Cadmium tellurite

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Cadmium tellurite
CdTeO3 crystal structure.png
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.036.316 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 239-963-9
PubChem CID
  • InChI=1S/Cd.H2O3Te/c;1-4(2)3/h;(H2,1,2,3)/q+2;/p-2
    Key: GKMPTXZNGKKTDU-UHFFFAOYSA-L
  • [Cd+2].[O-] [Te](=O)[O-]
Properties
CdO3Te
Molar mass 288.01 g·mol−1
Appearancecolourless solid [1]
Melting point 695 °C [1]
Boiling point 1050 °C (decomposes) [1]
insoluble [2]
Hazards
GHS labelling: [3]
GHS-pictogram-exclam.svg
Warning
H302, H312, H332
P261, P264, P270, P271, P280, P301+P317, P302+P352, P304+P340, P317, P321, P330, P362+P364, P501
Related compounds
Other anions
Cadmium telluride
Cadmium tellurate
Cadmium sulfite
Cadmium selenite
Other cations
Calcium tellurite
Strontium tellurite
Barium tellurite
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Cadmium tellurite is the tellurite salt of cadmium, with the chemical formula CdTeO3.

Contents

Preparation

Cadmium tellurite can be prepared by the reaction of cadmium sulfate and sodium tellurite in ammonia.

Properties

Cadmium tellurite is a colourless solid [1] that is insoluble in water. [2] It is a semiconductor. It is part of the monoclinic crystal system, with space group P21/c (No. 14). It can also crystallize in the cubic crystal system and hexagonal crystal system at temperatures above 540 °C. [4] [5]

Related Research Articles

<span class="mw-page-title-main">Tellurium</span> Chemical element, symbol Te and atomic number 52

Tellurium is a chemical element with the symbol Te and atomic number 52. It is a brittle, mildly toxic, rare, silver-white metalloid. Tellurium is chemically related to selenium and sulfur, all three of which are chalcogens. It is occasionally found in its native form as elemental crystals. Tellurium is far more common in the Universe as a whole than on Earth. Its extreme rarity in the Earth's crust, comparable to that of platinum, is due partly to its formation of a volatile hydride that caused tellurium to be lost to space as a gas during the hot nebular formation of Earth.

<span class="mw-page-title-main">Cadmium arsenide</span> Chemical compound

Cadmium arsenide (Cd3As2) is an inorganic semimetal in the II-V family. It exhibits the Nernst effect.

<span class="mw-page-title-main">Cadmium sulfide</span> Chemical compound

Cadmium sulfide is the inorganic compound with the formula CdS. Cadmium sulfide is a yellow solid. It occurs in nature with two different crystal structures as the rare minerals greenockite and hawleyite, but is more prevalent as an impurity substituent in the similarly structured zinc ores sphalerite and wurtzite, which are the major economic sources of cadmium. As a compound that is easy to isolate and purify, it is the principal source of cadmium for all commercial applications. Its vivid yellow color led to its adoption as a pigment for the yellow paint "cadmium yellow" in the 18th century.

<span class="mw-page-title-main">Cadmium sulfate</span> Chemical compound

Cadmium sulfate is the name of a series of related inorganic compounds with the formula CdSO4·xH2O. The most common form is the monohydrate CdSO4·H2O, but two other forms are known CdSO4·83H2O and the anhydrous salt (CdSO4). All salts are colourless and highly soluble in water.

<span class="mw-page-title-main">Cadmium chloride</span> Chemical compound

Cadmium chloride is a white crystalline compound of cadmium and chloride, with the formula CdCl2. This salt is a hygroscopic solid that is highly soluble in water and slightly soluble in alcohol. The crystal structure of cadmium chloride (described below), is a reference for describing other crystal structures. Also known are CdCl2•H2O and the hemipenahydrate CdCl2•2.5H2O.

<span class="mw-page-title-main">Tellurium dioxide</span> Chemical compound

Tellurium dioxide (TeO2) is a solid oxide of tellurium. It is encountered in two different forms, the yellow orthorhombic mineral tellurite, β-TeO2, and the synthetic, colourless tetragonal (paratellurite), α-TeO2. Most of the information regarding reaction chemistry has been obtained in studies involving paratellurite, α-TeO2.

<span class="mw-page-title-main">Cadmium selenide</span> Chemical compound

Cadmium selenide is an inorganic compound with the formula CdSe. It is a black to red-black solid that is classified as a II-VI semiconductor of the n-type. It is a pigment but applications are declining because of environmental concerns

<span class="mw-page-title-main">Sodium tellurite</span> Chemical compound

Sodium tellurite is an inorganic tellurium compound with formula Na2TeO3. It is a water-soluble white solid and a weak reducing agent. Sodium tellurite is an intermediate in the extraction of the element, tellurium; it is a product obtained from anode slimes and is a precursor to tellurium.

