Protactinium(IV) bromide

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Protactinium(IV) bromide
Kristallstruktur Uran(IV)-chlorid.png
Names
IUPAC name
Protactinium(IV) tetrabromide
Identifiers
3D model (JSmol)
  • InChI=1S/4BrH.Pa/h4*1H;/q;;;;+4/p-4
    Key: HWPJRUOTLXLOJI-UHFFFAOYSA-J
  • [Pa](Br)(Br)(Br)Br
Properties
PaBr4
Molar mass 550.652
Appearancered crystals
Structure
tetragonal crystal system [1] [2] ,tI20
I41/amd , No. 141
Related compounds
Other anions
Protactinium(IV) fluoride
Protactinium(IV) chloride
Protactinium(IV) iodide
Other cations
Uranium(IV) bromide
Thorium(IV) bromide
Praseodymium(III) bromide
Related compounds
Protactinium(V) bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Protactinium(IV) bromide is an inorganic compound. It is an actinide halide, composed of protactinium and bromine. It is radioactive, and has the chemical formula of PaBr4. It may be due to the brown color of bromine that causes the appearance of protactinium(IV) bromide to be brown crystals. Its crystal structure is tetragonal. [1] [2] Protactinium(IV) bromide is sublimed in a vacuum at 400 °C. [1] The protactinium(IV) halide closest in structure to protactinium(IV) bromide is protactinium(IV) chloride.

Contents

Preparation

Protactinium(IV) bromide can be prepared by reacting protactinium(V) bromide with hydrogen gas or aluminium: [3]

Properties

Protactinium(IV) bromide reacts with antimony trioxide to form protactinium bromate: [4]

See also

Related Research Articles

<span class="mw-page-title-main">Americium</span> Chemical element, symbol Am and atomic number 95

Americium is a synthetic chemical element; it has symbol Am and atomic number 95. It is radioactive and a transuranic member of the actinide series in the periodic table, located under the lanthanide element europium and was thus named after the Americas by analogy.

<span class="mw-page-title-main">Protactinium</span> Chemical element, symbol Pa and atomic number 91

Protactinium is a chemical element; it has symbol Pa and atomic number 91. It is a dense, radioactive, silvery-gray actinide metal which readily reacts with oxygen, water vapor and inorganic acids. It forms various chemical compounds in which protactinium is usually present in the oxidation state +5, but it can also assume +4 and even +3 or +2 states. Concentrations of protactinium in the Earth's crust are typically a few parts per trillion, but may reach up to a few parts per million in some uraninite ore deposits. Because of its scarcity, high radioactivity and high toxicity, there are currently no uses for protactinium outside scientific research, and for this purpose, protactinium is mostly extracted from spent nuclear fuel.

<span class="mw-page-title-main">Silver bromide</span> Chemical compound

Silver bromide (AgBr) is a soft, pale-yellow, water-insoluble salt well known for its unusual sensitivity to light. This property has allowed silver halides to become the basis of modern photographic materials. AgBr is widely used in photographic films and is believed by some to have been used for making the Shroud of Turin. The salt can be found naturally as the mineral bromargyrite.

<span class="mw-page-title-main">Hydrogen bromide</span> Chemical compound

Hydrogen bromide is the inorganic compound with the formula HBr. It is a hydrogen halide consisting of hydrogen and bromine. A colorless gas, it dissolves in water, forming hydrobromic acid, which is saturated at 68.85% HBr by weight at room temperature. Aqueous solutions that are 47.6% HBr by mass form a constant-boiling azeotrope mixture that boils at 124.3 °C (255.7 °F). Boiling less concentrated solutions releases H2O until the constant-boiling mixture composition is reached.

<span class="mw-page-title-main">Hypobromite</span> Ion, and compounds containing the ion

The hypobromite ion, also called alkaline bromine water, is BrO. Bromine is in the +1 oxidation state. The Br–O bond length is 1.82 Å. Hypobromite is the bromine compound analogous to hypochlorites found in common bleaches, and in immune cells. In many ways, hypobromite functions in the same manner as hypochlorite, and is also used as a germicide and antiparasitic in both industrial applications, and in the immune system.

<span class="mw-page-title-main">Organoactinide chemistry</span> Study of chemical compounds containing actinide-carbon bonds

Organoactinide chemistry is the science exploring the properties, structure, and reactivity of organoactinide compounds, which are organometallic compounds containing a carbon to actinide chemical bond.

<span class="mw-page-title-main">Strontium bromide</span> Chemical compound

Strontium bromide is a chemical compound with a formula SrBr2. At room temperature it is a white, odourless, crystalline powder. Strontium bromide imparts a bright red colour in a flame test, showing the presence of strontium ions. It is used in flares and also has some pharmaceutical uses.

