Selenium tetrabromide

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Selenium tetrabromide
Selenium tetrabromide.jpg
Selenium-tetrabromide-tetramer-from-alpha-xtal-3D-bs-17.png
Names
IUPAC name
Tetrabromo-λ4-selane
Other names
Selenium tetrabromide, selenium(IV) bromide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.256 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 232-181-9
PubChem CID
UNII
  • InChI=1S/Br4Se/c1-5(2,3)4
    Key: VTQZBGAODFEJOW-UHFFFAOYSA-N
  • InChI=1/Br4Se/c1-5(2,3)4
    Key: VTQZBGAODFEJOW-UHFFFAOYAY
  • Br[Se](Br)(Br)Br
Properties
SeBr4
Molar mass 398.576
Density 4.029 g/cm3
Melting point 75 °C (167 °F; 348 K) (dissolves)
Boiling point 115 °C (239 °F; 388 K) (sublimes)
Structure [1]
trigonal (α)
monoclinic (β)
P31c, No. 159 (α)
C2/c, No.15 (β)
16
Hazards
GHS labelling:
GHS-pictogram-acid.svg GHS-pictogram-skull.svg GHS-pictogram-silhouette.svg GHS-pictogram-pollu.svg
Danger
H301, H311, H314, H331, H351, H373, H410
P201, P202, P260, P261, P264, P270, P271, P273, P280, P281, P301+P310, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P308+P313, P310, P311, P312, P314, P321, P322, P330, P361, P363, P391, P403+P233, P405, P501
Related compounds
Other anions
Selenium tetrafluoride
Selenium tetrachloride
Other cations
Tellurium tetrabromide
Related compounds
Selenium dibromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Selenium tetrabromide is an inorganic compound with a chemical formula SeBr4.

Contents

Preparation

Selenium tetrabromide could be produced by mixing elemental bromine and selenium: [2] [3]

Properties

Selenium tetrabromide exists in two polymorphs, the trigonal, black α-SeBr4 and the monoclinic, orange-reddish β-SeBr4, both of which feature tetrameric cubane-like Se4Br16 units but differ in how they are arranged. [1] It dissolves in carbon disulfide, chloroform and ethyl bromide, but decomposes in water, [4] so that it produces selenous acid in wet air.

The compound is only stable under a bromine-saturated atmosphere; gas phase measurements of the gas density indicate that the compound decomposes into selenium monobromide and bromine. [3]

Related Research Articles

<span class="mw-page-title-main">Bromine</span> Chemical element, symbol Br and atomic number 35

Bromine is a chemical element; it has symbol Br and atomic number 35. It is a volatile red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour. Its properties are intermediate between those of chlorine and iodine. Isolated independently by two chemists, Carl Jacob Löwig and Antoine Jérôme Balard, its name was derived from the Ancient Greek βρῶμος (bromos) meaning "stench", referring to its sharp and pungent smell.

<span class="mw-page-title-main">Carbon tetrabromide</span> Chemical compound

Carbon tetrabromide, CBr4, also known as tetrabromomethane, is a bromide of carbon. Both names are acceptable under IUPAC nomenclature.

<span class="mw-page-title-main">Aluminium bromide</span> Chemical compound

Aluminium bromide is any chemical compound with the empirical formula AlBrx. Aluminium tribromide is the most common form of aluminium bromide. It is a colorless, sublimable hygroscopic solid; hence old samples tend to be hydrated, mostly as aluminium tribromide hexahydrate (AlBr3·6H2O).

Zirconium(IV) bromide is the inorganic compound with the formula ZrBr4. This colourless solid is the principal precursor to other Zr–Br compounds.

<span class="mw-page-title-main">Titanium tetrabromide</span> Chemical compound

Titanium tetrabromide is the chemical compound with the formula TiBr4. It is the most volatile transition metal bromide. The properties of TiBr4 are an average of TiCl4 and TiI4. Some key properties of these four-coordinated Ti(IV) species are their high Lewis acidity and their high solubility in nonpolar organic solvents. TiBr4 is diamagnetic, reflecting the d0 configuration of the metal centre.

<span class="mw-page-title-main">Ditellurium bromide</span> Chemical compound

Ditellurium bromide is the inorganic compound with the formula Te2Br. It is one of the few stable lower bromides of tellurium. Unlike sulfur and selenium, tellurium forms families of polymeric subhalides where the halide/chalcogen ratio is less than 2.

<span class="mw-page-title-main">Selenium oxybromide</span> Chemical compound

Selenium oxybromide (SeOBr2) is a selenium oxohalide chemical compound.

<span class="mw-page-title-main">Selenium compounds</span> Chemical compounds containing selenium

Selenium compounds are compounds containing the element selenium (Se). Among these compounds, selenium has various oxidation states, the most common ones being −2, +4, and +6. Selenium compounds exist in nature in the form of various minerals, such as clausthalite, guanajuatite, tiemannite, crookesite etc., and can also coexist with sulfide minerals such as pyrite and chalcopyrite. For many mammals, selenium compounds are essential. For example, selenomethionine and selenocysteine are selenium-containing amino acids present in the human body. Selenomethionine participates in the synthesis of selenoproteins. The reduction potential and pKa (5.47) of selenocysteine are lower than those of cysteine, making some proteins have antioxidant activity. Selenium compounds have important applications in semiconductors, glass and ceramic industries, medicine, metallurgy and other fields.