<span class="mw-page-title-main">Cadmium fluoride</span> Chemical compound

Cadmium fluoride (CdF2) is a mostly water-insoluble source of cadmium used in oxygen-sensitive applications, such as the production of metallic alloys. In extremely low concentrations (ppm), this and other fluoride compounds are used in limited medical treatment protocols. Fluoride compounds also have significant uses in synthetic organic chemistry. The standard enthalpy has been found to be -167.39 kcal. mole−1 and the Gibbs energy of formation has been found to be -155.4 kcal. mole−1, and the heat of sublimation was determined to be 76 kcal. mole−1.

<span class="mw-page-title-main">Mercury(I) sulfate</span> Chemical compound

Mercury(I) sulfate, commonly called mercurous sulphate (UK) or mercurous sulfate (US) is the chemical compound Hg2SO4. Mercury(I) sulfate is a metallic compound that is a white, pale yellow or beige powder. It is a metallic salt of sulfuric acid formed by replacing both hydrogen atoms with mercury(I). It is highly toxic; it could be fatal if inhaled, ingested, or absorbed by skin.

<span class="mw-page-title-main">Nickel(II) chromate</span> Chemical compound

Nickel(II) chromate (NiCrO4) is an acid-soluble compound, red-brown in color, with high tolerances for heat. It and the ions that compose it have been linked to tumor formation and gene mutation, particularly to wildlife.

<span class="mw-page-title-main">Zemannite</span>

Zemannite is a very rare oxide mineral with the chemical formula Mg0.5ZnFe3+[TeO3]3·4.5H2O. It crystallizes in the hexagonal crystal system and forms small prismatic brown crystals. Because of the rarity and small crystal size, zemannite has no applications and serves as a collector's item.

<span class="mw-page-title-main">Cadmium tetrafluoroborate</span> Chemical compound

Cadmium tetrafluoroborate is an ionic, chemical compound with the formula Cd(BF4)2. It is a crystalline solid, which is colorless and odorless. Cadmium tetrafluoroborate is most frequently used in the industrial production of high-strength steels, its purpose being to prevent hydrogen absorption, a source of post-production cracking of the metal, in the treated steels. Another application of the chemistry of cadmium tetrafluoroborate is fine tuning of the size of cadmium telluride nanomaterials.

A selenite fluoride is a chemical compound or salt that contains fluoride and selenite anions. These are mixed anion compounds. Some have third anions, including nitrate, molybdate, oxalate, selenate, silicate and tellurate.

The borotellurates are heteropoly anion compounds which have tellurate groups attached to boron atoms. The ratio of tellurate to borate reflects the degree of condensation. In [TeO4(BO3)2]8- the anions are linked into a chain. In [TeO2(BO3)4]10− the structure is zero dimensional with isolated anions. These arrangements of oxygen around boron and tellurium can have forms resembling silicates. The first borotellurates to be discovered were the mixed sodium rare earth compounds in 2015.

A tellurite fluoride is a mixed anion compound containing tellurite and fluoride ions. They have also been called oxyfluorotellurate(IV) where IV is the oxidation state of tellurium in tellurite.

A selenate selenite is a chemical compound or salt that contains selenite and selenate anions (SeO32- and SeO42-). These are mixed anion compounds. Some have third anions.

A tellurite tellurate is a chemical compound or salt that contains tellurite and tellurate anions (TeO32- and TeO42-). These are mixed anion compounds. Some have third anions.

<span class="mw-page-title-main">Praseodymium diiodide</span> Chemical compound

Praseodymium diiodide is a chemical compound with the empirical formula of PrI2, consisting of praseodymium and iodine. It is an electride, with the ionic formula of Pr3+(I)2e, and therefore not a true praseodymium(II) compound.

<span class="mw-page-title-main">Lithium tellurite</span> Chemical compound

Lithium tellurite is an inorganic compound, with the chemical formula Li2TeO3. It crystallises in the monoclinic crystal system, with space group C2/c. It can be prepared by reacting lithium oxide, lithium hydroxide or lithium carbonate with tellurium dioxide. It reacts with lithium fluoride at high temperatures in a 3:1 stoichiometric ratio to obtain Li7(TeO3)3F.

References

  1. 1 2 3 4 William M. Haynes (2016). CRC Handbook of Chemistry and Physics. CRC Press. p. 53. ISBN   978-1-4987-5429-3.
  2. 1 2 Cadmium tellurite, 99% at AlfaAesar, accessed on {{{Datum}}} (PDF) (JavaScript required).
  3. "Cadmium tellurite". pubchem.ncbi.nlm.nih.gov.
  4. Krämer, V.; Brandt, G. (1985-08-15). "Structure of cadmium tellurate(IV), CdTeO3". Acta Crystallographica Section C Crystal Structure Communications. 41 (8): 1152–1154. doi:10.1107/S0108270185006941.
  5. Poupon, Morgane; Barrier, Nicolas; Petit, Sébastien; Boudin, Sophie (2017). "A new β-CdTeO 3 polymorph with a structure related to α-CdTeO 3". Dalton Transactions. 46 (6): 1927–1935. doi:10.1039/C6DT04449B. ISSN   1477-9226. PMID   28112302.