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3D model (JSmol) | |
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Properties | |
LiB3O5 | |
Molar mass | 119.37 g·mol−1 |
Appearance | Colorless crystalline solid |
Density | 2.747 g/cm3 |
Melting point | 834 °C (1,533 °F; 1,107 K) |
Refractive index (nD) | 1.5656 |
Structure | |
Orthorhombic | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Lithium triborate (LiB3O5) or LBO is a non-linear optical crystal. It has a wide transparency range, moderately high nonlinear coupling, high damage threshold and desirable chemical and mechanical properties. This crystal is often used for second harmonic generation (SHG, also known as frequency doubling), for example of Nd:YAG lasers (1064 nm → 532 nm). LBO can be both critically and non-critically phase-matched. In the latter case the crystal has to be heated or cooled depending on the wavelength.
Lithium triborate was discovered and developed by Chen Chuangtian and others of the Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences. It has been patented. [1]
Lithium triborate (LBO) crystals are applicable in various nonlinear optical applications: [2]
A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The word laser is an anacronym that originated as an acronym for light amplification by stimulated emission of radiation. The first laser was built in 1960 by Theodore Maiman at Hughes Research Laboratories, based on theoretical work by Charles H. Townes and Arthur Leonard Schawlow.
Nonlinear optics (NLO) is the branch of optics that describes the behaviour of light in nonlinear media, that is, media in which the polarization density P responds non-linearly to the electric field E of the light. The non-linearity is typically observed only at very high light intensities (when the electric field of the light is >108 V/m and thus comparable to the atomic electric field of ~1011 V/m) such as those provided by lasers. Above the Schwinger limit, the vacuum itself is expected to become nonlinear. In nonlinear optics, the superposition principle no longer holds.
Nd:YAG (neodymium-doped yttrium aluminum garnet; Nd:Y3Al5O12) is a crystal that is used as a lasing medium for solid-state lasers. The dopant, neodymium in the +3 oxidation state, Nd(III), typically replaces a small fraction (1%) of the yttrium ions in the host crystal structure of the yttrium aluminum garnet (YAG), since the two ions are of similar size. It is the neodymium ion which provides the lasing activity in the crystal, in the same fashion as red chromium ion in ruby lasers.
Titanium-sapphire lasers (also known as Ti:sapphire lasers, Ti:Al2O3 lasers or Ti:sapphs) are tunable lasers which emit red and near-infrared light in the range from 650 to 1100 nanometers. These lasers are mainly used in scientific research because of their tunability and their ability to generate ultrashort pulses thanks to its broad light emission spectrum. Lasers based on Ti:sapphire were first constructed and invented in June 1982 by Peter Moulton at the MIT Lincoln Laboratory.
A diode-pumped solid-state laser (DPSSL) is a solid-state laser made by pumping a solid gain medium, for example, a ruby or a neodymium-doped YAG crystal, with a laser diode.
An optical parametric amplifier, abbreviated OPA, is a laser light source that emits light of variable wavelengths by an optical parametric amplification process. It is essentially the same as an optical parametric oscillator, but without the optical cavity.
Yttrium aluminium garnet (YAG, Y3Al5O12) is a synthetic crystalline material of the garnet group. It is a cubic yttrium aluminium oxide phase, with other examples being YAlO3 (YAP) in a hexagonal or an orthorhombic, perovskite-like form, and the monoclinic Y4Al2O9 (YAM).
Potassium titanyl phosphate (KTP) is an inorganic compound with the formula K+[TiO]2+PO3−4. It is a white solid. KTP is an important nonlinear optical material that is commonly used for frequency-doubling diode-pumped solid-state lasers such as Nd:YAG and other neodymium-doped lasers.
An optical parametric oscillator (OPO) is a parametric oscillator that oscillates at optical frequencies. It converts an input laser wave with frequency into two output waves of lower frequency by means of second-order nonlinear optical interaction. The sum of the output waves' frequencies is equal to the input wave frequency: . For historical reasons, the two output waves are called "signal" and "idler", where the output wave with higher frequency is the "signal". A special case is the degenerate OPO, when the output frequency is one-half the pump frequency, , which can result in half-harmonic generation when signal and idler have the same polarization.