Bromine compounds are compounds containing the element bromine (Br). These compounds usually form the -1, +1, +3 and +5 oxidation states. Bromine is intermediate in reactivity between chlorine and iodine, and is one of the most reactive elements. Bond energies to bromine tend to be lower than those to chlorine but higher than those to iodine, and bromine is a weaker oxidising agent than chlorine but a stronger one than iodine. This can be seen from the standard electrode potentials of the X2/X couples (F, +2.866 V; Cl, +1.395 V; Br, +1.087 V; I, +0.615 V; At, approximately +0.3 V). Bromination often leads to higher oxidation states than iodination but lower or equal oxidation states to chlorination. Bromine tends to react with compounds including M–M, M–H, or M–C bonds to form M–Br bonds.

<span class="mw-page-title-main">Strontium bromide</span> Chemical compound

Strontium bromide is a chemical compound with a formula SrBr2. At room temperature it is a white, odourless, crystalline powder. Strontium bromide imparts a bright red colour in a flame test, showing the presence of strontium ions. It is used in flares and also has some pharmaceutical uses.

<span class="mw-page-title-main">Silicon tetrabromide</span> Chemical compound

Silicon tetrabromide, also known as tetrabromosilane, is the inorganic compound with the formula SiBr4. This colorless liquid has a suffocating odor due to its tendency to hydrolyze with release of hydrogen bromide. The general properties of silicon tetrabromide closely resemble those of the more commonly used silicon tetrachloride.

Titanium(III) bromide is the inorganic compound with the formula TiBr3. It is a blue black paramagnetic solid with a reddish reflection. It has few applications, although it is a catalyst for the polymerization of alkenes.

<span class="mw-page-title-main">Selenium dibromide</span> Chemical compound

Selenium dibromide is a compound made of one selenium and two bromine atoms. It is unstable. No solid form of the compound has been discovered but it is a component of the equilibria in the vapour above selenium tetrabromide and in nonaqueous solutions. In acetonitrile solution, selenium reacts with SeBr4 to form an equilibrium mixture containing SeBr2, Se2Br2 and Br2. This covalent compound has a bent molecular geometry in the gas phase.

<span class="mw-page-title-main">Germanium tetrabromide</span> Chemical compound

Germanium tetrabromide is the inorganic compound with the formula GeBr4. It is a colorless solid that melts near room temperature. It can be formed by treating solid germanium with bromine, or by treating a germanium-copper mixture with bromine:

Osmium tetrabromide is the inorganic compound with the formula OsBr4. A black solid, this compound can be produced by heating osmium tetrachloride and bromine under pressure.

<span class="mw-page-title-main">Protactinium(IV) bromide</span> Chemical compound

Protactinium(IV) bromide is an inorganic compound. It is an actinide halide, composed of protactinium and bromine. It is radioactive, and has the chemical formula of PaBr4. It may be due to the brown color of bromine that causes the appearance of protactinium(IV) bromide to be brown crystals. Its crystal structure is tetragonal. Protactinium(IV) bromide is sublimed in a vacuum at 400 °C. The protactinium(IV) halide closest in structure to protactinium(IV) bromide is protactinium(IV) chloride.

Protactinium compounds are compounds containing the element protactinium. These compounds usually have protactinium in the +5 oxidation state, although these compounds can also exist in the +2, +3 and +4 oxidation states.

Iridium tetrabromide is a binary inorganic chemical compound of iridium and bromine with the chemical formula IrBr4. This is a salt of iridium metal and hydrobromic acid.

<span class="mw-page-title-main">Polonium tetrabromide</span> Chemical compound

Polonium tetrabromide, is a bromide of polonium, with the chemical formula PoBr4.

Thorium(IV) bromide is an inorganic compound, with the chemical formula of ThBr4.

References

  1. 1 2 Born, Ref. P.; Kniep, R.; Mootz, D. (1979). "Phasenbeziehungen im System Se-Br und die Kristallstrukturen des dimorphen SeBr4". Z. Anorg. Allg. Chem. 451 (1): 12–24. doi:10.1002/zaac.19794510103.
  2. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. pp. 772–774. ISBN   978-0-08-037941-8.
  3. 1 2 Tideswell, N. W.; McCullough, J. D. (1956). "Selenium Bromides. I. A Spectrophotometric Study of the Dissociation of Selenium Tetrabromide and Selenium Dibromide in Carbon Tetrachloride Solution1,2". Journal of the American Chemical Society. 78 (13): 3026–3029. doi:10.1021/ja01594a025.
  4. Perry, Dale L. (2011). Handbook of Inorganic Compounds. CRC Press. p. 360. ISBN   978-1-4398-1461-1.