<span class="mw-page-title-main">Berkelium compounds</span> Any chemical compound having at least one berkelium atom

Berkelium forms a number of chemical compounds, where it normally exists in an oxidation state of +3 or +4, and behaves similarly to its lanthanide analogue, terbium. Like all actinides, berkelium easily dissolves in various aqueous inorganic acids, liberating gaseous hydrogen and converting into the trivalent oxidation state. This trivalent state is the most stable, especially in aqueous solutions, but tetravalent berkelium compounds are also known. The existence of divalent berkelium salts is uncertain and has only been reported in mixed lanthanum chloride-strontium chloride melts. Aqueous solutions of Bk3+ ions are green in most acids. The color of the Bk4+ ions is yellow in hydrochloric acid and orange-yellow in sulfuric acid. Berkelium does not react rapidly with oxygen at room temperature, possibly due to the formation of a protective oxide surface layer; however, it reacts with molten metals, hydrogen, halogens, chalcogens and pnictogens to form various binary compounds. Berkelium can also form several organometallic compounds.

<span class="mw-page-title-main">Thorium compounds</span> Any chemical compound having at least one atom of thorium

Many compounds of thorium are known: this is because thorium and uranium are the most stable and accessible actinides and are the only actinides that can be studied safely and legally in bulk in a normal laboratory. As such, they have the best-known chemistry of the actinides, along with that of plutonium, as the self-heating and radiation from them is not enough to cause radiolysis of chemical bonds as it is for the other actinides. While the later actinides from americium onwards are predominantly trivalent and behave more similarly to the corresponding lanthanides, as one would expect from periodic trends, the early actinides up to plutonium have relativistically destabilised and hence delocalised 5f and 6d electrons that participate in chemistry in a similar way to the early transition metals of group 3 through 8: thus, all their valence electrons can participate in chemical reactions, although this is not common for neptunium and plutonium.

<span class="mw-page-title-main">Praseodymium(IV) fluoride</span> Chemical compound

Praseodymium(IV) fluoride (also praseodymium tetrafluoride) is a binary inorganic compound, a highly oxidised metal salt of praseodymium and fluoride with the chemical formula PrF4.

Neptunium (IV) oxalate is an inorganic compound, a salt of neptunium and oxalic acid with the chemical formula Np(C2O4)2. The compound is slightly soluble in water, forms crystalline hydrates—green crystals.

Lutetium(III) nitrate is an inorganic compound, a salt of lutetium and nitric acid with the chemical formula Lu(NO3)3. The compound forms colorless crystals, dissolves in water, and also forms crystalline hydrates. The compound is poisonous.

Curium compounds are compounds containing the element curium (Cm). Curium usually forms compounds in the +3 oxidation state, although compounds with curium in the +4, +5 and +6 oxidation states are also known.

Einsteinium compounds are compounds that contain the element einsteinium (Es). These compounds largely have einsteinium in the +3 oxidation state, or in some cases in the +2 and +4 oxidation states. Although einsteinium is relatively stable, with half-lives ranging from 20 days upwards, these compounds have not been studied in great detail.

<span class="mw-page-title-main">Praseodymium(III) iodide</span> Chemical compound

Praseodymium(III) iodide is an inorganic salt, consisting of the rare-earth metal praseodymium and iodine, with the chemical formula PrI3. It forms green crystals. It is soluble in water.

Protactinium(V) bromide is an inorganic compound. It is a halide of protactinium, consisting of protactinium and bromine. It is radioactive and has a chemical formula of PaBr5, which is a red crystal of the monoclinic crystal system.

<span class="mw-page-title-main">Protactinium(V) fluoride</span> Chemical compound

Protactinium(V) fluoride is a fluoride of protactinium with the chemical formula PaF5.

<span class="mw-page-title-main">Protactinium(IV) chloride</span> Chemical compound

Protactinium(IV) chloride is an inorganic compound. It is an actinide halide, composed of protactinium and chlorine. It is radioactive, and has the chemical formula of PaCl4. It is a chartreuse-coloured (yellowish-green) crystal of the tetragonal crystal system.

Protactinium compounds are compounds containing the element protactinium. These compounds usually have protactinium in the +5 oxidation state, although these compounds can also exist in the +2, +3 and +4 oxidation states.

UPt<sub>3</sub> Chemical compound

UPt3 is an inorganic binary intermetallic crystalline compound of platinum and uranium.

References

  1. 1 2 3 Tahri, Y; Chermette, H; Elkhatib, N; Krupa, J; Simoni, E (1990). "Electronic structures of thorium and protactinium halide clusters of [ThX8]4− type". Journal of the Less Common Metals. 158: 105–116. doi:10.1016/0022-5088(90)90436-N.
  2. 1 2 Brown, D.; Petcher, T. J.; Smith, A. J. (1968). "Crystal Structures of some Protactinium Bromides". Nature. 217 (5130): 737. Bibcode:1968Natur.217..737B. doi:10.1038/217737a0. S2CID   4264482.
  3. Руководство по неорганическому синтезу: В 6-ти т. Vol. 4. М.: Мир. Ред. Брауэр Г. 1985.
  4. Morss, Lester R.; Edelstein, Norman M.; Fuger, J. (2010). The chemistry of the actinide and transactinide elements. Volumes 1-6. Dordrecht: Springer. p. 874. ISBN   978-94-007-0211-0. OCLC   682907473.