Lanthanum tribromide"},"OtherNames":{"wt":""},"Section1":{"wt":"{{Chembox Identifiers\n| ChemSpiderID_Ref ={{chemspidercite|correct|chemspider}}\n| ChemSpiderID = 75393\n| PubChem = 83563\n| InChI = 1/3BrH.La/h3*1H;/q;;;+3/p-3\n| InChIKey = XKUYOJZZLGFZTC-DFZHHIFOAJ\n| SMILES = Br[La](Br)Br\n| StdInChI_Ref ={{stdinchicite|correct|chemspider}}\n| StdInChI = 1S/3BrH.La/h3*1H;/q;;;+3/p-3\n| StdInChIKey_Ref ={{stdinchicite|correct|chemspider}}\n| StdInChIKey = XKUYOJZZLGFZTC-UHFFFAOYSA-K\n| CASNo_Ref ={{cascite|correct|??}}\n| CASNo = 13536-79-3\n| RTECS = \n| EINECS = 236-896-7\n}}"},"Section2":{"wt":"{{Chembox Properties\n| Formula = LaBr3\n| MolarMass = 378.62 g/mol (anhydrous)\n| Appearance = white solid,[[hygroscopic]]\n| Density = 5.06 g/cm3,solid\n| Solubility = Very soluble\n| MeltingPtC = 783\n| BoilingPtC = 1577\n}}"},"Section3":{"wt":"{{Chembox Structure\n| Coordination = Tricapped trigonal prismatic
(nine-coordinate)\n| CrystalStruct = [[Hexagonal crystal system|hexagonal]] ([[Uranium trichloride#Structure|UCl3type]]),[[Pearson symbol|hP8]]\n| SpaceGroup = P63/m,No. 176\n}}"},"Section7":{"wt":"{{Chembox Hazards\n| ExternalSDS =\n| GHSPictograms ={{GHS07}}\n| GHSSignalWord = warning\n| HPhrases ={{HPhrases|H315|H319|H335}}\n| PPhrases ={{PPhrases|P261|P264|P271|P280|P302+P352|P304+P340|P305+P351+P338|P312|P321|P332+P313|P337+P313|P362|P403+P233|P405|P501}}\n| GHS_ref = GHS:[https://pubchem.ncbi.nlm.nih.gov/compound/83563#section=Safety-and-Hazards PubChem]\n| FlashPt = not flammable\n}}"},"Section8":{"wt":"{{Chembox Related\n| OtherAnions = [[Lanthanum(III) fluoride]]
[[Lanthanum(III) chloride]]
[[Lanthanum(III) iodide]]\n| OtherCations = [[Cerium(III) bromide]]
[[Praseodymium(III) bromide]]\n}}"}},"i":0}}]}" id="mwAg">.mw-parser-output .ib-chembox{border-collapse:collapse;text-align:left}.mw-parser-output .ib-chembox td,.mw-parser-output .ib-chembox th{border:1px solid #a2a9b1;width:40%}.mw-parser-output .ib-chembox td+td{width:60%}
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Names | |||
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IUPAC names Lanthanum(III) bromide Lanthanum tribromide | |||
Identifiers | |||
3D model (JSmol) | |||
ChemSpider | |||
ECHA InfoCard | 100.033.527 | ||
EC Number |
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PubChem CID | |||
CompTox Dashboard (EPA) | |||
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Properties | |||
LaBr3 | |||
Molar mass | 378.62 g/mol (anhydrous) | ||
Appearance | white solid, hygroscopic | ||
Density | 5.06 g/cm3, solid | ||
Melting point | 783 °C (1,441 °F; 1,056 K) | ||
Boiling point | 1,577 °C (2,871 °F; 1,850 K) | ||
Very soluble | |||
Structure | |||
hexagonal (UCl3 type), hP8 | |||
P63/m, No. 176 | |||
Tricapped trigonal prismatic (nine-coordinate) | |||
Hazards | |||
GHS labelling: [1] | |||
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Warning | |||
H315, H319, H335 | |||
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501 | |||
Flash point | not flammable | ||
Related compounds | |||
Other anions | Lanthanum(III) fluoride Lanthanum(III) chloride Lanthanum(III) iodide | ||
Other cations | Cerium(III) bromide Praseodymium(III) bromide | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Lanthanum(III) bromide (LaBr3) is an inorganic halide salt of lanthanum. When pure, it is a colorless white powder. The single crystals of LaBr3 are hexagonal crystals with melting point of 783 °C. It is highly hygroscopic and water-soluble. There are several hydrates, La3Br·x H2O, of the salt also known. It is often used as a source of lanthanum in chemical synthesis and as a scintillation material in certain applications.
