse rhombohedra and the absence of prism faces. There is no cleavage, and the fracture is conchoidal. The Mohs hardness is high, being 7.5–8; the specific gravity is 2.96. The crystals are sometimes perfectly colorless and transparent, but more often they are greyish or yellowish and only translucent; occasionally they are pale rose-red. In general appearance the mineral is not unlike quartz, for which indeed it has been mistaken. Its name comes from Ancient Greek: φέναξ, romanized: phénax, meaning "deceiver" due to its close visual similarity to quartz, named by Nils Gustaf Nordenskiöld in 1833.
Spessartine is a nesosilicate, manganese aluminium garnet species, Mn2+3Al2(SiO4)3. This mineral is sometimes mistakenly referred to as spessartite.
Grossular is a calcium-aluminium species of the garnet group of minerals. It has the chemical formula of Ca3Al2(SiO4)3 but the calcium may, in part, be replaced by ferrous iron and the aluminium by ferric iron. The name grossular is derived from the botanical name for the gooseberry, grossularia, in reference to the green garnet of this composition that is found in Siberia. Other shades include cinnamon brown (cinnamon stone variety), red, and yellow. Grossular is a gemstone.
Andradite is a mineral species of the garnet group. It is a nesosilicate, with formula Ca3Fe2Si3O12.
Lithiophilite is a mineral containing the element lithium. It is lithium manganese(II) phosphate with chemical formula LiMnPO4. It occurs in pegmatites often associated with triphylite, the iron end member in a solid solution series. The mineral with intermediate composition is known as sicklerite and has the chemical formula Li(Mn,Fe)PO4). The name lithiophilite is derived from the Greek philos (φιλός) "friend", as lithiophilite is usually found with lithium.
Eucryptite is a lithium bearing aluminium silicate mineral with formula LiAlSiO4. It crystallizes in the trigonal – rhombohedral crystal system. It typically occurs as granular to massive in form and may pseudomorphically replace spodumene. It has a brittle to conchoidal fracture and indistinct cleavage. It is transparent to translucent and varies from colorless to white to brown. It has a Mohs hardness of 6.5 and a specific gravity of 2.67. Optically it is uniaxial positive with refractive index values of nω = 1.570 – 1.573 and nε = 1.583 – 1.587.
Neptunite is a silicate mineral with the formula KNa2Li(Fe2+, Mn2+)2Ti2Si8O24. With increasing manganese it forms a series with mangan-neptunite. Watatsumiite is the variety with vanadium replacing the titanium in the formula.