Lithium tellurite

Last updated
Lithium tellurite
2.svg Li+.svg Tellurite-ion.svg
Identifiers
3D model (JSmol)
PubChem CID
  • InChI=1S/2Li.H2O3Te/c;;1-4(2)3/h;;(H2,1,2,3)/q2*+1;/p-2
    Key: NBPOTQRWKBWQSQ-UHFFFAOYSA-L
  • [Li+].[Li+].[O-][Te](=O)[O-]
Properties
Li2O3Te
Molar mass 189.48 g·mol−1
Appearancesolid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Lithium tellurite is an inorganic compound, with the chemical formula Li2TeO3. It crystallises in the monoclinic crystal system, with space group C2/c. [1] It can be prepared by reacting lithium oxide, [2] lithium hydroxide [3] or lithium carbonate [4] with tellurium dioxide. It reacts with lithium fluoride at high temperatures in a 3:1 stoichiometric ratio to obtain Li7(TeO3)3F. [4]

Related Research Articles

<span class="mw-page-title-main">Tellurium</span> Chemical element, symbol Te and atomic number 52

Tellurium is a chemical element with the symbol Te and atomic number 52. It is a brittle, mildly toxic, rare, silver-white metalloid. Tellurium is chemically related to selenium and sulfur, all three of which are chalcogens. It is occasionally found in native form as elemental crystals. Tellurium is far more common in the Universe as a whole than on Earth. Its extreme rarity in the Earth's crust, comparable to that of platinum, is due partly to its formation of a volatile hydride that caused tellurium to be lost to space as a gas during the hot nebular formation of Earth.

<span class="mw-page-title-main">Tellurium dioxide</span> Chemical compound

Tellurium dioxide (TeO2) is a solid oxide of tellurium. It is encountered in two different forms, the yellow orthorhombic mineral tellurite, β-TeO2, and the synthetic, colourless tetragonal (paratellurite), α-TeO2. Most of the information regarding reaction chemistry has been obtained in studies involving paratellurite, α-TeO2.

<span class="mw-page-title-main">Tellurate</span> Compound containing an oxyanion of tellurium

In chemistry tellurate is a compound containing an oxyanion of tellurium where tellurium has an oxidation number of +6. In the naming of inorganic compounds it is a suffix that indicates a polyatomic anion with a central tellurium atom.

<span class="mw-page-title-main">Sodium tellurite</span> Chemical compound

Sodium tellurite is an inorganic tellurium compound with formula Na2TeO3. It is a water-soluble white solid and a weak reducing agent. Sodium tellurite is an intermediate in the extraction of the element, tellurium; it is a product obtained from anode slimes and is a precursor to tellurium.

<span class="mw-page-title-main">Tellurium tetrafluoride</span> Chemical compound

Tellurium tetrafluoride, TeF4, is a stable, white, hygroscopic crystalline solid and is one of two fluorides of tellurium. The other binary fluoride is tellurium hexafluoride. The widely reported Te2F10 has been shown to be F5TeOTeF5 There are other tellurium compounds that contain fluorine, but only the two mentioned contain solely tellurium and fluorine. Tellurium difluoride, TeF2, and ditellurium difluoride, Te2F2 are not known.

<span class="mw-page-title-main">Lithium oxide</span> Chemical compound

Lithium oxide (Li
2
O) or lithia is an inorganic chemical compound. It is a white solid. Although not specifically important, many materials are assessed on the basis of their Li2O content. For example, the Li2O content of the principal lithium mineral spodumene (LiAlSi2O6) is 8.03%.

Selenium trioxide is the inorganic compound with the formula SeO3. It is white, hygroscopic solid. It is also an oxidizing agent and a Lewis acid. It is of academic interest as a precursor to Se(VI) compounds.