The scintillator material cerium activated lanthanum bromide (LaBr3:Ce) was first produced in 2001. [2] LaBr3:Ce-based radiation detectors offer improved energy resolution, fast emission and excellent temperature and linearity characteristics. Typical energy resolution at 662 keV is 3% as compared to sodium iodide detectors at 7%. [3] The improved resolution is due to a photoelectron yield that is 160% greater than is achieved with sodium iodide. Another advantage of LaBr3:Ce is the nearly flat photo emission over a 70 °C temperature range (~1% change in light output).[ citation needed ]
Today LaBr3 detectors are offered with bialkali photomultiplier tubes (PMT) that can be two inches in diameter and 10 or more inches long.[ citation needed ] However, miniature packaging can be obtained by the use of a silicon drift detector (SDD) or a Silicon Photomultiplier (SiPM). [4] These UV enhanced diodes provide excellent wavelength matching to the 380 nm emission of LaBr3. The SDD is not as sensitive to temperature and bias drift as PMT. The reported spectroscopy performance of the SDD configuration resulted in a 2.8% energy resolution at 662 keV for the detector sizes considered.
LaBr3 introduces an enhanced set of capabilities to a range of gamma spectroscopy radioisotope detection and identification systems used in the homeland security market. Isotope identification utilizes several techniques (known as algorithms) which rely on the detector's ability to discriminate peaks. The improvements in resolution allow more accurate peak discrimination in ranges where isotopes often have many overlapping peaks. This leads to better isotope classification. Screening of all types (pedestrians, cargo, conveyor belts, shipping containers, vehicles, etc.) often requires accurate isotopic identification to differentiate concerning materials from non-concerning materials (medical isotopes in patients, naturally occurring radioactive materials, etc.) Heavy R&D and deployment of instruments utilizing LaBr3 is expected in the upcoming years.
Neutron activation analysis (NAA) is a nuclear process used for determining the concentrations of elements in many materials. NAA allows discrete sampling of elements as it disregards the chemical form of a sample, and focuses solely on atomic nuclei. The method is based on neutron activation and thus requires a neutron source. The sample is bombarded with neutrons, causing its constituent elements to form radioactive isotopes. The radioactive emissions and radioactive decay paths for each element have long been studied and determined. Using this information, it is possible to study spectra of the emissions of the radioactive sample, and determine the concentrations of the various elements within it. A particular advantage of this technique is that it does not destroy the sample, and thus has been used for the analysis of works of art and historical artifacts. NAA can also be used to determine the activity of a radioactive sample.
X-ray fluorescence (XRF) is the emission of characteristic "secondary" X-rays from a material that has been excited by being bombarded with high-energy X-rays or gamma rays. The phenomenon is widely used for elemental analysis and chemical analysis, particularly in the investigation of metals, glass, ceramics and building materials, and for research in geochemistry, forensic science, archaeology and art objects such as paintings.
Photomultiplier tubes (photomultipliers or PMTs for short) are extremely sensitive detectors of light in the ultraviolet, visible, and near-infrared ranges of the electromagnetic spectrum. They are members of the class of vacuum tubes, more specifically vacuum phototubes. These detectors multiply the current produced by incident light by as much as 100 million times or 108 (i.e., 160 dB), in multiple dynode stages, enabling (for example) individual photons to be detected when the incident flux of light is low.
A scintillation counter is an instrument for detecting and measuring ionizing radiation by using the excitation effect of incident radiation on a scintillating material, and detecting the resultant light pulses.
A scintillator is a material that exhibits scintillation, the property of luminescence, when excited by ionizing radiation. Luminescent materials, when struck by an incoming particle, absorb its energy and scintillate. Sometimes, the excited state is metastable, so the relaxation back down from the excited state to lower states is delayed. The process then corresponds to one of two phenomena: delayed fluorescence or phosphorescence. The correspondence depends on the type of transition and hence the wavelength of the emitted optical photon.
Energy-dispersive X-ray spectroscopy, sometimes called energy dispersive X-ray analysis or energy dispersive X-ray microanalysis (EDXMA), is an analytical technique used for the elemental analysis or chemical characterization of a sample. It relies on an interaction of some source of X-ray excitation and a sample. Its characterization capabilities are due in large part to the fundamental principle that each element has a unique atomic structure allowing a unique set of peaks on its electromagnetic emission spectrum. The peak positions are predicted by the Moseley's law with accuracy much better than experimental resolution of a typical EDX instrument.
A gamma camera (γ-camera), also called a scintillation camera or Anger camera, is a device used to image gamma radiation emitting radioisotopes, a technique known as scintigraphy. The applications of scintigraphy include early drug development and nuclear medical imaging to view and analyse images of the human body or the distribution of medically injected, inhaled, or ingested radionuclides emitting gamma rays.
