Cadmium nitride

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Cadmium nitride
Kristallstruktur Lanthanoid-C-Typ.png
Identifiers
3D model (JSmol)
  • InChI=1S/3Cd.2N/q3*+2;2*-3
    Key: DSZUCHKZKXFZPK-UHFFFAOYSA-N
  • [Cd+2].[Cd+2].[Cd+2].[N-3].[N-3]
Properties
Cd3N2
Molar mass 365.256 g·mol−1
Appearanceblack solid [1]
Density 7.67 g·cm−3 [1]
Related compounds
Other cations
Zinc nitride
Mercury nitride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Cadmium nitride is a nitride of cadmium with the chemical formula Cd3N2.

Contents

Preparation

Cadmium nitride can be produced by thermal decomposition of cadmium amide at 180 °C: [1]

3 Cd(NH2)2 → Cd3N2 + 4 NH3

It can also be produced by thermal decomposition of cadmium azide at 210 °C. [2]

Properties

Cadmium nitride is a black solid that decomposes on contact with water and air. It will explode when reacting with dilute acids or alkalis. It is a crystal of inverse manganese(III) oxide structure with lattice constant a = 1079 pm. [1]

Related Research Articles

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<span class="mw-page-title-main">Melon (chemistry)</span>

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Thallium(I) oxide is the inorganic compound of thallium and oxygen with the formula Tl2O in which thallium is in its +1 oxidation state. It is black and produces a basic yellow solution of thallium(I) hydroxide (TlOH) when dissolved in water. It is formed by heating solid TlOH or Tl2CO3 in the absence of air. Thallium oxide is used to make special high refractive index glass. Thallium oxide is a component of several high temperature superconductors. Thallium(I) oxide reacts with acids to make thallium(I) salts.

Lithium carbide, Li
2
C
2
, often known as dilithium acetylide, is a chemical compound of lithium and carbon, an acetylide. It is an intermediate compound produced during radiocarbon dating procedures. Li
2
C
2
is one of an extensive range of lithium-carbon compounds which include the lithium-rich Li
4
C
, Li
6
C
2
, Li
8
C
3
, Li
6
C
3
, Li
4
C
3
, Li
4
C
5
, and the graphite intercalation compounds LiC
6
, LiC
12
, and LiC
18
.
Li
2
C
2
is the most thermodynamically-stable lithium-rich carbide and the only one that can be obtained directly from the elements. It was first produced by Moissan, in 1896 who reacted coal with lithium carbonate.

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2
)
n
. It is a solid, known only as a thermally unstable, insoluble white powder.

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9
H
3
N
13
or (HNCN)
3
(C
6
N
7
)
, whose molecule would consist of a heptazine H3(C
6
N
7
)
molecule, with three cyanamido groups H–N=C=N– or N≡C–NH– substituted for the hydrogen atoms.

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References

  1. 1 2 3 4 Handbuch der präparativen anorganischen Chemie / 1 (in German). Stuttgart. p. 1044. ISBN   3-432-02328-6. OCLC   310719485.
  2. Karau, Friedrich; Schnick, Wolfgang (2007). "Synthese von Cadmiumnitrid Cd3N2 durch thermischen Abbau von Cadmiumazid Cd(N3)2 und Kristallstrukturbestimmung aus Röntgen-Pulverbeugungsdaten". Zeitschrift für anorganische und allgemeine Chemie (in German). Wiley. 633 (2): 223–226. doi:10.1002/zaac.200600253. ISSN   0044-2313.