Lithium tellurite

Last updated
Lithium tellurite
2.svg Li+.svg Tellurite-ion.svg
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
  • InChI=1S/2Li.H2O3Te/c;;1-4(2)3/h;;(H2,1,2,3)/q2*+1;/p-2
    Key: NBPOTQRWKBWQSQ-UHFFFAOYSA-L
  • [Li+].[Li+].[O-][Te](=O)[O-]
Properties
Li2O3Te
Molar mass 189.48 g·mol−1
Appearancesolid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Lithium tellurite is an inorganic compound, with the chemical formula Li2TeO3. It crystallises in the monoclinic crystal system, with space group C2/c. [1] It can be prepared by reacting lithium oxide, [2] lithium hydroxide [3] or lithium carbonate [4] with tellurium dioxide. It reacts with lithium fluoride at high temperatures in a 3:1 stoichiometric ratio to obtain Li7(TeO3)3F. [4]

References

  1. ↑ Folger, F. Crystal structure of lithium tellurate(IV). Zeitschrift fuer Anorganische und Allgemeine Chemie, 1975. 411 (2): 103-110. ISSN: 0044-2313.
  2. ↑ Moret, Jacques; Cachau-Herreillat, Danielle; Norbert, Alain; Maurin, Maurice. Lithium oxide-tellurium dioxide system. Comptes Rendus des Seances de l'Académie des Sciences, Série C: Sciences Chimiques, 1971. 272 (23): 1870-1873. ISSN: 0567-6541.
  3. ↑ Breusov, O.N.; Revzina, T. V.; Druz, N. A. Synthesis and some properties of lithium tellurite. Zhurnal Neorganicheskoi Khimii, 1965. 10 (9): 1990-1992. ISSN: 0044-457X.
  4. 1 2 Jiang-He Feng, Chun-Li Hu, Hou-Ping Xia, Fang Kong, Jiang-Gao Mao (2017-12-04). "Li 7 (TeO 3 ) 3 F: A Lithium Fluoride Tellurite with Large Second Harmonic Generation Responses and a Short Ultraviolet Cutoff Edge" . Inorganic Chemistry. 56 (23): 14697–14705. doi:10.1021/acs.inorgchem.7b02670. ISSN   0020-1669. PMID   29131609. Archived from the original on 2020-07-09. Retrieved 2021-03-19.{{cite journal}}: CS1 maint: multiple names: authors list (link)
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