Names | |
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IUPAC name Azanylidynelanthanum | |
Other names Lanthanum mononitride, lanthanum(III) nitride | |
Identifiers | |
3D model (JSmol) | |
ChemSpider | |
ECHA InfoCard | 100.042.936 |
EC Number |
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PubChem CID | |
CompTox Dashboard (EPA) | |
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Properties | |
LaN | |
Molar mass | 152.912 g·mol−1 |
Appearance | Black powder |
Density | 6.73 g/cm3 |
Melting point | 2,450 °C (4,440 °F; 2,720 K) |
Insoluble | |
Hazards | |
GHS labelling: | |
Warning | |
H315, H319, H335 | |
P264, P271, P280, P302, P304, P305, P312, P313, P332, P338, P340, P351, P352, P362, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Lanthanum nitride is a binary inorganic compound of lanthanum and nitride with the chemical formula LaN. [1] [2]
Lanthanum nitride can be prepared from the reaction of nitrogen and lanthanum trihydride:
It can also be prepared from the reaction of ammonia and lanthanum trihydride: [3]
The reaction of nitrogen and lanthanum amalgam can also work: [4]
Lanthanum nitride forms black powder that is insoluble in water. [1] Their crystals are of the cubic system with the Fm3m space group. [5]
It is paramagnetic.
Lanthanum nitride reacts with water and moisture from the air: [6]
It reacts with acids:
LaN is used as a LED material, magnetic material, semiconductor, refractory material, dyes, catalyst. [7] [8]
The Haber process, also called the Haber–Bosch process, is the main industrial procedure for the production of ammonia. The German chemists Fritz Haber and Carl Bosch developed it in the first decade of the 20th century. The process converts atmospheric nitrogen (N2) to ammonia (NH3) by a reaction with hydrogen (H2) using an iron metal catalyst under high temperatures and pressures. This reaction is slightly exothermic (i.e. it releases energy), meaning that the reaction is favoured at lower temperatures and higher pressures. It decreases entropy, complicating the process. Hydrogen is produced via steam reforming, followed by an iterative closed cycle to react hydrogen with nitrogen to produce ammonia.
β-Carbon nitride (beta-carbon nitride), β-C3N4, is a superhard material predicted to be harder than diamond.
Lithium nitride is a compound with the formula Li3N. It is the only stable alkali metal nitride. The solid has a reddish-pink color and high melting point.
Beryllium nitride, Be3N2, is a nitride of beryllium. It can be prepared from the elements at high temperature (1100–1500 °C); unlike beryllium azide or BeN6, it decomposes in vacuum into beryllium and nitrogen. It is readily hydrolysed forming beryllium hydroxide and ammonia. It has two polymorphic forms cubic α-Be3N2 with a defect anti-fluorite structure, and hexagonal β-Be3N2. It reacts with silicon nitride, Si3N4 in a stream of ammonia at 1800–1900 °C to form BeSiN2.
Magnesium nitride, which possesses the chemical formula Mg3N2, is an inorganic compound of magnesium and nitrogen. At room temperature and pressure it is a greenish yellow powder.
Lanthanum chloride is the inorganic compound with the formula LaCl3. It is a common salt of lanthanum which is mainly used in research. It is a white solid that is highly soluble in water and alcohols.
Transition metal dinitrogen complexes are coordination compounds that contain transition metals as ion centers the dinitrogen molecules (N2) as ligands.
In chemistry, ammonolysis (/am·mo·nol·y·sis/) is the process of splitting ammonia into . Ammonolysis reactions can be conducted with organic compounds to produce amines (molecules containing a nitrogen atom with a lone pair, :N), or with inorganic compounds to produce nitrides. This reaction is analogous to hydrolysis in which water molecules are split. Similar to water, liquid ammonia also undergoes auto-ionization, , where the rate constant is k = 1.9 × 10-38.
Praseodymium(III) nitride is a binary inorganic compound of praseodymium and nitrogen. Its chemical formula is PrN. The compound forms black crystals, and reacts with water.
Lanthanum acetate is an inorganic compound, a salt of lanthanum with acetic acid with the chemical formula La(CH3COO)3.
Erbium nitride is a binary inorganic compound of erbium and nitrogen with the chemical formula ErN.
Ytterbium(III) nitride is a binary inorganic compound of ytterbium and nitrogen with the chemical formula YbN.
Samarium(III) nitride is a binary inorganic compound of samarium and nitrogen with the chemical formula SmN.
Dypsrosium nitride is a binary inorganic compound of dysprosium and nitride with the chemical formula DyN.
Cerium nitride is a binary inorganic compound of cerium and nitrogen with the chemical formula CeN.
Neptunium nitride is a binary inorganic compound of neptunium and nitrogen with the chemical formula NpN.
Americium nitride is a binary inorganic compound of americium and nitride with the chemical formula AmN.
Gadolinium(III) nitride is a binary inorganic compound of gadolinium and nitrogen with the chemical formula GdN.
Americium trihydride is a binary inorganic compound of americium and hydrogen with the chemical formula AmH3.
Lutetium nitride is a binary inorganic compound of lutetium and nitrogen with the chemical formula LuN.