A gamma-ray spectrometer (GRS) is an instrument for measuring the distribution of the intensity of gamma radiation versus the energy of each photon. The study and analysis of gamma-ray spectra for scientific and technical use is called gamma spectroscopy, and gamma-ray spectrometers are the instruments which observe and collect such data. Because the energy of each photon of EM radiation is proportional to its frequency, gamma rays have sufficient energy that they are typically observed by counting individual photons.
Explorer 11 was a NASA satellite that carried the first space-borne gamma-ray telescope. This marked the beginning of space gamma-ray astronomy. Launched on 27 April 1961 by a Juno II, the satellite returned data until 17 November 1961, when power supply problems ended the science mission. During the spacecraft's seven-month lifespan it detected twenty-two events from gamma-rays and approximately 22,000 events from cosmic radiation.
Photodetectors, also called photosensors, are sensors of light or other electromagnetic radiation. There are a wide variety of photodetectors which may be classified by mechanism of detection, such as photoelectric or photochemical effects, or by various performance metrics, such as spectral response. Semiconductor-based photodetectors typically use a p–n junction that converts photons into charge. The absorbed photons make electron–hole pairs in the depletion region. Photodiodes and photo transistors are a few examples of photo detectors. Solar cells convert some of the light energy absorbed into electrical energy.
Gamma-ray spectroscopy is the qualitative study of the energy spectra of gamma-ray sources, such as in the nuclear industry, geochemical investigation, and astrophysics. Gamma-ray spectrometry, on the other hand, is the method used to acquire a quantitative spectrum measurement.
Sodium iodide (chemical formula NaI) is an ionic compound formed from the chemical reaction of sodium metal and iodine. Under standard conditions, it is a white, water-soluble solid comprising a 1:1 mix of sodium cations (Na+) and iodide anions (I−) in a crystal lattice. It is used mainly as a nutritional supplement and in organic chemistry. It is produced industrially as the salt formed when acidic iodides react with sodium hydroxide. It is a chaotropic salt.
Neutron detection is the effective detection of neutrons entering a well-positioned detector. There are two key aspects to effective neutron detection: hardware and software. Detection hardware refers to the kind of neutron detector used and to the electronics used in the detection setup. Further, the hardware setup also defines key experimental parameters, such as source-detector distance, solid angle and detector shielding. Detection software consists of analysis tools that perform tasks such as graphical analysis to measure the number and energies of neutrons striking the detector.
The formation evaluation gamma ray log is a record of the variation with depth of the natural radioactivity of earth materials in a wellbore. Measurement of natural emission of gamma rays in oil and gas wells are useful because shales and sandstones typically have different gamma ray levels. Shales and clays are responsible for most natural radioactivity, so gamma ray log often is a good indicator of such rocks. In addition, the log is also used for correlation between wells, for depth correlation between open and cased holes, and for depth correlation between logging runs.
Strontium iodide (SrI2) is a salt of strontium and iodine. It is an ionic, water-soluble, and deliquescent compound that can be used in medicine as a substitute for potassium iodide . It is also used as a scintillation gamma radiation detector, typically doped with europium, due to its optical clarity, relatively high density, high effective atomic number (Z=48), and high scintillation light yield. In recent years, europium-doped strontium iodide (SrI2:Eu2+) has emerged as a promising scintillation material for gamma-ray spectroscopy with extremely high light yield and proportional response, exceeding that of the widely used high performance commercial scintillator LaBr3:Ce3+. Large diameter SrI2 crystals can be grown reliably using vertical Bridgman technique and are being commercialized by several companies.
Cerium(III) bromide is an inorganic compound with the formula CeBr3. This white hygroscopic solid is of interest as a component of scintillation counters.
Tail pulse generators simulate the outputs of radiation detectors, photomultiplier tubes (PMT's) and their electronics. They in turn test systems and components for linearity, stability, resolution, pile-up and count rate effects. Tail pulse generators are differentiated from standard logic pulse generators in that the rise and fall times are exponential.
A radionuclide identification device is a small, lightweight, portable gamma-ray spectrometer used for the detection and identification of radioactive substances. It is available from many companies in various forms to provide hand-held gamma-ray radionuclide identification. Since these instruments are easily carried, they are suitable for first-line responders in key applications of Homeland Security, Environmental Monitoring and Radiological Mapping. These devices have also found their usefulness in medical and industrial applications as well as a number of unique applications such as geological surveys. In the past two decades RIIDs have addressed the growing demand for fast, accurate isotope identification. These light-weight instruments require room temperature detectors so they can be easily carried and perform meaningful measurements in various environments and locations.
The ISOLDE Decay Station (IDS) is a permanent experiment located in the ISOLDE facility at CERN. The purpose of the experiment is to measure decay properties of radioactive isotopes using spectroscopy techniques for a variety of applications, including nuclear engineering and astrophysics. The experimental setup has been operational since 2014.