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3D model (JSmol) |
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ChemSpider | |||
ECHA InfoCard | 100.008.306 | ||
EC Number |
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PubChem CID | |||
CompTox Dashboard (EPA) | |||
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Properties | |||
LiSCN | |||
Molar mass | 65.02 g/mol | ||
Appearance | White hygroscopic solid | ||
Density | 1.44 g/cm3 [1] | ||
Melting point | 274 °C (525 °F; 547 K) [2] | ||
Boiling point | 550 °C (1,022 °F; 823 K) (decomposition) | ||
125 g/100 ml | |||
Solubility | Soluble in alcohol [1] | ||
Structure [2] [3] | |||
Orthorhombic (anhydrous, α-monohydrate, dihydrate) Monoclinic (β-monohydrate) | |||
C2/m (α-monohydrate) Pnam (β-monohydrate) Pnma (anhydrous, dihydrate) | |||
4 (α, β-monohydrate) 6 (anhydrous, dihydrate) | |||
Tetrahederal (α and β-monohydrate) | |||
Thermochemistry | |||
Std molar entropy (S | 9 e.u. [1] | ||
Std enthalpy of formation (ΔfH⦵298) | 5.0 kcal/mol [1] | ||
Hazards | |||
GHS labelling: | |||
Warning | |||
H302+H312+H332, H412 | |||
NFPA 704 (fire diamond) | |||
Related compounds | |||
Other cations | Sodium thiocyanate, Potassium thiocyanate | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Lithium thiocyanate is a chemical compound with the formula LiSCN. It is an extremely hygroscopic white solid that forms the monohydrate and the dihydrate. It is the least stable of the alkali metal thiocyanates due to the large electrostatic deforming field of the lithium cation. [1]
Lithium thiocyanate is hygroscopic and forms the anhydrous, monohydrate, and dihydrate, which melts at 274, 60, and 38 °C, respectively. [2] The monohydrate supercools after melting, as it recrystallizes at 36 °C. It is soluble in many organic solvents, such as ethanol, methanol, 1-propanol, and acetone. However, it is insoluble in benzene. [1]
Due to its hygroscopicity, the anhydrous form is hard to prepare. The anhydrous form is usually prepared by the reaction of lithium hydroxide and ammonium thiocyanate, then the water was removed by vacuum, then the resulting solid was dissolved in diethyl ether, followed by adding to petroleum ether to form the ether salt, then it was heated in vacuum at 110 °C to result in the anhydrous salt. The overall reaction is the following: [1]
The monohydrate has 2 forms, the α form, and the β form; the α form reversibly converts to the β form at 49 °C. The α form has the space group C2/m while the β form has the space group Pnam. More info on its crystallography are listed in the table below.
Compound | LiSCN [3] | α-LiSCN·H2O [2] | β-LiSCN·H2O [2] | LiSCN·2H2O [3] |
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Molar mass (g/mol) | 65.02 | 83.04 | 83.04 | 101.05 |
Crystal Structure | Orthorhombic | Orthorhombic | Monoclinic | Orthorhombic |
Space Group | Pnma | C2/m | Pnam | Pnma |
Lattice constant a (Å) | 12.151 | 15.027 | 13.226 | 5.721 |
Lattice constant b (Å) | 3.736 | 7.597 | 7.062 | 8.093 |
Lattice constant c (Å) | 5.299 | 6.707 | 8.166 | 9.66.9 |
β | 96.147° | |||
Coordination number | 6 | 4 | 4 | 6 |
Calculated density (g/cm3) | 1.80 | 1.45 | 1.45 | 1.50 |
Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations Na+ and hydroxide anions OH−.
In chemistry, a hydrate is a substance that contains water or its constituent elements. The chemical state of the water varies widely between different classes of hydrates, some of which were so labeled before their chemical structure was understood.
Lithium hydroxide is an inorganic compound with the formula LiOH. It can exist as anhydrous or hydrated, and both forms are white hygroscopic solids. They are soluble in water and slightly soluble in ethanol. Both are available commercially. While classified as a strong base, lithium hydroxide is the weakest known alkali metal hydroxide.
Copper(II) nitrate describes any member of the family of inorganic compounds with the formula Cu(NO3)2(H2O)x. The hydrates are blue solids. Anhydrous copper nitrate forms blue-green crystals and sublimes in a vacuum at 150-200 °C. Common hydrates are the hemipentahydrate and trihydrate.
Europium(III) chloride is an inorganic compound with the formula EuCl3. The anhydrous compound is a yellow solid. Being hygroscopic it rapidly absorbs water to form a white crystalline hexahydrate, EuCl3·6H2O, which is colourless. The compound is used in research.
Cobalt(II) chloride is an inorganic compound of cobalt and chlorine, with the formula CoCl
2. The compound forms several hydrates CoCl
2·nH
2O, for n = 1, 2, 6, and 9. Claims of the formation of tri- and tetrahydrates have not been confirmed. The anhydrous form is a blue crystalline solid; the dihydrate is purple and the hexahydrate is pink. Commercial samples are usually the hexahydrate, which is one of the most commonly used cobalt compounds in the lab.
