Lanthanum nitride

Last updated
Lanthanum nitride
Names
IUPAC name
Azanylidynelanthanum
Other names
Lanthanum mononitride, lanthanum(III) nitride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.042.936 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 247-245-1
PubChem CID
  • InChI=1S/La.N
    Key: QCLQZCOGUCNIOC-UHFFFAOYSA-N
  • [La+3].[N-3]
Properties
LaN
Molar mass 152.912 g·mol−1
AppearanceBlack powder
Density 6.73 g/cm3
Melting point 2,450 °C (4,440 °F; 2,720 K)
Insoluble
Hazards
GHS labelling:
GHS-pictogram-exclam.svg
Warning
H315, H319, H335
P264, P271, P280, P302, P304, P305, P312, P313, P332, P338, P340, P351, P352, P362, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Lanthanum nitride is a binary inorganic compound of lanthanum and nitride with the chemical formula LaN. [1] [2]

Contents

Preparation

Lanthanum nitride can be prepared from the reaction of nitrogen and lanthanum trihydride:

2LaH3 + N2 → 2LaN + 3H2

It can also be prepared from the reaction of ammonia and lanthanum trihydride: [3]

LaH3 + NH3 → LaN + 3H2

The reaction of nitrogen and lanthanum amalgam can also work: [4]

2La + N2 → 2LaN

Physical properties

Lanthanum nitride forms black powder that is insoluble in water. [1] Their crystals are of the cubic system with the Fm3m space group. [5]

It is paramagnetic.

Chemical properties

Lanthanum nitride reacts with water and moisture from the air: [6]

LaN + 3H2O → La(OH)3 + NH3

It reacts with acids:

LaN + 4HCl → LaCl3 + NH4Cl

Uses

LaN is used as a LED material, magnetic material, semiconductor, refractory material, dyes, catalyst. [7] [8]

Related Research Articles

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The Haber process, also called the Haber–Bosch process, is the main industrial procedure for the production of ammonia. The German chemists Fritz Haber and Carl Bosch developed it in the first decade of the 20th century. The process converts atmospheric nitrogen (N2) to ammonia (NH3) by a reaction with hydrogen (H2) using an iron metal catalyst under high temperatures and pressures. This reaction is slightly exothermic (i.e. it releases energy), meaning that the reaction is favoured at lower temperatures and higher pressures. It decreases entropy, complicating the process. Hydrogen is produced via steam reforming, followed by an iterative closed cycle to react hydrogen with nitrogen to produce ammonia.

β-Carbon nitride Chemical compound

β-Carbon nitride (beta-carbon nitride), β-C3N4, is a superhard material predicted to be harder than diamond.

<span class="mw-page-title-main">Lithium nitride</span> Chemical compound

Lithium nitride is a compound with the formula Li3N. It is the only stable alkali metal nitride. The solid has a reddish-pink color and high melting point.

<span class="mw-page-title-main">Beryllium nitride</span> Chemical compound

Beryllium nitride, Be3N2, is a nitride of beryllium. It can be prepared from the elements at high temperature (1100–1500 °C); unlike beryllium azide or BeN6, it decomposes in vacuum into beryllium and nitrogen. It is readily hydrolysed forming beryllium hydroxide and ammonia. It has two polymorphic forms cubic α-Be3N2 with a defect anti-fluorite structure, and hexagonal β-Be3N2. It reacts with silicon nitride, Si3N4 in a stream of ammonia at 1800–1900 °C to form BeSiN2.

<span class="mw-page-title-main">Magnesium nitride</span> Chemical compound

Magnesium nitride, which possesses the chemical formula Mg3N2, is an inorganic compound of magnesium and nitrogen. At room temperature and pressure it is a greenish yellow powder.

<span class="mw-page-title-main">Lanthanum(III) chloride</span> Chemical compound

Lanthanum chloride is the inorganic compound with the formula LaCl3. It is a common salt of lanthanum which is mainly used in research. It is a white solid that is highly soluble in water and alcohols.

<span class="mw-page-title-main">Transition metal dinitrogen complex</span> Coordination compounds with N2

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Praseodymium(III) nitride is a binary inorganic compound of praseodymium and nitrogen. Its chemical formula is PrN. The compound forms black crystals, and reacts with water.

<span class="mw-page-title-main">Lanthanum acetate</span> Chemical compound

Lanthanum acetate is an inorganic compound, a salt of lanthanum with acetic acid with the chemical formula La(CH3COO)3.

Erbium nitride is a binary inorganic compound of erbium and nitrogen with the chemical formula ErN.

Ytterbium(III) nitride is a binary inorganic compound of ytterbium and nitrogen with the chemical formula YbN.

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<span class="mw-page-title-main">Dysprosium nitride</span> Chemical compound

Dypsrosium nitride is a binary inorganic compound of dysprosium and nitride with the chemical formula DyN.

Cerium nitride is a binary inorganic compound of cerium and nitrogen with the chemical formula CeN.

Neptunium nitride is a binary inorganic compound of neptunium and nitrogen with the chemical formula NpN.

Americium nitride is a binary inorganic compound of americium and nitride with the chemical formula AmN.

Gadolinium(III) nitride is a binary inorganic compound of gadolinium and nitrogen with the chemical formula GdN.

Americium trihydride is a binary inorganic compound of americium and hydrogen with the chemical formula AmH3.

Lutetium nitride is a binary inorganic compound of lutetium and nitrogen with the chemical formula LuN.

References

  1. 1 2 "Lanthanum Nitride". American Elements . Retrieved 8 February 2024.
  2. Derz, Friedrich W. (18 May 2020). H-Z. Walter de Gruyter GmbH & Co KG. p. 1179. ISBN   978-3-11-232209-3 . Retrieved 8 February 2024.
  3. Foster, L. S. (1945). The Preparation of Crucibles from Nitrides. U.S. Atomic Energy Commission. Technical Information Service. p. 8. Retrieved 8 February 2024.
  4. Young, R. A.; Ziegler, W. T. (November 1952). "Crystal Structure of Lanthanum Nitride 1,2". Journal of the American Chemical Society . 74 (21): 5251–5253. doi:10.1021/ja01141a004. ISSN   0002-7863 . Retrieved 8 February 2024.
  5. Young, R. A.; Ziegler, W. T. (November 1952). "Crystal Structure of Lanthanum Nitride 1,2". Journal of the American Chemical Society . 74 (21): 5251–5253. doi:10.1021/ja01141a004. ISSN   0002-7863 . Retrieved 8 February 2024.
  6. "Lanthanum Nitride Powder, LaN, CAS 25764-10-7 - Heeger Materials". Heeger Materials Inc. Retrieved 8 February 2024.
  7. "Lanthanum Nitride (LaN) Powder (CAS No. 25764-10-7)". samaterials.com. Retrieved 8 February 2024.
  8. Deng, Zihao; Kioupakis, Emmanouil (1 June 2021). "Semiconducting character of LaN: Magnitude of the bandgap and origin of the electrical conductivity". AIP Advances. 11 (6). arXiv: 2106.04646 . Bibcode:2021AIPA...11f5312D. doi:10.1063/5.0055515. S2CID   235376911 . Retrieved 8 February 2024.