<span class="mw-page-title-main">Niobium pentoxide</span> Chemical compound

Niobium pentoxide is the inorganic compound with the formula Nb2O5. A colorless, insoluble, and fairly unreactive solid, it is the most widespread precursor for other compounds and materials containing niobium. It is predominantly used in alloying, with other specialized applications in capacitors, optical glasses, and the production of lithium niobate.

Tellurium compounds are compounds containing the element tellurium (Te). Tellurium belongs to the chalcogen family of elements on the periodic table, which also includes oxygen, sulfur, selenium and polonium: Tellurium and selenium compounds are similar. Tellurium exhibits the oxidation states −2, +2, +4 and +6, with +4 being most common.

The iodate fluorides are chemical compounds which contain both iodate and fluoride anions (IO3 and F). In these compounds fluorine is not bound to iodine as it is in fluoroiodates.

The sulfate fluorides are double salts that contain both sulfate and fluoride anions. They are in the class of mixed anion compounds. Some of these minerals are deposited in fumaroles.

The telluride oxides or oxytellurides are double salts that contain both telluride and oxide anions. They are in the class of mixed anion compounds.

A selenite fluoride is a chemical compound or salt that contains fluoride and selenite anions. These are mixed anion compounds. Some have third anions, including nitrate, molybdate, oxalate, selenate, silicate and tellurate.

The borotellurates are heteropoly anion compounds which have tellurate groups attached to boron atoms. The ratio of tellurate to borate reflects the degree of condensation. In [TeO4(BO3)2]8- the anions are linked into a chain. In [TeO2(BO3)4]10− the structure is zero dimensional with isolated anions. These arrangements of oxygen around boron and tellurium can have forms resembling silicates. The first borotellurates to be discovered were the mixed sodium rare earth compounds in 2015.

A tellurite fluoride is a mixed anion compound containing tellurite and fluoride ions. They have also been called oxyfluorotellurate(IV) where IV is the oxidation state of tellurium in tellurite.

A selenate selenite is a chemical compound or salt that contains selenite and selenate anions (SeO32- and SeO42-). These are mixed anion compounds. Some have third anions.

A tellurite tellurate is a chemical compound or salt that contains tellurite and tellurate anions (TeO32- and TeO42-). These are mixed anion compounds. Some have third anions.

Lithium telluride (Li2Te) is an inorganic compound of lithium and tellurium. Along with LiTe3, it is one of the two intermediate solid phases in the lithium-tellurium system. It can be prepared by directly reacting lithium and tellurium in a beryllium oxide crucible at 950°C.

<span class="mw-page-title-main">Europium compounds</span> Chemical compounds with at least one europium atom

Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.

References

  1. Folger, F. Crystal structure of lithium tellurate(IV). Zeitschrift fuer Anorganische und Allgemeine Chemie, 1975. 411 (2): 103-110. ISSN: 0044-2313.
  2. Moret, Jacques; Cachau-Herreillat, Danielle; Norbert, Alain; Maurin, Maurice. Lithium oxide-tellurium dioxide system. Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1971. 272 (23): 1870-1873. ISSN: 0567-6541.
  3. Breusov, O.N.; Revzina, T. V.; Druz, N. A. Synthesis and some properties of lithium tellurite. Zhurnal Neorganicheskoi Khimii, 1965. 10 (9): 1990-1992. ISSN: 0044-457X.
  4. 1 2 Jiang-He Feng, Chun-Li Hu, Hou-Ping Xia, Fang Kong, Jiang-Gao Mao (2017-12-04). "Li 7 (TeO 3 ) 3 F: A Lithium Fluoride Tellurite with Large Second Harmonic Generation Responses and a Short Ultraviolet Cutoff Edge". Inorganic Chemistry. 56 (23): 14697–14705. doi:10.1021/acs.inorgchem.7b02670. ISSN   0020-1669. PMID   29131609. Archived from the original on 2020-07-09. Retrieved 2021-03-19.{{cite journal}}: CS1 maint: multiple names: authors list (link)