Zabuyelite | |
---|---|
General | |
Category | Carbonate mineral |
Formula (repeating unit) | Li2CO3 |
IMA symbol | Zab [1] |
Strunz classification | 5.AA.05 |
Crystal system | Monoclinic |
Crystal class | Prismatic (2/m) (same H-M symbol) |
Space group | C2/c |
Identification | |
Formula mass | 73.89 g/mol |
Color | Colorless |
Cleavage | {100} perfect; {011} good |
Tenacity | Brittle |
Mohs scale hardness | 3 |
Streak | White |
Specific gravity | 2.09 |
Optical properties | Biaxial (–) |
Refractive index | nα = 1.4285, nβ = 1.5672, nγ = 1.5743 |
Birefringence | δ = 0.1458 |
Pleochroism | none |
2V angle | 25° |
References | [2] [3] [4] |
Zabuyelite is the natural mineral form of lithium carbonate, with a formula Li 2 C O 3. It was discovered in 1987 at Lake Zabuye, Tibet, after which it is named. It forms colorless vitreous monoclinic crystals.
It occurs as inclusions within halite in lithium rich evaporites and as solid phase in fluid inclusions in the mineral spodumene. Associated minerals include halite, gaylussite and northupite in the Tibet locality. [4]
In addition to the Tibetan salt lake it has been reported from Bikita and Kamativi in Zimbabwe, from Kings Mountain, Cleveland County, North Carolina, US and the Tanco pegmatite, Bernic Lake, Manitoba, Canada. [4]
Celestine (the IMA-accepted name) or celestite is a mineral consisting of strontium sulfate (SrSO4). The mineral is named for its occasional delicate blue color. Celestine and the carbonate mineral strontianite are the principal sources of the element strontium, commonly used in fireworks and in various metal alloys.
Lepidolite is a lilac-gray or rose-colored member of the mica group of minerals with chemical formula K(Li,Al)3(Al,Si,Rb)4O10(F,OH)2. It is the most abundant lithium-bearing mineral and is a secondary source of this metal. It is the major source of the alkali metal rubidium.
Petalite, also known as castorite, is a lithium aluminum phyllosilicate mineral LiAlSi4O10, crystallizing in the monoclinic system. Petalite occurs as colorless, pink, grey, yellow, yellow grey, to white tabular crystals and columnar masses. It occurs in lithium-bearing pegmatites with spodumene, lepidolite, and tourmaline. Petalite is an important ore of lithium, and is converted to spodumene and quartz by heating to ~500 °C and under 3 kbar of pressure in the presence of a dense hydrous alkali borosilicate fluid with a minor carbonate component. Petalite (and secondary spodumene formed from it) is lower in iron than primary spodumene, making it a more useful source of lithium in, e.g., the production of glass. The colorless varieties are often used as gemstones.
Halite, commonly known as rock salt, is a type of salt, the mineral (natural) form of sodium chloride (NaCl). Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, pink, red, orange, yellow or gray depending on inclusion of other materials, impurities, and structural or isotopic abnormalities in the crystals. It commonly occurs with other evaporite deposit minerals such as several of the sulfates, halides, and borates. The name halite is derived from the Ancient Greek word for "salt", ἅλς (háls).
Sylvite, or sylvine, is potassium chloride (KCl) in natural mineral form. It forms crystals in the isometric system very similar to normal rock salt, halite (NaCl). The two are, in fact, isomorphous. Sylvite is colorless to white with shades of yellow and red due to inclusions. It has a Mohs hardness of 2.5 and a specific gravity of 1.99. It has a refractive index of 1.4903. Sylvite has a salty taste with a distinct bitterness.
Thermonatrite is a naturally occurring evaporite mineral form of sodium carbonate, Na2CO3·H2O.
Elbaite, a sodium, lithium, aluminium boro-silicate, with the chemical composition Na(Li1.5Al1.5)Al6Si6O18(BO3)3(OH)4, is a mineral species belonging to the six-member ring cyclosilicate tourmaline group.
Lithiophilite is a mineral containing the element lithium. It is lithium manganese(II) phosphate with chemical formula LiMnPO4. It occurs in pegmatites often associated with triphylite, the iron end member in a solid solution series. The mineral with intermediate composition is known as sicklerite and has the chemical formula Li(Mn,Fe)PO4). The name lithiophilite is derived from the Greek philos (φιλός) "friend," as lithiophilite is usually found with lithium.
Triphylite is a lithium iron(II) phosphate mineral with the chemical formula LiFePO4. It is a member of the triphylite group and forms a complete solid solution series with the lithium manganese(II) phosphate, lithiophilite. Triphylite crystallizes in the orthorhombic crystal system. It rarely forms prismatic crystals and is more frequently found in hypidiomorphic rock. It is bluish- to greenish-gray in color, but upon alteration becomes brown to black.
Polyhalite is an evaporite mineral, a hydrated sulfate of potassium, calcium and magnesium with formula: K2Ca2Mg(SO4)4·2H2O. Polyhalite crystallizes in the triclinic system, although crystals are very rare. The normal habit is massive to fibrous. It is typically colorless, white to gray, although it may be brick red due to iron oxide inclusions. It has a Mohs hardness of 3.5 and a specific gravity of 2.8. It is used as a fertilizer.
Hanksite is a sulfate mineral, distinguished as one of only a handful that contain both carbonate and sulfate ion groups. It has the chemical formula Na22K(SO4)9(CO3)2Cl.
Portlandite is a hydroxide-bearing mineral typically included in the oxide mineral class. It is the naturally occurring form of calcium hydroxide (Ca(OH)2) and the calcium analogue of brucite (Mg(OH)2).
Hectorite is a rare soft, greasy, white clay mineral with a chemical formula of Na0.3(Mg,Li)3Si4O10(OH)2.
Nahcolite is a soft, colourless or white carbonate mineral with the composition of sodium bicarbonate (NaHCO3) also called thermokalite. It crystallizes in the monoclinic system.
Antarcticite is an uncommon calcium chloride hexahydrate mineral with formula CaCl2·6H2O. It forms colorless acicular trigonal crystals. It is hygroscopic and has a low specific gravity of 1.715.
Zabuye Lake is a hypersaline, landlocked soda lake located at an elevation of 4,400 metres (14,400 ft) in the Shigatse Prefecture of Tibet Autonomous Region, 1,050 km (650 mi) from Lhasa. The lake gives its name to the mineral zabuyelite (lithium carbonate, Li2CO3), which was discovered here in 1987 and has been mined since 2004–2005. In 2008, the salt mine at the lake was regarded as the major source of lithium in China.
Syngenite is an uncommon potassium calcium sulfate mineral with formula K2Ca(SO4)2·H2O. It forms as prismatic monoclinic crystals and as encrustations.
Qingsongite is a rare boron nitride mineral with cubic crystalline form. It was first described in 2009 for an occurrence as minute inclusions within chromite deposits in the Luobusa ophiolite in the Shannan Prefecture, Tibet Autonomous Region, China. It was recognized as a mineral in August 2013 by the International Mineralogical Association. It is named after Chinese geologist Qingsong Fang (1939–2010). Qingsongite is the only known boron mineral that is formed deep in the Earth's mantle. Associated minerals or phases include osbornite, coesite, kyanite and amorphous carbon.
Picromerite is a mineral from the class of hydrous sulfates lacking additional anions, and containing medium to large cations according to the Nickel–Strunz classification.
Lithiophosphate is a natural form of (pure) lithium orthophosphate. It is an exceedingly rare mineral, occurring in some special types of pegmatites.