Lithium molybdate

Last updated
Lithium molybdate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.601 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 236-977-7
PubChem CID
  • InChI=1S/2Li.Mo.4O/q2*+1;;;;2*-1 Yes check.svgY
    Key: NMHMDUCCVHOJQI-UHFFFAOYSA-N Yes check.svgY
  • InChI=1/2Li.Mo.4O/q2*+1;;;;2*-1/r2Li.MoO4/c;;2-1(3,4)5/q2*+1;-2
    Key: NMHMDUCCVHOJQI-FFXFYZCHAF
  • [Li+].[Li+].[O-][Mo]([O-])(=O)=O
Properties
Li2MoO4
Molar mass 173.82 g/mol
Appearancewhite odorless powder
hygroscopic or transparent crystal
Density 3.07 g/cm3 (pure crystal), 2.66 g/cm3 (hydrated crystal)
Melting point 705 °C (1,301 °F; 978 K)
very soluble
Hazards
GHS labelling: [1]
GHS-pictogram-exclam.svg
Warning
H315, H319, H335
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
NFPA 704 (fire diamond)
3
0
1
Related compounds
Other cations
sodium molybdate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
X mark.svgN  verify  (what is  Yes check.svgYX mark.svgN ?)

Lithium molybdate (Li 2 Mo O4) is a chemical compound. It is mainly used as an inhibitor in some types of industrial air conditioning.

Uses

Lithium molybdate is used as corrosion inhibitor in LiBr (Lithium bromide) absorption chiller for industrial central air conditioning. It is manufactured and shipped as either a colorless, transparent fluid or a white crystal powder. In either state it not classified as a hazardous material.

Li2MoO4 crystals have been found applicable for cryogenic phonon-scintillation detectors, which are used to investigate some rare nuclear processes. [2] The use of Li2MoO4 ceramics for antennas has been studied due to their low loss dielectric properties and the possibility to fabricate them by a room-temperature densification method instead of conventional sintering. [3] Li2MoO4 (LMO) have also been used with hollow glass microspheres (HGMS) to make low permittivity composite which has been used to make lenses for lens antennas. [4]

Related Research Articles

<span class="mw-page-title-main">Scintillator</span> Type of material

A scintillator is a material that exhibits scintillation, the property of luminescence, when excited by ionizing radiation. Luminescent materials, when struck by an incoming particle, absorb its energy and scintillate. Sometimes, the excited state is metastable, so the relaxation back down from the excited state to lower states is delayed. The process then corresponds to one of two phenomena: delayed fluorescence or phosphorescence. The correspondence depends on the type of transition and hence the wavelength of the emitted optical photon.

<span class="mw-page-title-main">Molybdenite</span> Molybdenum disulfide mineral

Molybdenite is a mineral of molybdenum disulfide, MoS2. Similar in appearance and feel to graphite, molybdenite has a lubricating effect that is a consequence of its layered structure. The atomic structure consists of a sheet of molybdenum atoms sandwiched between sheets of sulfur atoms. The Mo-S bonds are strong, but the interaction between the sulfur atoms at the top and bottom of separate sandwich-like tri-layers is weak, resulting in easy slippage as well as cleavage planes. Molybdenite crystallizes in the hexagonal crystal system as the common polytype 2H and also in the trigonal system as the 3R polytype.

A semiconductor detector in ionizing radiation detection physics is a device that uses a semiconductor to measure the effect of incident charged particles or photons.

<span class="mw-page-title-main">Lithium tantalate</span> Chemical compound

Lithium tantalate (LiTaO3) is a perovskite which possesses unique optical, piezoelectric and pyroelectric properties which make it valuable for nonlinear optics, passive infrared sensors such as motion detectors, terahertz generation and detection, surface acoustic wave applications, cell phones and possibly pyroelectric nuclear fusion. Considerable information is available from commercial sources about this salt.

<span class="mw-page-title-main">Lithium hydride</span> Chemical compound

Lithium hydride is an inorganic compound with the formula LiH. This alkali metal hydride is a colorless solid, although commercial samples are grey. Characteristic of a salt-like (ionic) hydride, it has a high melting point, and it is not soluble but reactive with all protic organic solvents. It is soluble and nonreactive with certain molten salts such as lithium fluoride, lithium borohydride, and sodium hydride. With a molar mass of 7.95 g/mol, it is the lightest ionic compound.

<span class="mw-page-title-main">Lithium fluoride</span> Chemical compound

Lithium fluoride is an inorganic compound with the chemical formula LiF. It is a colorless solid, that transitions to white with decreasing crystal size. Although odorless, lithium fluoride has a bitter-saline taste. Its structure is analogous to that of sodium chloride, but it is much less soluble in water. It is mainly used as a component of molten salts. Formation of LiF from the elements releases one of the highest energy per mass of reactants, second only to that of BeO.

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Silver molybdate (Ag2MoO4), a chemical compound, is a yellow, cubic crystalline substance often used in glass. Its crystals present two types of electronic structure, depending on the pressure conditions to which the crystal is subjected. At room temperature, Ag2MoO4 exhibits a spinel-type cubic structure, known as β-Ag2MoO4, which is more stable in nature. However, when exposed to high hydrostatic pressure, the tetragonal α-Ag2MoO4 forms as a metastable phase.

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Gadolinium oxysulfide (Gd2O2S), also called gadolinium sulfoxylate, GOS or Gadox, is an inorganic compound, a mixed oxide-sulfide of gadolinium.

