Perbromyl fluoride

Perbromyl fluoride

Names
Other names Bromine fluoride trioxide
Identifiers
CAS Number	25251-03-0  Y
3D model (JSmol)	Interactive image
PubChem CID	44233513
InChI InChI=1S/BrFO3/c2-1(3,4)5 Key: FHRGMUIQMATFDZ-UHFFFAOYSA-N
SMILES F[Br](=O)(=O)=O
Properties
Chemical formula	BrO3F
Molar mass	146.899 g·mol−1
Appearance	colorless gas
Melting point	−110 °C (−166 °F; 163 K) [1] (approx. temperature of solidification)
Solubility in water	reacts with water
Related compounds
Related compounds	Periodyl fluoride Perchloryl fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Perbromyl fluoride is an inorganic compound of bromine, fluorine, and oxygen with the chemical formula Br O ₃ F . ^[1]

Synthesis

Synthesis of perbromyl fluoride is by the effect of antimony pentafluoride on a solution of potassium perbromate in hydrofluoric acid: ^[2]

KBrO₄ + 2 SbF₅ + 3 HF → BrO₃F + K[SbF₆] + H[SbF₆]·H₂O

Physical properties

Perbromyl fluoride is a colorless gas at room temperature that is stable in the absence of moisture. ^[3]

Chemical properties

Perbromyl fluoride reacts with water to produce perbromic acid and hydrogen fluoride:

BrO₃F + H₂O → HBrO₄ + HF

References

1. Appleman, Evan H.; Studier, Martin H. (July 1969). "Perbromyl fluoride". Journal of the American Chemical Society . 91 (16): 4561–4562. Bibcode:1969JAChS..91.4561A. doi:10.1021/ja01044a049. ISSN   0002-7863.
2. Steudel, Ralf (20 April 2011). Chemistry of the Non-Metals: With an Introduction to Atomic Structure and Chemical Bonding. Walter de Gruyter. p. 265. ISBN   978-3-11-083082-8 . Retrieved 5 June 2023.
3. U. S. Atomic Energy Commission Division of Plans and Atomic Energy Research: Life and Physical Sciences, Reactor Development, Waste Management. U.S. Government Printing Office. 1970. p. 10. Retrieved 5 June 2023.