Tin(II) chloride, also known as stannous chloride, is a white crystalline solid with the formula SnCl2. It forms a stable dihydrate, but aqueous solutions tend to undergo hydrolysis, particularly if hot. SnCl2 is widely used as a reducing agent (in acid solution), and in electrolytic baths for tin-plating. Tin(II) chloride should not be confused with the other chloride of tin; tin(IV) chloride or stannic chloride (SnCl4).
Lithium perchlorate is the inorganic compound with the formula LiClO4. This white or colourless crystalline salt is noteworthy for its high solubility in many solvents. It exists both in anhydrous form and as a trihydrate.
Dicalcium phosphate is the calcium phosphate with the formula CaHPO4 and its dihydrate. The "di" prefix in the common name arises because the formation of the HPO42– anion involves the removal of two protons from phosphoric acid, H3PO4. It is also known as dibasic calcium phosphate or calcium monohydrogen phosphate. Dicalcium phosphate is used as a food additive, it is found in some toothpastes as a polishing agent and is a biomaterial.
Lithium sulfate is a white inorganic salt with the formula Li2SO4. It is the lithium salt of sulfuric acid.
Lithium peroxide is the inorganic compound with the formula Li2O2. It is a white, nonhygroscopic solid. Because of its high oxygen:mass and oxygen:volume ratios, the solid has been used to remove CO2 from the atmosphere in spacecraft.
Methyllithium is the simplest organolithium reagent with the empirical formula CH3Li. This s-block organometallic compound adopts an oligomeric structure both in solution and in the solid state. This highly reactive compound, invariably used in solution with an ether as the solvent, is a reagent in organic synthesis as well as organometallic chemistry. Operations involving methyllithium require anhydrous conditions, because the compound is highly reactive toward water. Oxygen and carbon dioxide are also incompatible with MeLi. Methyllithium is usually not prepared, but purchased as a solution in various ethers.
Lithium nitrite is the lithium salt of nitrous acid, with formula LiNO2. This compound is hygroscopic and very soluble in water. It is used as a corrosion inhibitor in mortar. It is also used in the production of explosives, due to its ability to nitrosate ketones under certain conditions.
Cobalt(II) iodide or cobaltous iodide are the inorganic compounds with the formula CoI2 and the hexahydrate CoI2(H2O)6. These salts are the principal iodides of cobalt.
Sodium metaborate is a chemical compound of sodium, boron, and oxygen with formula NaBO
2. However, the metaborate ion is trimeric in the anhydrous solid, therefore a more correct formula is Na3B3O6 or (Na+)3[B3O6]3−. The formula can be written also as Na
2O·B
2O
3 to highlight the relation to the main oxides of sodium and boron. The name is also applied to several hydrates whose formulas can be written NaBO2·nH2O for various values of n.
Lead(II) thiocyanate is a compound, more precisely a salt, with the formula Pb(SCN)2. It is a white crystalline solid, but will turn yellow upon exposure to light. It is slightly soluble in water and can be converted to a basic salt (Pb(CNS)2·Pb(OH)2 when boiled. Salt crystals may form upon cooling. Lead thiocyanate can cause lead poisoning if ingested and can adversely react with many substances. It has use in small explosives, matches, and dyeing.
Ammonium carbamate is a chemical compound with the formula [NH4][H2NCO2] consisting of ammonium cation NH+4 and carbamate anion NH2COO−. It is a white solid that is extremely soluble in water, less so in alcohol. Ammonium carbamate can be formed by the reaction of ammonia NH3 with carbon dioxide CO2, and will slowly decompose to those gases at ordinary temperatures and pressures. It is an intermediate in the industrial synthesis of urea (NH2)2CO, an important fertilizer.
Cerium nitrate refers to a family of nitrates of cerium in the +3 or +4 oxidation state. Often these compounds contain water, hydroxide, or hydronium ions in addition to cerium and nitrate. Double nitrates of cerium also exist.
Thorium(IV) nitrate is a chemical compound with the formula Th(NO3)4. A white solid in its anhydrous form, it can form tetra- and pentahydrates. As a salt of thorium it is weakly radioactive.
Gallium(III) sulfate refers to the chemical compound, a salt, with the formula Ga2(SO4)3, or its hydrates Ga2(SO4)3·xH2O. Gallium metal dissolves in sulfuric acid to form solutions containing [Ga(OH2)6]3+ and SO42− ions. The octadecahydrate Ga2(SO4)3·18H2O crystallises from these solutions at room temperature. This hydrate loses water in stages when heated, forming the anhydrate Ga2(SO4)3 above 150 °C and completely above 310 °C. Anhydrous Ga2(SO4)3 is isostructural with iron(III) sulfate, crystallizing in the rhombohedral space group R3.