<span class="mw-page-title-main">Lithium titanate</span> Chemical compound

Lithium titanates are chemical compounds of lithium, titanium and oxygen. They are mixed oxides and belong to the titanates. The most important lithium titanates are:

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<span class="mw-page-title-main">Molybdate</span>

In chemistry a molybdate is a compound containing an oxoanion with molybdenum in its highest oxidation state of 6. Molybdenum can form a very large range of such oxoanions which can be discrete structures or polymeric extended structures, although the latter are only found in the solid state. The larger oxoanions are members of group of compounds termed polyoxometalates, and because they contain only one type of metal atom are often called isopolymetalates. The discrete molybdenum oxoanions range in size from the simplest MoO2−
4
, found in potassium molybdate up to extremely large structures found in isopoly-molybdenum blues that contain for example 154 Mo atoms. The behaviour of molybdenum is different from the other elements in group 6. Chromium only forms the chromates, CrO2−
4
, Cr
2
O2−
7
, Cr
3
O2−
10
and Cr
4
O2−
13
ions which are all based on tetrahedral chromium. Tungsten is similar to molybdenum and forms many tungstates containing 6 coordinate tungsten.

<span class="mw-page-title-main">Manganese(II) molybdate</span> Inorganic compound

Managnese(II) molybdate is an inorganic compound with the chemical formula MnMoO4. α-MnMoO4 has a monoclinic crystal structure. It is also antiferromagnetic at low temperatures.

<span class="mw-page-title-main">Iron(II) molybdate</span> Chemical compound

Iron(II) molybdate is an inorganic compound with the chemical formula FeMoO4.

Lithium molybdenum purple bronze is a chemical compound with formula Li
0.9
Mo
6
O
17
, that is, a mixed oxide of molybdenum and lithium. It can be obtained as flat crystals with a purple-red color and metallic sheen.

<span class="mw-page-title-main">NASICON</span>

NASICON is an acronym for sodium (Na) Super Ionic CONductor, which usually refers to a family of solids with the chemical formula Na1+xZr2SixP3−xO12, 0 < x < 3. In a broader sense, it is also used for similar compounds where Na, Zr and/or Si are replaced by isovalent elements. NASICON compounds have high ionic conductivities, on the order of 10−3 S/cm, which rival those of liquid electrolytes. They are caused by hopping of Na ions among interstitial sites of the NASICON crystal lattice.

The room-temperature densification method was developed for Li2MoO4 ceramics and is based on the water-solubility of Li2MoO4. It can be used for the fabrication of Li2MoO4 ceramics instead of conventional thermal sintering. The method utilizes a small amount of aqueous phase formed by moistening the Li2MoO4 powder. The densification occurs during sample pressing as the solution incorporates the pores between the powder particles and recrystallizes. The contact points of the particles provide a high pressure zone, where solubility is increased, whereas the pores act as a suitable place for the precipitation of the solution. Any residual water is removed by post-processing typically at 120 °C. The method is suitable also for Li2MoO4 composite ceramics with up to 30 volume-% of filler material, enabling the optimization of the dielectric properties.

Heli Maarit Jantunen is a Finnish Professor of Technology at the University of Oulu and a member of the Scientific Advisory Board for the National Defense. She works on microelectronics and is a member of the 6G Flagship.

<span class="mw-page-title-main">Lithium aluminium germanium phosphate</span> Chemical compound

Lithium aluminium germanium phosphate, typically known with the acronyms LAGP or LAGPO, is an inorganic ceramic solid material whose general formula is Li
1+x
Al
x
Ge
2-x
(PO
4
)
3
. LAGP belongs to the NASICON family of solid conductors and has been applied as a solid electrolyte in all-solid-state lithium-ion batteries. Typical values of ionic conductivity in LAGP at room temperature are in the range of 10–5 - 10–4 S/cm, even if the actual value of conductivity is strongly affected by stoichiometry, microstructure, and synthesis conditions. Compared to lithium aluminium titanium phosphate (LATP), which is another phosphate-based lithium solid conductor, the absence of titanium in LAGP improves its stability towards lithium metal. In addition, phosphate-based solid electrolytes have superior stability against moisture and oxygen compared to sulfide-based electrolytes like Li
10
GeP
2
S
12
(LGPS) and can be handled safely in air, thus simplifying the manufacture process. Since the best performances are encountered when the stoichiometric value of x is 0.5, the acronym LAGP usually indicates the particular composition of Li
1.5
Al
0.5
Ge
1.5
(PO
4
)
3
, which is also the typically used material in battery applications.

References

  1. "Lithium molybdate". pubchem.ncbi.nlm.nih.gov.
  2. Barinova, O. P.; Danevich, F. A.; Degoda, V. Ya.; Kirsanova, S. V.; Kudovbenko, V. M.; Pirro, S.; Tretyak, V. I. (2010-01-21). "First test of Li2MoO4 crystal as a cryogenic scintillating bolometer". Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment. 613 (1): 54–57. Bibcode:2010NIMPA.613...54B. doi:10.1016/j.nima.2009.11.059.
  3. Kähäri, Hanna; Ramachandran, Prasadh; Juuti, Jari; Jantunen, Heli (2017). "Room-Temperature Densified Li2MoO4 Ceramic Patch Antenna and the Effect of Humidity". International Journal of Applied Ceramic Technology. 14: 50–55. doi:10.1111/ijac.12615. ISSN   1744-7402.
  4. Kokkonen, Mikko; Nelo, Mikko; Chen, Jiangcheng; Myllymäki, Sami; Jantunen, Heli (2020). "Low Permittivity Environmentally Friendly Lenses for Ku Band". Progress in Electromagnetics Research Letters. 93: 1–7. doi: 10.2528/pierl20060108 . S2CID   221461236.