Lithium niobate is a synthetic salt consisting of niobium, lithium, and oxygen. Its single crystals are an important material for optical waveguides, mobile phones, piezoelectric sensors, optical modulators and various other linear and non-linear optical applications. Lithium niobate is sometimes referred to by the brand name linobate.
This is a list of acronyms and other initialisms used in laser physics and laser applications.
Caesium lithium borate or cesium lithium borate (CsLiB6O10), also known as CLBO, is a non-linear crystal for ultraviolet applications and generates the fourth and fifth harmonics of the Nd:YAG fundamental laser wavelength (1064 nm).
An optical frequency multiplier is a nonlinear optical device in which photons interacting with a nonlinear material are effectively "combined" to form new photons with greater energy, and thus higher frequency. Two types of devices are currently common: frequency doublers, often based on lithium niobate (LN), lithium tantalate (LT), potassium titanyl phosphate (KTP) or lithium triborate (LBO), and frequency triplers typically made of potassium dihydrogen phosphate (KDP). Both are widely used in optical experiments that use lasers as a light source.
Second-harmonic generation (SHG), also known as frequency doubling, is the lowest-order wave-wave nonlinear interaction that occurs in various systems, including optical, radio, atmospheric, and magnetohydrodynamic systems. As a prototype behavior of waves, SHG is widely used, for example, in doubling laser frequencies. SHG was initially discovered as a nonlinear optical process in which two photons with the same frequency interact with a nonlinear material, are "combined", and generate a new photon with twice the energy of the initial photons, that conserves the coherence of the excitation. It is a special case of sum-frequency generation (2 photons), and more generally of harmonic generation.
In optics, a supercontinuum is formed when a collection of nonlinear processes act together upon a pump beam in order to cause severe spectral broadening of the original pump beam, for example using a microstructured optical fiber. The result is a smooth spectral continuum. There is no consensus on how much broadening constitutes a supercontinuum; however researchers have published work claiming as little as 60 nm of broadening as a supercontinuum. There is also no agreement on the spectral flatness required to define the bandwidth of the source, with authors using anything from 5 dB to 40 dB or more. In addition the term supercontinuum itself did not gain widespread acceptance until this century, with many authors using alternative phrases to describe their continua during the 1970s, 1980s and 1990s.
Neodymium-doped yttrium lithium fluoride (Nd:YLF) is a lasing medium for arc lamp-pumped and diode-pumped solid-state lasers. The YLF crystal (LiYF4) is naturally birefringent, and commonly used laser transitions occur at 1047 nm and 1053 nm.
Frequency addition source of optical radiation is used for a certain type of guide star laser deployed at US Air Force Research Laboratory facilities SOR and AMOS. The laser light is produced in a sum-frequency generation process from two solid-state laser sources that operate at different wavelengths. The frequencies of the sources add directly to a summed frequency. Thus, if the source wavelengths are and , the resulting wavelength is
Deuterated potassium dihydrogen phosphate (KD2PO4 or K2H2PO4) or DKDP single crystals are widely used in non-linear optics as the second, third and fourth harmonic generators for Nd:YAG and Nd:YLF lasers. They are also found in electro-optical applications as Q-switches for Nd:YAG, Nd:YLF, alexandrite and Ti-sapphire lasers, as well as for Pockels cells.
Barium borate is an inorganic compound, a borate of barium with a chemical formula BaB2O4 or Ba(BO2)2. It is available as a hydrate or dehydrated form, as white powder or colorless crystals. The crystals exist in the high-temperature α phase and low-temperature β phase, abbreviated as BBO; both phases are birefringent, and BBO is a common nonlinear optical material.
Lightwave Electronics Corporation was a developer and manufacturer of diode-pumped solid-state lasers, and was a significant contributor to the creation and maturation of this technology. Lightwave Electronics was a technology-focused company, with diverse markets, including science and micromachining. Inventors employed by Lightwave Electronics received 51 US patents, and Lightwave Electronics products were referenced by non-affiliated inventors in 91 US patents.