Tungsten nitride

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Tungsten nitride (W2N, WN, WN2) is an inorganic compound, a nitride of tungsten. [1] It is a hard, solid, brown-colored ceramic material that is electrically conductive and decomposes in water.

It is used in microelectronics as a contact material, for conductive layers, and barrier layers between silicon and other metals, e.g. tungsten or copper. It is less commonly used than titanium nitride or tungsten films.

Tungsten nitride forms together with tungsten dioxide, tungsten trioxide, and tungsten pentoxide when an incandescent light bulb breaks while the filament is heated.

Tungsten silicide is another material with similar use.

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3
N
4
is the most thermodynamically stable and commercially important of the silicon nitrides, and the term ″Silicon nitride″ commonly refers to this specific composition. It is a white, high-melting-point solid that is relatively chemically inert, being attacked by dilute HF and hot H
3
PO
4
. It is very hard. It has a high thermal stability with strong optical nonlinearities for all-optical applications.

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References

  1. Liu, Chengxiang; Wang, Chao; Meng, Xiangwei; Li, Xingyun; Qing, Qing; Wang, Xianfen; Xue, Ruiying; Yu, Qiang; Yang, Jialei; Wang, Kuikui; Zhao, Xiaoju; Chen, Wei; Qiao, Zhen-An; Zhao, Xiu Song (2020-11-01). "Tungsten nitride nanoparticles anchored on porous borocarbonitride as high-rate anode for lithium ion batteries" . Chemical Engineering Journal. 399: 125705. doi:10.1016/j.cej.2020.125705. ISSN   1385-8947. S2CID   224904157.